Geochemical Characterization of Source Rocks in Block 1A Muglad Basin, Wizeen Oil Field, South Sudan

Abstract

This study applies Rock-Eval 6 pyrolysis to cuttings from wells WZNW-1 and WZW-1 to assess organic richness, kerogen type, and thermal maturity in Baraka and Abu Gabra formations. Baraka contains mainly type III organic matter, while Abu Gabra contains type II to type II/III organic matter, and proposes Baraka as an additional source rock interval. Several reported Rock-Eval values and their interpretations require reconciliations before the source rock conclusions can be supported.

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Mile, T. (2026) Geochemical Characterization of Source Rocks in Block 1A Muglad Basin, Wizeen Oil Field, South Sudan. Open Journal of Yangtze Oil and Gas, 11, 151-169. doi: 10.4236/ojogas.2026.114005.

1. Introduction

Block 1A is located within the Muglad Basin. Muglad Basin in Central Africa is located in the middle of the African Plate and is a Mesozoic and Cenozoic rift basin formed by strike-slip extension of the Central African shear zone. Muglad Basin is filled with a Cretaceous—Cenozoic non-marine sedimentary succession which is more than 13,000 m thick in the deepest parts of the Kaiking Trough. Three major episodes of extensional tectonics are recognized: Early Cretaceous (140 - 95 Ma), Late Cretaceous (95 - 65 Ma), and Paleogene (65 - 30 Ma) [1]. Each episode started as a rifting phase and ended with a sag phase (Figure 1).

The Stratigraphic succession of each rift-related depositional cycle begins near the rift margins with basal sand, followed upwards by a shale-dominated interval, reflecting the deepening of the basin. Shale-dominated sediments accumulated during periods of active rifting when subsidence was maximum. Sand-dominated sediments accumulated when the rates of subsidence were relatively low, especially during the thermal sag phases. Syn-rift deposits of the first cycle (Abu Gabra Formation) are dominated by extensive lacustrine shales [2]. The lake water depth was apparently sufficient for the accumulation and preservation of organic-rich shales, that is the main source rocks for the oils found in this basin.

Figure 1. Generalized stratigraphy of Muglad Basin [3].

Later in this period, the structural framework of the Cretaceous formations was basically formed and entered the sag sedimentation period, in which the Bentiu Formation was dominated by a large package of blocky sandstone. The syn-rift deposits of the second episode (Aradeiba, Zarqa, and Ghazal Formations) and the third episode (Nayil and Tendi Formations) consist mainly of lacustrine to fluvial overbank shales in lower parts, while upper parts are dominated by fluvial sands [4]. In early stages, Aradeiba-Ghazal had relatively intensive faulting activities with high-quality mudstone. At sagging sedimentation stages, the Amal Formation was characterized by massive blocky sandstones. The activities of the Central-Africa Shearing Belt stopped in the Paleogene, but the Muglad basin, due to the effect of the Red Sea separation and the East African Rift Valley, entered a new rift development period, as shown in the Generalized Stratigraphy of Muglad Basin in Figure 1.

Wizeen oil field is one of the newly discovered fields which is located in NE of Toma South oil field in Muglad Basin. Currently, the wells that have been drilled in Wizeen oil field are seven. These include WZNW-1, WZW-1, WZN-3, WZN-2, WZN-1, WZ-2 and WZ-1. The WZNW-1 was drilled in 2024 as a study well and correlated with WZW-1. Because there is potential for hydrocarbon reserves in the northwest of Wizeen. However, there is little understanding of source rock within the Wizeen oil field. Abu Gabra is the only source rock known in the Muglad Basin with good and critical petroleum systems, as in Figure 2 and Figure 3. During the drilling of these wells, there are some formations which indicate good potential for source rocks. Therefore, there is a need to evaluate the source rocks within the Muglad Basin, whether the hydrocarbons originate only from Abu Gabra or whether there is another source rock within the Wizeen oil field.

This study aims to characterize the source rocks of the Barak and Abu Gabra interval from wells WZNW-1 and WZW-1. It will: 1) evaluate the oil potential; 2) characterize the organic matter; 3) identify zones conducive to hydrocarbon generation, all coupled with their level of maturity, based on geochemical analysis results obtained from Rock-Eval 6 analysis.

Figure 2. Generalized petroleum system [3].

Figure 3. Petroleum system elements and processes of the Muglad Basin with significant accumulation of oil and gas [2].

2. Materials and Methods

2.1. Materials

A total of 480 cuttings samples from two oil wells (WZNW-1, WZW-1) were used in this study. 120 samples from WZNW-1 were collected from shale lithology at a depth of (2000 - 3000 m), interval of Baraka formation. Also, 120 samples of shale lithology at a depth of (4000 - 5500m), interval of Abu Gabra formation, were collected for this study. In WZW-1, 120 samples of shale lithology were collected at a depth of (1000 - 1600 m), in the Baraka formation interval. In the Abu Gabra interval, 120 samples were also collected between the depths of (2000 - 5000 m). These samples were put into clean boxes and transported to the laboratory for analysis using Rock-Eval 6 Pyrolysis. These samples were collected from these two wells in the sedimentary basin of the Muglad Basin (South Sudan) in the Wizeen oil field (Figures 4-6). It is important to note that the stratigraphic stages were delineated through biostratigraphic studies. The samples were analyzed using Rock-Eval 6 at the laboratory of the Egyptian Petroleum Research Institute Center.

2.2. Methods

2.2.1. Sample Processing

The method builds upon the work of [5], which determined the organic matter accumulation rate and kerogen type in the rock using parameters such as TOC, HI, S2, and Tmax.

Samples consist of 20 g of already ground rock cuttings screened from shale lithology and placed in a beaker. Liquid soap and water are added, and the mixture is allowed to settle for half an hour. The samples were then processed with water through a column composed of two sieves (800 and 100 µm), followed by drying in an oven at a temperature between 30˚C and 50˚C to remove the contaminants from the samples. The dried samples were crushed and homogenized in an agate mortar. Subsequently, 65 to 100 mg of each sample is weighed using a precision balance. These samples are then placed in crucibles and loaded into the carousel of the Rock-Eval 6 apparatus for analysis.

Figure 4. Geological map of the study area in Muglad Basin, South Sudan [3].

Figure 5. Time structure map of study wells [3].

2.2.2. Analysis Principle of Sample or Programmed Pyrolysis Method

Rock-Eval pyrolysis is a physicochemical method that involves heating a quantity of 65 to 100 mg of ground rock at a progressive temperature increase of 25˚C/min up to 650˚C under an inert atmosphere (helium). This process determines the quantity and quality of hydrocarbon and oxygenated compounds (CO2) released during pyrolysis (Figure 7). The essential data is acquired through a single analysis lasting one hour per sample. The effluents emitted during the temperature

Figure 6. RMS Amp attribute of the study wells with other Wizeen wells [3].

Figure 7. Photo of the Rock-Eval 6 apparatus.

ramp-up are collected and quantified. The parameters measured or calculated in this study are:

  • S2: This represents the oil potential or hydrocarbons derived from pyrolysis. It corresponds to the quantity of hydrocarbon compounds generated by the cracking of kerogen when the rock is heated up to 600˚C. It is expressed in mg HC/g of rock (Table 1).

  • TOC (Total Organic Carbon): This gives the weight proportion of total organic matter in one gram of sample (% weight). It helps determine the petroleum potential of source rocks. While essential for classifying source rocks, TOC is less relevant than S2 in estimating oil potential because it includes inert carbons incapable of generating hydrocarbons (Table 1).

Table 1. Petroleum potential of source rocks [6].

Organic Matter (OM)

Rock Eval Parameters

TOC (% Poids)

S2 (mg HC/g Roche)

Petroleum Potential

0 < TOC < 0.5

0 < S2 < 2.5

Poor

0.5 < TOC < 1

2.5 < S2 < 5

Fair

1 < TOC < 2

5 < S2 < 10

Good

2 < TOC < 4

10 < S2 < 20

Very good

TOC > 4

S2 > 20

Excellent

  • Tmax (˚C): This is the pyrolysis temperature and a key parameter of Rock Eval. It quantifies the thermal maturity of a rock and represents the temperature of maximum hydrocarbon generation. Tmax values are less reliable when S2 < 0.2 mg HC/g rock [7]. Tmax allows a coarse evaluation of the degree of organic matter maturation (Table 2). This maturity level depends on other factors, including the type of organic matter.

Table 2. Thermal maturity [8].

Rock-Eval Parameters

Tmax (˚C)

Thermal maturity

Tmax < 435

Immature

435 < Tmax < 445

Early maturity

445 < Tmax < 450

Peak Maturity

450 < Tmax < 470

Advanced maturity

Tmax > 470

Over mature

  • HI (Hydrogen Index): This is the proportion of hydrocarbon effluents emitted during pyrolysis relative to TOC. Its formula is: HI = (100 × [S2/TOC]), expressed in mg HC/g TOC. It is important to note that the hydrogen content of organic matter is one of the most significant factors controlling the generation of oil and gas. [9] demonstrated that the hydrogen in kerogen is proportional to the hydrocarbons S2 released during pyrolysis, and that the hydrogen index correlates with the H/C ratio of kerogen. Therefore, marine organisms and algae have higher HI values compared to terrestrial organisms. HI is used to assess the type and origin of organic matter in sedimentary rocks (Table 3).

Table 3. Type of kerogen and expelled products.

HI (mg HC/g TOC)

Type of kerogen

Hydrocarbon formed

<50

IV

-

50 - 200

III

Gas

200 - 300

III/II

Oil and Gas

300 - 600

II

Oil

>600

I

Oil

The results obtained were interpreted using petrographic software.

2.2.3. Quality Control

1) Calibration and Reference Materials

Standard Reference Materials: calibration and routine quality control of the Rock-Eval 6 device are classically performed using the certified standard reference material IFPEN-160000. This standard is run to validate hydrocarbon (HC), carbon monoxide (CO), and carbon dioxide (CO2) infrared and FID responses.

TOC and Mineral Carbon: Certified reference standards to ensure correct splitting of total organic carbon (TOC) and mineral carbon (Min C) across temperature ramps.

2) Blank Procedures

Baseline Checks: Empty crucible (blank) runs are scheduled between sample sequences to monitor system cleanliness, memory effects, and baseline stability in both the pyrolysis and oxidation oven.

Contamination Tracking: Blanks verify that no residual hydrocarbons or carbon gases bleed over from high-concentration source rock or organic-rich shale samples.

Then the results are interpreted using a petrographic software model 10.1029/2005GC000932.

3. Results and Discussion

The purpose of geochemical (Rock-Eval Pyrolysis) analysis is to identify and measure important parameters and constraints relating to source rock quality, quantity, and kerogen type. These parameters also help to resolve the composition and origin of the organic matter to evaluate the source rock effectively. What follows is a discussion of the results obtained from detailed geochemical analysis of the targeted source interval.

3.1. Quantity of Organic Matter (TOC wt%)

3.1.1. Baraka Formation

From Table 4, pyrolysis results of WZNW-1, the TOC% ranges between 1.1 and 1.4 weight percent. This means the studied source rock from these samples can be classified as fair to good generative potential.

From WZW-1 in the Baraka formation, the TOC% also ranges between 1.1 and 1.4 weight percent. These studied source rocks can be classified as fair to good generative potential (Table 5). Generally, Baraka source rocks can be classified as fair to good source rocks [6] (Figure 8).

3.1.2. Abu Gabra Formation

The TOC% in WZNW-1 from the Abu Gabra formation ranges between 1.1 and 2.1 weight percent. These studied source rocks can be classified as fair to very good generative potential (Table 6) and Figure 9. In WZW-1, the TOC% ranges between 0.9 and 1.4 weight percent. These source rocks can be classified as fair to good generative potential [6] (Table 7) and Figure 9. Although the TOC% shows fair to very good generative potential in two wells (WZW-1 and WZNW-1), most of S2 falls between 0.5 and 1.7. That implies that it is poor.

Table 4. Summarized pyrolysis results of WZNW-1 for defined source rock interval for Baraka formation.

Baraka Formation

Well

Depth (m)

Lithology

S1 (mg HC/g Sediment)

S2 (mg HC/g Sediment)

TOC (wt%)

HI (mg HC/g TOC)

OI (mg HC/g TOC)

Tmax (˚C)

WZNW-1

2000 - 2200

shale

0.2

0.9

1.1

90

55

419

shale

0.2

0.9

1.1

90

56

419

shale

0.2

0.9

1.1

90

55

417

shale

0.4

0.8

1.2

50

58

418

shale

0.4

0.8

1.3

50

59

420

shale

0.3

1.0

1.3

100

100

429

shale

0.2

1.0

1.2

100

150

439

shale

0.2

1.1

1.3

100

150

439

shale

0.1

1.2

1.3

110

100

439

shale

0.2

1.2

1.4

110

100

440

2200 - 2400

shale

0.1

1.3

1.4

100

100

440

shale

0.1

1.3

1.4

190

130

440

shale

0.3

1.1

1.3

190

130

440

shale

0.2

1.1

1.3

190

130

440

shale

0.1

1.2

1.4

180

140

445

shale

0.2

1.2

1.4

170

140

445

shale

0.3

1.1

1.4

170

140

445

WZNW-1

shale

0.2

1.2

1.3

170

140

444

shale

0.3

1.0

1.3

160

130

444

shale

0.3

1.0

1.3

160

130

443

2400 - 3000

shale

0.3

1.0

1.4

160

130

443

shale

0.3

1.0

1.4

150

130

440

shale

0.3

1.0

1.3

150

140

440

shale

0.2

1.1

1.3

160

140

440

shale

0.4

1.0

1.4

170

140

440

shale

0.3

1.1

1.4

180

130

440

shale

0.2

1.1

1.3

180

130

440

shale

0.3

1.1

1.4

170

130

441

shale

0.2

1.2

1.4

180

130

441

shale

0.2

1.2

1.4

180

130

440

Figure 8. Plot TOC% versus S2 for the Baraka formation samples.

Table 5. Summarized pyrolysis results of WZW-1 for defined source rock interval for Baraka formation.

Baraka formation

Well

Depth (m)

Lithology

S1 (mg HC/g sediment)

S2 (mg HC/g sediment)

TOC

(wt%)

HI (mg HC/g TOC)

OI (mg HC/g TOC)

Tmax

(˚C)

WZW-1

1000 - 1200

shale

0.6

0.5

1.1

92

49

420

shale

0.5

0.6

1.1

92

49

420

shale

0.1

1.1

1.2

99

50

429

shale

0.1

1.1

1.2

99

50

432

shale

0.4

1.0

1.4

100

50

439

shale

0.2

1.2

1.4

99

60

439

shale

0.1

1.3

1.4

100

60

438

shale

0.1

1.2

1.3

100

50

438

shale

0.2

1.2

1.4

190

60

440

shale

0.2

1.1

1.3

190

60

440

1200 - 1400

shale

0.2

1.1

1.3

190

70

442

shale

0.2

1.1

1.3

190

60

442

shale

0.2

1.0

1.2

200

60

440

shale

0.3

1.1

1.4

200

70

440

shale

0.1

1.1

1.2

200

70

440

shale

0.2

1.1

1.4

200

60

442

shale

0.2

1.2

1.4

200

60

442

shale

0.2

1.2

1.4

190

60

441

shale

0.2

1.2

1.2

190

70

441

shale

0.2

1.0

1.3

200

60

441

1400 - 1600

shale

0.1

1.1

1.3

200

60

441

shale

0.2

1.2

1.2

200

60

440

shale

0.3

1.0

1.3

200

60

440

shale

0.3

1.0

1.3

199

60

440

shale

0.2

1.1

1.3

199

60

441

shale

0.2

1.1

1.3

190

60

440

shale

0.2

1.0

1.2

200

60

440

shale

0.3

1.0

1.3

200

70

440

shale

0.3

1.1

1.4

200

60

441

shale

0.3

1.1

1.4

200

60

442

Table 6. Summarized pyrolysis results of WZNW-1 for defined source rock interval for Abu Gabra formation.

Abu Gabra formation

Well

Depth (m)

Lithology

S1 (mg HC/g sediment)

S2 (mg HC/g sediment)

TOC

(wt%)

HI (mg HC/g TOC)

OI (mg HC/g TOC)

Tmax

(˚C)

WZNW-1

4000 - 4500

shale

0.5

0.6

1.1

54.5

55

410

shale

0.6

0.5

1.1

50

56

440

shale

0.4

0.6

1.0

200

56

440

shale

0.5

0.7

1.2

200

56

440

shale

0.4

0.8

1.2

200

56

440

shale

0.4

0.8

1.2

220

55

442

shale

0.5

0.7

1.3

220

58

442

shale

0.4

1.0

1.4

210

58

442

shale

0.5

1.0

1.5

210

58

445

shale

0.5

1.0

1.5

250

100

439

4500 - 5000

shale

0.4

1.1

1.5

260

100

439

shale

0.3

1.1

1.4

260

90

443

shale

0.3

1.1

1.4

250

90

443

shale

0.5

1.1

1.6

250

80

442

shale

0.5

1.2

1.7

250

100

443

shale

0.4

1.2

1.6

260

110

443

shale

0.4

1.2

1.6

260

110

442

shale

0.4

1.2

1.6

260

120

444

shale

0.7

1.1

1.8

270

120

444

shale

0.8

1.1

1.9

280

140

444

5000 - 5500

shale

0.4

1.5

1.9

280

146

443

shale

0.6

1.5

2.1

270

148

443

shale

0.5

1.5

2.0

270

149

442

shale

0.5

1.5

2.0

280

150

442

shale

0.4

1.6

2.0

280

150

444

shale

0.3

1.6

1.9

270

149

443

shale

0.2

1.7

1.9

270

149

443

shale

0.4

1.7

2.1

270

148

444

shale

0.3

1.7

2.0

280

146

444

shale

0.4

1.6

2.0

280

148

444

Table 7. Summarized pyrolysis results of WZW-1 for defined source rock interval for Abu Gabra formation.

Abu Gabra formation

Well

Depth (m)

Lithology

S1

(mgHC/g sediment)

S2

(mgHC/g sediment)

TOC

(wt%)

HI

(mgHC/g TOC)

OI

(mgHC/g TOC)

Tmax

(˚C)

WZW-1

2000 - 3000

shale

0.1

0.9

1.0

90

50

420

shale

0.2

0.8

1.0

300

50

440

shale

0.1

0.9

1.0

300

49

440

shale

0.1

1.0

1.1

290

49

440

shale

0.2

1.0

1.2

290

48

440

shale

0.1

1.1

1.2

290

48

441

shale

0.2

1.0

1.2

280

47

441

shale

0.1

1.1

1.2

280

50

440

shale

0.2

1.0

1.2

280

50

429

shale

0.2

1.0

1.3

270

50

429

3000 - 4000

shale

0.2

1.0

1.3

270

50

431

shale

0.3

1.1

1.3

270

50

431

shale

0.3

1.0

1.4

280

49

440

shale

0.2

1.1

1.3

290

49

440

shale

0.4

1.0

1.4

280

52

440

shale

0.3

1.1

1.4

300

52

442

shale

0.3

1.1

1.4

300

52

442

shale

0.1

1.2

1.4

280

51

441

shale

0.1

1.2

1.3

300

51

442

shale

0.2

1.2

1.3

290

51

441

4000 - 5000

shale

0.2

1.2

1.4

290

52

442

shale

0.3

1.0

1.4

290

50

440

shale

0.3

1.0

1.3

390

50

440

shale

0.3

1.0

1.3

300

49

440

shale

0.2

1.1

1.3

300

49

441

shale

0.3

1.0

1.3

300

50

441

shale

0.3

1.0

1.3

300

50

440

shale

0.3

1.1

1.4

290

49

440

shale

0.3

1.1

1.4

290

49

440

shale

0.3

1.1

1.4

290

49

440

Figure 9. Plot TOC% versus S2 for the Abu Gabra formation samples.

3.2. Genetic Type and Classification of Organic Matter

The determination of the genetic type of organic matter is essential in predicting the oil and gas potential and also in typifying the kerogen. To differentiate between genetic types of organic matter, hydrogen index (HI) can be used [8] [10] [11]. Accordingly, a HI between 50 - 200 mg HC/g TOC indicates a gas-generating potential (kerogen type III). When HI ranges between 200 - 300 mg HC/g TOC, then its kerogen type is II - III, which can produce mixed hydrocarbons (gas and oil but mostly gas). On the other hand, HI ranging from 300 - 600 mg HC/g TOC indicates mainly type II kerogen (oil and gas-prone). Furthermore, HI > 600 mg HC/g TOC classifies the kerogen as type I (oil-prone) [8].

The relation between OI and HI can be plotted on a modified van Krevelen diagram (Figure 10 and Figure 11), which is used to determine the origin and type of the kerogen [12]. Also, the plots of TOC% versus S2 (mg HC/g Rock) (Figure 12) as well as the Tmax versus hydrogen index (Figure 13) cross plots help in determining the kerogen type and thermal maturity level. The 2 plots indicate that.

3.2.1. Baraka Formation

From the Baraka formation, HI (Hydrogen Index) from two wells (WZNW-1, WZW-1) ranges between 50 and 200 mg HC/g TOC. This indicates a gas-generating potential. It implies that kerogen type III is present in most of the samples, as in Table 4, Table 5, and Figure 10.

Figure 10. Plot of the studied Baraka formation samples on a modified van Krevelen diagram.

3.2.2. Abu Gabra Formation

In the Abu Gabra formation, HI (Hydrogen Index) from two wells (WZNW-1, WZW-1) ranges between 200 and 300 mg HC/g TOC. This indicates an oil-generating potential. It implies that kerogen type II and type II - III are present in most of the samples. Type II produces oil, and type II - III produces mixed hydrocarbons (oil & gas, mostly gas) (Table 6, Table 7 and Figure 11).

Figure 11. Plot of the studied Abu Gabra samples on a modified van Krevelen diagram.

3.3. Thermal Maturation

Many physical and chemical properties of organic matter are changeable during the thermal evolution of a source rock, during the diagenesis, catagenesis, and metagenesis stages. These changes can be indications for thermal maturity [13]. Assessment of thermal maturity of organic matter in the studied wells was carried out using pyrolysis Tmax values (Figures 12-15 and Table 1, Tables 4-7).

Pyrolysis Tmax is the most widely used method in evaluating thermal maturity of a source rock, which differs significantly according to the kerogen type [7] [13] [14]. The oil generation window lies between Tmax values of 435˚C and 465˚C [6].

3.3.1. Baraka Formation

The Tmax values of the Baraka formation samples from WZW-1, range between 435˚C and 450˚C. This means they are all mature. Then, the Tmax values for the samples from WZNW-1 range between 415˚C and 450˚C. The Tmax values for other samples from WZNW-1 range between 415˚C and 430˚C. This means they are immature. Other samples from WZNW-1 range between 430˚C and 450˚C. They are mature and within the oil window Figure 12 and Figure 14.

Figure 12. Plot of the study Baraka formation samples on a Tmax versus hydrogen index diagram.

Figure 13. Plot of the study Abu Gabra formation samples on a Tmax versus hydrogen index diagram.

Figure 14. Plot of Baraka formation Tmax versus Depth for the studied wells (solid lines are based on [6].

3.3.2. Abu Gabra Formation

For Abu-Gabra formation, the Tmax values for most of the samples range between 430˚C and 450˚C for both WZW-1 and WZNW-1. This implies that most of the samples are mature, and they are within the oil window (Figure 13 and Figure 15).

4. Conclusions

The following can be concluded.

1) The quantity of the organic carbon of the studied Bara formation rock is classified as fair to good Generative potential. They correspond mainly to kerogen type III. Then, the Abu Gabra formation is classified as fair to very good generative potential. They correspond to maily kerogen type II and type II - III.

2) For evaluating the thermal maturity, pyrolytic Tmax was used. It shows that most of WZW-1 and WZNW-1 samples are located in the immature and mature stages in the Baraka formation, whereas Abu Gabra samples are also located between the immature and mature stages.

3) The Baraka formation seems to be one of the sour rocks in the Muglad Basin, in addition to the known Abu Gabra source rock.

Figure 15. Plot of Abu Gabra formation Tmax versus Depth for the studied wells (solid lines are based on [6].

5. Recommendations

Although this study presents a relatively comprehensive organic geochemical analysis, the following studies are suggested here.

  • Organic petrography should be undertaken to directly determine vitrinite reflectance values. These should then be compared with pyrolysis and biomarker-derived vitrinite reflectance values presented here for accurate thermal maturity estimation.

  • Organic stable isotope analyses can be used to continue to refine the origins and environments of deposition of the various source-rock lithofacies.

  • If oil samples are recovered from the formation, “oil to source correlation” could be informative in some more wells in the Wizeen oil field.

Conflicts of Interest

The author declares no conflicts of interest regarding the publication of this paper. It is for educational purposes.

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