Modelling of In-Situ Soil Water Characteristics Based on Multiple-Years Monitoring

Abstract

Soil water characteristics are one of the essential factors for understanding storage and flow of water in soils, recognized as a series of relations between soil water potential ψ [J?kg?1] and soil water content θ [m3?m?3]. Because a series of ψ-θ relations shows hysteretic behaviors, it is often difficult to correctly express it by using a single-valued function θ (ψ). Aiming at describing in-situ soil water hysteresis, this study formulated a model of soil water hysteresis based on ψ-θ relations observed in a field. The model assumption derived from the observed features was that any scanning curve is a similitude of a corresponding main curve on the ψ-θ plane. The model can work along randomly-ordered drying-wetting cycles by citing only a pair of the main curves. The two main curves should share the driest and wettest extremities, while there is almost no restriction on the types of mathematical functions to express any of the main curves. The model algorithm allows for calculating an unknown water content θ1 [m3?m?3] for a given water potential ψ1 [J?kg?1] by citing a latest known moisture condition (ψ0, θ0). The model reproduced well the general trend of the measured ψ-θ relations throughout the study period, except for the cases in which the chances of reversals in drying-wetting directions were wrongly input into the model in the series of measurements of ψ [J?kg?1]. It was also difficult for the model to reproduce a long continual wetting process found in the domain of ψ ≥ ?1 [J?kg?1], implying the possible improvement of the model performance by modifying the model so that the model can deal with multi-modal pore systems like volcanic ash soils or other types of structured soils rich in soil aggregates.

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Iiyama, I. (2026) Modelling of In-Situ Soil Water Characteristics Based on Multiple-Years Monitoring. Journal of Geoscience and Environment Protection, 14, 98-108. doi: 10.4236/gep.2026.146006.

1. Introduction

Characteristics of how a soil retains water are represented by a relation between soil water content θ [m3∙m−3] and soil water potential ψ [J∙kg−1]. And a curve drawn by a series of ψ-θ plots obtained through drying or wetting the soil is called a soil water retention curve (SWRC). A SWRC can be approximated as a mathematical function θ(ψ) and is used to diagnose soil moisture conditions or to analyze water flow in soils. However, a field-observed ψ-θ relation is not necessarily expressed by a single-valued function of θ(ψ) but may be described as a multiple-valued function, depending on the direction of change in ψ [J∙kg−1]. This is called soil water hysteresis.

In soil water hysteresis, a value of θ [m3∙m−3] in a wetting process of a soil becomes larger than that in a drying process for a given ψ [J∙kg−1] so that the two processes draw two different paths on a ψ-θ plane. The path of ψ-θ relation that is drawn when a soil with its possible maximum water content θmax [m3∙m−3] is incrementally drained toward its possible driest condition with the water content θmin [m3∙m−3] is called the main drying SWRC θmd(ψ), and the path for its reverse process is called the main wetting SWRC θmw(ψ). Since a soil in a field is generally exposed to intermediate moisture conditions between the two extremities through drying-wetting cycles, paths of ψ-θ relations observed in the field should be drawn between the two main curves on the ψ-θ plane and are called scanning drying SWRCs θscd(ψ) or scanning wetting SWRCs θscw(ψ).

Possible causes of soil water hysteresis have been listed like the “bottle-neck effect”, the “contact-angle effect”, the entrapment of air in a wetting soil, and any process through which the pore geometry of a soil may vary as time passes with cycles of wetting and drying (Kutilek & Nielsen, 1994; Hillel, 1998). And although these phenomenological interpretations are quite rational, they are also too microscopic or too detailed to be practically modelled by mathematical expressions. As a result, more macroscopic approaches have been proposed and tested for modelling soil water hysteresis.

The independent domain theory (Poulovassilis, 1962; Philip, 1964; Mualem, 1973; Mualem, 1974) and the dependent domain theory (Mualem & Dagan, 1975; Poulovassilis & El-Ghamry, 1978) are pioneering works about modelling soil water hysteresis. These theories have evolved mechanistically and have been confirmed to reproduce and predict well hysteretic behaviors of ψ-θ relations. However, it is often cumbersome to effectively incorporate them into the algorithm to describe the trajectory of ψ-θ plots for many repetitions of drying-wetting cycles. Thus, instead, the empirical model proposed by Scott et al. (1983) has been widely adopted. The conciseness of this model owes mainly to the feature that it can draw a series of θscd(ψ) and θscw(ψ) by citing only a pair of θmd(ψ) and θmw(ψ) that are expressed with the same type of mathematical function. Application of the empirical model can certainly improve the accuracy of numerically predicting water flow in soils (Kool & Parker, 1987) with such a positive feature that the model can be easily calibrated with a limited number of parameters (Parker & Lenhard, 1987; Lenhard et al., 1991).

However, there have been a relatively small number of studies that dealt with features of in-situ ψ-θ relations when modelling and simulating hysteretic behaviors in SWRC, presumably because there had been relatively few ψ-θ relations obtained from long-term monitoring in fields in the era of model development about soil water hysteresis. On the other hand, recent studies tend to observe in-situ ψ-θ relations for longer periods, increasingly clarifying the features of hysteretic behaviors of in-situ ψ-θ relations (Bordoni et al., 2017; Zhang et al., 2022; Iiyama, 2024). Therefore, it seems worth developing a model of soil water hysteresis by referring to features of in-situ ψ-θ relations.

This study aimed at modelling soil water hysteresis based on features of field-observed ψ-θ relations. The model was developed so that it can be available if the two main curves θmd(ψ) and θmw(ψ) share the driest and wettest extremities θmin [m3∙m−3] and θmax [m3∙m−3] on the ψ-θ plain while it can work even when θmd(ψ) and θmw(ψ) are expressed in different types of mathematical functions from each other.

2. Materials and Methods

2.1. Model Development

The model of hysteretic behaviors in soil water characteristics was developed based on the features of the in-situ ψ-θ relations found in Iiyama (2024). The observed features were that any scanning curve on the ψ-θ plain was a similitude of a corresponding main curve and the ratio of the similitude was determined mainly by the distance in the direction of θ [m3∙m−3] between the scanning curve and the corresponding main curve. Because any scanning curve should be formulated in any domain of ψ [J∙kg−1] with any region of θ [m3∙m−3], the model development should start from an arbitrary point (ψ0, θ0) on the ψ-θ plain.

Suppose that a ψ-θ relation has been at any point (ψ0, θ0) on a wetting process θscw(ψ):

θ 0 = θ scw ( ψ 0 ) (1)

Then, assume that:

(a1) the wettest extremity for θscw(ψ) is the same as that for θmw(ψ):

lim ψ0 θ scw ( ψ )= lim ψ0 θ mw ( ψ )= θ max , (2)

(a2) the domain and range for θscw(ψ) are ψ ≥ ψ0 [J∙kg−1] and θ0 ≤ θ [m3∙m−3] ≤ θmax, (a3) the specific water capacity of θscw(ψ) can be approximated as:

θ scw ψ = θ max θ 0 θ max θ mw ( ψ 0 ) θ mw ψ . (3)

Certainly, the amount of water that the soil with the moisture condition (ψ0, θ0) can absorb at its maximum should be θmax − θ0 [m3∙m−3], while the amount of water that the soil on the main wetting process with ψ = ψ0 [J∙kg−1] can absorb at its maximum should be θmax − θmw0) [m3∙m−3]. Both the observed features and the phenomenological interpretations support that θscw(ψ) can be formulated as the similitude of θmw(ψ) with the similarity ratio of (θmax − θ0)/(θmax − θmw0)) as shown in Equation (3).

When θscw(ψ) satisfies the assumptions (a1) through (a3), the following equation can hold true:

θ max θ scw ( ψ ) θ max θ mw ( ψ ) = θ max θ 0 θ max θ mw ( ψ 0 ) . (4)

And solving Equation (4) for θscw(ψ) gives

θ scw ( ψ )= θ max θ max θ 0 θ max θ mw ( ψ 0 ) ( θ max θ mw ( ψ ) ) (5)

The scanning drying SWRC θscd(ψ) can be obtained in the same manner as θscw(ψ). The derivation of θscd(ψ) is based on the following assumptions:

(a4) the driest extremity for θscd(ψ) is the same as that for θmd(ψ):

lim ψ θ scd ( ψ )= lim ψ θ md ( ψ )= θ min , (6)

(a5) the domain and range for θscd(ψ) are ψ ≤ ψ0 [J∙kg−1] and θmin ≤ θ [m3∙m−3] ≤ θ0,

(a6) the specific water capacity of θscd(ψ) can be approximated as:

θ scd ψ = θ 0 θ min θ md ( ψ 0 ) θ min θ md ψ (7)

These assumptions and the concept of the similitude between the main and scanning drying curves lead to the following equation:

θ scd ( ψ ) θ min θ md ( ψ ) θ min = θ 0 θ min θ md ( ψ 0 ) θ min . (8)

And rearranging Equation (8) gives:

θ scd ( ψ )= θ min + θ 0 θ min θ md ( ψ 0 ) θ min ( θ md ( ψ ) θ min ) (9)

By using Equations (5) and (9), an unknown water content θ1 [m3∙m−3] for a given water potential ψ1 [J∙kg−1] can be calculated from a latest known moisture condition (ψ0, θ0) through the following algorithm:

(i) a latest known moisture condition (ψ0, θ0) and a new soil water potential ψ1 [J∙kg−1] is given.

(ii) determine dψ1 = ψ1 − ψ0 [J∙kg−1].

(iii) judge if the process from (ψ0, θ0) to (ψ1, θ1) is a wetting one (dψ1 ≥ 0) or a drying one (dψ1 < 0), select either of θscw(ψ) and θscw(ψ), and evaluate θ1 [m3∙m−3], such as:

(iii-a) when dψ1 ≥ 0, θ1 [m3∙m−3] is determined by using θscw(ψ) of Equation (5)

(iii-b) when dψ1 < 0, θ1 [m3∙m−3] is determined by using θscd(ψ) of Equation (9).

(iv) update (ψ0, θ0) with (ψ1, θ1) and return to (i).

This algorithm indicates that θ1 [m3∙m−3] on any of wetting or drying processes can be derived from ψ0 [J∙kg−1], ψ1 [J∙kg−1], and θ0 [m3∙m−3], while it does not require any specific values of (ψ, θ) at which drying-wetting direction changes as reversal points. And if the two main curves share the same pair of the two extreme water contents θmin [m3∙m−3] and θmax [m3∙m−3], the model can be run even when the types of the mathematical functions θmd(ψ) and θmw(ψ) are different from each other (Figure 1).

Figure 1. An example of the series of simulated ψ-θ relations obtained by the algorithm (i) through (iv) (solid line). A sample series of ψ was input into the model so that two reversal points are fictitiously given. The main drying and wetting curves used for drawing the scanning curves are expressed as θmd(ψ) = θmin + (θmax − θmin) exp(0.001ψ) (dashed line) and θmw(ψ) = θmin + (θmax − θmin)(1 – exp(5/ψ)) (dotted line), respectively, with θmin = 0.1 [m3∙m−3] and θmax = 0.7 [m3∙m−3]. The types of mathematical function for the main curves are imaginarily selected as a sample pair of main curves.

2.2. Field Data Sets

The model described in the previous section was tuned by using the time series of in-situ ψ-θ relations. The in-situ data sets were obtained in a meadow field (350 × 80 m; 36˚29'23''N, 139˚59'14''E) located in the Utsunomiya University Farm in Moka city, Tochigi, Japan. The details of the meadow field in this study were described in Iiyama (2024).

Two study sites (sites A and B) were placed at 2 and 8 [m] away from a larch tree row in the study field. And two data-sampling points were set at 0.4 and 1 [m] in depth at each site. The study period was from June 2013 to March 2020. Volumetric water content θ [m3∙m−3] and soil water potential ψ [J∙kg−1] had been coincidently measured at each of the sampling points two to three times a week. For measuring θ [m3∙m−3], a capacitance-type soil moisture sensing system (Diviner 2000, Sentek Pty Ltd., Stepney, South Australia) was used. This system was specifically calibrated for the study field (Iiyama, 2016). For measuring ψ [J∙kg−1], the tensiometer tubes were permanently installed, and air-pressure in the head space of each tensiometer tube was measured by a digital manometer (PG-100-102VP; NIDEC COPAL Electronics Corp., Tokyo, Japan), while the height of water column in the tensiometer tube was measured by a tape measure. Then, the measured air-pressure and water column height were converted into a value of ψ [J∙kg−1].

Among the four sampling points, large and clear hysteretic behaviors on the in-situ ψ-θ relations were observed at 1 [m] in depth in the site A (Iiyama, 2024). Thus, this study used the data sets obtained from this sampling point. The soil in this sampling point had the particle density ρs of 2.808 [Mg∙m−3] and the bulk density ρd of 0.519 [Mg∙m−3], indicating that the saturated volumetric water content θs = 1 − ρds [m3∙m−3] was 0.815 [m3∙m−3]. And the air-dried water content was 0.050 [m3∙m−3].

2.3. Model Parameters

The model in this study can work when a pair of the main drying and wetting SWRCs θmd(ψ) and θmw(ψ) is given. Thus, it was necessary to select a pair of main SWRCs. Any type of mathematical expression can be taken for describing any of the two main curves, while both main curves should share the water contents at the two extremities θmin [m3∙m−3] and θmax [m3∙m−3]. Thus, among a large number of possibilities about a pair of the two main curves, the following forms were selected in this study:

θ md ( ψ )= θ min + θ max θ min 1+ | γ d ψ | μ d (10)

θ mw ( ψ )= θ min + θ max θ min 1+ | γ w ψ | μ w (11)

These expressions include six parameters such as γd [kg∙J−1], γw [kg∙J−1], θmin [m3∙m−3], θmax [m3∙m−3], μd [kg∙J−1], and μw [kg∙J−1].

For identifying the parameter set, it was difficult to select a certain subset of the entire measured data set for the parameter identification process, because it had taken most of the study period from June 2013 to March 2020 for the measured ψ-θ relations to complete drawing the largest hysteresis loop on the ψ-θ plane. Therefore, this study hypothesized that if the model developed in this study adequately extracts the features of the in-situ ψ-θ relations, at least one parameter set should be found with which the model can explain the hysteretic behaviors of any portions of the measured ψ-θ relations.

Based on the hypothesis, all the measured ψ-θ relations in the study period were used for searching the model parameter set. Then, the simulated ψ-θ relations with the obtained parameter set were compared with the measured ψ-θ relations of each year for the discussion about the performance and weak points of the model in this study.

The parameter values were determined by the method of least squares. The solver add-in of Microsoft Excel was used for minimizing the sum of the squared residuals. Each of the residuals was calculated for each date of measurement as the difference between the measured and simulated values of θ [m3∙m−3]. The values of the simulated θ [m3∙m−3] were obtained one after another once a known set of θ [m3∙m−3] and ψ [J∙kg−1] is given as an initial condition, in accord with the recurrence relation described in the model development process.

However, there were 14 times of no measurement period of longer than 1 week among 716 times of measurement in the 82-month study period. Because an occurrence of long no measurement term can disturb the prerequisite of the model that whether an unknown θ1 [m3∙m−3] will be on a wetting or a drying process depends on its corresponding ψ1 [J∙kg−1] and the very latest known pair of ψ0 [J∙kg−1] and θ0 [m3∙m−3]. This means that too long a time period between ψ0 [J∙kg−1] and ψ1 [J∙kg−1] must prevent the model from judging correct timings and number of reversals in drying-wetting direction during the no measurement period. Thus, every time when a no measurement period occurred, the model running was restarted by setting the pair of ψ [J∙kg−1] and θ [m3∙m−3] measured just after the no measurement period.

For searching an adequate set of the model parameters, the following conditions were considered from the phenomenological view point:

(c1) θmax ≤ 0.815 [m3∙m−3], since the saturated volumetric water content of the soil was 0.815 [m3∙m−3].

(c2) θmin ≥ 0.050 [m3∙m−3], since the air-dried water content of the soil was 0.050 [m3∙m−3].

(c3) θmd(ψ) ≥ θmw(ψ) for any ψ [J∙kg−1] in the domain of interest.

(c4) θmd(ψ) - θmw(ψ) ≤ δ for ψ = −0.01 [J∙kg−1], where δ [m3∙m−3] was set as small as possible to make θmd(ψ) and θmw(ψ) asymptotically get close to each other under the almost-saturated condition with ψ = −0.01 [J∙kg−1], equivalent to the soil water suction of about 1 [mmH2O]. At the same time, when too small a value is assigned to δ [m3∙m−3], the main loop becomes too small to enclose all the measured ψ-θ plots.

3. Results and Discussion

Figure 2 shows the main and scanning curves by the model plotted with the measured ψ-θ relations. The parameter values obtained for Equations (10) and (11) were γd = 0.006 [kg∙J−1], γw = 39.15 [kg∙J−1], θmin = 0.353 [m3∙m−3], θmax = 0.636 [m3∙m−3], μd = 1.146 [kg∙J−1], and μw = 0.647 [kg∙J−1], and enabled the resultant two main curves to enclose all the measured ψ-θ plots and to satisfy all the conditions (c1) through (c4).

The trajectory of the modeled ψ-θ relations reproduced the general trend of the measured ψ-θ relations throughout the study period (Figure 2(i)). Particularly, the model successfully explained the measured fact that the ψ-θ plots had consistently resided in the region of θ ≥ 0.50 [m3∙m−3] for the first 4 years (Figures 2(ii)-(v)).

Among the subgraphs for the first 4 years, the model showed a sudden unrealistic upward shift in θ [m3∙m−3] from 0.52 to 0.60 [m3∙m−3] with ψ ≒ −1.3 [J∙kg−1] (Figure 2(v)). However, this shift was apparent because there was a no measurement term of more than 1 week between the dates of these two measurements, suggesting that the soil had become almost saturated and, then, dried again during the no measurement period and, as a result, the model failed to recognize the actual rising and lowering in ψ [J∙kg−1]. Other cases in which no measurement terms deteriorated the model performance were found for the data sets measured in 2013 through 2015. On Figure 2(ii), Figure 2(iii), and Figure 2(iv), the underestimations of θ [m3∙m−3] took place several times in the region of 0.50 [m3∙m−3] ≤ θ ≤ 0.55 [m3∙m−3] with the domain of −100 [J∙kg−1] ≤ ψ ≤ −10 [J∙kg−1]. In this domain, the more times reversals of drying-wetting direction occur, the more θ [m3∙m−3] lowered in the study site. The model reproduced well this observed feature and, at the same time, can erroneously predict hysteretic behaviors if the chances of reversals in drying-wetting direction are wrongly input into the model among a series of ψ [J∙kg−1].

Figure 2. The main curves and scanning curves obtained by fitting the model of soil water hysteresis to the time-series of the measured ψ-θ relations. The dashed and dotted lines in each subgraphs indicate the main drying curve θmd(ψ) and the main wetting curve θmw(ψ), respectively, while the solid line denotes the modeled ψ-θ relations. The measured ψ-θ plots are expressed by the plus symbols “+”. The subgraph (i) displays the plots for the entire study period, and each of the subgraphs (ii) through (viii) shows the plots for each year.

The measured θ [m3∙m−3] lowered below 0.50 [m3∙m−3] only in the last 3 years of the study period (Figures 2(vi)-(viii)), and the measured ψ [J∙kg−1] had never gone above −0.1 [J∙kg−1] except for those in the last year (Figure 2(viii)). The model followed well the long continual drying processes found in 2017 and 2018 (Figure 2(vi) and Figure 2(vii)), while it also reproduced the loop-like behavior of the measured ψ-θ relations in the region of 0.40 [m3∙m−3] ≤ θ ≤ 0.45 [m3∙m−3] with the domain of −100 [J∙kg−1] ≤ ψ ≤ −0.1 [J∙kg−1] (Figure 2(vii)), suggesting that if the model parameters had been identified without considering the data set measured in the last 3 years, the resultant model would have failed to explain the entire hysteretic behavior observed in the 82 months.

The measured ψ-θ relations traveled from the region of θ ≤ 0.45 [m3∙m−3] to the region of θ ≥ 0.55 [m3∙m−3] in 2019 (Figure 2(viii)). This continual wetting process took more than half a year and can be separated roughly into two processes. In the first wetting process, the SWRC shifted up into the region of 0.45 [m3∙m−3] ≤ θ ≤ 0.50 [m3∙m−3] until May in 2019. In the second wetting process, θ [m3∙m−3] became more than 0.55 [m3∙m−3] by October in 2019. The first wetting process was reproduced by the model relatively well. In the second process, on the other hand, the model partially failed to follow the trajectory of the measured ψ-θ relations so that the modeled curve dropped by the region of 0.50 [m3∙m−3] ≤ θ ≤ 0.55 [m3∙m−3] while the measured ψ-θ relations skipped this region and directly reached the region of θ ≥ 0.55 [m3∙m−3].

The failure of the model to reproduce the wetting process in October in 2019 indicated that it was difficult for the model to explain the process in which water is entering into such large pores as filled with water of potential higher than −1 [J∙kg−1]. This difficulty implied that the model performance can be improved by distinguishing a coarse pore system from the entire pore system of the soil when developing the model of soil water hysteresis.

This study assumed a-priori that the pore size distribution of the soil is of single modal, because single-peaked functions as shown in Equations (10) and (11) were applied to the description of the two main curves. On the other hand, the soil in this study could retain relatively large amount of water in coarse pores and, thus, its in-situ SWRC tended to have roughly 10% smaller θ [m3∙m−3] than the corresponding laboratory-measured SWRC under near saturated conditions (Iiyama, 2016). In addition, θmax determined in this study was 0.636 [m3∙m−3], obviously lower than the saturated water content of the soil (0.815 [m3∙m−3]), meaning that the coarse pore system had rarely been filled with water for the study period of 82 months and the resultant measured ψ-θ relations must have prevented the modeling process from correctly considering the drying-wetting cycles of the coarse pore system.

In the same manner as the difference between the determined θmax [m3∙m−3] and the actual saturated water content, θmin determined in this study was 0.353 [m3∙m−3], higher than the air-dried water content of the soil (0.050 [m3∙m−3]). The gap between these two numerals implied that very fine pores in the soil had had almost no experience of drying-wetting cycles, and their soil water characteristics had no need to be, and were not sufficiently, considered in the model of this study. These features also suggested that it is promising to develop a model that can simulate hysteretic behaviors found in multi-modal pore systems like volcanic ash soils.

4. Conclusion

This study showed the derivation and algorithm of the model of soil water hysteresis that can reproduce the time series of the relations between soil water potential ψ [J∙kg−1] and soil water content θ [m3∙m−3] along in-situ drying-wetting cycles. The assumption of the model derivation was based on the observed features of the in-situ ψ-θ relations. The model requires a pair of the main drying and wetting curves θmd(ψ) and θmw(ψ), both of which can be described by any type of mathematical expression only if they share the driest and wettest extremities. The model can calculate an unknown water content θ1 [m3∙m−3] for a given water potential ψ1 [J∙kg−1] and any latest known moisture condition (ψ0, θ0), when drawing the series of scanning drying and wetting curves θscd(ψ) and θscw(ψ).

The model reproduced well the general trend of the measured ψ-θ relations throughout the study period. Particularly, the model imitated the observed processes of ψ-θ relations through which the repetitions of reversals in drying-wetting direction in the domain of ψ ≤ −50 [J∙kg−1] caused gradual lowering of θ [m3∙m−3]. However, the model underestimated θ [m3∙m−3] in this domain when the chances of reversals in drying-wetting direction were wrongly input into the model in the series of ψ [J∙kg−1].

The model also made errors in a long continual wetting process in the domain of ψ ≥ −1 [J∙kg−1] in which water entered into coarse pores. This error implied that the model can be improved by separating the whole pore system of the soil into several pore systems including a coarse pore system, as water can hardly enter in and can easily drain from these coarse pores in soils. Therefore, further studies are necessary to modify the model of soil water hysteresis so that it can deal with multi-modal pore systems like volcanic ash soils or other types of structured soils rich in soil aggregates.

Acknowledgements

The author thanks Mr. T. Shiozawa, Mr. E. Saito, Mr. K Seino, and Mr. N. Yamaguchi at the Utsunomiya University Farm who have managed the study field. The author also thanks Mr. T. Hirai of the former student in the Graduate school of Agriculture, Utsunomiya University, and Mr. H. Ajito, Ms. M. Anzai, Ms. K. Arakawa, Ms. M. Cho, Ms. N. Goka, Mr. T. Hoshino, Mr. D. Iimura, Mr. J. Kaneko, Mr. T. Kurata, Mr. K. Ogasawara, Mr. Y. Sakanishi, Mr. H. Shoji, Mr. H. Suto, Mr. S. Takaki, Mr. K. Tezuka, Mr. N. Totsuka, Mr. K. Tsukagoshi, and Mr. Y. Usui of the former students in the Faculty of Agriculture, Utsunomiya University, for their works in the field and in the laboratory.

Conflicts of Interest

The author declares no conflicts of interest regarding the publication of this paper.

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