The quality of water is of vital importance to mankind since it is directly linked with human health. The quality of groundwater is equally important to its quantity due to the suitability of water for various purposes ranging from drinking, domestic, industrial and agricultural purposes all over the world [1] . The quality of groundwater in a particular region is a function of physical, chemical and biological parameters. According to [2] , groundwater quality depends on the quality of recharged water, quantity and quality of generated waste, sewage treatment and subsurface geochemical processes. The variation of groundwater quality in an area is a function of physical and chemical parameters that are greatly influenced by geological formations and anthropogenic activities [1] . Groundwater contamination has become a great problem due to rapid growth of population, industrialization and urbanization rate in the metropolitan city all over the world. Quality of groundwater is normally characterized by different physicochemical parameters level. These parameters change widely due to various types of pollution, seasonal variation and groundwater extraction [3] . Sitting of open dumpsite near the residential areas can have adverse effect on nearby water sources if the leachate emanated from decomposed solid waste infiltrate and pollute the water table. Hydrochemical study reveals the quality of water suitable for domestic and agricultural purpose. Further, it is possible to understand the change in quality due to rock water interaction or any type of anthropogenic influence [4] .

Several researchers have identified contamination plumes from disposal sites [5] - [7] with most of these studies focusing on defining the spatial extent of groundwater pollution based on geochemical analysis results. However, the investigation of the suitability of groundwater collected from hand-dug wells within the vicinity of open dumpsite for irrigation needs was not included. [1] have studied groundwater quality and its suitability for drinking and agricultural use in Chithar River Basin, Tamil, Nadu, India. The quality of groundwater in Tarkwa Gold mining area in Ghana was assessed by [8] . [9] carried out hydrochemical analysis and evaluation of groundwater quality in Tumkur Taluk, Karnataka, India for the suitability of water for irrigation purpose. [10] evaluated the suitability of local groundwater quality for domestic and irrigation purposes in Periyakulam Taluk of Theni district, Tamil Nadu India. [11] have also studied groundwater and its suitability for irrigation in the southeastern part of the Ranga Reddy district, Andrapradesh, India.

The present study was carried out for both dry and wet seasons from hand-dug wells bordering Aba-Eku landfill for better understanding of spatial and seasonal distribution of hydrogeochemical constituents of groundwater as well as its suitability for domestic and irrigation purposes.

Ibadan lies approximately within the square of longitudes 3˚35'E and 4˚10'E and latitude 7˚20'N and 7˚40'N. The study area, Aba Eku located within Ibadan metropolis and located on longitude 3˚59'009''E and 3˚59'973''E and latitude 7˚19'270''N and 7˚19'843''N. The dumpsite is bothered by residential buildings. The study area falls within the humid and subhumid tropical climate of southwestern Nigeria with a mean annual rainfall of about 1230 mm and mean maximum temperature of 32˚C. Relief in Ibadan is gently undulating and ranges between 200 - 234 m (above mean sea level). Aba-Eku landfill is one of the four designated open dumpsites managed and maintained by Oyo State Waste Management Authority. It was opened in 1998 and is still active till date. It is located along Ijebu Igbo road covering an area of approximately 10 hecatares.

Geologically, the study area lies within the basement complex rock (Figure 1) characterized by crystalline rocks of Precambrian age with the main rock types comprising quartzites, banded gneiss, augen gneisses and migmatites while the minor ones include pegmatitic intrusion, quartz veins and dolerite dykes [12] .

Ten groundwater samples were collected during March and August 2013 at ten different locations from hand- dug wells around the dumpsite (Figure 2). The distance of the hand-dug wells to the landfill, depth of the well and depth to static water level for both seasons were shown in Table 1. The samples were collected in precleaned and sterilized 2 L polyethylene bottles. Parameters such as pH, TDS and EC were determined on sites with the aid of multipurpose conductivity meter. Other parameters of interest analyzed in the laboratory were Ca²⁺, Mg²⁺, Na⁺, K⁺, TH, , , and using standard procedures recommended by APHA (1998). Concentrations of Na⁺ and K⁺ were determined using flame photometric method, , and with titrimetric method, by UV spectrophotometric method while amount was determined using turbidimetric method. The absorption mode of Atomic Absorption Spectrophotometric (AAS) method was used for the determination of Ca²⁺ and Mg²⁺ concentrations while total hardness (TH) was determined by Ethy-

lene Diamine Tetra Acetic Acid (EDTA) titration method using Eriochrome black-T as an indicator. The analytical data can be used for the classification of water for various purposes and their percentage compliance with the World Health Organization (WHO) as well as Nigerian Standard for Driking Water Quality (NSDWQ).

Maximum and minimum concentrations of major ions present in the water samples and their percentage compliance with WHO and NSDWQ limits for both dry and wet seasons are as shown in Table 2, while Table 3 shows the comparison between values of each parameter during dry and wet seasons sampling periods.

The pH values of groundwater range from 6.69 to 7.59 and 6.51 to 7.06 during dry and wet seasons respectively. The pH values during both seasons fall within the WHO and NSDWQ permissible range of 6.5 - 8.5. Fifty percentage of analyzed samples have pH values below 7.0 during dry season while this increase to 80% during wet season. This indicates that there is more dissolution of pollutants during the rainy season. The total Hardness (TH) values during dry and wet seasons ranged from 08 to 288 mg/L and from 132 to 446 mg/L respectively. Based on [14] classification, 40% of samples fall under the “soft” class, 50% under “moderate” class

while 10% falls under “Hard” class during the dry season. During wet season of sample collection, none falls under “soft” class of hardness, 10% fall under “moderate” class, 70% fall under “Hard” class while the remaining 20% fall under “very hard” class. The chloride ion concentration values ranged from 17 to 106 mg/L and 10 to 120 mg/L during dry and wet seasons respectively and these were found to lie within the permissible level of 250 mg/L. The nitrate values during dry season ranged from 1.4 to 4.8 mg/L. However, during wet season, it ranged from 0 to 3.3 mg/L. Unpolluted natural water usually contains only minute quantities of nitrate. The groundwater samples in both seasons have their nitrate values lie below the limit of 50 mg/L by WHO and

NSDWQ. The values of sulphate ions in the groundwater samples ranged from 13.4 to 144 mg/L during dry season and 10.3 to 75.3 mg/L during wet season. However, sulphate lie below 200 mg/L according to WHO and NSDWQ limit. The Na⁺ and K⁺ values ranged from 08 to 40 mg/L and 0 to 5 mg/L during dry season and lie below the limits set by WHO and NSDWQ. During wet season, Na⁺ and K⁺ values ranged from 11 to 26 mg/L and 01 to 4 mg/L respectively. The low pottassium concentrations in both seasons compared to Na⁺ concentration may be due to the resistant of potassium minerals to decomposition by weathering process. Also its low concentration in natural water is as a consequence of its tendency to be fixed by clay minerals and participate in the formation of secondary minerals.

The Ca²⁺ and Mg²⁺ concentration values during dry and wet seasons ranged from 0.1 to 5.9 mg/L; 0.4 to 14.8 mg/L and 1.6 to 15.1 mg/L; 4.2 to 26.2 mg/L respectively.

The EC values range from 148 μS/cm to 784 μS/cm during dry season and 202 μS/cm to 539 μS/cm during wet season. The TDS values lie within the WHO and NSDWQ limits. The TDS values in both seasons showed that all the water samples irrespective of the season belong to “freshwater” class based on [15] classifications as presented in Table 4.

The abundance of major ions in groundwater during both seasons is in the following order: Na⁺ > Mg²⁺ > Ca²⁺ > K⁺ and > > > >. It was observed that higher values of concentrations of most parameters were noticed in well 5 during both seasons. This may be attributed to close proximity of well 5 to Aba Eku dumpsite (20 m distance to the landfill).

The degree of a linear association between any two analyzed parameters measured by Pearson’s Correlation coefficient for both dry and wet seasons are presented in Table 5 and Table 6 respectively. There is a strong association between EC and TDS, , TH and Na⁺ during both sampling periods. This confirmed the fact that EC depends largely on the quality of the dissolved salts present in the sample.

The major ions in groundwater samples were found to be within the permissible limits of WHO and NSDWQ, thus suitable for domestic purpose. However, water from location 5 showed higher values of concentration of most parameters than other locations due to its nearness to the landfill. Generally, the groundwater quality of the study area in both seasons based on the interpretation of hydrochemical analyses is hard, fresh and alkaline in nature. The dominant groundwater type in both seasons was CaHCO₃ type. Alkaline earth (Ca²⁺ and Mg²⁺) exceeds alkalis (Na⁺ and K⁺) and weak acids (and) exceed strong acids (and). There is a strong association between EC and TDS, , TH and Na⁺ during both seasons. The suitability of groundwater for irrigation purpose based on calculated irrigation parameters showed that sizeable number of the groundwater

samples will neither cause salinity hazards nor have adverse effects on the soil properties and thus suitable for irrigation needs.

The authors are grateful to the Institute of Food Security, Environmental Resources and Agricultural Research (IFSERAR) of Federal University of Agriculture, Abeokuta (FUNAAB), Nigeria for funding part of this research work through research grant no: FUNAAB/IFSERAR/IRG100.