The oldest 35 pieces of the continental crust mostly composed of tonalitic-trondjemitic-granodioritic (TTG) gneisses imprint the Earth’s evolution during much of its ca. 4.5 Ga history [1]. The study of the Archean continental crust provides geological and geochemical insights to the early Earth due to asteroid and meteoritic impacts [2].

The Arctic region of the Fennoscandian Shield hosts large-scale strategic deposits, such as Neoarchean banded-iron formations (BIF) in the Olenegorsk ore area, Paleoproterozoic PGE-Cu-Ni and PGE-Cr-Ti deposits in the Monchegorsk, Fedorovo-Pana and Imandra ore areas, Cu-Ni deposits in Pechenga, as well as major Paleozoic apatite-nepheline and phosphorite deposits in the Khibiny, Lovozero, Kovdor, etc. Therefore, the study of their basement or continental crust is essential for understanding of processes that governed the deposits evolution.

The north-eastern part of the Fennoscandian Shield hosts the Murmansk, Central-Kola and Belomorian (White Sea) megablocks with the Archean continental crust (Figure 1). Previous Sm-Nd isotope data on rocks of the basement with continental crust (TTG and paragneisses) have yielded ages older than 3.0 Ga [3]. There has been very little evidence of of Paleoarchean and Eoarchean rocks in the basement of the Belomorian megablock established on the basis of detrital zircons sampled from metasediments of the Lapland-Kola granulite belt [4].

New U-Pb ID-TIMS and SHRIMP zircon ages of TTG in the Voche-Lambina area have been estimated at 2.9 - 2.82 Ga with Sm-Nd model ages of 3.0 Ga for the same rocks with positive εNd values of +0.6 to +3.2 [5]. There had been no chance to find a typical TTG complex with Paleoarchean zircon ages in the Central-Kola megablock for a long time. Only several SHRIMP zircon data had been available for the gneisses, which were not older than 3.6 Ga [6]. Precise zircon core ages of gneisses and TTG in the north-eastern Fennoscandian Shield (Siurua, Finland) estimated at Nordsim at 3.45 and 3.73 Ga [7] have revived the study of the oldest rocks in the Central-Kola megablock.

According to Holta et al. [8], the Fennoscandian Shield hosts the Murmansk, Belomorian, Norbotten and Karelian provinces with TTG and amphibolites with the age range of 2.7 - 2.8 Ga, as well as paragneisses, greenstone belts and sanukitoids, with the age range of 2.72 - 2.75 Ga. The Karelian province comprises the West-Karelian and the Central-Karelian subprovinces. The Vodlozero province is composed of TTG gneisses and amphibolites of greenstone belts with the ages of 2.9 to 3.5 Ga.

The Belomorian province comprises TTG and amphibolites (2.7 - 2.9 Ga), which were modified in the Paleoproterozoic. Eclogites have been recently reported to occur there [9].

The province also hosts the Voche-Lambina geological site. SHRIMP analysis of zircons from TTG has yielded the age of 3158.2 ± 8.2 Ma [5] [10].

The studied rocks refer to grey gneisses of the Central-Kola megablock basement within the Murmansk province (Figure 2). They occur near the monument to the Defenders of the Soviet Arctic (Murmansk, Russia). These rocks are composed of garnet-biotite gneisses with kyanite and sillimanite. Besides, there are biotite-amphibole gneisses with migmatites and amphibolites. This subprovince accommodates mafic and felsic volcanics, quartzites, granodiorites, plagiogranites and tonalities [6] [11].

Zircons have been separated from gneiss samples with the weight of about 30 kg. The U-Pb (ID-TIMS) dating of single grains has been carried out using the method described by Krogh [12] with an artificial ²⁰⁵Pb spike; the results are shown in Table 1. Following this method, the samples have been dissolved in strong (48%) hydrofluoric acid at a temperature of 205˚C - 210˚C during 1 to 10 days. To dissolve the fluorides, the samples have been reacted with 3.1 N HCl at a temperature of 130˚C for 8 to 10 hours. To determine the isotope composition of lead and to measure the concentrations of lead and uranium, the sample has been divided into two aliquots in 3.1 N HCl, and a mixed Pb + U tracer has been added. Pb and U have been separated on an AG 1 × 8, 200 - 400 mesh anion exchanger in Teflon columns. The laboratory blank for the whole analysis is 0.1 - 0.08 ng for Pb and 0.01 - 0.04 ng for U. All isotopic determinations for zircons have been made on a Finnigan MAT-262 mass spectrometer; the Pb isotopic composition has been analyzed on a secondary-ion multiplier in an ion-counting mode. The measurements of the Pb isotopic composition are accurate to 0.025% when calibrated against the NBS SRM-981 standards. The U and Pb concentrations have been measured in a single-filament mode with added H₃PO₄ and silica gel using the method described by Scharer and Gower [13] and Scharer et al. [14]. Pb and U concentrations have been measured within the temperature ranges of 1350 - 1450 and 1450˚C - 1550˚C, respectively. All the isotopic ratios are corrected for mass discrimination during the static processing of replicate analyses of the SRM-981 standard (0.12% + 0.04% per a.m.u.). The errors in the U-Pb ratios are calculated during the statistical treatment of replicate analyses of the IGFM-87 standard and are assumed equal to 0.5%. If the actual analytical errors are higher, they are reported in the table of isotopic data. Isochrons and sample points have been calculated using the Squid and Isoplot programs [15] [16].

Age values have been calculated with conventional decay constants for U [17], all errors are reported at a 2-sigma level. Corrections for common Pb are made according to Stacey and Kramers [18]. Besides, corrections are made for the composition of Pb separated from syngenetic plagioclase or microcline if the admixture of common Pb is >10% of the overall Pb concentration and the

²⁰⁶Pb/²⁰⁴Pb ratios are <1000. Table 1 provides the results.

The zircon fraction from the same gneisses has been analyzed using the SHRIMP method described by Williams et al. [19] at the A.P. Karpinsky Russian Geological Research Institute (VSEGEI); the results are given in Table 2 and Figure 6(b). All geochemical REE and trace element analyses of the whole rock have been made at the Institute of Geology and Mineralogy, Siberian Branch RAS, Novosibirsk, using the method described by Panteeva et al. [20].

Рetrography and Geochemistry of Gneisses in the Central-Kola Megablock

Petrographically, high-alumina gneisses include garnet-biotite, sillimanite-garnet-biotite, staurolite-kyanite-sillimanite-garnet-biotite gneisses [11]. These rocks are dark grey, fine-medium-grained and slightly schistose (Figure 2). Their texture is a combination of granoblastic, porphyroblastic and lepidoblastic varieties. The rocks consist of quartz, plagioclase, biotite, garnet, sillimanite, kyanite, staurolite and chlorite (Figure 3).

Plagioclase occurs as colorless isometric and usually not twinned grains. Some of them are slightly sericitized. Quartz appears in small irregular grains (0.2 - 0.6 mm) and also forms large lenses up to 3.5 mm in length (Figure 3(b)). Biotite is found in tabular or flaky 0.05 - 0.90 mm grains uniformly scattered throughout the rock. Biotite may also intergrow with garnet (Figure 3(a)). Garnet occurs as large porphyroblasts (2 - 3 mm) with irregular outlines and encloses quartz and biotite inclusions. Some of the garnet cracks are filled with fine-grained mica. Sillimanite forms colorless elongated prismatic grains with a length of up to 0.6 mm; fine-grained fibrolites are less common (Figure 3(d)). Kyanite grains include quartz, which has an elongated prismatic (0.3 - 1.1 mm) shape with irregular outlines. Staurolite is represented by sporadic elongated prismatic grains with a length of up to 0.5 mm (Figure 3(c)).

Errors are 1-sigma; Pb_c and Pb* indicate the common and radiogenic portions, respectively. Error in TEMORA Standard calibration—0.28%. (1) Common Pb corrected using measured ²⁰⁴Pb.

Isotope ID-TIMS and SHRIMP Data

Gneisses were sampled from the vast outcrops of the Central-Kola megablock to determine the age of a submeridional basite dyke, which cuts the complex of high-alumina paragneisses (Figure 1(b) and Figure 2).

According to the IUGS TAS plot, gneisses comply with the dacite field of tholeitic series (Table 3; Figure 4). The gneiss samples are rich in LREEs and poor in HREEs (Table 4; Figure 5), which conforms to typical TTG patterns according to Moyen and Martin [21].

Four grains of single zircon crystals have yielded the age of 2753 ± 3 Ma in the U-Pb isochron (Figure 6(a)), which corresponds to the amphibolite facies metamorphism. The lower intersect of the Discordia-concordia line is at 443 ± 130 Ma. It reflects the Paleozoic magmatic activity in the north-eastern Fennoscandian Shield (Figure 6(a)) and circular alkaline Khibiny-Lovozero-Kovdor massifs, etc. One zircon point plots in the U-Pb isochron near the age of 3.17 Ga and implies the magmatic origin of the zircon (Table 1) from the oldest population. Hand-picked grains have magmatic oscillatory zoning and a diagnostic core with older ages.

All SHRIMP zircon ages for the high-alumina gneisses with different peaks and intervals of origin at 2794 - 2763 Ma are similar to the ID-TIMS data of amphibolite metamorphism (2753 ± 3 Ma). The data in the range of 2924 - 2886 Ma seem to reflect the low-granulite facies metamorphism. One point coinciding with the concordant age of 3695 ± 5 Ma represents the oldest age of the studied gneisses (Figure 6(b) and Figure 7(a)). Coeval SIMS and LA-ICP-MS isotope measurements have been carried out for the Finnish part of the Fennoscandian Shield (Figure 7(b)). In result, the age of 3.45 Ga has been obtained for the rims and the age of 3.73 Ga has been obtained for the core parts of the zircon from

^acomposition for high alumina gneisses of Central Kola megablock; ^baverage composition of Archaean grey gneisses according to [21].

^a,bcomposition for high alumina gneisses of the Central Kola megablock; ^caverage composition of Archaean grey gneisses according to [21].

the Siurua TTG complex [7]. The U-Pb and Sm-Nd data [24] (Figure 7(b)) are found close to the U-Pb (ID-TIMS) and SHRIMP zircon data on the Central-Kola megablock.

The new U-Pb (ID-TIMS) data on single zircons from paragneisses of the Central-Kola megablock show the age of 3.17 Ga. The cores of these zircons have the age of 3695 ± 5 Ma (SHRIMP-II) and ca. 100 Ma older ages as compared to paragneisses of the Central-Kola megablock, according to Myskova et al. [6] (Figure 7(a)). The age of the amphibolite facies metamorphism has been estimated at 2753 ± 3 Ma.

The Voche-Lambina geological site lies at the boundary between the Belomorian mobile block and the Central-Kola domain [5]. New Neoarchean U-Pb data on single zircons of the Voche-Lambina TTG have yielded the age of 3158.2 ± 8.2 Ma. The zircon has low U and Pb concentration and the low U/Th ratio of 0.2. REE plots for grey gneisses show high fractionation of La/Yb > 30 riched in LREE and poor in heavy Yb (<0.6 ppm). The precise (ID-TIMS) single zircon age of the amphibolite facies metamorphism has been estimated at 2704.3 ± 5.9 Ma. Model Sm-Nd WR data indicate the protolith ages of 3.4 to 3.2 Ga, positive εNd of +1.29 to +3.3 and ISr of 0.702 [5].

Thus, the new data on single zircon grains from TTG and paragneisses of the Central-Kola megablock imply a long-term and discrete evolution of the continental crust in the Fennoscandian Shield (3.17 - 3.73 Ga). Noteworthy, the oldest part of the Hadean component is well-preserved in zircons that were subject to high-pressure metamorphism in Finland and granulite facies metamorphism [25] in Siberia (Aldan Shield, Russia). The latter has been dated using the ID-TIMS

method; the single zircon age has been estimated at 3.94 Ga.

For the first time, zircons from the Central-Kola megablock have been dated using the SHRIMP method. As a result, the oldest age of 3.7 Ga has been obtained. Taking into account the age of Siurua TTG, Finland (3.73 Ga), these results suggest the presence of older (Hadean) rocks with zircon ages of >4.0 Ga. It will also allow specifying the age of the continental crust, which provides the basement necessary for the formation of the regional deposits, such as the Neoarchean BIF in the Olenegorsk ore area, Paleoproterozoic PGE-Cu-Ni and PGE-Cr-Ti deposits (Monchegorsk, Fedorovo-Pana and Imandra ore areas) and Cu-Ni deposits (Pechenga, as well as large-scale Proterozoic apatite-nepheline and phosphorite deposits (Khibiny, Lovozero, Kovdor, etc.).

The paper is devoted to the outstanding scientists and huge enthusiasts of fundamental geology and geochronology Academician RAS Mitrofanov F.P. (1935-2014), Bibikova E.V. (1934-2016) and G. Wasserburg (1927-2016). Many thanks to J. Ludden, F. Corfu, V. Todt, and U. Poller for their assistance in U-Pb single zircon measurements and to G. Wasserburg for the baddeleyite measurements with a ²⁰⁵Pb spike.

The current research has been financially supported by grants 18-05-70082, 18-35-00246 mol_a and 18-35-00152 mol_a of the Russian Foundation of Basic Research, and Scientific Research Contract No. 0226-2019-0053.

The authors declare no conflicts of interest regarding the publication of this paper.

Bayanova, T., Kunakkuzin, E., Serov, P., Steshenko, E., Borisenko, E., Larionov, A. and Turkina, O. (2020) The Oldest Grey Gneisses and Tonalite-Trondhjemite Granodiorites in the Fen- noscandian Shield: ID-TIMS and SHRIMP Data. Open Journal of Geology, 10, 124-136. https://doi.org/10.4236/ojg.2020.102007