Anthill (termitaria) is a habitat of termites constructed with soils of modified texture, increased content of organic matter, phosphorus (P), nitrogen (N), and potassium (K) due to biological activities of the ants [1] [2] [3] . According to Akinboboye and Ogunfayo [4] , grain size distribution of silt and clay from different locations vary with different anthills but all show low plasticity. Anthill soil could be used in place of shale for the production of cement if it was well graded [4] .

Anthills were used in geochemical mineral exploration by West [5] in the Leopard Mine of Zimbabwe where termites transported elements from depth to the surface for construction of termitaria. According to Affam and Arhin [6] , the height of anthill or termite mound reflects the depth of burrowing. Thus the higher the anthill the deeper the depth burrowed by termites. According to Rao and Raju [7] , where termite mounds occur in large numbers particularly in tropical areas with thick overburden, their efficacy as prospecting tool could be employed.

The study area is located at about 20 km west of Winneba junction in Gomoa East district, located in the south-eastern part of the Central Region of Ghana. The district experiences two rainfall seasons―the major rainy season is from March/April-June/July while the minor season is from September-November. The main dry season is from November to March and a minor one from mid-July to mid-August [8] . Mean annual rainfall currently ranges between 70 mm and 90 mm in the southern coastal belt and between 90 mm and 110 mm in the north-western semi-deciduous forest areas [8] . According to Anon. [8] , the district has two main vegetation zones―the dry coastal savannah and the moist semi-deciduous forest. The coastal savannah consists of grassland with scattered patches of thicketsin the south-east.

The area of study is underlain by the Birimian Supergroup composed of metavolcanic rocks with isolated amphibolite due partly to contact metamorphism from granitoid intrusives; generally foliations dip at 5˚ to 20˚ towards the north-northwest (Figure 1) [9] [10] .

Of the many anthills which occur on either side of the highway from Apam junction to Winneba junction in Ghana, three of them which were used for the study, were located at about 20 km west of Wnneba junction. Their positions were picked using GPS and sampled at the surface from three spot heights after their circumferences were measured at the base at 5 cm from the ground, middle, and at the top. To avoid contamination of samples, mount surfaces were cleaned by scrapping with a metal chisel, bagged and labelled. Samples from the field were dried in the open sun, coned and quartered to obtain a representative sample. A quarter of the sample was taken, weighed to 500 g, soaked in water and passed through 0.075 mm sieve to separate the upper size (sand fraction) and under size (fine fraction). Grain size distribution for the sand fraction was obtained through sieving and under size dried and weighed. These analyses were done in the Geotechnical Laboratory of the University of Mines and Technology at Tarkwa in Ghana. Elemental composition was determined on two batches of samples by X-Ray fluorescence analysis at the Geological Survey Department (GSD) in Accra, Ghana.

At GSD, each sample with a labelled tag was put in a crucible, oven dried at a temperature of about 105 degrees Celsius for 20 minutes after which samples were removed and put into glass desiccators to prevent moisture entry whilst cooling. Then 4 g of each sample was then mixed with about 0.9 g of wax powder,

homogenised by milling for about 5 minutes and then compressed under a load of 15 tonnes to obtain a 32 mm diameter pellet. X-ray florescence analysis was conducted using SPECTRO X-LAB 2000 multi element analyser to obtain major oxides (wt. %) and trace elements (ppm).

The land surface of the study area was gently undulating, occupied by poorly drained, dark olive brown clay or yellowish red silt clay with scarce iron oxide and manganese oxide nodules. Anthills used for the study were wider at the base (6.0 - 6.8 m), reduced near the middle by about 1.0 m and smaller at the top by a third. These structures were up to 2 m high (Figure 2). Samples taken from anthills with contrasting colours (brown, brownish yellow and light brown) were coned and quartered to obtain a sample weight of about 500 g (Figure 3 and Figure 4 respectively). XRF analyses were conducted on anthills 1 and 2. Table 1 shows sieve analysis of soils. Anthill 1 had higher mass retained on 2.00 mm

sieve size (8.6 g) followed by anthill 2 (2.2 g) and then anthill 3 (1.7 g); total mass above 0.075 mm sieve size was higher in anthill 3 (231.4 - 276.6 g), followed by anthill 1 (151.5 - 179.1 g) and then anthill 2 (107.7 g - 118.0 g); fines were higher in anthill 2 (392.3 - 382.0 g), followed by anthill 1 (320.9 - 348.5 g) and least in anthill 3 (223.4 - 268.6 g) (Table 1). For major oxides, SiO₂ range from 51.70 - 60.24 wt. %, Al₂O₃ (22.18 - 28.88 wt. %), total FeO (12.22 - 15.24 wt. %), MgO (1.20 - 1.90 wt. %) (Table 2). Graphs of mass against sieve sizes (over size and under size) were plotted for anthills 1 to 3 (Figures 5-7). Histograms of mass retained on sieve sizes were plotted against height in anthills, respectively (Figure 8 and Figure 9). SiO₂ (wt. %) was plotted against Al₂O₃ (wt. %), total FeO (wt. %), MnO (wt. %), and K₂O (wt. %) to determine their correlation and variation with height (as shown in Figures 10-13).

Percentage of soil grain size from anthills which passed through sieve size 0.075 mm was more than the retained (Table 1). Thus, the fraction of fines was more than sand fraction in the clay used in molding the anthills. According to Anon. [11] the size of these termites from subterranean worker termites might be as short as 3.175 mm to up to 9.525 mm in length, soldiers might be slightly longer, while the reproductive queens and kings could be over 19.050 mm. Hence such small creatures which carried grain sizes up to 2 mm must have used much effort or team work to offset gravity on the load. Yet in their effort to build the mighty structures, relatively smaller masses of grains could have been used for the construction at higher parts of the anthill/mound. Figure 8 shows decrease in mass of sand size grains with increasing termite mound height whilst for finer grains, mass increased higher up the termite mound.

SiO₂ (wt. %) decreased higher up of anthill 1 but increased with increasing height in anthill 2 (Figure 10). Surprisingly, Al₂O₃ content generally increased higher up the anthills. Total FeO increased higher up anthill 1, but decreased

steadily to the top of anthill 2. MnO was fairly constant in both anthills and almost homogeneous with height. K₂O decreased with height in anthill 1 and

increased with height in anthill 2. The variations in the concentration of the major oxides suggest that soils used to construct the anthills were possibly derived

from different rock types or there were differences in termite preference for clay richer in selective SiO₂ or total FeO.

The anthills showed that the termites had similar building techniques. Soils for construction of anthills were mainly sand and clay of varied proportions. The variation in grain size differed from one locality to another and height on the anthill as more fines (<0.075 mm) were used in the construction of the upper parts.

SiO₂ was positively correlated with total FeO, Al₂O₃, MnO, and K₂O. Whilst SiO₂, total FeO and Al₂O₃ increased with height; there was a decrease in K₂O with height of anthill. Major oxides were different in anthill 1 and 2 possibly due to differences in rock types from which these soils were derived. There could also be different types of termites involved in the construction process as different anthills exhibited clay richer in silica or total iron oxide. Hence during mineral prospecting, geochemical sampling and analysis of upper portions of anthills (where fine fractions usually occur) are recommended as these portions may yield valuable information of the geology of the area. Care should, however, be taken for uniformity of sample material in terms of colour, type and size of anthills.

Tetteh, G.M. and Zuyeri, J.K.A. (2017) Grain Size and Major Oxide Analyses of Selected Anthill Soils from Winneba Area, Ghana. Journal of Geoscience and Environment Protection, 5, 264-274. https://doi.org/10.4236/gep.2017.59018