<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">OJEE</journal-id><journal-title-group><journal-title>Open Journal of Energy Efficiency</journal-title></journal-title-group><issn pub-type="epub">2169-2637</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/ojee.2017.63005</article-id><article-id pub-id-type="publisher-id">OJEE-78102</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Engineering</subject></subj-group></article-categories><title-group><article-title>
 
 
  Comparing of Hydrogen On-Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yu.</surname><given-names>S. Nechaev</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>V.</surname><given-names>G. Makotchenko</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>M.</surname><given-names>B. Shavelkina</given-names></name><xref ref-type="aff" rid="aff3"><sup>3</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>M.</surname><given-names>Yu. Nechaev</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>A.</surname><given-names>Veziroglu</given-names></name><xref ref-type="aff" rid="aff4"><sup>4</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>T.</surname><given-names>N. Veziroglu</given-names></name><xref ref-type="aff" rid="aff4"><sup>4</sup></xref></contrib></contrib-group><aff id="aff2"><addr-line>A. V. Nikolaev Institute of Inorganic Chemistry, The Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia</addr-line></aff><aff id="aff1"><addr-line>I. P. Bardin Central Research Institute for Ferrous Metallurgy, Dpt. G. V. Kurdyumov Institute of Metals Science and Physics, Moscow, Russia</addr-line></aff><aff id="aff4"><addr-line>International Association for Hydrogen Energy, Miami, FL, USA</addr-line></aff><aff id="aff3"><addr-line>The Joint Institute for High Temperature, The Russian Academy of Sciences, Moscow, Russia</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>yuri1939@inbox.ru(YSN)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>01</day><month>08</month><year>2017</year></pub-date><volume>06</volume><issue>03</issue><fpage>73</fpage><lpage>79</lpage><history><date date-type="received"><day>April</day>	<month>3,</month>	<year>2017</year></date><date date-type="rev-recd"><day>Accepted:</day>	<month>July</month>	<year>29,</year>	</date><date date-type="accepted"><day>August</day>	<month>1,</month>	<year>2017</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  It presented a comparative consideration of General Motors long-term activities on the current subject of fuel-cell-powered electric vehicles vs Toyota Mirai recent results, relevant to prospects on more efficient and safe technologies of the hydrogen on-board storage. It also presented a call on the project International cooperation. The main aim of this paper is to attract attention of General Motors, Toyota and/or other large car companies to a real possibility of developing and using, in the nearest future, of the break-through hydrogen on-board storage technology based on the solid H&lt;sub&gt;2&lt;/sub&gt; intercalation into graphite nanostructures.
 
</p></abstract><kwd-group><kwd>GM’ Activities vs Toyota Mirairesults</kwd><kwd> Prospects on Developing of a Break-Through Hydrogen On-Board Storage Technology</kwd><kwd> The Solid H&lt;sub&gt;2&lt;/sub&gt; Intercalation into Graphite Nanostructures</kwd><kwd> Call on the Project International Cooperation</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>In the connection with the intensive working out of the current subject of fuel-cell-powered electric vehicles in different countries, a comparative consideration is expedient of General Motors long-term (from 1964 up to nowadays [<xref ref-type="bibr" rid="scirp.78102-ref1">1</xref>] ) activities vs Toyota Mirai recent results (from 1993 up to nowadays [<xref ref-type="bibr" rid="scirp.78102-ref2">2</xref>] ), relevant to prospects on more efficient technologies of the hydrogen on-board storage. It is necessary to emphasize that Toyota and General Motors, during the long-term period, have been among the largest car companies in the World, and they have also been in a perpetual rivalry.</p></sec><sec id="s2"><title>2. About Toyota Mirairecent Results</title><p>As is noted in [<xref ref-type="bibr" rid="scirp.78102-ref2">2</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref3">3</xref>] , the automaker has been selling the Toyota Mirai in Japan since December 2014, but began sales in California in October 2015―marking the first time hydrogen-powered vehicles were sold in the United States. A Toyota spokesperson told Tech Insider that Toyota plans to sell 30,000 a year worldwide by 2020.</p><p>Toyota Mirai has the following characteristics [<xref ref-type="bibr" rid="scirp.78102-ref2">2</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref3">3</xref>] :</p><p>1) power output 153 HP (114 kW);</p><p>2) two carbon fiber high-pressure tanks for hydrogen on-board storage;</p><p>3) fuel compressed H<sub>2</sub> gas maximum filling pressure 87.5 MPa;</p><p>4) normal operating pressure 70 MPa;</p><p>5) hydrogen storage density (capacity) 5.7 weight %;</p><p>6) hydrogen storage mass about 5.0 kg;</p><p>7) the driving range at 312 miles.</p></sec><sec id="s3"><title>3. About General Motors Long-Term Activities and Recent Results</title><p>Recently, GM has delivered fuel cell military vehicle-the Colorado ZH2, along with the US Army Tank Automotive Research, Development and Engineering Center [<xref ref-type="bibr" rid="scirp.78102-ref1">1</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref3">3</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref4">4</xref>] . It is the most extreme off-road-capable fuel-cell-powered electric vehicle ever from GM. The Colorado ZH2 fuel cell vehicle is undergoing the extreme military testing in 2017 [<xref ref-type="bibr" rid="scirp.78102-ref5">5</xref>] .</p><p>GM says [<xref ref-type="bibr" rid="scirp.78102-ref4">4</xref>] that the test vehicle would get a bit less than 200 miles of driving range from the fuel cell. But over time, with newer fuel cells, the range could double. Some of the Colorado gear GM is using isn’t the absolute latest technology, but that’s intentional, because it has already been certified and GM wants to spend the 2017 year testing, not waiting for approvals then hasty testing. Built on a modified Chevrolet Colorado chassis, the vehicle contains several technologies that may one day change the auto industry [<xref ref-type="bibr" rid="scirp.78102-ref3">3</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref4">4</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref5">5</xref>] .</p></sec><sec id="s4"><title>4. On Solving the Current Problem of the Effective and Safe Hydrogen On-Board Storage</title><p>Despite the above noted Toyota and General Motors results [<xref ref-type="bibr" rid="scirp.78102-ref1">1</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref3">3</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref4">4</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref5">5</xref>] , along with results of other large car companies [<xref ref-type="bibr" rid="scirp.78102-ref2">2</xref>] , the problem of the effective and safe hydrogen on-board storage has yet been under consideration of a number of scientists, for instance, [<xref ref-type="bibr" rid="scirp.78102-ref6">6</xref>] - [<xref ref-type="bibr" rid="scirp.78102-ref12">12</xref>] .</p><p>In this connection, it is expedient to attract attention of both the scientists and the car companies to a real possibility of developing of a break-through hydrogen on-board storage technology of intercalation of solid molecular hydrogen of a high density into graphite nanofibers. It could be one of the problem solution ways.</p><p>The technology physics has been developed in [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] on the basis of the thermodynamic analysis [<xref ref-type="bibr" rid="scirp.78102-ref18">18</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref19">19</xref>] of a large massive of the related experimental and theoretical data, including [<xref ref-type="bibr" rid="scirp.78102-ref20">20</xref>] - [<xref ref-type="bibr" rid="scirp.78102-ref31">31</xref>] ones.</p><p>A related microphotograph of hydrogenated graphite nanofibers is shown in <xref ref-type="fig" rid="fig1">Figure 1</xref> (taken from [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] ). A comparison of this possible break-through technology [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] with the known ones is presented in <xref ref-type="fig" rid="fig2">Figure 2</xref> (taken from [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] ). Hence, a related International research project (see the next Item) seems rather expedient.</p></sec><sec id="s5"><title>5. Synopsis of the International Research Project “Thermodynamic Aspects of Hydrogen Sorption and Intercalation in Nanostructured Carbon-Based Materials, Relevance for Clean Energy Applications”</title><p>The project is devoted to the definition of thermodynamic characteristics and</p><fig id="fig1"  position="float"><label><xref ref-type="fig" rid="fig1">Figure 1</xref></label><caption><title> Micrograph of hydrogenated graphite nanofibers (GNFs) with Pd-catalyst (hydrogenated at 300 K and initial pressure of P<sub>(H2gas</sub><sub>)</sub> ≈ 8 MPa) after release from them, at 300 K for 10 min {according to data [<xref ref-type="bibr" rid="scirp.78102-ref21">21</xref>] }, of the intercalated solid H<sub>2</sub> nanophase (17 mass. %) of a high density of ρ<sub>H2</sub>≈ 0.5 g/cm<sup>3</sup> (analysisresults [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] ). The arrows in the picture indicate some of the slit-like closed nanopores of the lens shape, where the solid H<sub>2</sub> intercalated nanophase (under pressure of ~50 GPa) was localized (according to [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] ). Such a pressure level can be also evaluated by the consideration of the material deformation and the necessary stresses for forming such lens shape closed nanopores {at the expense of the energy of association of penetrating (into the nanopores) hydrogen atoms to molecules “captured” inside the nanopores [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] }. It may be considered as an extraordinary manifestation of both the Kurdjumov-like effect, and the spillover effect [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] </title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/1-2650141x2.png"/></fig><fig id="fig2"  position="float"><label><xref ref-type="fig" rid="fig2">Figure 2</xref></label><caption><title> It is shown (in the face of known achievements) US DOE system targets for 2010 and 2015, relevant to gravimetric and volumetric hydrogen on-board storage densities. The large red circle is related to the possible break-through technology [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] of the solid molecular hydrogen intercalation into the hydrogenated separate graphite nanofibers (see <xref ref-type="fig" rid="fig1">Figure 1</xref>)</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/1-2650141x3.png"/></fig><p>the disclosure of the atomic mechanisms of processes of hydrogen sorption and intercalation in expanded graphite and graphene materials. It is related to the current unresolved problems of the clean energy, including the problem of a compact and safe storage of hydrogen in eco-cars [<xref ref-type="bibr" rid="scirp.78102-ref6">6</xref>] - [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] .</p><p>In the project three methods of synthesis of carbon nanostructures will be used: 1) a method of destructive thermal decomposition of some intercalated in graphite compounds based on polyfluoride carbon; 2) plasma jet method, based on the pyrolysis of carbon-containing materials in a DC plasma torch; 3) the method of chemical vapor deposition.</p><p>The conventional experimental techniques will be used for the identification and the characterization of the synthesized nanostructures (X-ray diffraction, thermogravimetry, electron microscopy, Raman spectroscopy, etc.).</p><p>For obtaining the project research results, the following will be used: 1) the unique technology of hydrogenation of carbon materials and nanomaterials in a gas at a pressure of molecular hydrogen up to 30 MPa and temperatures up to 870 K, as well as the technology of hydrogenation by superthermal hydrogen atoms; 2) methods of thermogravimetric analysis and thermal desorption analysis (with using the original developments [<xref ref-type="bibr" rid="scirp.78102-ref18">18</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref19">19</xref>] ) of hydrogenated materials and nanomaterials; 3) approaches and methods [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] - [<xref ref-type="bibr" rid="scirp.78102-ref19">19</xref>] of thermodynamic analysis of the experimental data obtained by the project participants, and comparison of the test results with the related theoretical and experimental data of other researchers to reveal the atomic mechanisms of the hydrogensorption and intercalation processes.</p><p>By using these methods, it will be determined the thermodynamic characteristics of hydrogen sorption (hydrogen concentrations, the equilibrium constants, the standard enthalpy changes, the activation volumes, the rate constants, the activation energies) and disclosed the atomic mechanisms of sorption for different hydrogen states in the expanded graphite (the first time) and graphene materials.</p><p>The further research of the physics [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] of intercalation of the solid, liquid or gaseous molecular hydrogen of a high density in the carbon nanostructures will be held.</p><p>At the first time, the experimental study of the possibility of intercalation of the high-density molecular hydrogen in compacted expanded graphite and multilayer graphene will be held.</p><p>The development of prospects of the advance technology of effective and safe storage of intercalated high density hydrogen in carbon nanomaterials and their urgent in the field of hydrogen energy applications will be determined.</p></sec><sec id="s6"><title>6. Conclusion</title><p>There are reasons, including [<xref ref-type="bibr" rid="scirp.78102-ref13">13</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref25">25</xref>] study results, to attract attention of General Motors, Toyota and/or other large car companies to a real possibility of developing and using, in the nearest future, of the break-through hydrogen on- board storage technology (<xref ref-type="fig" rid="fig1">Figure 1</xref> and <xref ref-type="fig" rid="fig2">Figure 2</xref>).</p><p>The further studies of the physics [<xref ref-type="bibr" rid="scirp.78102-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.78102-ref17">17</xref>] of such a possible unique technology are expedient, may be, within the project International cooperation.</p></sec><sec id="s7"><title>Cite this paper</title><p>Nechaev, Yu.S., Makotchenko, V.G., Shavelkina, M.B., Ne- chaev, M.Yu., Veziroglu, A. and Veziroglu, T.N. (2017) Comparing of Hydrogen On- Board Storage by the Largest Car Companies, Relevance to Prospects for More Efficient Technologies. Open Journal of Energy Efficiency, 6, 73-79. https://doi.org/10.4236/ojee.2017.63005</p></sec></body><back><ref-list><title>References</title><ref id="scirp.78102-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">CHFCA Weekly Fuel (2016) News, GM Marks 50 Years of Fuel Cell Research. CHFCA Weekly Fuel, Vancouver.</mixed-citation></ref><ref id="scirp.78102-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Muoio, D. (2016) 8 Hydrogen-Powered Cars in the Works Right Now. CHFCA Weekly Fuel, Vancouver.</mixed-citation></ref><ref id="scirp.78102-ref3"><label>3</label><mixed-citation publication-type="other" xlink:type="simple">Posluszny, R. (2015) What It’s Really Like Driving a Hydrogen Fuel Cell Car. The Toyota Mirai Is Full of Surprises. 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