Several scholars visited Santorini (Figure 1(a)) in Greece in the 1870s to study the eruptions on Nea Kameni. Among them was the French geologist Ferdinand

Fouqué [1] . He showed that there are two prominent pumice layers on Santorini which he named ponce inferieure and ponce superieure―the Lower Pumice Series (LPS) and the Upper Pumice Series (UPS). He shows the LPS as a continuous layer that underlies other (apparently younger) volcanic rocks on Santorini. The LPS and UPS are similar in their general appearance, but seemingly had different ages. Figure 1(a) summarises the theme of our paper: Are the two pu- mice layers identical or not?

The LBA eruption started with precursory activity, followed by air-fall, base surge and pyroclastic flows. The phases, deposits, and effects of the LBA eruption are described in detail elsewhere [2] [3] [4] . A direct and precise date is now available based on radiocarbon analyses of two olive trees that were buried alive in the pumice of this eruption (1613 ± 13 cal. y BC based on the first olive tree) [5] [6] [7] . This date is about 100 years younger than the conventional archaeological date [6] . The strength of the eruption is a topic of discussion; it is considered to have been the most violent known eruption in the past 10,000 years [8] .

The tephra of the first phase of the LBA eruption covers the tops of Thera, Therasia and Aspronisi of the Santorini volcanic island group. The wind mostly carried it in a south-easterly direction where it today provides an important marker horizon for geologists and archaeologists. The tephra has been found both in deep-sea cores and on land in Anatolia, the eastern part of Crete, and partly also in the Levant and in Northern Egypt [9] [10] [11] [12] [13] .

According to Fouqué and later scholars this pumice series (Figure 2) only appears on the lowermost parts of the caldera wall on Thera, more specifically in the lower part of the caldera wall at Oia and between Fira and Cape Akrotiri. In the following, we argue that the LPS and UPS are essentially the same layer. However, a recent study claims to have found the LPS on the island of Anaphi, which lies about 30 km east of Santorini [14] .

Fouqué (1879:206) depicted both pumice layers in a diagram showing Cape Alonaki on the caldera wall of Thera. Furthermore, he extrapolated from the angle of outer slopes of the volcanic edifice that the central part of the Santorini ring island had a height of about 450 meters. He considered that the caldera was created when the volcanic island exploded around 2000 BC. This concept was adopted by generations of geologists for the next 120 years and the two pumice layers were considered to be the products of separate eruptions at the beginning and end of a magmatic cycle, as will be shown below.

In 1936 Neumann van Padang [15] presented a detailed description of the geology of Santorini, including the above-mentioned pumice layers from the caldera wall of Thera. He followed Fouqué and concluded that the UPS and LPS were similar, but different, layers that occurred at distinct levels on the caldera wall. He considered that they were deposited by two strong eruptions, each of which produced thick pumice layers and triggered events of caldera formation.

When deep-sea cores of the Eastern Mediterranean became available, Nin- kovich and Heezen [16] identified the LPS and UPS from Santorini. Based on the enormous distribution area of the LPS in the Eastern Mediterranean, it was concluded that this eruption must have been bigger than that which produced the UPS. However, in 1985 A. Vinci [17] showed that the so-called LPS ash in deep-sea cores from the Eastern Mediterranean was not derived from Santorini but had a Campanian source.

Pichler and Kussmaul [18] mapped Santorini in 1969-1970 and, concerning the LPS, mainly followed the work of Neumann van Padang. Furthermore, they divided the LPS into LPS1 and LPS2 that they considered came from two different vents emptying the same magma chamber. Ice core signals in the Greenland ice sheet were detected in 1987 and resulted in an age of 1645 ± 7 years for the LBA eruption [19] . Sparks and Wilson [20] presented a review of the LBA eruption deposits in 1990.

A study by Vitaliano et al. [21] showed that the chemical compositions of the UPS and LPS could not be distinguished in various geochemical diagrams. However, Druitt et al.’s comparison of LPS1 and LPS2 showed that their chemical compositions lie in the range of the LBA eruption, but at either end of that range [22] . Radiometric ages for LPS1 and LPS2 were presented (K-Ar dating): 203 ± 24 ka for LPS1 and 180 ka for LPS2. The age of LPS1 is based on obsidian in a welded ignimbrite below Oia.

Heiken and McCoy [23] offered a graphic portrayal of the island before the LBA eruption. Based on fission track analyses of the LPS, Seward et al. [24] calculated an age of 100,000 years. Since 1985 the discussion has focused on the strength of the LBA eruption since underwater investigations around Santorini had revealed more pyroclastic deposits on the sea floor than expected. The strength of the LBA eruption therefore increased in the literature [25] .

A study of about 1450 calcareous blocks of stromatolites from the Santorini volcano was performed by Eriksen [26] . The stromatolitic blocks had been ejected in the third phase of the LBA eruption. Radiocarbon dating showed that it was possible that they had formed their build-ups in shallow seawater near the later eruption crater inside the water-filled caldera 12,000 years before the LBA eruption. This analysis of the stromatolites proved that the Santorini caldera existed prior to this eruption.

Druitt and Francaviglia [27] demonstrated that pumice on the caldera wall of the LBA eruption dips down towards the caldera, confirming the existence of an earlier caldera.

In 1999 Druitt et al. [22] adopted the ideas of Neumann van Padang that the two pumice series triggered two calderas. They argued for a magmatic megacycle with a time interval of 200,000 years when identical eruption series were created.

Since the 1970s, three of us have been working on Santorini, amongst other places in the now abandoned pumice quarries on Thera and Therasia. Even though the number of good field sites is rapidly decreasing on Santorini due to human activities, it is still possible to get important geological information from the steep walls of the caldera. Modern tools like GIS and GPS are also very useful [27] . From decades of fieldwork and research on the geology of Santorini, we have found that it is necessary to make some general changes in geological interpretations, as we show below.

Concentric terraces are closely related to the formation of a caldera. The latter is a volcano-tectonic collapse structure that is commonly sub-circular and funnel shaped. After a strong eruption, when the magma chamber is emptied and the roof of the chamber cannot stand the weight of the overlying material, it sometimes collapses. After the main collapse the caldera wall is unstable for a long time and erosion and down-sliding effect material on the wall. For example, a lava is more durable than tuff and terraces form on the upper surfaces of the more resistant layers.

For Santorini, it could have been the Cape Riva Eruption (around 21,000 years ago) that formed a caldera with concentric terraces on its wall, like those at Cape Alonaki on Thera (Figure 2). Concentric terraces were also recently discovered on the caldera wall above Balos harbour. This observation, together with the rediscovery of a Cycladic house [28] that had been buried under the pumice of the LBA eruption, clearly indicates that there is no Lower Pumice Series material here.

Volcano-tectonic forces on the Akrotiri Peninsula had lifted the marine sediments to a height of 200 m. The uplifted part of it contains marine fossils of Plio-Pleistocene age [29] . The peninsula has an in-situ cover of the UPS, whereas the steep slopes are covered by material of the LBA eruption that is resting on narrow terraces which can be followed for several kilometres along the caldera wall of Thera. The volcanic deposits have been partly reworked on the inner side of the caldera. During the surge phase of the eruption pumice was plastered against the steep slope of the caldera wall and subsequently slid down and came to rest on the natural terraces of the old caldera wall.

Due to mining activity (ca. 1850-1900 AD) above Balos harbour where the Cycladic house was found, most of the pumice mantle has been removed, including the ruins of the house. However, the characteristic platform on top of the thick lava is still visible.

Neumann van Padang tried to find the excavation site in 1936 but did not succeed. In a profile he shows “Bu” at a height of 67 m; “Bu” means LPS. Geological maps by later scholars also show LPS in this area.

However, in 2009 we rediscovered the platform where a house with three rooms stood prior to the LBA eruption [30] . We used satellite images together with information provided by the French scientists to find the location. A platform at 62 m above sea level fitted perfectly with the description. Even the original thickness (22 m) of pumice that buried the house with the three rooms is visible on the caldera wall below Mount Loumaravi.

The up to 60 m thick pumice layers below Fira (Figure 3) have the same overall appearance, the same sequence and the same erosional pattern as the UPS in the

nearby Fira quarry. In this quarry there are faults which show that tectonic movements played a role in their development and current position on the caldera wall. In the abandoned pumice quarries near Fira there is an abrupt shift from the lower to the upper products of the LBA eruption. The lowermost part of the UPS is in direct contact with the upper part of the so-called LPS (Figure 4 and Figure 5).

In May 1978, WLF [31] found a black patch of charcoal powder in the Karageorghis quarry that had been lying directly under the pumice of the LBA eruption. At first it seemed that this was a heap of branches that a bulldozer had recently crushed, as indicated by the course of bulldozer tracks. A sample of this material was radiocarbon dated, providing a calibrated age of 1700 BC corresponding to other radiocarbon dates of the LBA eruption from Santorini in the 1970s. However, in 2008 the driver of that bulldozer informed WLF that the black powder came from an in situ standing tree which had been destroyed during the mining process. Furthermore, we found ceramic items of Cycladic origin―a closed painted vessel and a larger open unpainted vessel―inside the Karageorghis quarry at a level below that of the destroyed tree. Here the UPS rested on a down-faulted terrace (Figure 6). The late archaeologist Charalambos Sigalas excavated this site. He informed us that human bones and skulls had been found

there. This area was therefore possibly used as a cemetery in the Bronze Age. The radiocarbon dated tree and the pottery show that the two sections of the profile in this quarry have the same age as the LBA eruption.

The quarry shows, on a small scale, how we could interpret the settings on the nearby caldera wall. In the quarry the radiocarbon date of the tree in the upper part of Figure 6 and the Cycladic age of the lower part show that the pumice of the LBA eruption was deposited on stepwise arranged terraces. Both parts have the same age and belong to the LBA eruption.

The thick pumice layer at Ammoudi, below Oia, which existed before mining started in the second half of the 19th century, belongs to the LBA eruption and not to the LPS, as testified by pottery shards and obsidian tools found below the pumice.

During fieldwork around Oia in 1987, Ulrike Eriksen observed painted pottery [32] under the UPS of the LBA eruption on the caldera wall below Megalo Vouno. It was at the same height on the caldera wall as where Heiken and McCoy [23] had seen deeply weathered rock, indicating that there was an old caldera wall here. The above-mentioned pottery shows that the UPS here was deposited on the inner side of the caldera wall.

In order to obtain data about the horizontal distribution of the so-called LPS we searched for all kinds of information. We know that the LPS was not observed [33] at three drill sites of the Greek Institute of Geology and Mineral Exploration on Thera (Athinios, Aghia Anna and Megalochori (Figure 1(b); letters A-C)).

The people who lived on Thera and Therasia 3600 years ago might have had access to a pumice deposit. Pumice was―and still is―a valuable tool for polishing and grinding purposes. Moreover, it is an excellent material in which to excavate caves (Figure 7). We therefore tried to investigate geological and archaeological sites where the Bronze Age surface is accessible and contacted the scholars who excavated these sites (Figure 1(b); 1 - 19), but no traces of LPS were found.

The discovery of two olive trees buried alive by the pumice of the LBA eruption gave us not only the possibility of dating the eruption directly and precisely, but also the idea of studying the soil―the cultivated field in which the trees grew. A several meters thick weathered tuff is exposed at this site (Figure 1(b); 8). The highest part consists of a ca. 30 cm thick layer with clear traces of human activity―ploughing, small fragments of ceramics and obsidian, and decayed plant material in the form of moulds of roots and twigs. Here we searched especially for lumps of pumice, but none were found in the several hundred meters long outcrop.

According to C. Doumas (director of the Akrotiri excavation) “isolated artefacts made of pumice” (pers. comm. Oct. 2015) older than the LBA eruption have

been found in the Akrotiri excavation. We think that this pumice most probably came from Santorini itself, where several pumice layers are present in the caldera wall which was accessible in the Bronze Age.

The pumice used by the Thereans could be from, for example, the Cape Riva ignimbrite that outcrops in the Akrotiri excavation where houses are built partly on top of this ignimbrite and at “pillar 17” where it forms a clear edge. Furthermore, this welded ignimbrite is also exposed in the nearby Potamos Kamaras valley and the Mavromatis quarry (Figure 1(b); 12) on Thera where rounded lumps of pumice up to 20 cm in diameter have been baked into the base of the welded ignimbrite. This site is quite close to an archaeological site where Cycladic houses of the Bronze Age were excavated [19] . In addition, the Phtellos excavation [34] near Fira shows no trace of an accessible major pumice layer.

Only a few hundred meters from the Cycladic house which had been excavated by Gorceix and Mamet in 1874 we observed that 10 caves were dug into the soft pumice of the first eruption phase of the LBA eruption. When we studied the caldera wall in detail it became evident that the same LBA eruption products were repeated three times on the caldera wall above Balos harbour, indicating that the pumice and ash of the LBA eruption had mantled the entire volcanic edifice, including the inner side of the caldera. Erosion has removed most of it but remnants are still visible where concentric terraces existed on the wall. The caves of a former monastery above Balos harbour were dug into the pumice of the LBA eruption that is resting on a narrow concentric terrace. They all have a horizontal depth of about 4.5 meters where the cave diggers met the hard rock of the marine block of the Akrotiri Peninsula (Figure 7). The system of concentric terraces could be used as roads and shelter for the inhabitants of the pre-LBA eruption ring-island.

One could argue that the LPS was locally eroded away prior to the LBA eruption, but it has not been found in drillings or at excavation sites. Furthermore, the so-called LPS deposits in deep-sea drillings are not from Santorini. Archaeological evidence of Cycladic objects at several localities under the so-called LPS proves that these objects were buried by the LBA eruption and not by an older layer of pumice some 200,000 years ago. Its products were partly deposited on the inner side of the commonly steeply sloping caldera wall. The topography, slumping and later erosion led to difficulties in interpreting the local stratigraphy.

A water-filled caldera existed at Santorini before the LBA eruption. The LBA pumice draped the entire landscape and was thickest on terraces on the caldera wall (Figure 2(d)). After erosion, pumice remained on terraces at distinct levels (Figure 7). Pumice on two major terraces was interpreted as being formed by separate explosive volcanic eruptions 200,000 years apart, but in fact were both part of the same LBA eruptive event. Study of the caldera wall and localities on Thera suggests that the LPS does not exist and the magmatic cycle theory is consequently invalid. The pumice below Fira was deposited on the inner side of an existing caldera during the LBA eruption. The caldera wall, consisting of lavas and pyroclastic layers, was intersected by radial and concentric faults. We deduce this from small eruption points arranged in curved tectonic lines which predate the LBA eruption. Tectonic events gave rise to curved terraces and niches on the caldera wall upon which the products of the LBA eruption were depo- sited. These deposits have been partly reworked by down-sliding since they contain xenoliths of older pyroclastic material, such as dark lapilli from the older Upper Scoria Series. This can possibly also explain the old radiometric data obtained for the LPS and its slightly darker colour. The locality below Oia where Druitt [21] sampled is an isolated occurrence of welded pumice which could be a relic of an old intra-caldera volcano.

One could argue that the LPS was locally eroded away prior to deposition of the LBA eruption, but it has not been found in drillings or at excavation sites. Furthermore, the so-called LPS deposits in deepsea drillings are not from San- torini. Archaeological evidence of Cycladic objects at several localities under the so-called LPS proves that these objects were buried by the LBA eruption and not by an older layer of pumice. Rediscovery of an old excavation site at Balos helped us to solve a 150 years old enigma: both the so-called LPS and the UPS were deposited by the same LBA eruption around 1613 BC. Its products were partly deposited on the inner side of the commonly steeply sloping caldera wall. The topography, slumping and later erosion led to difficulties in interpreting the local stratigraphy.

We thank Michael and Jeppe Lykke Friedrich for help with the fieldwork and Giorgios Nomikos for logistic assistance. Grethe Storgaard assisted with drawings.

All the authors performed fieldwork and discussed the manuscript equally. A.H.S. contributed with archaeological research. M.F. provided drill data. W.L.F., A.H.S. and J.R.W. wrote the manuscript.

Friedrich, W.L., Sørensen, A.H., Wilson, J.R., Fytikas, M., Pavlides, S. and Katsipis, S. (2017) A Major Change in the Stratigraphy of the Santorini Volcano in Greece. International Journal of Geosciences, 8, 767-780. https://doi.org/10.4236/ijg.2017.86043