<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">IJG</journal-id><journal-title-group><journal-title>International Journal of Geosciences</journal-title></journal-title-group><issn pub-type="epub">2156-8359</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/ijg.2017.82008</article-id><article-id pub-id-type="publisher-id">IJG-74248</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Earth&amp;Environmental Sciences</subject></subj-group></article-categories><title-group><article-title>
 
 
  Structural Control of Auriferous Mineralization in the Birimian: Case of the Agbahou Deposit in the Region of Divo, C&amp;ocirc;te d’Ivoire
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>N’Guessan</surname><given-names>Nestor Houssou</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Marc</surname><given-names>Ephrem Allialy</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Fossou</surname><given-names>Jean-Luc Hervé Kouadio</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Allou</surname><given-names>Gnanzou</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Geology of Basement and Metallogeny Laboratory (GBML), Training and Research Unit of Earth Sciences and Mining Re-sources, University of Felix HOUPHOUET-BOIGNY, Abidjan-Cocody, Cote d’Ivoire</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>nestor.houssou@gmail.com(NNH)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>09</day><month>02</month><year>2017</year></pub-date><volume>08</volume><issue>02</issue><fpage>189</fpage><lpage>204</lpage><history><date date-type="received"><day>December</day>	<month>16,</month>	<year>2016</year></date><date date-type="rev-recd"><day>Accepted:</day>	<month>February</month>	<year>18,</year>	</date><date date-type="accepted"><day>February</day>	<month>21,</month>	<year>2017</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  Located in the southwestern of the Oume-Fettekro greenstone belt, the Agbahou gold deposit is controlled by structural factors. Geophysics, teledetection and core data suggest the presence of NE and NW faults. However, the NE-faults define two major shear zones (ATZ: Agbahou Tectonic Zone and WTZ: West Tectonic Zone) that control the Agbahou gold mineralization. These first order structures are subparallel to the regional tectonic grain mostly north-east oriented. They seem to respectively develop on the both arms (eastern and western) of an anticline moderately plunging ~25
  &#176; towards northeast. Each shear-zone contains several second-order shear-zones or lenses of variable direction and of 50
  &#176; - 80
  &#176; dip. NW-faults however correspond to strike-slip faults and their development should be related to transcurrent tectonics. They acted as control channels on the distribution of gold mineralizations. The ductile-brittle character of shear-zones favored the ascent of hydrothermal fluids and the formation of multiple auriferous quartz veins: veins Type IIa and veins Type IIb relating respectively to the shear-veins and extensional veins. However, Agbahou also shows the existence of a disseminated sulphides-bearing mineralization within host-rocks. At Agbahou, the precipitation of gold probably occurred in a post to late ductile-brittle deformation period.
 
</p></abstract><kwd-group><kwd>Gold-Bearing Mineralization</kwd><kwd> Structural Control</kwd><kwd> Birimian</kwd><kwd> Agbahou</kwd><kwd> Ivory Coast</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>The shear zones associated with birimian greenstone belts in West Africa (Hein et al., 2004 [<xref ref-type="bibr" rid="scirp.74248-ref1">1</xref>] , Hein, 2010 [<xref ref-type="bibr" rid="scirp.74248-ref2">2</xref>] , Feybesse et al., 2006 [<xref ref-type="bibr" rid="scirp.74248-ref3">3</xref>] , Tshibubudze et al., 2009 [<xref ref-type="bibr" rid="scirp.74248-ref4">4</xref>] , Lompo, 2010 [<xref ref-type="bibr" rid="scirp.74248-ref5">5</xref>] ; Baratoux et al., 2011 [<xref ref-type="bibr" rid="scirp.74248-ref6">6</xref>] , Perrouty et al., 2012 [<xref ref-type="bibr" rid="scirp.74248-ref7">7</xref>] , etc.) have become the major structural elements that receive special attention in the search for gold mineralization. Most gold mining sites, as well as gold deposits and deposits in exploration or exploitation, seem to be aligned with these me- gastructures. In C&#244;te d’Ivoire, the shear zones show an NE to ENE orientation and develop either inside the greenstone belts or in the contacts of these with the plutonites.</p><p>The Agbahou gold deposit is characterized by NE and NW lineaments, highlighted by geophysical data and remote sensing (Gillick, 2001 [<xref ref-type="bibr" rid="scirp.74248-ref8">8</xref>] , Houssou, 2013 [<xref ref-type="bibr" rid="scirp.74248-ref9">9</xref>] ). These lineaments have never been studied directly because of the scarcity of rock outcrops and the lack of depth work (drillholes). Recent exploration works done by BHP Minerals, Jandera (GoldIvoire), Etruscan Resources and then Endeavor Mining, including pits, trenches and drillholes, provided further details on the lithostructural context of this gold mineralization. The bidirectionality of lineaments is probably at the origin of a polyphase deformation that has generated several generations of quartz veins. Tshibubudze and Hein (2013) [<xref ref-type="bibr" rid="scirp.74248-ref10">10</xref>] have demonstrated such quartz veins intimately associated with the junction of NE and NW lineaments in the Essakane gold deposit in Burkina Faso. Their work made it possible to classify these quartz veins and then establish a relationship between them and gold mineralization.</p><p>Around Agbahou, several gold mineralizations are under exploration or exploitation (Bonikro, Akissi-So, Assondji-So, Agbal&#233;, M’bazo, etc.). This region seems to be potentially rich in gold mineralizations. However, the almost total absence of outcrops and the lack of the depth work in the region have not led to make a real lithostructural study. Our work, mainly based on core drilling, is therefore a contribution to the improvement of the geological knowledge on the birimian belts and the associated gold mineralizations. The major contributions includes: 1) the precision of the nature of birimian greenstone belts in an area of deep superficial coverage; 2) the highlighting of structural factors controlling mineralizations of Agbahou.</p><p>In our study, we will present the results of our field investigations into the lithostructural control of gold mineralization in the Agbahou deposit. Particular emphasis will be placed on the types of deformation, geometric features controlling gold mineralization and their implication for mineral exploration in West Africa.</p></sec><sec id="s2"><title>2. Geological Context</title><p>The Agbahou gold deposit is located at about 230 km at the NW of Abidjan (C&#244;te d’Ivoire), in other words, 20 km by bird flight from the Bonikro gold deposit (<xref ref-type="fig" rid="fig1">Figure 1</xref>). The region of Agbahou belongs to the Proterozoic domain of Cote d’Ivoire, separated from the Archean domain by the fault of Sassandra (Bessoles, 1977 [<xref ref-type="bibr" rid="scirp.74248-ref11">11</xref>] ). According to Pothin et al. (2000) [<xref ref-type="bibr" rid="scirp.74248-ref12">12</xref>] , this Precambrian basement was structured between 3450 and 1026 Ma. Indeed, the Archean domain</p><fig id="fig1"  position="float"><label><xref ref-type="fig" rid="fig1">Figure 1</xref></label><caption><title> Simplified geological map of the West African craton with some mines and gold deposits, and the location of the Agbahou deposit (Map redesigned from Milesi et al., 1992 [<xref ref-type="bibr" rid="scirp.74248-ref13">13</xref>] )</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-2801385x2.png"/></fig><p>or Kenema-Man domain was structured by the Leonian (3500 - 2900 Ma) and Liberian (2900 - 2500 Ma) orogenies. The structuring of the Proterozoic domain or Baoul&#233;-Mossi domain on the other hand is still a subject for discussion. For some authors (Tagini, 1971 [<xref ref-type="bibr" rid="scirp.74248-ref14">14</xref>] , Yace, 1993 [<xref ref-type="bibr" rid="scirp.74248-ref15">15</xref>] ), the structuring took place during a single orogeny, the Eburnean (2500 - 1600 Ma), while others (Lemoine, 1988 [<xref ref-type="bibr" rid="scirp.74248-ref16">16</xref>] , Boher, 1991 [<xref ref-type="bibr" rid="scirp.74248-ref17">17</xref>] ) support an establishment during two orogenies, the Burkinian (2400 - 2150 Ma) and the Eburnean (ss) (2120 - 1800 Ma).</p><p>The Proterozoic domain of Cote d’Ivoire is marked by a predominance of felsic rocks and an epi to mesozonal metamorphism. It is subdivided according to Papon (1973) [<xref ref-type="bibr" rid="scirp.74248-ref18">18</xref>] into two distinct zones: the SASCA type zone located in the southwest of the country where the Archean formations are well preserved and the zone of geosynclinal type which occupies the rest of the domain. The formations of this second zone are attributed to the Birimian (Arnould, 1961 [<xref ref-type="bibr" rid="scirp.74248-ref19">19</xref>] , Bonhomme, 1962 [<xref ref-type="bibr" rid="scirp.74248-ref20">20</xref>] ). They are in the form of volcano sedimentary and plutonic belts generally oriented NE-SW and intruded by massive or oriented grani- toid (<xref ref-type="fig" rid="fig1">Figure 1</xref>).</p><p>The auriferous mineralizations of Agbahou, Bonikro, Angovia, Afema, Tongon, Tengrela, etc., are located in the Proterozoic domain. As for the auriferous mineralization of Ity, it is located in the Toul&#233;pleu-Ity belt at the age of Birimian (Feybesse and Mil&#233;si, 1994 [<xref ref-type="bibr" rid="scirp.74248-ref21">21</xref>] , Feybesse et al., 1990 [<xref ref-type="bibr" rid="scirp.74248-ref22">22</xref>] ) in the Archean domain (<xref ref-type="fig" rid="fig1">Figure 1</xref>).</p><p>The geology of the Oume-Fettekro belt, to which the Agbahou deposit belongs, is known from the works of Yace (1982) [<xref ref-type="bibr" rid="scirp.74248-ref23">23</xref>] , Lemoine (1988) [<xref ref-type="bibr" rid="scirp.74248-ref16">16</xref>] , Mortimer (1990) [<xref ref-type="bibr" rid="scirp.74248-ref24">24</xref>] , Leake (1992) [<xref ref-type="bibr" rid="scirp.74248-ref25">25</xref>] , Daouda (1998) [<xref ref-type="bibr" rid="scirp.74248-ref26">26</xref>] , Houssou (2013) [<xref ref-type="bibr" rid="scirp.74248-ref9">9</xref>] , Ouattara Z. (2015) [<xref ref-type="bibr" rid="scirp.74248-ref27">27</xref>] , Ouattara Z., et al. (2015) [<xref ref-type="bibr" rid="scirp.74248-ref28">28</xref>] , etc. It is formed by a greenstone belt oriented NE-SW to NNE-SSW and delimited by recent granitoid. According to Yace (1982) [<xref ref-type="bibr" rid="scirp.74248-ref23">23</xref>] , these birimian formations are formed by schists and quartzites in the midst of which large lenses of volcano-sedi- mentary rocks appear, some of which may be in synclinal or anticlinal positions.</p><p>At the scale of the Agbahou gold deposit, geology is defined by two major lithological units of birimian age intersected by dyke formations: a mafic to intermediate volcanic unit (basalt-andesite) and a volcano-sedimentary unit and associated sediments (<xref ref-type="fig" rid="fig2">Figure 2</xref>). This second unit consists of tuff type pyroclastites (mafic and felsic) and metasediments (sandstone, siltstone and shale).</p><p>These formations, except the dykes, are generally deformed and metamorphosed in the green schist to amphibolite facies. They occur in the form of meta- basalts, meta-andesites, schists (chloritoschists, calcochloritoschists and sericito- schists), amphibolites, mylonites and breccias. The dyke formations are basic to intermediate and acid. The formers appear to be subparallel to schistosity and correspond to microdiorites and microgabbros. The laters, the felsites, formed of rhyolite and rhyodacite intersect the schistosity and show frank contacts with their host rocks, the metabasites.</p><fig id="fig2"  position="float"><label><xref ref-type="fig" rid="fig2">Figure 2</xref></label><caption><title> Agbahou Mine Lithostructural Map (Lieben F., et al., 2015, in: Mian, J., 2015 [<xref ref-type="bibr" rid="scirp.74248-ref29">29</xref>] )</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-2801385x3.png"/></fig></sec><sec id="s3"><title>3. Material and Methods</title><p>Our works are mainly based on the analysis of cores and the interpretation of data. This analysis consists of the cores logging including lithologies and structures description, the measurement of direction and dip or dip-direction of structural features, the selection of samples from different lithologies and mineralizations, the confection of thin sections and their microscopic study.</p><p>The description of cores takes into account the intervals of lithological facies and mineralization, their mineralogical composition, the alteration minerals, the sulphides and their proportions, the deformation gradient, the structures, the presence of quartz veins, the weathering profiles and oxidation levels.</p><p>Several thin sections (51 in total) of rock and ore samples were made at the University of Accra, Ghana. They were observed with a polarizing microscope in the Laboratory of Geology of the Basement and Metallogeny (LGSM) of Felix Houphouet-Boigny University, Abidjan in Cote d’Ivoire. This microscopic study made it possible to determine the mineralogical assemblages of lithologies, quartz veins and their walls, and to reveal microstructures (schistosities, folds, etc.).</p></sec><sec id="s4"><title>4. Structural Context of Mineralization</title><p>The Agbahou region experienced significant deformation phenomena, the magnitude of which was revealed by geophysical data (Gillick, 2001) [<xref ref-type="bibr" rid="scirp.74248-ref8">8</xref>] , remote sensing (Houssou, 2013) [<xref ref-type="bibr" rid="scirp.74248-ref9">9</xref>] , drilling cores (Tourigny, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref30">30</xref>] , Tourigny and Houssou, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] , Houssou, 2013 [<xref ref-type="bibr" rid="scirp.74248-ref9">9</xref>] ) and mine pits. These data suggest the existence of a regional tectonic grain parallel to the NE birimian direction and major faults. We distinguish two families of faults: NE faults and NW faults. The NE dislocations correspond to shear zones, the principal of which is called the Agbahou Tectonic Zone (ATZ). It is a first order megastructure, estimated at more than 300 m wide and 2 km long (Tourigny, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref30">30</xref>] ). A second Tectonic Zone (WTZ) was also highlighted in the Western area. These tectonic zones appear subparallel or intersect at narrow angles the penetrative schistosity S1 oriented NE-SW. The NW dislocations, on the other hand, which appear to be more recent, intersect or simply shift the previous structures.</p><p>In fact, the schistosity S1 is the most common fabric in the volcanic and volcano-sedimentary formations of the Agbahou deposit (Tourigny, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref30">30</xref>] ). It affects and obliterates the bedding S0. In metatuffs and metapelites, S0 is the oldest preserved structure. It is expressed by an alternation of centimetric to decimetric levels. The schistosity S1 is penetrative in most formations. S1 is expressed on the one hand by the preferential orientation of phyllite minerals (chlorite, sericite) and carbonates (calcite, dolomite and ankerite) in the hydrothermally altered formations and on the other hand by the flattening of the minerals or clasts in metapyroclastites. S1 is in large part responsible for the tectonic grain of the district and for the spatial distribution of lithologies. At the microscopic scale, schistosity S1 is expressed by an alternation of bands of quartz- calcite and chlorite-epidote &#177; biotite &#177; sericite in metabasalts and orthoschists or sericite-biotite &#177; chlorite in metatuffs, metapelites and paraschists (<xref ref-type="fig" rid="fig3">Figure 3</xref>(a)). S1 schistosity-parallel calcite veinlets are abundant and show evidence of boudinage and pinch and swell structures.</p><p>This S1 schistosity is rarely observed because the drillholes are located at the heart of the shear zone; the shear zone being dominated by a local schistosity or mylonitic schistosity (Sm) more intense as suggested by Bourges et al. (1998) [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] . This schistosity strongly obliterated the regional schistosity S1. S1 and Sm show sometimes similar directions or make small angles between them (<xref ref-type="fig" rid="fig2">Figure 2</xref>). They generally follow the Birimian north-east direction with a dip of 50˚ to 60˚ to the southeast. However, in the flexure zones of the shear zones, they become north-west or north-south and steeply dipping of the order of 70˚. Stretching lineations rarely observed in cores indicate the presence of a possible inverse fault movement (Eisenlohr, 1998 [<xref ref-type="bibr" rid="scirp.74248-ref32">32</xref>] ).</p><p>Deformed rocks often exhibit small-scale crenulation schistosities (<xref ref-type="fig" rid="fig3">Figure 3</xref>(a) and <xref ref-type="fig" rid="fig3">Figure 3</xref>(b)). This crenulation S2 is characterized by microfolds which intersect and redirect S0 and S1. These microfolds are parallel with vertical to subvertical axial planes, tight to isoclinal (<xref ref-type="fig" rid="fig3">Figure 3</xref>(b)). The axes of microfolds seem to orient NS to NNW with wavelengths of around 5 cm and amplitudes of 3 cm (Tourigny, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref30">30</xref>] ). S2 corresponds to a phase of ductile deformation less intense than that at the origin of the main schistosity.</p><p>In the sedimentary rocks, the shear zones are often characterized by transposition phenomena of narrow black shale panels (<xref ref-type="fig" rid="fig3">Figure 3</xref>(c)).</p><p>At Agbahou, the folds are rather rare; only a few asymmetric folds and intra- foliar folds were observed in drill cores. Their axial planes are generally subparallel to the axial plan of the schistosity S1. Unlikely to folds, the fractures are common. The host rocks appear to be much fractured and form groundwater reservoirs. Under the microscope, micro-fractures are generally filled with</p><fig id="fig3"  position="float"><label><xref ref-type="fig" rid="fig3">Figure 3</xref></label><caption><title> Crenulation schistosities and transposition. (a) Crenulation schistosity S2 undulating the schistosity S1 in a quartz (Qtz) and chlorite (Chl)-rich tectonite. (b) Planar surfaces S0 and S1 crenulated in the hinge of a major fold. (c) Transposition structure (black arrow) with a tectonic band parallel to the schistosity S1</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-2801385x4.png"/></fig><p>quartz, calcite and pyrite minerals. The formation of these fractures was probably due to a post-to-late-tectonic hydraulic fracturing accompanied by a rise in fluids.</p></sec><sec id="s5"><title>5. Geometrie of Mineralisation of Gold</title><sec id="s5_1"><title>5.1. Shear Zones</title><p>Agbahou gold mineralization appears to be largely controlled by two major Tectonic Zones: ATZ (Agbahou Tectonic Zone) and WTZ (West Tectonic Zone) (<xref ref-type="fig" rid="fig2">Figure 2</xref>). The ATZ is developed in the contact zone between a mafic volcanic sequence and a tuff-volcanoclastic sequence (Tourigny and Houssou, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] ); this contact being oriented NE to NNE and dip 40˚ - 60˚ SE. The WTZ, on the other hand, appears to be more developed in the mafic volcanic sequence and ends up further north in a sedimentary sequence. It starts in the south by an ENE direction and progressively evolves towards the north in a NNE direction. These main shear zones host several second-order ductile-brittle shear zones. They are posterior to the development of the regional S1 schistosity and carry multiple mineralized quartz veins.</p><p>The formations associated with the shear zones are mostly tectonoclasts or tectonic breccias (schists and mylonites) intensely altered (silicification, carbonation and sulphidation and to a lesser degree sericitization and chloritization). The shear schistosity Sm shows a more pronounced development than the regional schistosity S1. This Sm schistosity is generally subparallel to the mineralized lenses and shows an attitude similar to that of the regional schistosity S1. However, in the intensely deformed zones there is a rapid reorientation of the schistosity S1 with a strong angle with respect to the main shear zone.</p></sec><sec id="s5_2"><title>5.2. Mineralized Lenses</title><p>The mineralization of Agbahou contains mineralized lenses with multiple quartz veins or heavily sulphurous and gold-bearing zones. In plan (<xref ref-type="fig" rid="fig2">Figure 2</xref>), it is observed that the lenses generally follow the shear zones and evolve in NNE to NE or ENE direction (mainly in the west sector). In cross-section, the dips of the mineralized lenses are essentially southeast. In the northern sector, they are 40˚ - 60˚ SE or 60˚ - 70˚ SE dip. In the southern area, mineralization shows more gentle dips of the order of 35˚ - 50˚ SE. In the western sector, the dips of the mineralized lenses are around 35˚ - 45˚ SE. According to Tourigny and Houssou (2008) [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] , the different lenses are separated from each other by weakly mineralized panels where the ductile deformation appears more important than the hydraulic fracturing. In Agbahou, there are two main types of gold mineralization: the “quartz vein” type and the “pyrite” type associated with calcochloritoschists hosting pyrite and/or calcite veinlets parallel to the schistosity.</p></sec><sec id="s5_3"><title>5.3. Veins of Quartz</title><p>Several generations and categories of quartz veins have been highlighted in Agbahou. These veins are generally parallel or intersecting with schistosities. The mineralized quartz veins show a NE to NNE direction, but also ENE (sector West) with varying dips: 40˚ - 50˚ or 70˚ - 80˚ in the northern sector, 30˚ - 40˚ in the south and 30˚ - 60˚ in the western part. However, there are NW or EW directions with steep dips of 70˚ - 80˚ corresponding in general to measurements probably taken in zones of curvature of sheared veins.</p><p>The quartz veins associated with the Agbahou gold mineralization can be classified into three generations:</p><p>・ The first generation (I) comprises many quartz-carbonate veins and veinlets which are generally parallel to the S1 schistosity. They are found in strongly schistosed panels which are sometimes strongly sulphided, but weakly mineralized in gold. They show microfolds, boudinage and pinch and swell structures.</p><p>・ The second generation (II) consists of quartz veins which intersect with schistosities and host shear-zones. Gold is associated with quartz-calcite veins with or without tectonoclasts, and sometimes lesser amounts of pyrrhotite, pyrite, arsenopyrite and manganese oxides. The highly mineralized quartz veins are in zones of intense deformation which preferentially develop in the contact zones between the volcanic and sedimentary units.</p><p>・ The third generation (III) of quartz veins is undeformed and crosscuts all structures and even late acid dykes (rhyolite and rhyodacite). The gold contents of these veins are very low.</p><p>However, Agbahou gold mineralization is for the most part controlled by two families of second-generation quartz veins: type IIa veins and type IIb veins. According to Poulsen (1986) [<xref ref-type="bibr" rid="scirp.74248-ref33">33</xref>] and Robert and Brown (1986) [<xref ref-type="bibr" rid="scirp.74248-ref34">34</xref>] , the orientation, shape and structural elements of these veins have close geometric relationships with host shear-zones (<xref ref-type="fig" rid="fig4">Figure 4</xref>).</p><sec id="s5_3_1"><title>5.3.1. Quartz Veins of Type IIa</title><p>These are smoky quartz veins (<xref ref-type="fig" rid="fig5">Figure 5</xref>(a)). They develop in areas of strong brittle deformation. They are veins of lenticular shape which can have thickness</p><fig id="fig4"  position="float"><label><xref ref-type="fig" rid="fig4">Figure 4</xref></label><caption><title> Geometrical relations between shear-zones and quartz veins (Poulsen, 1986 [<xref ref-type="bibr" rid="scirp.74248-ref33">33</xref>] )</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-2801385x5.png"/></fig><p>of about ten meters. Geometrically, they are similar to the veins formed parallel to the shear zone (Poulsen, 1986 [<xref ref-type="bibr" rid="scirp.74248-ref33">33</xref>] , Robert and Brown, 1986 [<xref ref-type="bibr" rid="scirp.74248-ref34">34</xref>] , <xref ref-type="fig" rid="fig4">Figure 4</xref>). They have a massive appearance and do not contain fragments of host rocks but are bordered by visible alteration zones (silicification, carbonation, etc.). The veins IIa have a pegmatitic texture and are formed of quartz and plagioclases (<xref ref-type="fig" rid="fig5">Figure 5</xref>(b)). The quartz shows microfractures filled with sulphides (pyrite and pyrrhotite) and gold. The plagioclases contain inclusions of quartz, thus showing their posteriority to quartz. Type IIa veins show a low deformation gradient. However, their walls have undergone a higher gradient deformation. They correspond to syntectonic veins which have been placed in fractures associated with the ductile-brittle deformation.</p></sec><sec id="s5_3_2"><title>5.3.2. Quartz Veins of Type IIb</title><p>These are quartz veins mottled by the presence of tectonoclasts from the country rocks. These veins are similar to the extension veins (Poulsen 1986 [<xref ref-type="bibr" rid="scirp.74248-ref33">33</xref>] , Robert and Brown 1986 [<xref ref-type="bibr" rid="scirp.74248-ref34">34</xref>] , <xref ref-type="fig" rid="fig4">Figure 4</xref>). They intersect the schistosity with a high angle and are of variable directions and dips (35˚ - 45˚).</p><p>They are not volumetrically important but are in the form of sigmoidal veins in echelon that can extend over several meters. Type IIb veins are defined by a typical breccia structure containing 30% - 50% subangular fragments of hydrothermally altered tectonoclasts (<xref ref-type="fig" rid="fig5">Figure 5</xref>(c) and <xref ref-type="fig" rid="fig5">Figure 5</xref>(d)). Their implementation was undoubtedly made under conditions of local compression and high differential stresses by one or more fracturing episode (s). These veins are separated by structural panels of low gold content. Type IIb veins are composed of quartz-calcite and tectonoclasts, sometimes containing up to 5% sulphides (pyrite, pyrrhotite, arsenopyrite and gold). These veins show two mineralogical units under the microscope: a quartz-feldspathic unit with a pegmatitic texture and a tectonoclastic</p><fig id="fig5"  position="float"><label><xref ref-type="fig" rid="fig5">Figure 5</xref></label><caption><title> Macroscopic and microscopic appearance of quartz veins. (a) Smoky quartz vein type IIa; (b) Pegmatitic texture with large crystals of fractured quartz and plagioclases; (c) Type IIb quartz vein with subangular and brecciated tectonoclasts; (d) Tectonoclasts in quartz veins of Type IIb; (e) Texture with double lithological unit: a quartzo-plagioclastic unit associated with a tectonoclastic unit rich in chlorite-sericite-carbonates; (f) Phenocrystal subautomorph of arsenopyrite with multiple inclusions of gangue</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-2801385x6.png"/></fig><p>unit with aphanitic texture rich in chlorite, sericite and carbonates (<xref ref-type="fig" rid="fig5">Figure 5</xref>(e)). Quartz is generally fractured, while feldspars show signs of distortion. We note the presence of subautomorphic phenocrysts of pyrite or arsenopyrite with multiple inclusions of gangue (<xref ref-type="fig" rid="fig5">Figure 5</xref>(f)). Quartz veins type IIb, by their breccia or cataclastic structure show a very strong deformation gradient. Their spatial distribution in gold mineralization suggests that these quartz veins developed between or in shear zones, preferentially in the most carbonated and/or silicified and competent terrains. They recorded several episodes of brittle deformation and did not show significant ductile deformation. They were probably formed under conditions of high local compression by one or more episodes of hydraulic fracturing.</p></sec></sec></sec><sec id="s6"><title>6. Discussion</title><p>Birimian gold deposits have similar lithostratigraphic contexts, despite some di- fferences noted here and there. The Agbahou gold deposit is regionaly located in the Oume-Fettekro greenstone belt intruded by granitoids. Locally, the deposit contains a mafic to intermediate volcanic unit (basalt and andesite), a volcanose- dimentary unit (tuff and volcanoclastite) and a sedimentary unit (sandstone, siltstone and shale), all stretched in the NE-SW birimian direction. They are intruded by concordant dykes of diorite and gabbro, and by discordant dykes of rhyodacite and rhyolite. Generally, the mineralization of Agbahou appears to de- velop more in mafic volcanics than in volcanoclastites and sediments. Agbahou’s litho-structural data are similar to the regionally known gold deposits. One can cite the gold mineralizations of the Afema province (south-east of Cote d’Ivoire) which are located in the contact zone between volcanic and volcano-sedimentary birimian formations oriented NE and intruded by plutonites.</p><p>Our work suggests that the Agbahou deposit is controlled by two major shear zones: ATZ (Agbahou Tectonic Zone) and WTZ (West Tectonic Zone). These shear zones can be interpreted as first order megastructures (Robert and Brown, 1986 [<xref ref-type="bibr" rid="scirp.74248-ref34">34</xref>] ; Robert, 1990 [<xref ref-type="bibr" rid="scirp.74248-ref35">35</xref>] ). Similar to several gold mineralizations in C&#244;te d’Ivoire (Af&#233;ma, Angovia, etc.) and elsewhere in West Africa, these NE-SW to NNE-SSW oriented shear zones occupy the contact zones or are squarely developed in a single sequence of rocks. The Ashanti gold deposits (Ashanti, Konongo, Bogosu, Prestea and Abawso mines) (Oberth&#252;r et al., 1997 [<xref ref-type="bibr" rid="scirp.74248-ref36">36</xref>] , Wille and Klemd, 2004 [<xref ref-type="bibr" rid="scirp.74248-ref37">37</xref>] ) and also the gold deposits of Bonikro (Ouattara, 2015 [<xref ref-type="bibr" rid="scirp.74248-ref27">27</xref>] ) and Bobosso (Gnanzou, 2014 [<xref ref-type="bibr" rid="scirp.74248-ref38">38</xref>] ), for example, are located in NE-NNE shear zones and intersect birimian sediments near volcanic contact.</p><p>The ATZ and the WTZ probably correspond to major fault systems developed on the eastern and western limb, not far from the hinges of an Anticlinorium (<xref ref-type="fig" rid="fig2">Figure 2</xref>); this anticlinal plunging moderately towards the northeast (Sinclair, 1999 [<xref ref-type="bibr" rid="scirp.74248-ref39">39</xref>] ). According to Tourigny (2008) [<xref ref-type="bibr" rid="scirp.74248-ref30">30</xref>] , the dip would be of the order of 25˚. Significant gold concentrations of Agbahou (&gt;1.0 g/t Au) plunge 25˚ towards the northeast (Tourigny and Houssou, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] ). This plunge of gold mineralization probably suggests the existence of deep unexplored lenses or quartz veins.</p><p>Like Agbahou, the Abawso gold deposit is located on the north-west limb steeply dipping of an anticline, with an axis plunging rather towards south-west (Wille and Klemd, 2004 [<xref ref-type="bibr" rid="scirp.74248-ref37">37</xref>] ). The NE plunge of the Agbahou gold mineralization could reveal the existence of unexplored quartz veins and/or indicate the origin and the circuit of the mineralizing fluids (Tourigny and Houssou, 2008 [<xref ref-type="bibr" rid="scirp.74248-ref31">31</xref>] ). Following the example of several world-known gold mineralizations, Agbahou is regionally located not far from granitoid intrusion. The host formations of the auriferous mineralization are deformed, metamorphosed and marked by a higher schistosity and an important mylonitisation. ATZ and WTZ show contours parallel to the regional schistosity that would result from both the NW-SE regional shortening and diapirism-forming granitoids during the Eburnian tectonothermal event between 2.2 and 2.1 Ga (Feybesse et al., 2006 [<xref ref-type="bibr" rid="scirp.74248-ref3">3</xref>] , Lompo, 2009 [<xref ref-type="bibr" rid="scirp.74248-ref40">40</xref>] ). Within the Agbahou deposit, two families of major faults are distinguished: NE faults and NW faults. According to Mil&#233;si et al. (1992) [<xref ref-type="bibr" rid="scirp.74248-ref13">13</xref>] , Vidal and Alric (1994) [<xref ref-type="bibr" rid="scirp.74248-ref41">41</xref>] , Feybesse et al. (2006) [<xref ref-type="bibr" rid="scirp.74248-ref3">3</xref>] and Lompo (2009) [<xref ref-type="bibr" rid="scirp.74248-ref40">40</xref>] , the NW faults correspond to strike slip faults and their development in the West African Birimian is attributed to transcurrent tectonics. However, here they seem not to be marked by a major displacement. On the other hand, they acted as channels controlling the distribution of gold mineralization (Feybesse et al., 2006 [<xref ref-type="bibr" rid="scirp.74248-ref3">3</xref>] ). They transported and trapped hydrothermal fluids. The shear zones of Agbahou, Sabodala in Senegal (Sylla and N’gom, 1997 [<xref ref-type="bibr" rid="scirp.74248-ref42">42</xref>] ), Abawso in Ghana (Wille and Klemd 2004 [<xref ref-type="bibr" rid="scirp.74248-ref37">37</xref>] ) and Taparko in Burkina Faso (Bourges et al., 1998 [<xref ref-type="bibr" rid="scirp.74248-ref43">43</xref>] ) show the same sinistral reverse displacement, the orientations being variable and respectively N020-N040, NS-N020, N100-120 and N170. According to Bourges et al. (1998) [<xref ref-type="bibr" rid="scirp.74248-ref43">43</xref>] , transcurrent sinistral shear has evolved towards inverse sinistral shear. As for the Diabatou gold shear zone (in Burkina Faso), it is marked by an inverse dextral movement (Mil&#233;si, 1989 [<xref ref-type="bibr" rid="scirp.74248-ref44">44</xref>] , Mil&#233;si et al., 1992 [<xref ref-type="bibr" rid="scirp.74248-ref13">13</xref>] , Klemd et al., 1997 [<xref ref-type="bibr" rid="scirp.74248-ref45">45</xref>] ). The Harbor Lights gold deposit in Australia, on the other hand, is interpreted as a normal shear zone with a dip around 30˚ (Skwarnecki, 1987 [<xref ref-type="bibr" rid="scirp.74248-ref46">46</xref>] and 1988 [<xref ref-type="bibr" rid="scirp.74248-ref47">47</xref>] ; Vearncombe, 1992 [<xref ref-type="bibr" rid="scirp.74248-ref48">48</xref>] ) in which the deformation processes are partly similar to those of inverse shear zones containing most of the gold deposits.</p><p>The main ATZ shear zone contains more than eight (8) supposed second- order ductile-fragile shear-zones (Robert and Brown, 1986 [<xref ref-type="bibr" rid="scirp.74248-ref34">34</xref>] ; Robert, 1990 [<xref ref-type="bibr" rid="scirp.74248-ref35">35</xref>] ) of NE-SW direction and dip 50˚ - 80˚ SE. These shear zones of smaller scales are posterior to the development of the schistosity S1 and contain the main auriferous quartz veins. Work by Wille and Klemd (2004) [<xref ref-type="bibr" rid="scirp.74248-ref37">37</xref>] on the Abawso gold deposit (Ghana) revealed features similar to Agbahou with a NNE orientation and a dip of 50˚ - 90˚ SE. Similar mineralized lenses of NE-SW to NNE-SSW orientation and steeply dipping, which are parallel to the regional schistosity, are also observed in the Ashanti belt deposits (in Ghana).</p><p>In Agbahou and in most auriferous deposits, there is a polyphase deformation with fracturing which has manifested in several ways. This fracturing is responsible for the formation of several generations of quartz veins. According to Bonnemaison (1986) [<xref ref-type="bibr" rid="scirp.74248-ref49">49</xref>] , Herrington and Wilkinson (1993) [<xref ref-type="bibr" rid="scirp.74248-ref50">50</xref>] , the deformation evolved from a ductile to a ductile-brittle style following the classical evolution of gold-bearing quartz veins. The NE and NNE stretching of the main shear zones shows that the Agbahou gold deposit is closely related to the Eburnean event (2120 - 1800 Ma). This explains its similarity with several known gold deposits in the West African and, in particular, C&#244;te d’Ivoire birrimian lands.</p></sec><sec id="s7"><title>7. General Conclusions</title><p>Remote sensing, geophysics and drilling have established the litho-structural context of the Agbahou gold deposit. This work reveals that this region is characterized by a large stable zone formed of granitoid, intruding an unstable domain with particularly high topographies. This area, composed of volcanic, volcano sedimentary and sedimentary sequences of birimian age, is home to numerous faults, some of which are responsible for the emplacement of Agbahou gold mineralization.</p><p>Agbahou gold mineralization is controlled by two major shear zones: ATZ (Agbahou Tectonic Zone) and WTZ (West Tectonic Zone). They are generally oriented NE to NNE and located in birimian volcanic, volcano sedimentary and sedimentary assemblages intruded by granitoids. Drill core studies reveal intensively deformed ductile-brittle deformation in contact zones (N040, 50˚ SE) between soft sediments and more competent volcanics. It controls the emplacement of mineralized lenses and gold-bearing quartz veins. The contours of the shear zones (ATZ and WTZ) are parallel to the regional schistosity. The first- order shear zones have second-order ductile-brittle shear zones, oriented NE to NNE and dipping 50˚ - 80˚ SE. These secondary shear zones host multiple gold- bearing quartz veins.</p><p>The structure of Agbahou deposit consists of two major events: 1) regional plicative deformation at the origin of NE-NNE stretching of regional tectonic fabrics, accompanied by a green schist facies metamorphism; 2) faults formation, reactivation of regional tectonic fabrics, development of Tectonic Zones (ATZ and WTZ) and formation of secondary structures, accompanied by metamorphism, sometimes reaching amphibolite facies. This implementation of the faults induced hydraulic fracturing in areas of high pressure and favored the formation of gold-bearing hydrothermal quartz veins.</p><p>Our work lists the potential targets as a priority for future follow-up work in the area. It includes geological and metallogenic data which can serve as a guideline for mining prospecting. It is a good contribution to the study of deposits of gold mineralization in West Africa.</p></sec><sec id="s8"><title>Cite this paper</title><p>Houssou, N.N., Allialy, M.E., Kouadio, F.J.-L.H. and Gnan- zou, A. (2017) Structural Control of Auri- ferous Mineralization in the Birimian: Case of the Agbahou Deposit in the Region of Divo, C&#244;te d’Ivoire. International Journal of Geosciences, 8, 189-204. https://doi.org/10.4236/ijg.2017.82008</p></sec></body><back><ref-list><title>References</title><ref id="scirp.74248-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Boher, M. (1991) Crustal Growth in West Africa at 2.1 Ga. Contribution of Isotopic Geochemistry. Doctorate, Univ. Nancy, Nancy, 180 p.</mixed-citation></ref><ref id="scirp.74248-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Papon, A. (1973) Geology and Mineralization of Southwestern C&amp;ocirc;te d’Ivoire. 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