The chemical composition of the tailings sample was characterized by XRF. The data is presented in Table 1. The rich chemical composition in oxides in mine tailing are SiO₂ (78.32 wt%), Al₂O₃ (17.50 wt%) and Fe₂O₃ (2.11 wt%). However, Fe₂O₃ is not what we want because it gives a brown color to ceramics. Therefore, iron removal is required to the tailings until the Fe₂O₃ content is under the maximum limit (1.8 wt%) for ceramic applications according to the Chinese standard GB/T 14563-1993.

The tailings are the mixtures of many minerals. Generally, the minerals can be distinguished out by Mineral Liberation Analyzer (MLA). Table 2 shows the mineral composition of the tailings. Quartz and kaolinite are the major minerals of the tailings, which take up 91.98 wt% of the tailings. Quartz and kaolinite are commonly utilized in ceramic application. Therefore, they can be of industrial interest after a proper treatment processing. The other silicates, such as feldspar, biotite, muscovite and amphibole, are also generally used as sintering aid in ce-

ramic applications. The iron- and titanium-contained minerals include titanomagnetite, limonite, pyrite, ilmenite, rutile and leucoxene, which make up 1.72 wt% of the tailings. The total content of rare earth minerals is only 0.04 wt%, which include monazite, xenotime, parisite and colloidal rare earth.

The SEM images of the minerals are shown in Figures 1-5.

Figure 1 shows the SEM images of kaolinite particles in the tailings. The kaolinite particles are observed as aggregation of microcrystalline flakes, which is consistent with the results in these references [9] [11] -[13] . The kaolinite grains are irregular in shapes. The particle size of the kaolinite grains is estimated in the range of 50 - 300 μm. It is also found that monazite, biotite and magnetite are embedded in the kaolinite grains. The chemical compositions and their concentrations of kaolinite measured by EDS are Fe₂O₃ 0.57%, TiO₂ 0.10%, Al₂O₃ 39.24%, SiO₂ 58.36%, K₂O 0.12%, CaO 0.19% and MgO 1.05% (in weight percent). Specially, it has been reported that the magnetite grains embedded in the kaolinite grains may not be removed by magnetic method [8] or chemical method [9] [10] . Therefore, 0.24 wt% Fe₂O₃ of the tailings (0.57% * 0.42 (kaolinite content in tailings) = 0.24%) still remain in the tailings even if after iron removal.

The chemical compositions and their concentrations of feldspar measured by EDS are K₂O 7.50%, Na₂O 4.62%, CaO 0.51%, Al₂O₃ 19.59%, SiO₂ 67.58% and FeO 0.20% (in weight percent). Fe element is incorporated in the crystal lattice of feldspar. Most of feldspar has been weathered into kaolinite.

Quartz is the major mineral in the tailings according to the data in Table 2. Figure 2 shows the SEM images of the quartz particles. As can be seen, the quartz is associated with magnetite, muscovite, or parisite.

Magnetite is the main iron-bearing minerals in the tailings. EDS results show the chemical elements of the magnetite mineral include Fe 66.28%, Ti 3.18%, Mn 0.51%, Zn 0.49%, K 0.01%, Al 0.95%, Si 0.67% and O 27.92% (in weight percent).

The SEM image of magnetite particles associated with the TiO₂ is shown in Figure 3(A). The titanomagnetite mineral forms a grid mark pattern in the cross-section of magnetite grain. Figure 3 shows that it is hard to separate titanomagnetite from magnetite by sieving separation method. Figure 3(B) shows the image of the magnetite associated kaolinite. In fact, Figure 1(D) and Figure 3(B) show that kaolinite and magnetite have the similar associated mineral structure. This associated structure results in the difficulty in the separation of magnetite from kaolinite.

Limonite is another iron-bearing mineral found in the tailings. EDS results show the chemical elements of the magnetite mineral include Fe 53.19%, Ti 0.52%, Mn 0.62%, Zn 0.08%, Ca 0.24%, Al 3.57%, Si 3.05%, Cr 0.11%, S 0.44% and O 38.12% (in weight percent).

Figure 4 shows the SEM image of limonite particles. Limonite particles found to be are granular and dust- like. The particle size is in the range of 0.1 μm - 0.08 mm. 80 wt% of limonite has particle sizes of less than 0.01 mm. And most of the dust-like limonite particles are mixed with kaolinite.

The chemical composition of ilmenite in the sample is 52.38% TiO₂, 41.23% FeO and 6.40% MnO (in weight

percent). Ilmenite in the tailings is granular and very fine. The particles size distribution is in the range of 0.1 μm - 0.15 mm. Ilmenite grains are mostly associated with magnetite, kaolinite or xenotimeetc, as shown in Figure 5.

Kaolinite and quartz together make up 91.98% of the ion-adsorption rare earth tailings. It implies that the tailings can be re-utilized in ceramic application if the Fe content is less than 1.8% according to the requirement of TC-3 grade in the national standard GB/T 14563-1993. However, the content of Fe₂O₃ in the tailings is 2.11%, thus, further treatment to remove the iron is required.

Table 3 shows the distribution of Fe element in the tailings. It shows that titanomagnetite, kaolinite and limonite are the main Fe-bearing minerals in the tailings. Only titanomagnetite and limonite can be removed by magnetic separator methods. If titanomagnetite and limonite are removed, the Fe content in the tailings decreased to 1.23%, which meets the requirement of the standard of TC-3 grade for ceramic industry applications.

To ascertain the various particle sizes, the particle size distribution of the tailings is characterized by standard sieves method. Table 4 shows the particle size distribution and the grade of SiO₂, Al₂O₃, Fe₂O₃ and TiO₂ in the distribution. The +0.4 mm and −0.043 mm fraction are the main of the particle size distribution. The grade of SiO₂ decreases with decreasing particle size. The grade of SiO₂ in the +0.4 mm fraction is larger than 91.46%, implying that coarse grains are quartz and they can be separated by 0.4 mm sieve. Correspondingly, the fine grains (<0.043 mm) are kaolinite because the grade of Al₂O₃ increases with decreasing particle size. The change

of the Fe₂O₃ grade is in accord with that of Al₂O₃. Considering the discussion in section 3.1, it can be concluded that the iron-bearing minerals is mostly mixed with kaolinite. The methods of iron removal from kaolinite reported in reference [8] -[11] can be applied in the tailings.

The −0.4 mm fraction of the tailings is treated by a periodic high-gradient magnetic separator (SSS-I-145). The Fe content of the sorted tailings is measure by XRF. The effect of the magnetic induction on the Fe content is listed in Table 5.

As can be seen, the Fe grade of the sorted tailings decreases with the increase of the magnetic induction. However, the ratio of iron removal is not proportional to the magnetic induction. The ratio of iron removal increases quickly with the increase of the magnetic induction before the magnetic induction is 0.6 Tesla. And then, the ratio of iron removal increases slightly (4.68%) when the magnetic induction increases further from 0.6 T to 1 T. When the magnetic induction is 0.6 T, the Fe grade of the sorted tailings is 1.06 wt% and the ratio of iron removal is 50.41%, indicating most of titanomagnetite and limonite is removed. Therefore, the magnetic induction of 0.6 Tesla is more economical.

To remove the iron in kaolinite, redox method [9] [10] is attempted in the experiment. The −10 μm, −7 μm and −5 μm fractions of the tailings are obtained by settling method according to Stokes equation. The iron removal of the fine tailings is listed in Table 6.

The results in Table 6 show that the iron removal of the tailings by H₂O₂ treatment is insufficient in all the three fractions of the tailings, implying that most of Fe element is in the oxidized state. By using the Na₂S₂O₄ treatment, the Fe content of the −7 μm fraction changed from 1.68% to 1.27%, which is equivalent to 25.4% removal, indicating that Na₂S₂O₄ method is the good way to the iron removal of the fine tailings.