<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">SNL</journal-id><journal-title-group><journal-title>Soft Nanoscience Letters</journal-title></journal-title-group><issn pub-type="epub">2160-0600</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/snl.2011.13016</article-id><article-id pub-id-type="publisher-id">SNL-6165</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Chemistry&amp;Materials Science</subject></subj-group></article-categories><title-group><article-title>
 
 
  Universal 2D Soft Nano-Scale Mosaic Structure Theory for Polymers and Colloids
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>ia</surname><given-names>lin Wu</given-names></name><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib></contrib-group><author-notes><corresp id="cor1">* E-mail:<email>jlwu@dhu.edu.cn</email></corresp></author-notes><pub-date pub-type="epub"><day>20</day><month>07</month><year>2011</year></pub-date><volume>01</volume><issue>03</issue><fpage>86</fpage><lpage>95</lpage><history><date date-type="received"><day>April</day>	<month>4th,</month>	<year>2011</year></date><date date-type="rev-recd"><day>May</day>	<month>10th,</month>	<year>2011</year>	</date><date date-type="accepted"><day>May</day>	<month>17th,</month>	<year>2011.</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  A basic concept in chain-particle cluster-motion, from frozen glassy state to melt state, is the 2D soft nano-scale mosaic structure formed by 8 orders of 2D interface excitation (IE) loop-flows, from small to large in inverse cascade and rearrangement structure in cascade along local one direction. IE has additional repulsive energy and extra vacancy volume. IE results from that the instantaneous synchronal polarized electron charge coupling pair is able to parallel transport on the interface between two neighboring chain-particles with antiparallel delocalization. This structure accords with de Gennes’ mosaic structure picture, from which we can directly deduce glass transition temperature, melt temperature, free volume fraction, critical entangled chain length, and activation energy to break solid lattice. This is also the inherency maximum order-potential structure in random systems.
 
</p></abstract><kwd-group><kwd>Glass Transition Theory</kwd><kwd> Soft Matrix</kwd><kwd> Mosaic Structure</kwd><kwd> Macromolecular Motion</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>This letter is an introduction of the motion principle in polymer physics theory. The confluence of both the thermodynamic and the kinetic dimensions of the solid ↔ liquid glass transition (GT) presents one of the most formidable problems in condensed matter physics [<xref ref-type="bibr" rid="scirp.6165-ref1">1</xref>]. Many theories [<xref ref-type="bibr" rid="scirp.6165-ref2">2</xref>], containing current Mode-Coupling Theories, have been proposed to explain glasses and GT; however, GT theory is still an open problem [<xref ref-type="bibr" rid="scirp.6165-ref2">2</xref>]. An acceptable GT theory should be in accordance with de Gennes’ simple mosaic structure picture [<xref ref-type="bibr" rid="scirp.6165-ref3">3</xref>]. a) The size of the clusters at GT corresponds to the boson peak wavelength, clusters slightly more compact than the matrix: they cannot grow in size because of frustration effects. Mode-Coupling Theories cannot describe this, because they do not incorporate frustration. b) Clusters move rather than molecules, the required cavity space (“vacancy”) for cluster motion is not empty, but filled with the low density matrix. c) The soft matrix is surrounding the clusters. d) An unsolved problem is what mechanism to balance kinetic and potential at the GT. In polymer engineering, GT may be thought of as an inverse cascade—cascade mode along external stress direction. This idea comes from the insight for cooperative orientation activation energy, <img src="7-4600020\616a7b91-3de1-435b-91f6-b900b481e2a5.jpg" />, on polyester melt high-speed spinning-line [<xref ref-type="bibr" rid="scirp.6165-ref4">4</xref>]. When the work of the stress on over 5000 M/min spinning-line reaches<img src="7-4600020\410bfe72-863a-4cf9-997f-07a1f85fc61f.jpg" />, the structure of the yarn is stable and reaches full orientation, called as FOY (Full Orientation Yarn) in current polyester fiber industry. This phenomenon is called stress-induced GT. The rate of change of the stress-induced liquid-to-solid GT is 10<sup>7</sup> times of that in general quencher from melt state to frozen glass state. A logical explanation is that the macromolecules can complete liquid-to-solid GT with full orientation within the millisecond of time in z-space. Their motion mode, within the entire range from melt transition temperature <img src="7-4600020\0f0adcee-4113-40a2-a306-f4f99ac1de60.jpg" /> to GT temperature<img src="7-4600020\8cfad0e6-72d0-4ab1-b271-fb71ed710d50.jpg" />, allows the direction of inverse cascade-cascade in every “excited domain” is in arbitrary in melt state and all apt to z-axial on melt spinning-line; and finally the mode is frozen in glasses as the soft matrix.</p><p>On the other hand, in physical theory, many complicated phenomena originate from the global properties of parallel transport of simple quantum systems (Berry’s Phase) [<xref ref-type="bibr" rid="scirp.6165-ref5">5</xref>]. In addition, crucial to the endeavor of GT theory is a deeper understanding of the systematics of bonding in condensed matter within a framework going considerable beyond the current GT picture [<xref ref-type="bibr" rid="scirp.6165-ref6">6</xref>]. Thus, the GT theoretical approach may come down to the parallel transport of “bonding” on intermolecular interfaces. This “bonding” here is called as the interface excitation (IE) the new and crucial concept introduced in this letter. Nine physical ingredients, random, self-similar, twobody interaction, fluctuation, frustration, and percolation, delocalization, Berry’s phase and Brownian regression potential, have been incorporated at the GT and in macromolecular motion. The incorporation of physical ingredients results in the 2D soft nano-scale mosaic structure in “excited domain”.</p></sec><sec id="s2"><title>2. Theoretical Model</title><sec id="s2_1"><title>2.1. Intermolecular Interface Excitation</title><p>Van der Waals interaction includes the contribution of instantaneous induced dipole—induced dipole. Generally, instantaneous polarized dipole electron charges randomly distribute on an interface 1 - 2 forming electron cloud (blue zone) on x-y projection plane in <xref ref-type="fig" rid="fig1">Figure 1</xref>(a).</p><p>At GT, an interesting and unexplored corner of Van der Waals interaction theories is that the instantaneous synchronal polarized electron charge coupling pair (two small blue dots) may parallel transport on an interface, e.g., the interface 1-2 between particles <img src="7-4600020\379344f5-5e29-4dfb-a790-f989c393f8de.jpg" /> and <img src="7-4600020\510158de-8e80-47d4-8e39-88b042e02aa6.jpg" /> in <xref ref-type="fig" rid="fig1">Figure 1</xref>(b) during the local time of (<img src="7-4600020\13e8138b-533d-4bda-aed4-0614a5935fcd.jpg" />,<img src="7-4600020\89dd0a69-815a-4d71-b566-603f364d8872.jpg" />), and the</p><p>interface 2 - 3 between <img src="7-4600020\5ed2fa53-9f49-4516-b0cd-f60d765bb98c.jpg" /> and <img src="7-4600020\ca0e68b0-1764-4d4b-ae06-7c0a630ee4a8.jpg" /> in <xref ref-type="fig" rid="fig1">Figure 1</xref>(c) during the local time of (<img src="7-4600020\d2310188-173b-4bcf-969b-7682b87b8725.jpg" />,<img src="7-4600020\ffe3be49-9151-4966-947e-04f8dd5311fb.jpg" />). The state of parallel transport of coupling pair is defined as interface excitation on 2D projection plane. Black-broken line arrow on an ion denotes its delocalizing direction in <xref ref-type="fig" rid="fig1">Figure 1</xref>.</p><p>Thus, the site-phase difference between two z-component molecules, or chain-particles, is p: the state of all polarized electron charges in each instantaneous dipole in the two z-component chain-particles, in <xref ref-type="fig" rid="fig1">Figure 1</xref>(b-1) or 1(c-1), must be in the same state and in the z-axial minimum energy state of single chain-particle instantaneous dipole. In Figures 1 (b-2) and 1(c-2) is respectively the projection of (b-1) and (c-1) on x-y plane. This means IE has an additional repulsive energy <img src="7-4600020\92b27448-c277-4081-bec4-3195b10a2925.jpg" /> and an extra vacancy volume<img src="7-4600020\3d781e41-09b0-4f2a-aeab-f597b75fd894.jpg" />. Two instantaneous synchrony z-axial polarized electron charges parallel transport from one end to other end on an interface, as in <xref ref-type="fig" rid="fig1">Figure 1</xref>(b-2), that is simply denoted by an arrowhead, as (1&#174;2) in <xref ref-type="fig" rid="fig1">Figure 1</xref>(d). The two IE states of (b-1) and (c-1) occur at different local times. The directions of the next two parallel transports of instantaneous polarized electron charges of the reference <img src="7-4600020\ea805c8c-e341-49ed-bb65-1e9db4a6cd78.jpg" /> particle denote as two red-broken line arrowheads in <xref ref-type="fig" rid="fig1">Figure 1</xref>(c-1). Thus, an IE loop-flow 1 &#174; 2 &#174; 3 &#174; 4 &#174; 1, occurs during the local time of (<img src="7-4600020\c0a8cd87-5a7e-4d08-ab4d-fd5dd39f30ed.jpg" />,<img src="7-4600020\92f30a63-4786-441c-b9fa-d758e692ade1.jpg" />) denoted as loop-<img src="7-4600020\a09dbd5f-10c4-4985-94d1-71be9460d06a.jpg" />, in <xref ref-type="fig" rid="fig1">Figure 1</xref>(d). It is able to offer a non-integrable Berry’s Phase potential <img src="7-4600020\e4dcce37-6b28-414d-8604-3cef97f5de7f.jpg" /> to induce ion <img src="7-4600020\4c8baf68-44db-4724-973c-360af1066296.jpg" /> (the center of mass of <img src="7-4600020\35aac303-2844-4b35-b37a-21e3ee33faf4.jpg" /> particle) z-direction a conceivable displacement<img src="7-4600020\230fe695-4b4f-446b-a335-ef0c81c492af.jpg" />.</p></sec><sec id="s2_2"><title>2.2. 5-Particle Cooperative Excited Field</title><p>The IE loop-flow in <xref ref-type="fig" rid="fig1">Figure 1</xref>(d) also defined a 2D action particle <img src="7-4600020\487c48db-5366-4811-8a9d-8076429e59e3.jpg" /> to GT, also denoted as<img src="7-4600020\4f7e1ea4-e356-40ce-8922-50b59c605154.jpg" />. The needful time (<img src="7-4600020\c5b7b1b7-c4d1-431e-b8fe-e02cf5aeb963.jpg" />,<img src="7-4600020\10447b3a-b0eb-4409-b526-befadcd4e48d.jpg" />) to form loop-<img src="7-4600020\094569aa-dc67-4a23-8247-e50b8e0da7f5.jpg" /> defined as the zero order of relaxation time<img src="7-4600020\82a0cf61-3bc6-4c7b-9c0c-2f3620ddb3c7.jpg" />. Thus each IE in <xref ref-type="fig" rid="fig1">Figure 1</xref> has also the relaxation time of <img src="7-4600020\e3cf65a5-078c-4902-ba40-8a6ac7036dbb.jpg" /> scale. At the GT, because only 2D closed cycle-flow (that will generate a non-integrable phase p and an additional z-axial induced energy) corresponds to the abnormal heat capacity and boson peak [3,7-9], we need only discuss all the IE loopflows on reference <img src="7-4600020\d88d6e68-b7b4-4ba0-aacd-c28851b557dc.jpg" /> (particle local) filed. The discussion further simplify to only consider the loop-flows formed by several consecutive arrows on a 2D projection plane, see Figures 2-5, and each arrow denotes an IE that has the same IE energy <img src="7-4600020\eb16fdfc-18be-49d9-aed0-47a32fb16051.jpg" /> for flexible chain system. The advantage of the model is that it is also able to describe complex system. Some arrows with different markers denote the different IE energies correspond to the non-flexible chain system.</p><p>The formation of a central excited particle <img src="7-4600020\69af3f45-5e47-4145-8a95-a978c3894ea4.jpg" /> can be also regarded as the cooperative contribution from its 4 neighboring particle fields, <img src="7-4600020\454ab39d-8fdc-458e-88f8-21760d3752d6.jpg" />, <img src="7-4600020\5c52e5c2-0f5d-45d5-b92f-4508a80d44dc.jpg" />, <img src="7-4600020\26e22b6b-e62c-401f-b45c-d512c523f097.jpg" /><img src="7-4600020\cc88bb1c-391c-4901-a48a-b4e6df3714e6.jpg" />, and <img src="7-4600020\6af7803d-e1fb-44c0-8582-1a9928e68c6b.jpg" /> based on Brownian motion theory <xref ref-type="fig" rid="fig2">Figure 2</xref>.</p><p>At the instant (local) time <img src="7-4600020\25195d14-4e2a-4e20-9559-a9d3f2b44a1a.jpg" /> in <img src="7-4600020\eff9c377-dbad-446f-a742-55775f9f7d5c.jpg" /> field, once 4th loop-flow <img src="7-4600020\bff103c1-26c8-4dbb-83ef-fba14bce1cd9.jpg" /> is finished, a new loop-flow of a<sub>0</sub> surrounded by the 12 IEs, 1 &#174; 5 &#174; 6 &#174; 4 &#174; 7 &#174; 8 &#174; 3 &#174; 9 &#174; 10 &#174; 2 &#174; 11 &#174; 12 &#174; 1, with <img src="7-4600020\07f72151-ec32-4dff-8d28-a9712eae4783.jpg" /> timescale will occur as in <xref ref-type="fig" rid="fig2">Figure 2</xref>. The new symmetric loop-flow defined as the first order of transient 2D IE loop-flow and first order of 2D cluster in a<sub>0</sub> field, which are all denoted as<img src="7-4600020\8d8e2985-057c-4faf-b2c2-17096b1df2e9.jpg" />. Whose cycle direction is negative, contrary to that of<img src="7-4600020\8c1bd03c-52b5-47e0-a15e-8b8b391d36b5.jpg" />. The energy of IE with <img src="7-4600020\3f30968f-eefa-4819-8dc0-1cf5d297f939.jpg" /> on the loop denoted as<img src="7-4600020\b7e1b825-4764-4235-be46-33491a24cc21.jpg" />. The 4 excited particles are 4 concomitant mosaic cells with<img src="7-4600020\4b61c766-f6a9-4719-84bf-a763a1af073d.jpg" />. Loop <img src="7-4600020\2cf8f1ce-3137-45e2-bf57-32a5c838c254.jpg" /> has 12 IEs and is of the loop potential energy of 12<img src="7-4600020\9f48101a-715f-4072-9d02-6f4fb7e0a254.jpg" />. This means that the evolution energy from <img src="7-4600020\56168d28-4601-4e0a-833f-6cf6e5c9b34b.jpg" /> to <img src="7-4600020\aa5c1797-0019-48b5-8e03-f574feec0c85.jpg" /> is 8<img src="7-4600020\64ae51b3-e520-4f50-9538-5fcf113b0a7c.jpg" />. The number of cooperative excitation particles in <img src="7-4600020\34d91b09-62b1-4aba-85db-0fa50f2fbaed.jpg" /> is 5.</p><p>Similarly, the 2nd order of transient 2D IE loop-flow and 2D cluster with<img src="7-4600020\6bedce7a-42aa-4624-b15f-244d6aeb8a5d.jpg" />, denoted as<img src="7-4600020\2a46f158-9fd0-4893-9be6-01d9694a95b2.jpg" />, is formed at the instant local time <img src="7-4600020\184e1b24-2faf-4155-9278-41033eeeea0e.jpg" /> when its 4 neighboring particle fields:<img src="7-4600020\5beaca99-2bbe-4a37-a8e8-9db9b8675b96.jpg" />, <img src="7-4600020\3a44da9b-bba6-43c2-a714-edbb62d136eb.jpg" />, <img src="7-4600020\290c631e-69bf-4751-836e-5199cc4f4404.jpg" />, and <img src="7-4600020\6360d2b2-a4c7-4975-8ca4-3e647016005f.jpg" /> finished in <img src="7-4600020\0a65b6f0-1aec-470c-9bfe-d91e3c41d988.jpg" /> field. Whose cycle direction is positive, contrary to that of<img src="7-4600020\98485303-7985-4141-8fa1-a456d43dc44d.jpg" />, in <xref ref-type="fig" rid="fig3">Figure 3</xref>(e). The yellow area in <xref ref-type="fig" rid="fig3">Figure 3</xref>(e) represents <img src="7-4600020\0ff2a456-9c19-4ea5-84ee-0a68bb94107c.jpg" /> loop in <img src="7-4600020\364d46bd-f3b6-4c13-a069-0f5fda05e2d7.jpg" /> field, which is a first order of mosaic structure in<img src="7-4600020\0e55ab77-bce8-4f8d-a8ba-ba99845862d5.jpg" />. The streamline diagram of parallel transport between two clusters <img src="7-4600020\31309f16-f39e-497c-9e4e-dca15aa1fb60.jpg" /> and <img src="7-4600020\09ceb73a-6e42-4ddb-87ac-7423fa4bbaff.jpg" /> is <xref ref-type="fig" rid="fig3">Figure 3</xref>(a). 4 such mosaic structures, <img src="7-4600020\11eb2ba6-7428-4f4f-b02c-874e1e96f261.jpg" />, <img src="7-4600020\eb9def98-34b6-400b-941a-d6e2752c40b4.jpg" />, <img src="7-4600020\8c501ac5-a131-4905-9a86-d9a3ae06d093.jpg" />, and <img src="7-4600020\0852eec5-2b04-4e1c-90ec-2351d07792ce.jpg" /> <img src="7-4600020\f932f087-6f0e-467b-b597-14055dea7c58.jpg" /> cooperatively generate <img src="7-4600020\cd18cbb3-985a-443e-95e2-32287e7dfcf2.jpg" /> in <img src="7-4600020\ba202168-cd07-404b-b5cc-de24f7b639d3.jpg" /> field.</p><p>The energy of IE on loop <img src="7-4600020\2d2ff5a5-6b54-49f8-8b63-477d0efa8fe0.jpg" /> is denoted as <img src="7-4600020\30e46902-d9bf-456f-b4b3-7b43843d9b44.jpg" /> <img src="7-4600020\d4a8c551-290b-4e87-83fd-ff1f3ed39dc9.jpg" />. The number of IEs of loop <img src="7-4600020\ae49a276-979d-4d3e-82c6-ce98ff7a1509.jpg" /> is 20. The number of IEs inside loop <img src="7-4600020\091de81e-1153-4ee5-aa07-107b3302647e.jpg" /> is 12, and equals to the number of the IEs of<img src="7-4600020\702a5f56-db83-4cd6-af06-34f2526cfe7b.jpg" />. This means that the evolution energy from <img src="7-4600020\939eb49e-a586-4a42-ba4a-4dd2cc388250.jpg" /> to <img src="7-4600020\997d1fd9-f58b-4fc5-bfeb-0ebe43456fd5.jpg" /> is 8 <img src="7-4600020\fca6664d-9621-4402-90a8-a199807f9f44.jpg" /> <img src="7-4600020\f8b00c2d-54ef-4085-a531-35680e47f1c3.jpg" />. The number of cooperative excitation particles in <img src="7-4600020\5d7704a5-cc33-46da-b012-58196ddd6e73.jpg" /> is 13 surrounded by 20 IEs. Thus, 20 IEs can excite 13 particles to hop randomly along local +z-axial direction.</p><p>In the same way, the third order of 2D IE loop-flow and cluster at the instant time <img src="7-4600020\e3c23145-4ef9-48bf-8220-1142262094f6.jpg" /> in a<sub>0</sub> field, <img src="7-4600020\762f1a7b-5a52-4e99-8c5a-fde2777c2114.jpg" />, can be obtained as in <xref ref-type="fig" rid="fig4">Figure 4</xref>, which formed by the contribution of its 4 neighboring second order loop-flows, <img src="7-4600020\1f1ee7bd-dd3b-4485-8fff-a32cec79c08c.jpg" />, <img src="7-4600020\de12e81d-2ba1-438c-ac20-103659da7828.jpg" />, <img src="7-4600020\a35f6e3c-5e0a-4acc-8a2b-ee566b8ec3cc.jpg" />, and<img src="7-4600020\12abc1bd-cd0b-4512-ba39-654f3329110c.jpg" />, respectively</p><p>and deasil interacted with <img src="7-4600020\f36f531e-b544-4b31-aab2-2f3c2344e8ae.jpg" /> in <img src="7-4600020\52aa217e-a670-46ba-90ec-81f3a7e170c3.jpg" /> field. In <xref ref-type="fig" rid="fig4">Figure 4</xref>, the yellow area represents loop <img src="7-4600020\e00973fd-81e7-44f4-8910-d5ae47521a0c.jpg" /> in <img src="7-4600020\5744c73e-4e01-4e07-9991-b95eacc07564.jpg" /> field (whose symmetric center is<img src="7-4600020\14b931c1-5fc7-4b7d-a6ae-db7b9f9cd0de.jpg" />) which is a second order of mosaic structure in a<sub>0</sub> field. The number of IEs of loop <img src="7-4600020\d9b74288-fd36-4847-b059-c77bb60146e7.jpg" /> is 28. The number of IEs inside loop <img src="7-4600020\46680e63-4983-4fc3-b312-c9ab708e4b17.jpg" /> is 20, which equals to the number of the IEs on loop<img src="7-4600020\0d9459c5-9ba3-4ace-aa12-ad13ab93d64d.jpg" />. This means the evolution energy from <img src="7-4600020\66c043a0-616c-473f-b127-c3a95a84bc3c.jpg" /> to <img src="7-4600020\9ac41be7-507d-4cf8-8e93-b9b453d4ae01.jpg" /> is 8<img src="7-4600020\e2737871-b640-4025-9062-013d159fbe12.jpg" />. The number of cooperative excitation particles in third order cluster is 25.</p><p>Thus, 28 IEs can excite 25 particles to hop randomly along local z-axial direction.</p><p>From the results of<img src="7-4600020\b08b5f30-91ee-4a52-a448-f0fde8572d01.jpg" />, <img src="7-4600020\80c71804-b73f-4d49-8119-20edd0010548.jpg" />and<img src="7-4600020\eee1eac1-f61c-4f6e-904d-c4f61330abb5.jpg" />, it is clear that the more the number of cooperatively delocalization particles is, the less the average needful IE energy for each particle is. The key point is what the minimum excited energy is and what the number of cooperatively delocalization particles excited by the energy at the GT is.</p><p>There are 4 neighboring concomitant excitation centers surrounding the referenced particle center. Thus, the excited field in <xref ref-type="fig" rid="fig2">Figure 2</xref> is defined as 5-particle cooperative excited field to break solid-lattice.</p><p>The forming of i-th order cluster <img src="7-4600020\3f61ced8-49ba-4a4c-931a-e785b78e87cc.jpg" /> always results from the cooperative contributions of its 4 neighboring (i-1)-th order of clusters around the central particle. This property origins from Brownian motion and is called as the priority of central particle, which is probably the primary reason to generate dynamic heterogeneity [<xref ref-type="bibr" rid="scirp.6165-ref2">2</xref>] and non-ergodic [<xref ref-type="bibr" rid="scirp.6165-ref9">9</xref>] at GT. That means the spatial directions and localities of all the succedent IEs will be completely confirmed, Figures 2-5, once the first IE with the direction 1 &#174; 2 showed in <xref ref-type="fig" rid="fig1">Figure 1</xref>(d) appears at the local time <img src="7-4600020\9f3e0d3f-eeff-4abd-b429-369ce7d388da.jpg" /> in <img src="7-4600020\dab3891d-e2bf-447d-add3-47ee27625fd2.jpg" /> field, otherwise, the total excitation energies will increase. That is the reason and advantage to bring the signature of arrowhead into the standout mode of IE to get the minimum energy required to excite GT. Here the IE represented by arrow is scaled by the IE energy <img src="7-4600020\84e8635c-9bbd-43ca-bad7-577860b8451e.jpg" /> and thus the arrow is of a unit length for different wave lengths of harmonic and anharmonic frequencies on the (energy) lattice model. IE energy <img src="7-4600020\ef8f6974-9f86-4adb-8a9d-28b3a07ee136.jpg" /> does not depend on temperature in flexible polymer system.</p></sec><sec id="s2_3"><title>2.3. Eighth Order of 2D Cluster and Percolation</title><p>a) The number of IEs of i-th order of 2D cluster can be calculated as <img src="7-4600020\2eff5077-76ec-443c-89e8-57fcec324aa1.jpg" /> = 4 (2i + 1) = 12, 20, 28, 36, 44, 52, 60, and (68) for i = 1, 2… 8 and <img src="7-4600020\4c2ae6a8-7006-4e56-8c27-2fda22e8d9d4.jpg" /> = 4. Note that <img src="7-4600020\a6b73bed-0a51-46f0-ba4a-c03837db228e.jpg" /> will be corrected as 60 by geometric frustration-percolation transition.</p><p>b) The number of excitation particles in i-th order of cluster is respectively: <img src="7-4600020\e6cd5b3d-2bb5-48dd-b3a5-df76c23b78b1.jpg" />= <img src="7-4600020\96e81d5c-43a5-4ed6-8b9d-22f6554f674f.jpg" /> + 4i = 5, 13, 25, 41, 61, 85, 113, and (145) for i = 1, 2… 8 and <img src="7-4600020\9b783566-a74d-47ec-9878-81d924baa4a2.jpg" /> = 1. Note that <img src="7-4600020\1a6d4ee7-1b4b-414e-b004-da55a71bbb43.jpg" /> also will be corrected as 136 by geometric frustration-percolation transition.</p><p>c) For z-axial i-th order 2D cluster, the evolution energy from <img src="7-4600020\57f94ef8-547f-4554-b850-41d7a6041a5b.jpg" /> to <img src="7-4600020\a0100527-45e4-4478-9aeb-1e2cbc587a5c.jpg" /> is 8<img src="7-4600020\c2a302e9-1793-4025-bb97-44710ee9770a.jpg" />, we emphasize, this evolution is orienting. The energy to excite i-th order cluster orientable evolution thus is the energy of one external degree of freedom (DoF) to i-th order of cluster (loop-flow) orienting, denoted as<img src="7-4600020\36aff0e1-eb28-4005-8f7b-c5770d22a3e9.jpg" />. So we directly deduce from a)</p><disp-formula id="scirp.6165-formula133978"><label>(1)</label><graphic position="anchor" xlink:href="7-4600020\6e87d325-a09f-4a14-8fb8-5e7a7e0c8a75.jpg"  xlink:type="simple"/></disp-formula><p>d) During the time of (<img src="7-4600020\0d9b7dc2-97f7-4e18-b4bc-d2ce9d682eb6.jpg" />,<img src="7-4600020\eb75497d-2768-4afd-8cc7-a33467799750.jpg" />) in the referenced <img src="7-4600020\48b51a1b-163b-4f2d-9dcd-18bf42df6813.jpg" /> field, each of its 4 neighboring (<img src="7-4600020\6c7ba1ce-499b-413a-a09c-728e3d74c634.jpg" />, <img src="7-4600020\9bb23d6d-a610-4adc-8e8d-e1e1077fd45d.jpg" />, <img src="7-4600020\1f86a51c-789c-47ce-9ea7-093fe4f04ee8.jpg" />, and<img src="7-4600020\80d9508a-ae23-4320-88b9-9c3195dab221.jpg" />) local coordinates can take any direction (fragmentized and atactic lattices) because of fluctuation. However, from c), at the instant time<img src="7-4600020\c406c383-9948-400f-9dbd-58b138eaaa02.jpg" />, the direction of i-th order cluster always starts sticking to the direction of the referenced first order cluster. This characteristic in random systems comes from the Brownian regression motion, or the characteristic of Graph of Brownian Motion. This means that each neighboring i-th order of cluster also has one external DoF of energy as<img src="7-4600020\3132b219-38f7-47dc-b2d6-6780b7ebdf2f.jpg" />. So the i-th order</p><p>of cluster in the (i + 1)-th order is of 5 inner DoF and taking any directions during the time of (<img src="7-4600020\dd1ac980-c366-4a3b-b765-0c331b208b35.jpg" />,<img src="7-4600020\685e2ead-9870-4738-8909-7df3d34c0363.jpg" />) in <img src="7-4600020\dcc14a48-3245-4c46-b6fa-536e765237de.jpg" /> field.</p><p>In the same way, the 8th order of transient 2D cluster, <img src="7-4600020\12cc2dba-b2e3-41cb-9901-181912bcb634.jpg" />, can be obtained in <img src="7-4600020\f551c687-afbe-4cbe-b821-f7776fabcac9.jpg" /> field, as in <xref ref-type="fig" rid="fig5">Figure 5</xref>. As there is no 9th cluster in system, (the result of limited domain-wall vibration frequencies based on Random First-Order Transition Theory proposed by Wolynes et al [2,7]) percolation should be adopted at the instant time<img src="7-4600020\b08b1841-cc97-4ef3-8cb3-4ba468982745.jpg" />, and the 8th order of cluster must be corrected by percolation.</p><p>The uncorrected number of IEs of <img src="7-4600020\b784b1d4-7223-40d0-95a3-8e0ee8f85f33.jpg" /> is 68, denoted by blue-black arrows in <xref ref-type="fig" rid="fig5">Figure 5</xref>. When percolation appears in system, the 4 excited cells, by thick upward diagonal lines, with τ<sub>8</sub> in <img src="7-4600020\cc4ddb8c-f731-44e2-91f8-70c6bb56dddf.jpg" /> are also the mosaic cells of in the 4 neighboring <img src="7-4600020\a1dcd493-d416-4a0a-a529-c7a8e94616e6.jpg" />-clusters (Note: here the 4 <img src="7-4600020\46207cec-41f2-4dab-8382-8d3580a4e8f0.jpg" />-clusters are respectively in the 4 neighboring 5-particle cooperative excited fields) with <img src="7-4600020\3b66fb81-bcf8-4bcf-b949-d96a9e1638d1.jpg" /> field. And 4 cells with <img src="7-4600020\445ef307-f528-430f-ac4b-82ad6624fe52.jpg" /> in the 4 neighboring <img src="7-4600020\db948b35-a08c-4344-aca9-5ab312dc3ef7.jpg" />-clusters, by the color of blue green, are also the mosaic cells in<img src="7-4600020\e0b11191-4c0e-4961-912e-cab65e893058.jpg" />. (A region of space that can be identified by a single mean field solution is called a mosaic cell [<xref ref-type="bibr" rid="scirp.6165-ref10">10</xref>]. Mosaic cell is identified by the different action time in our work.) The 4 thick-black inverted arrows in <xref ref-type="fig" rid="fig5">Figure 5</xref> are the mutual interfaces of <img src="7-4600020\93f8d714-fc8c-420b-b53e-65fdaf0913a6.jpg" /> and its 4 <img src="7-4600020\bde792e1-4f61-4f78-9215-f570ec742867.jpg" />-clusters in neighboring 4 5-particle cooperative excited fields. Thus the number of interfaces of <img src="7-4600020\dc1a4671-576f-419f-8fba-9a619cbc9a61.jpg" /> should be corrected as 60, that is, <img src="7-4600020\e93cee9c-c7a4-4c96-964d-30f16799ae13.jpg" />(corrected by percolation) = 60.</p><p>Note that there are 4 inverted thick-black arrows in the corrected <img src="7-4600020\f981210b-2b14-4afd-a711-caa3c5441a2f.jpg" /> loop-flow in <xref ref-type="fig" rid="fig5">Figure 5</xref>. Thus, the number of excited particles in <img src="7-4600020\e10f42f6-aa12-4e4d-857c-0d5ea898ad4a.jpg" /> should be firstly corrected as 141 because the 4 mosaic cells of<img src="7-4600020\84d61ac3-b852-42c6-bf63-37f2eadb1fb7.jpg" />, marked by the color of blue green, belong to that of the <img src="7-4600020\d39ff41a-08e8-4043-b3bf-3ed209f12444.jpg" />-clusters neighboring 5-particle cooperative excited fields. In addition, the central 5 empty cells, according with de Gennes’ simple picture of a localized “vacancy” among clusters [<xref ref-type="bibr" rid="scirp.6165-ref3">3</xref>], representing the 5 particles in <img src="7-4600020\332e265c-5215-4589-9901-2b1da765ac7b.jpg" /> have first delocalized (indicates <img src="7-4600020\bddc43be-c62d-4116-9e9b-2d7641e0f61a.jpg" /> local coordinates invalidation partly!). Therefore, the number of cooperative excited particles in 8th order of cluster should finally be corrected as 136.</p></sec></sec><sec id="s3"><title>3. Results and Discussions</title><sec id="s3_1"><title>3.1. Average Energy of Cooperative Migration</title><p>In <xref ref-type="fig" rid="fig5">Figure 5</xref>, each (small square) chain-particle has a zaxial hopping energy <img src="7-4600020\cfb1e44f-96e7-41de-bd16-f6a9ee8e38a5.jpg" /> that comes from the non-integrable phase of parallel transport of its 4 IEs surround its z-axis. From (1), the energy of cooperative migration along z-direction in a domain is<img src="7-4600020\faaeddfd-84a1-4eac-bcb1-f3d1e0871a01.jpg" />. As the migrating direction in different domain can be statistically selected as x-, y-, z-axial, and the appearing of all thawing domains is one by one and forming flow-percolation, the average energy of cooperative migration, <img src="7-4600020\20130c0c-a61e-4928-a18d-cfad1dd95595.jpg" />, along one local space direction can be denoted by<img src="7-4600020\d6d6b61a-2861-4585-ad37-067dc388d50d.jpg" />, the non-integrable random Brownian directional regression energy for excited particles inside 8th order of loop-flow. <img src="7-4600020\91621a95-e07a-42a7-8168-88995ef0eae0.jpg" />can be also balanced by the random thermal motion energy of <img src="7-4600020\a4ef100f-b8e0-4c27-bc8d-9d457224cb0a.jpg" /> for general unexcited particles.</p><disp-formula id="scirp.6165-formula133979"><label>(2)</label><graphic position="anchor" xlink:href="7-4600020\50aed6f1-eebb-442d-b7fb-bd25cfc2d3b8.jpg"  xlink:type="simple"/></disp-formula><p>Here <img src="7-4600020\9eae02f9-4e17-42d8-b1b1-ae6be60aa427.jpg" /> is similar to the energy of Curie temperature in magnetism, also the energy of a ‘critical temperature’ existing in the GT presumed by Gibbs based on thermodynamics years ago [<xref ref-type="bibr" rid="scirp.6165-ref11">11</xref>]. The denotation of <img src="7-4600020\8ca2c4d7-9a94-4ef9-9510-8ddf129b478c.jpg" /> is the same as that of Gibbs. E<sub>mig</sub> along one direction, e.g., along the direction of external stress at GT, is an intrinsic attractive potential energy, independent of temperature and external stress and response time. This will be one of the key concepts directly prove the WLF equation. It stands to reason that the attractive potential comes of the IE loop-flows in Brownian motion existing in any random system at any temperature.</p></sec><sec id="s3_2"><title>3.2. Fractal Dimension</title><p>The 8 orders of loop-flows in <xref ref-type="fig" rid="fig5">Figure 5</xref> are the track records of selected IEs, from many dipole charge-electron pairs in fluctuation in 3D local space, respectively at the instant of<img src="7-4600020\7a7e583c-7ec9-474a-97e1-6c45546e6048.jpg" />, <img src="7-4600020\9255f28f-a0a4-4bd5-ab90-dc0abcbe32df.jpg" />,<img src="7-4600020\a763b7f3-1c29-4dc0-b767-3b68873978c2.jpg" />…<img src="7-4600020\9f15cd75-e6ef-47c4-a2ee-d73e1fe1ba1d.jpg" />discrete time on a reference <img src="7-4600020\388a73cb-1063-49b6-b885-83cc9e2d15bb.jpg" /> particle 2D projection plane. In other words, in 3D <img src="7-4600020\117a9f53-e0bb-49c2-a541-af25e60f0b9b.jpg" /> local space, the cyclic direction, selected from many random oriented IE loops, returns to the direction of &#177; z-axial at the instant of <img src="7-4600020\98924153-4a0a-48fe-940f-62bc3cfbd8e6.jpg" /> (i = 0, 1, 2, …8) time, which indicates that the distribution of IE loop in 3D local space obeys the distribution of the Graph of Brownian Motion [<xref ref-type="bibr" rid="scirp.6165-ref12">12</xref>]. Therefore, it can be directly obtain the Hausdorff fractal dimension<img src="7-4600020\301e569b-d36c-436f-afe4-47bbf5eae019.jpg" />, or the Box fractal dimension d<sub>c</sub> of dipole charge electron coupling pairs at the GT is the fractal dimension d<sub>f</sub> of Graph of Brownian Motion [<xref ref-type="bibr" rid="scirp.6165-ref12">12</xref>],</p><disp-formula id="scirp.6165-formula133980"><label>(3)</label><graphic position="anchor" xlink:href="7-4600020\8fe4072c-dd6a-4934-8d21-5e3d0d0154fa.jpg"  xlink:type="simple"/></disp-formula></sec><sec id="s3_3"><title>3.3. Eight-Order of Hard-Spheres and Chain Segments</title><p>We introduce the concept of i-th order of directional 3D hard-sphere (hard-cluster) for directional i-th order of 2D cluster in order to reflect the number of particles in an orienting and compacted cluster in density fluctuation when the maximum loop-<img src="7-4600020\f4cd604b-1294-4eeb-b248-172bb8984ecc.jpg" /> occurs.</p><p>a) Compacting cluster and density fluctuation. The first order of hard-sphere <img src="7-4600020\bae39c7e-b4ec-4a9e-81d3-b1524e7848f5.jpg" /> contains 5 (the number of particles in<img src="7-4600020\e0e9e5b3-56a1-4d9d-97bb-99a033e0d928.jpg" />) + 12 (the number of interfaces of<img src="7-4600020\db014de7-08ee-4fbf-aa78-e018b5f6847f.jpg" />, each interface corresponds to an excited particle taking in any direction in 3D local space) = 17 chain-particles that are compacted to form a hard-sphere. Which has an internal density larger than average, because the IEs with extra volumes on <img src="7-4600020\c23d2a76-4314-482c-b948-6282a3fdcc99.jpg" /> inside <img src="7-4600020\4315b553-42d6-4857-ac49-92c6833d0f2e.jpg" /> have been compacted and transferred to that on <img src="7-4600020\cd64ceef-3d1c-4be2-95f9-373697b3ea5a.jpg" /> (static electricity screen effect of IE loop-flow).</p><p>b) Hard-sphere with finite acting facets. Note that <img src="7-4600020\4c3b337e-9082-4360-b34f-c67a9bf9e2a5.jpg" /> is a vector. The direction of <img src="7-4600020\cd23f0cb-cfe0-4ff8-ae05-e9f78f430d7c.jpg" /> is negative, as same as the direction of<img src="7-4600020\1bb76f5b-f0ac-4246-a06c-be476dc3ba84.jpg" />, if the direction of <img src="7-4600020\85ce06b7-2916-4ab6-b414-81915eed8c8e.jpg" /> is positive. Finite acting facets surround this orienting 3D hard-sphere. The complexity of dynamical hard-sphere here comes down to the finite acting facets in mosaic structures.</p><p>c) 8 orders of self-similar z-axial 3D hard-spheres. In the same way, the second order of hard-sphere <img src="7-4600020\3201f560-a20f-464f-93a6-f56f929d77c0.jpg" /> contains 13 (the number of particles in<img src="7-4600020\dc4da09e-0e57-458e-9169-fefdad3930d7.jpg" />) + 20 (the number of interfaces of<img src="7-4600020\8b64c012-3353-4440-88bf-4e15687dcb29.jpg" />, the number of side-excited particles) = 33 excited particles. The direction of <img src="7-4600020\3a3940fc-89da-494c-b1ab-283abd105f5a.jpg" /> is positive. Therefore, the number, <img src="7-4600020\6a16621b-c95a-46e5-90ad-b4d077659a7c.jpg" />, of particles in i-th order of hard-sphere <img src="7-4600020\39a3bc90-00c0-4681-9e85-fcaf5fc84129.jpg" /> can be obtained as</p><disp-formula id="scirp.6165-formula133981"><label>(4)</label><graphic position="anchor" xlink:href="7-4600020\b5efa686-f82e-4632-a069-6ae145377077.jpg"  xlink:type="simple"/></disp-formula><p>In (4), the sign denotes the moving direction along z-axial of i-th order hard-sphere. By i-th order of hardsphere is meant that the interaction-interface energy of its two-body is the IE energy or transferred energy, <img src="7-4600020\414d95d8-430c-4bd3-b453-560c83b714e8.jpg" />, independent of the distance of two excited cents of two-body in z-space.</p><p>d) 8 orders of self-similar chain-segments. In <xref ref-type="fig" rid="fig5">Figure 5</xref>, each of 200 acting (excited) particles connects with a z-component chain-particle in a chain. Accordingly, in macromolecular system, the lengths of the 8 orders of zcomponent statistical chain-segments <img src="7-4600020\e28b1b1d-7052-409b-997f-977449709e06.jpg" /> (if chain-long N &#179; 200) are also categorize as 8 orders</p><disp-formula id="scirp.6165-formula133982"><label>(5)</label><graphic position="anchor" xlink:href="7-4600020\c0eb6b3c-0565-4c88-95d0-5e67bf43e6c1.jpg"  xlink:type="simple"/></disp-formula><p>e) Number of structure rearrangements. The number of particles in the 8th order of hard-sphere, <img src="7-4600020\39496df0-efcf-45cf-801d-dc192204ceb5.jpg" />, or the 8th order of chain-segment sizes, l8, also is the number of particles <img src="7-4600020\915a5149-d296-49d4-aa8b-99181d3fae26.jpg" /> in structure rearrangement in &#160;<img src="7-4600020\8edb017b-5bc8-47c6-b85f-5b21811dad8c.jpg" /> and<img src="7-4600020\c3cc2d4b-5ae8-4aa7-98d9-ef8db833351f.jpg" />, can be easily found out from <xref ref-type="fig" rid="fig5">Figure 5</xref>. The number of excited particles in corrected <img src="7-4600020\17409905-0381-46b8-a51c-db8a329c3b15.jpg" /> is 136. The number of interfaces of <img src="7-4600020\7284e419-94a9-4075-ad28-d00c009e6b88.jpg" /> before percolation is 68, from which subtracts 4 mutual interfaces (that belong to 4 neighboring local fields) of <img src="7-4600020\3fa5625d-c07c-4e85-862c-11a1a934271b.jpg" /> and its 4 neighboring <img src="7-4600020\651f5d20-2fc1-48ee-b9cc-719d8b65704e.jpg" />-clusters when percolation appears, and each of the 64 (= 68 - 4) interfaces respectively relates to a side-excited particle taking any direction. Thus, the number of acting particles in <img src="7-4600020\4cb6b9d5-1225-4414-90b4-c4946377a778.jpg" /> is 136 + 64 = 200, a magic number in mosaic nano-structure,<img src="7-4600020\6ce18256-a5bd-47cd-9857-47dc94f34f8d.jpg" />.</p><p>The numerical value is consistent with the conjectural results of encompassing rearrangements [<xref ref-type="bibr" rid="scirp.6165-ref13">13</xref>]. <img src="7-4600020\31e00cb5-5e27-49eb-adc4-fb621af421f1.jpg" />is also the critical entangled macromolecule length. The numerical value is in accordance with the experimentally determined critical entanglement chain length of ~ 200 [<xref ref-type="bibr" rid="scirp.6165-ref14">14</xref>].</p><p>f) Evolution direction of cluster growth transition. From <img src="7-4600020\8412d683-69f1-4ee0-99b4-aa7d1d918824.jpg" /> = 200, <img src="7-4600020\cf87b7f0-4125-4ce9-a771-26acd23e76cb.jpg" />&#187; 5.8 (chain-particle units), which is the size of ‘cage’ at GT. According to the definitions of 2D clusters and 3D hard-sphere, an interaction of two z-space i-th order of 3D hard-spheres is always equal to the IE interaction with<img src="7-4600020\1b6187a1-5c9f-4779-a60d-89311f771ecc.jpg" />. This means that the cluster in [<xref ref-type="bibr" rid="scirp.6165-ref3">3</xref>] turns out to be i-th order of hard-sphere. During the time of (<img src="7-4600020\ad900bc1-69ca-4ca3-a1ce-0689c3bee821.jpg" />,<img src="7-4600020\b773d674-b12c-44e6-b654-46081582f9ac.jpg" />), i-th order of 2D clusters cannot be welded together, as same as [<xref ref-type="bibr" rid="scirp.6165-ref3">3</xref>], however, at the instant time<img src="7-4600020\860eefd8-8ab9-4289-93c2-77a3ae86ea43.jpg" />, all i-th order of 2D clusters in local field will be compacted together to form a compacted (i + 1)-th order of 2D cluster with the evolution direction of <img src="7-4600020\1d8b2af3-3274-4522-9fcf-61e653680abf.jpg" /> in inverse cascade.</p></sec><sec id="s3_4"><title>3.4. Localization-Delocalization (Percolation) Transition Energy, <img src="7-4600020\e309409f-758a-4a55-84aa-9235ea450074.jpg" /></title><p>The steady excited energy is exactly the flow-percolation energy in percolation on a continuum of classical model in condensed matter physics. The energy of steadily ‘excited state energy flow’ in the process of <img src="7-4600020\2a273c27-7ee9-47b5-9bcf-1e428bf82b07.jpg" /> vanishing and reoccurring is defined as the localization-delocalizetion (percolation) transition energy, named as <img src="7-4600020\f163450e-c2fb-4c59-9e7c-5fe240068858.jpg" /> (the same denotation of <img src="7-4600020\80c620b7-b17c-4384-884b-72d526ba5cc7.jpg" /> as Zallen [<xref ref-type="bibr" rid="scirp.6165-ref1">1</xref>] did) at GT. The 8 orders of mosaic structures directly manifest that the external DoF of an (inverse cascade) excited state energy flow is 1 and the (i - 1) order inner DoF of a (cascade) ith order cluster in renewed cluster state (rearrangement structures) is 5 at GT.</p><p>a) Macroscopic melt temperature<img src="7-4600020\898ea210-7f6f-41b2-a347-69ac54cc68e4.jpg" />. It is a very important consequence that the external DoF of an energy flow is 5 in the melting state phase transition; and the renewed energy of a microscopic i-th order cluster (i &lt; 8), <img src="7-4600020\c4e10263-f0cc-49a2-aa00-63f2bb1ee003.jpg" />, being in renewed cluster within (i + 1)- th order cluster zone, is numerically equal to the energy of the macroscopic melting state of<img src="7-4600020\60e808c8-86d9-44fa-972f-776f8bc53749.jpg" />. Namely, <img src="7-4600020\f2e0c9bd-5cb4-4ef9-9c57-4e81024a3b97.jpg" /><img src="7-4600020\fe9744f7-9e35-41a8-ad58-05419995b468.jpg" />, i &lt; 8, corresponds to 5 inner DoF, in which<img src="7-4600020\44237ecd-1f50-4516-b731-fd0251a84d6f.jpg" />, (10); <img src="7-4600020\854f4e45-7d4a-4f14-b68e-fd01319e9b19.jpg" />denotes the energy of one external DoF of i-th order loop-flow in <img src="7-4600020\63154793-62d2-49c3-b129-adaa67ae170e.jpg" /> field. The energy of macroscopic melting state can be denoted as<img src="7-4600020\02933ab2-1f05-40a1-9d62-029f45f971f9.jpg" />,</p><disp-formula id="scirp.6165-formula133983"><label>(for flexible system)</label><graphic position="anchor" xlink:href="7-4600020\66327e4c-cedb-42f5-9312-0d9379b4b533.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.6165-formula133984"><label>(6)</label><graphic position="anchor" xlink:href="7-4600020\ed72cdee-3585-4edc-8633-c62dc031c374.jpg"  xlink:type="simple"/></disp-formula><p>b) Percolation transition energy<img src="7-4600020\f3972ac3-c98d-4c17-bf4f-922d90668984.jpg" />. The step (interface) number of <img src="7-4600020\db27093d-84ab-41b2-9545-1c329f302a68.jpg" />-loop is <img src="7-4600020\ae8d8f9a-f445-4341-8395-5f7cd7c8c53f.jpg" /> = 60.<img src="7-4600020\eb5c12d8-6aa4-459f-8526-ef24a7029e69.jpg" />, is less than 60<img src="7-4600020\1850a38f-7527-4c8e-b9c4-6373272e721c.jpg" /> because of the regression state energy effect of IE and the dynamical mosaic structures of IE loop-flows. The IE energies on <img src="7-4600020\f82ef1ee-217c-40bd-80a7-8926631514fb.jpg" />-loop in <xref ref-type="fig" rid="fig5">Figure 5</xref> are shared by <img src="7-4600020\1852ce2d-f27d-4da8-b932-129167c500d5.jpg" /> –<img src="7-4600020\6e9f05ac-fdf5-4361-928f-c2f10a421b87.jpg" />interfaces and <img src="7-4600020\14d8e482-af3d-424c-a53d-8566e5a5b47c.jpg" /> –<img src="7-4600020\00dfdebb-4e0e-4019-9ad4-b40761f34754.jpg" />interfaces.</p><p>The key concepts are that a few of interfaces, named as L<sub>inver</sub>, on the <img src="7-4600020\01064b52-5ba7-47b9-b072-7392572323e6.jpg" />-loop will be excited by the interfaces with relaxation time of <img src="7-4600020\d4bcee92-d1a8-4a0a-b2d2-f96929cfaf33.jpg" /> in new local fields after<img src="7-4600020\26f9d0af-74f4-4d50-b544-c532814c82fc.jpg" />. This is the effect of mosaic structures, or, L<sub>inver</sub> is the step number of mosaic in slow inverse cascade. The others, named as L<sub>cas</sub>, on the <img src="7-4600020\4b09b9c1-7d0f-4d3e-a563-f65af1b57ae0.jpg" />-loop will one by one vanish and their excited energy will rebuild many new <img src="7-4600020\0fb7b95a-91e8-4b0f-a481-fc9b214f1afa.jpg" />-interfaces in the new local fields in fast cascade.&#160;</p><p>Thus, in the flow-percolation on a continuum, the 60 interfaces of a reference <img src="7-4600020\465c5dde-0e11-4521-a9c7-09f4f44db823.jpg" />-loop in <xref ref-type="fig" rid="fig5">Figure 5</xref> are dynamically divided into two parts: the L<sub>cas</sub> interfaces that occur at the local time of <img src="7-4600020\b9266ff8-7987-499f-8d8d-eabc4d674708.jpg" /> in <img src="7-4600020\d27afcb3-1bd6-431c-b3e6-0a3450e0019d.jpg" /> field and the L<sub>inver</sub> interfaces that are the mosaic structures of energy flow and occur at a time after<img src="7-4600020\032aed02-e7c7-4c4e-946a-c1cf14607de2.jpg" />. Formula (7) is obtained</p><disp-formula id="scirp.6165-formula133985"><label>(7)</label><graphic position="anchor" xlink:href="7-4600020\18980eac-d232-47d1-8964-cbfe878f7f6a.jpg"  xlink:type="simple"/></disp-formula><p>The energy of <img src="7-4600020\0127256d-2f38-4830-ac9c-bb8ea91cfa21.jpg" /> is also the fast-process cascade energy of rebuilding new <img src="7-4600020\88aee1a3-89a2-4fd7-ac29-068dda800a38.jpg" /> loop-flows when the L<sub>cas</sub> interfaces vanish. The energy of L<sub>inver</sub> is the slow-process inverse cascade energy of all <img src="7-4600020\81a4bbc1-f463-42f3-8e9c-3bfaecd9d5c9.jpg" /> loop-flows from <img src="7-4600020\f377eafb-b795-48c2-bdd1-f69f6e9c2acd.jpg" /> to <img src="7-4600020\8975e35b-8723-4c65-a05a-5113285e6624.jpg" /> in new local fields.</p><p>The balance excited energy of inverse cascade and cascade in flow-percolation (contained many local fields) is exactly the localized energy<img src="7-4600020\b4b84b6b-50ef-4304-8dd9-80b5bc130f77.jpg" />. Therefore, in fastprocess cascade, <img src="7-4600020\3886f1fa-5125-4bc2-b9e8-a42192266e68.jpg" />, in which <img src="7-4600020\7ba4e5c9-3698-484d-9f07-c1526ba94409.jpg" /> is used as timescale of <img src="7-4600020\b3eed7ed-358d-4c8d-9c74-a1b9cc6738b4.jpg" /> vanishing, <img src="7-4600020\b7f47ed4-96e6-45b6-b04e-a8802e55135c.jpg" />here is the cascade potential energy in flow-percolation.</p><p>Since the excited energy in inverse cascade is not dissipated, the evolution energy of each order closed loop is<img src="7-4600020\47129fad-b55d-4a5e-aa71-3a8b346ea3a9.jpg" />, (1), namely, the ‘singular point energy’ of any i-th order IE closed cycle (Gauss theorem).</p><p>Each mosaic step (either the inverted arrow, or the shared interface by <img src="7-4600020\cf60307d-2f3c-492a-be69-cc6b5835052a.jpg" /> –<img src="7-4600020\8f279f40-58f6-427a-b95e-df99a5636c3d.jpg" />) in <xref ref-type="fig" rid="fig5">Figure 5</xref> connects a mosaic closed cycle <img src="7-4600020\3b65d97d-2f3b-4cd8-b40f-6daf4393de68.jpg" /> that does not belong to the reference a<sub>0</sub> local field. Thus, in the slow-process inverse cascade from <img src="7-4600020\5daf22e4-d35e-4364-83da-13cffcea6475.jpg" /> to <img src="7-4600020\c8ef4ece-41b1-4f6b-9b0d-2f942d73624a.jpg" /> in flow-percolation, the number of the inverse cascade energy <img src="7-4600020\a3e192a1-88fa-4fd0-8032-1937ce034357.jpg" /> forming mosaic step is<img src="7-4600020\65b241a2-16a0-4d40-b04b-aff8258b71ec.jpg" />. For flexible polymer,<img src="7-4600020\377746f6-1039-4333-a267-be0ff0199bd0.jpg" />. Therefore, formula (8) is obtained</p><disp-formula id="scirp.6165-formula133986"><label>(8)</label><graphic position="anchor" xlink:href="7-4600020\b8b47170-d0c1-4f2e-a4f0-5a63eaf60fe9.jpg"  xlink:type="simple"/></disp-formula><p>Or &#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160;<img src="7-4600020\e37f82e6-17fb-4121-8bc3-23e1c81984f0.jpg" />(9)</p><p>Equation 8 is a representative mean field formula. It can be seen that the physics meaning of the right term containing left term on equation is the contribution of mosaic structure. Equation 9 denotes that the delocalized energy <img src="7-4600020\44dbea1a-97e4-40ac-b8bd-e79a1f9f9d43.jpg" /> (the localized energy, the percolation transfer energy, the transfer energy from inverse cascade to cascade) at the GT has 8 components, <img src="7-4600020\06763c06-4f92-4c7c-a0c5-3a577b8a027f.jpg" />, i = 1, 2…8 and the numerical value of each component energy is the same, namely, 20/3<img src="7-4600020\b26ce980-2ac9-43f2-89cd-faec65f963bd.jpg" />. This is also one of the singularities at GT. <img src="7-4600020\60375a97-2c35-4787-8d61-71570d26d4e0.jpg" />is a characteristic invariable with 8 order of relaxation times at the GT, independent of GT temperature<img src="7-4600020\edcf058b-3cb1-4c7f-b5f2-b9ab08d77fca.jpg" />.</p><p>c) Glass transition temperature<img src="7-4600020\1979f6af-0f72-4e72-b2ed-8f6b991c8171.jpg" />. We see <img src="7-4600020\0a99f88a-eb48-4a78-a5d0-d4817c74636f.jpg" /> also comes from the directional non-integrable additional energy at GT, instead of general thermo-random motion energy of molecules. Similar to (2), z-axial non-integrable random regression vibration energy, <img src="7-4600020\8603b512-3942-45e7-b942-880c33e29414.jpg" />, of i-th order clusters with <img src="7-4600020\4163304a-1bea-48b3-a9c9-078e4b8d8310.jpg" /> can be used to denote the energy of<img src="7-4600020\3889894f-fee4-4b9a-a095-08755100cef5.jpg" />, and it can be also balanced by random thermal vibration (<img src="7-4600020\885a8f54-2537-4b21-91d4-bb8c93bdb69a.jpg" />-scale) energy of <img src="7-4600020\d00616b3-4666-4146-b0cc-46c6114a6124.jpg" /> for general unexcited particles. That is</p><disp-formula id="scirp.6165-formula133987"><label>(10)</label><graphic position="anchor" xlink:href="7-4600020\04fe208a-0598-4b48-ab02-4ff9a8d3da8d.jpg"  xlink:type="simple"/></disp-formula><p>The numerical value of <img src="7-4600020\27d475f9-0572-40fc-b927-b1b92ea49fdb.jpg" /> that can be called the fixed point of clusters from small (<img src="7-4600020\25476886-0c57-4ba9-894d-ace6820ad07a.jpg" />,<img src="7-4600020\801730e3-f4c6-4cea-8a45-ab8a98b7718b.jpg" />scale) to large (<img src="7-4600020\24c8d19b-10bd-402d-a310-f16bed5097e6.jpg" />,<img src="7-4600020\2607ca7e-cf4f-4a0f-b4a1-ddb6f50e7ea6.jpg" />scale) in inverse cascade at GT, it is independent of GT temperature<img src="7-4600020\cd653976-2b78-42ce-8a6a-940dd0712105.jpg" />. <img src="7-4600020\64293509-d214-46ea-a8d7-78d7144c7370.jpg" />is traditionally accepted as GT temperature, which is obtained by slow heating rate. Therefore, <img src="7-4600020\d4ab6d69-6508-43e4-8eec-8f2b3d6175f1.jpg" />is a measurable by experiments. From (2), numerical relationship is:</p><disp-formula id="scirp.6165-formula133988"><label>(11)</label><graphic position="anchor" xlink:href="7-4600020\d37054d6-41f0-45c3-9be9-b17587c3ab17.jpg"  xlink:type="simple"/></disp-formula><p>d) Geometric frustration and high-density percolation. It can be seen that Equation 9 is based on the result of corrected <img src="7-4600020\5258f402-92f4-4c0d-badf-fab45aede25a.jpg" /> value and this correction from <img src="7-4600020\37c492ed-1f30-4636-a8d4-c8dc1ec7df1d.jpg" /> to <img src="7-4600020\6dd4f428-94f5-4473-a620-49846390d907.jpg" /> in <xref ref-type="fig" rid="fig5">Figure 5</xref> also can be regard as the geometric frustration effect, which appearance corresponds to the GT [2,3,8] This also indicates that the percolation at GT belongs to the high-density percolation [<xref ref-type="bibr" rid="scirp.6165-ref1">1</xref>]. The filling factor of instantaneous polarized dipole <img src="7-4600020\380f68de-11f6-4c3e-a092-dcdd25ecb8c2.jpg" /> in <xref ref-type="fig" rid="fig1">Figure 1</xref>(d) is also 1.</p></sec><sec id="s3_5"><title>3.5. Activation Energy to Break Solid Lattice</title><p><xref ref-type="fig" rid="fig5">Figure 5</xref> has given out the number of all IE states at GT: the 320 different IE states. The numerical value is from</p><disp-formula id="scirp.6165-formula133989"><label>(12)</label><graphic position="anchor" xlink:href="7-4600020\fa1b1b5a-e1f5-49b3-8a99-c96adcecfd47.jpg"  xlink:type="simple"/></disp-formula><p>The 8 evolution IE states together with the 4 IEs on a reference particle a<sub>0</sub> will evolve a new first order of IE loop-flow being of 12 IEs when 8th order cluster appears.</p><p>The energy summation of the 320 different IE states is named the cooperative orientation activation energy to break solid lattice, denoted as<img src="7-4600020\ad39f7b4-bfb3-4f75-b22b-09b74ded6f00.jpg" />. The reason to call it activation energy is that although in microscopical, the energy to break solid lattice is seemly only<img src="7-4600020\bbfa5144-d8d6-499f-aefb-8480ca9ff75a.jpg" />, &lt;<img src="7-4600020\f1b81680-8c41-41b5-8dce-3622898788ec.jpg" />, in microcosmic, the energy of 320 IE space-time states in every solid domain is needed. Thus,</p><disp-formula id="scirp.6165-formula133990"><label>(13)</label><graphic position="anchor" xlink:href="7-4600020\04f2d2e5-dd69-45df-9442-d8f749f7091e.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.6165-formula133991"><label>(14)</label><graphic position="anchor" xlink:href="7-4600020\7eec6ff6-4b7b-43de-b8a8-467dda27a992.jpg"  xlink:type="simple"/></disp-formula><p>Using&#160;&#160; <img src="7-4600020\86d324ac-c8bd-4221-8cc8-e0bc876167a8.jpg" />, thus,<img src="7-4600020\9c284d54-a87c-4abe-bf3b-82c7a4c86cdd.jpg" />(15)</p><p><img src="7-4600020\e7989219-0bc8-43f5-83f4-44f9ece5ab26.jpg" />can be measured on melt high-speed spinningline. In fact, the author [<xref ref-type="bibr" rid="scirp.6165-ref4">4</xref>] had obtained the experimental data of <img src="7-4600020\be555caa-6957-4205-917f-eece9721ebdb.jpg" /> for polyethylene terephthalate (PET) by using the on-line measuring on the stretch orientation zone during melt high-speed spinning. The experimental result shows <img src="7-4600020\0a8ea4b9-3588-4699-9738-98cfcf048f8e.jpg" /> (for PET) &#187; 1/6<img src="7-4600020\210e900b-b850-4373-bab1-4a2187b362d9.jpg" /> (for PET), and<img src="7-4600020\7ad3423b-ff11-4f3b-9ebc-cea620b301c6.jpg" />. Thus, for PET, the extra IE energy <img src="7-4600020\7ba4fa6e-7a3a-49a3-9f39-202e5e552d7d.jpg" /></p><disp-formula id="scirp.6165-formula133992"><label>(16)</label><graphic position="anchor" xlink:href="7-4600020\975dcd15-8173-4435-8640-f391975ea6d7.jpg"  xlink:type="simple"/></disp-formula><p>Moreover,<img src="7-4600020\19fd184f-4b87-4eb9-bc9a-d9f78e331c01.jpg" />.</p><p><img src="7-4600020\6f8c17c6-c122-4e51-bfb2-9d0293fda97f.jpg" />is the energy of one DoF of <img src="7-4600020\657aae9b-1245-4c7e-92a4-73027dd138f6.jpg" />-loop. This value is consistent with the experimental results (4 ~ 12 x 10<sup>-3</sup> eV) for Boson peak measured by high-resolution inelastic neutron scattering [<xref ref-type="bibr" rid="scirp.6165-ref12">12</xref>].</p></sec><sec id="s3_6"><title>3.6. Free Volume</title><p>The classical free volume ideas have been questioned because of the misfits with pressure effects, but here the pressure effects should be indeed minor [<xref ref-type="bibr" rid="scirp.6165-ref2">2</xref>]. It is interesting in our model that there is no so-called classical free volume with an atom (molecule) migrating in system. Except the 8th order of 2D clusters, in the i-th order of clusters, all (i - 1)-th order of 2D clusters are compacted to form i-th order clusters, and the extra volumes of the IEs of all (i - 1)-th order clusters vanish and reappear on the interfaces of i-th order. Thus, when the central 8th order loop appears and vanish in cascade, the extra vacancy volumes of the IEs on the loop suddenly form vacancy volumes of 5 cavity sites in the center of the loop, in <xref ref-type="fig" rid="fig5">Figure 5</xref>, in order to induce the first order of cluster delocalization. The definition of free volume is modified by the cooperatively appearing 5 cavities, i.e., using clusters rather than atoms, same as that proposed by de Gennes [<xref ref-type="bibr" rid="scirp.6165-ref2">2</xref>]. The modified free volume idea is still true, because the action of pressure should be only through the same percolation field generating cavity volume; and the extra volume energy in the 8 orders of loop-flows in <xref ref-type="fig" rid="fig5">Figure 5</xref> should be balanced with the external pressure or tension. Each cavity is also an orientation vector as same as the direction of excited domain. Since all excited domains are in random orienting at GT, 5 statistically isotropic 3D cavities (so-called classical free volume) thus are obtained by per 200 statistically isotropic 3D particles. In other words, the free volume fraction: 5/200 = 0.025 can be directly and explicitly obtained, which is in accordance with the experimental results for flexible polymer.</p></sec><sec id="s3_7"><title>3.7. Mode-Coupling and Icosahedral Directional Ordering</title><p>In the inverse cascade at GT, if each IE appears in the way of one arrow after another according to the appearance probability as mentioned in Figures 2-5, the probability is rather low. In fact, the more probable situation is the evolutive mode of self-similar 2body-3body cluster coupling in the soft matrix of IE loop-flows in <xref ref-type="fig" rid="fig6">Figure 6</xref>.</p><p>In <xref ref-type="fig" rid="fig6">Figure 6</xref>, the i-th order of IE loop-flows can be simply denoted as some squares with IE <img src="7-4600020\bcae12a1-22e5-45f0-9c5d-fc9759c0cdee.jpg" /> in (a), each of which is self-similar with <xref ref-type="fig" rid="fig1">Figure 1</xref>(d). <xref ref-type="fig" rid="fig6">Figure 6</xref>(a) first evolves into three 2-body interaction in (b), then into two three-body interactions in (c), named as i-th order of 2body-3body cluster coupling in 5-particle cooperative excited field. Finally into (i + 1)-th order of IE loop-flow in (d) and cooperatively eliminate IEs inside the loop-flow (static screen effect) in order to form 8 order 2D IE loop-flows and clusters slightly more compact than the matrix.</p><p>The mode of 2body-3body cluster coupling is in statistically advantage (soft matter concept): e.g., per 4 IEs needs 5 instantaneous polarized ions in Figures 1(d) and 6(a). The parameter of polarized ion numberdensity of per IE (the density of particles occupy additional vacancy volume in IEs) in soft matrix, <img src="7-4600020\6e0b1721-00ca-447d-b869-4734c4de064f.jpg" />= 5/4 = 1.25. However, 21 IEs needs 24 polarized ions, the ion number-density <img src="7-4600020\36e7ce3d-56fd-4738-9f26-6ac02f2e2608.jpg" /> = 24/21 &#187; 1.14 in <xref ref-type="fig" rid="fig6">Figure 6</xref>(b), large than <img src="7-4600020\68243774-f4c9-4798-a9ce-252de7710a73.jpg" /> = 22/20 = 1.1 in <xref ref-type="fig" rid="fig6">Figure 6</xref>(c), each evolutive 3body cluster only needs the excitation energy of 10 IEs. In <xref ref-type="fig" rid="fig6">Figure 6</xref>(c), the two clusters (two 3body clusters excited at different times need 20 IEs) move randomly and they are not in superposition. Once they are in superposition, <xref ref-type="fig" rid="fig6">Figure 6</xref>(c) immediately mutates into <xref ref-type="fig" rid="fig6">Figure 6</xref>(d) to form first order of uncompacted cluster, <img src="7-4600020\45266318-f4df-467d-915b-5d941a7a520b.jpg" />= 17/16 &#187; 1.06 in <xref ref-type="fig" rid="fig6">Figure 6</xref>(d). Finally, the IEs inside the loop-flow disappear to form hard-cluster. The parameter <img src="7-4600020\765b0128-a9d2-4f6d-89a3-b4f8efdb6476.jpg" /> will be less and less in inverse cascade with cluster augment.</p><p>The minimum value of the polarized ion number density <img src="7-4600020\4177607a-d2f7-467e-9410-b509fa54b8f3.jpg" /> = 200/320 = 5/8, in 8th order 2D cluster in <xref ref-type="fig" rid="fig5">Figure 5</xref>, which indicates the single-ion polarization is slow process formed IE closed loop, <xref ref-type="fig" rid="fig1">Figure 1</xref>(d), corresponding the maximum static electricity repulsive state in polarized field. In addition, there are 60 + z-axial hopping ions and 60 - z-axial hopping ions in 136 z-axial excited particles in <xref ref-type="fig" rid="fig5">Figure 5</xref>. The 120 ions form 60 pairs of antiparallel ion-pairs. So, the polarized ion pair number density in IE soft matrix, <img src="7-4600020\a395cf07-e672-413f-95f3-45471fa32998.jpg" />= 120/320 = 3/8, which indicates the polarization of a pair of ion is fast process, <xref ref-type="fig" rid="fig1">Figure 1</xref>(b) in IE. It is an important relation equation has been fined that<img src="7-4600020\1db76e3d-9e1c-48e6-8555-e1557d1d3035.jpg" />. This implicates the polarized structure of classical boson peak in local polarized filed. Especially, the number of 60 pairs of antiparallel ions inside 8th order loop-flow equals the number of the 60 pairs of synchronal polarized electron charges on the loop-flow. Therefore, z-axial slower randomly non-integrable kinetic energy of antiparallel ionpairs inside 8-th order loop-flow also balances the faster induced potential energy on the IE loop-flow, which is a kind of mode-coupling scheme between the fast-motion induced charge-electron coupling pairs and the slow-motion delocalized ion pairs.</p><p>Moreover, there is still 16 (= 136 - 120) + z-axial remainder ions inside the 8-th order of loop-flow, which can offer a static charge repulsive force to facilitate the first excited + z-axial ion a<sub>0</sub> delocalization in <xref ref-type="fig" rid="fig5">Figure 5</xref>. Since the 16 + z-axial ions to drive ion a<sub>0</sub> to leave its coordinates needs 320 IEs, 16/320 = 1/20, this leads to each directional delocalization uncompacted particle needs 20 z-directional excited interfaces with <img src="7-4600020\18e1260d-9cbb-424b-a44e-d385f36daff3.jpg" /> in its 8-th order of loop-flow. On the other hand, disappearing the 8-th order of loop-flow of reference a<sub>0 </sub>particle also needs its 4 concomitant excited particle, <img src="7-4600020\20bfd56f-8d6f-4600-9ee5-fcf1a49d3b9b.jpg" />, <img src="7-4600020\8530562c-522a-4f2a-9170-f0dab6e21455.jpg" />, <img src="7-4600020\679f0275-8986-4f45-a0a6-ad6c2e72ef34.jpg" />, and<img src="7-4600020\10ede628-64b7-41ee-9def-66fa7d8f3fec.jpg" />, one by one finish respective 8th order of loopflows in inverse cascade and delocalize along z-axial. This leads to 5 compacted conformational rearrangement particles in cascade precisely need 20 z-directional excited interfaces disappearing with<img src="7-4600020\d2e79832-ca54-4a96-8c83-135627278bac.jpg" />. That is another explanation for icosahedral directional ordering at the GT.</p><p>Distinctly, the mode-coupling scheme based on mosaic geometric structure adopted in this paper is different from the mathematical expressions in the current modecoupling theory of GT. However, the spirit in both modecoupling schemes is the same that deals with the coupling of fast-slow relaxation modes and two density modes in structure rearrangements at the GT. In our scheme, we focus on finding out the three direction nonintegrable energies<img src="7-4600020\5db4f591-79b2-4d96-9869-b3aa978da71c.jpg" />, <img src="7-4600020\4a17dd2a-ef01-41c0-93fc-8e5115bb58d6.jpg" />and <img src="7-4600020\ed43c1a8-932e-48a8-8ce1-c7ce58f452d6.jpg" /> existing in the coordinate invalidation from i-th order clusters to (i + 1)-th order in solid-to-liquid transition, whatever the time complications of anharmonic frequencies may be. The mode-coupling trick is that the relaxation time complications have been beforehand reduced and replaced by the long time Brownian directional regressions with the 2p closed loop-flows of IEs in <xref ref-type="fig" rid="fig5">Figure 5</xref>.</p></sec></sec><sec id="s4"><title>4. Conclusions</title><p>It is proposed that the soft matrix surrounding clusters is 2D soft nano-scale 8 orders of IE loop-flows; the filling factor of 2D lattices is 1. The key of the theory is that the random thermo-motion kinetic energy, from glass transition to melt transition, should be balanced by the nonintegrable random regression vibration energy in random systems. That is, entire molecule-cluster delocalization energy (also the GT energy) origins form the maximum order potential energy in random systems. This 2D structure corresponds to the appearance of boson peak and geometric frustration at the GT, and can directly deduce three non-integrable directional energies:<img src="7-4600020\dc964218-7c4a-4ce7-aaea-cfabe7bfde36.jpg" />, <img src="7-4600020\c7f024bb-d1af-4f45-b340-a12e0b92fedc.jpg" />, and <img src="7-4600020\963d7c51-79ff-4753-b2fe-ccc69fc69bdc.jpg" /> along one local space direction, respectively corresponding to Gibbs temperature<img src="7-4600020\f95bf544-1ab3-4c41-9f71-1fb035210abe.jpg" />, glass transition temperature<img src="7-4600020\5d4d51fd-6d4f-485d-956f-f71a08ef6d09.jpg" />, and melt transition temperature<img src="7-4600020\22d0a6dd-8174-4650-ab69-c8cd80127ed7.jpg" />.</p></sec><sec id="s5"><title>5. Acknowledgements</title><p>The author is grateful to all colleagues he had the pleasure to collaborate and interact, especially when he found the fundamental physics origin for the orientation activation energy obtained experimentally on melt high-speed spinning-line. In particular, the author would like to thank, in random order, Yuan Tseh Lee and Sheng Hsien Lin of Academia Sinica (Taiwan), Yun Huang of Beijing University, Da-Cheng Wu of Sichuan University for useful discussions.</p></sec><sec id="s6"><title>REFERENCES</title></sec></body><back><ref-list><title>References</title><ref id="scirp.6165-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">R. Zallen, “The Physics of Amorphous Solids,” Wiley Interscience, New York, 1983. 
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