<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">JSEMAT</journal-id><journal-title-group><journal-title>Journal of Surface Engineered Materials and Advanced Technology</journal-title></journal-title-group><issn pub-type="epub">2161-4881</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/jsemat.2015.53015</article-id><article-id pub-id-type="publisher-id">JSEMAT-57136</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Chemistry&amp;Materials Science</subject><subject> Engineering</subject></subj-group></article-categories><title-group><article-title>
 
 
  Erosion Behavior of AISI 6061-T6
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>uan</surname><given-names>Rodrigo Laguna-Camacho</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hermilo</surname><given-names>Martínez-García</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Frumencio</surname><given-names>Escamilla-Rodríguez</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Carlos</surname><given-names>Alarcón-Rosas</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Celia</surname><given-names>María Calderón-Ramón</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lizeth</surname><given-names>Ríos-Velasco</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lizeth</surname><given-names>Ríos-Velasco</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Matilde</surname><given-names>Pelcastre-Lozano</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Álvaro</surname><given-names>Casados-Sánchez</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Melesio</surname><given-names>González-Gómez</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff2"><addr-line>Facultad de Ciencias Químicas, Universidad Veracruzana, Poza Rica de Hidalgo, Veracruz, Mexico</addr-line></aff><aff id="aff1"><addr-line>Faculty of Electrical and Mechanical Engineering, Universidad Veracruzana, Veracruz, Mexico</addr-line></aff><pub-date pub-type="epub"><day>01</day><month>06</month><year>2015</year></pub-date><volume>05</volume><issue>03</issue><fpage>136</fpage><lpage>146</lpage><history><date date-type="received"><day>2</day>	<month>March</month>	<year>2015</year></date><date date-type="rev-recd"><day>accepted</day>	<month>12</month>	<year>June</year>	</date><date date-type="accepted"><day>15</day>	<month>June</month>	<year>2015</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  In this work, erosion tests were performed to study the behavior of an aluminium alloy known as AISI 6061-T6 against the impact action of aluminium oxide abrasive particles. This material was selected because of its high ductility and tenacity. An erosion rig based on that in ASTM G76-95 was used to conduct the tests. The alumina particles had a particle size between 300 and 400 μm. Four incident angles, 30&amp;deg, 45&amp;deg, 60&amp;deg and 90&amp;deg were used to conduct the erosion tests. The particle velocity and the abrasive flow rate were 24 &#177; 2 m/s and 63 &#177; 0.5 g/min. The room temperature was between 35&amp;degC and 40&amp;degC. Chemical analysis of the material and abrasive particles were obtained using energy dispersive X-ray analysis (EDS). SEM images were employed to identify the wear mechanisms, which were characterized by high plastic deformation. The erosion rates were obtained and the results indicated that the maximum erosion damage was achieved at 30&amp;deg reducing progressively at normal incidence.
 
</p></abstract><kwd-group><kwd>Erosion</kwd><kwd> AISI 6061-T6</kwd><kwd> Aluminium Oxide</kwd><kwd> Wear Mechanisms</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Erosion is a wear process where the material removal is caused by the continuous impact of solid particles, a liquid and a combination of them on a surface. This wear process has been reported in several industrial components such as pipes [<xref ref-type="bibr" rid="scirp.57136-ref1">1</xref>] , bends [<xref ref-type="bibr" rid="scirp.57136-ref2">2</xref>] , control valves [<xref ref-type="bibr" rid="scirp.57136-ref3">3</xref>] , steam turbine blades [<xref ref-type="bibr" rid="scirp.57136-ref4">4</xref>] and other mechanical elements. In relation to erosion studies on aluminum alloys, different investigations have been conducted. For instance, Christman [<xref ref-type="bibr" rid="scirp.57136-ref5">5</xref>] carried out erosion tests using ball bearings of 5 mm diameter on AISI 7075-T6 with different conditions and on AISI</p><p>1100, which is an annealed commercially pure aluminum. These materials were tested at low impact angles and normal incidence. The main emphasis in this work was material loss mode at normal impacts (90˚). This led to a detailed study of the interaction of successive overlapping craters due to they found significant metal loss at normal incidence only when such overlap occurred. In almost all cases, the material removal was originated from the intersection of the craters. AISI 7075 alloy exhibited metal loss only at the intersection of craters, never in remote parts of the second crater. Overlapping craters on AISI 1100 material gave only splinters (lips or platelets) around the rim. In addition to this, it was observed that high strength AISI 7075-T6 was much less erosion resistant than soft ductile pure aluminum AISI 1100. This tendency was observed at low and high incident angles. The maximum erosion damage was observed at low impact angles, 20˚ and 35˚. Cousens &amp; Hutchings [<xref ref-type="bibr" rid="scirp.57136-ref6">6</xref>] presented detailed observations of the surface and subsurface features of aluminium alloys such as fully hardened 6061-T6, annealed 6061-0 and commercial purity aluminium 1100, eroded by glass beads at normal incidence. They proposed a new wear mechanism for erosive weight loss. A novel technique utilizing roll bonding to place marker layers underneath the specimen surface provided evidence of the pattern of flow of metal during erosion. Veerabhadra-Rao P. et al. [<xref ref-type="bibr" rid="scirp.57136-ref7">7</xref>] conducted a study of the morphology of the wear damage produced on two metals, an aluminium alloy (6061-T6511) and copper, by normal impact of spherical glass erodent particles. The results indicated that plastic deformation of the aluminium was characterized by radial tracks and concentric rings, these surface characteristics were identified in the craters formed by the direct impacts of the abrasive particles. The wear damage was more pronounced as the time was elapsed. Other significant factor was the pressure in the system, as it was increased, then the particle velocity was greater and more erosion was caused in the samples. In this research work, the main purpose was to study the erosion behavior of an aluminum alloy (AISI 6061-T6). The importance of this work is to know the wear modes of this aluminum alloy at different incident angles and determine the erosion rates under these particular conditions. Another significant aspect is to study the capacity of the aluminum oxide (angular shape) to deform the tested material. Erosion tests using an apparatus similar to that in ASTM G76-95 were conducted to establish the erosion rates at different incident angles, 30˚, 45˚, 60˚ and 90˚. In addition, the wear mechanisms were identified using SEM images.</p></sec><sec id="s2"><title>2. Experimental Details</title><sec id="s2_1"><title>2.1. Specimens</title><p>The material used in the tests was AISI 6061-T6. This aluminum alloy is a medium to high strength heat-treata- ble alloy with a very good corrosion resistance and weldability. It has medium fatigue strength. T6 means solution heat treated and artificially aged. This alloy has applications in different industries such as helicopter rotor skins, tubing, truck frames, boilermaking and rivets. The alloy specimens were ground flat with 180-grit silicon carbide paper. The initial R<sub>a</sub> roughness average value was 6.35 nm (R<sub>a</sub>) with a standard deviation of 0.15, after 10 measurements. <xref ref-type="fig" rid="fig1">Figure 1</xref> shows two 3D profiles of the initial roughness obtained using an AFM (Microscope diMultimode V, Vecco, Controller di Nanoscope V) on random locations of the specimen surface. The projected surface areas were 10 &#215; 10 &#181;m<sup>2</sup> and 5 &#215; 5 &#181;m<sup>2</sup>, respectively.</p><fig-group id="fig1"><label><xref ref-type="fig" rid="fig1">Figure 1</xref></label><caption><title> 3D roughness profiles, (a) R<sub>a</sub> = 10.4 nm; (b) R<sub>a</sub> = 6.35 nm.</title></caption><fig id ="fig1_1"><label> (b)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x5.png"/></fig><fig id ="fig1_2"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x6.png"/></fig></fig-group><p><xref ref-type="fig" rid="fig2">Figure 2</xref>(a) and <xref ref-type="fig" rid="fig2">Figure 2</xref>(b) shows a micrograph of the specimen before erosion tests with different magnifications. The EDS analysis was performed to obtain the chemical composition of the tested material and the results presented the following elements, carbon (C) 0.023 wt%, silicon (Si) 0.80 wt%, copper (Cu) 0.40 wt%, oxygen (O) 5.94 wt%, magnesium (Mg) 1.19 wt% and aluminum (Al) 69.3 wt%. The Al samples had a Berkovich hardness of 126 with a standard deviation of 3.66 and a Young Modulus of 90 GPa with a standard deviation of 2.33 after 15 measurements. The applied load was 100mN. These results were obtained using a Nano indentation Tester (TTX-NHT, CSM Instruments).</p><p>The samples had a rectangular shape with dimensions of 50 mm &#215; 25 mm and 3 mm in thickness. The abrasive particles used were aluminum oxide (alumina) with an angular shape as shown in <xref ref-type="fig" rid="fig3">Figure 3</xref>(a) and <xref ref-type="fig" rid="fig3">Figure 3</xref>(b). The chemical composition of the abrasive particles presented elements such as oxygen (O) 10.31 wt%, fluorine (F) 4.48 wt%, aluminum (Al) 22.33 wt%, silicon (Si) 3.47 wt%, chromium (Cr) 9.63 wt%, iron (Fe) 45.11 wt% and nickel (Ni) 4.67 wt%. Particle size distribution was obtained using an Analysette 28 image sizer. The particle size grain was between 300 and 400 &#181;m (<xref ref-type="fig" rid="fig3">Figure 3</xref>(c)). Most particles were found in this particular range. The hardness and density of the abrasive particle is 1800 HV and 3.99 g/cm<sup>3</sup> [<xref ref-type="bibr" rid="scirp.57136-ref8">8</xref>] .</p></sec><sec id="s2_2"><title>2.2. Test Procedure</title><p>The erosion tests were performed by using a rig, which is based on that in the ASTM G76-95 [<xref ref-type="bibr" rid="scirp.57136-ref9">9</xref>] . The schematic diagram of the rig developed is presented in <xref ref-type="fig" rid="fig4">Figure 4</xref>. In this rig, the abrasive particles are accelerated from a nozzle by using a compressed air stream that caused them to impact the surface of the material. The average particle velocity was measured with an opto-electronic flight-timer similar to that described by Kosel and Anand [<xref ref-type="bibr" rid="scirp.57136-ref10">10</xref>] . This system offers the possibility to measure the particle velocity in an accurate mode and the design does not request high costs.</p><p>The material was eroded for 20 min although each sample was removed every 2 min to determine the mass loss. The impact angles used for the tests were 30˚, 45˚, 60˚ and 90˚. These angles were selected to evaluate the material at low and high impact angles. A particle velocity of 24 &#177; 2 m/s and an abrasive flow rate of 63 &#177; 0.5 g/min were used to conduct the tests. In all of the tests, the specimens were located 10 mm from the end of the stainless steel nozzle. The nozzle had the following dimensions: 4.7 mm internal diameter, 6.3 mm external diameter and a length of 260 mm. The room temperature was between 35˚C and 40˚C. The specimens were weighed using an analytical balance (with an accuracy of &#177;0.0001 g) before the start of each test and removed every 2 min, cleaned by using acetone and weighed again to determine the amount of mass loss. Micrographs of the eroded surfaces were obtained using a Scanning Electron Microscope (SEM) Quanta 3D FEG (FEI) to analyze the specimens and to identify the possible wear mechanisms.</p></sec></sec><sec id="s3"><title>3. Erosion Results</title><sec id="s3_1"><title>3.1. Erosion Damage at 30˚</title><p>The erosion damage at 30˚ was characterized by high plastic deformation on the surfaces as observed in <xref ref-type="fig" rid="fig5">Figure 5</xref> and <xref ref-type="fig" rid="fig6">Figure 6</xref>. In this particular case, micro-cutting and micro-ploughing (grooves on the surface) actions were</p><fig id="fig2"  position="float"><label><xref ref-type="fig" rid="fig2">Figure 2</xref></label><caption><title> SEM images of AISI 6061-T6, (a) 100&#215;, (b) 500&#215;</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x7.png"/></fig><fig-group id="fig3"><label><xref ref-type="fig" rid="fig3">Figure 3</xref></label><caption><title> Abrasive particle, (a) (b) Morphology of alumina; (c) Particle size distribution.</title></caption><fig id ="fig3_1"><label> (b)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x8.png"/></fig><fig id ="fig3_2"><label>(c)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x9.png"/></fig></fig-group><fig id="fig4"  position="float"><label><xref ref-type="fig" rid="fig4">Figure 4</xref></label><caption><title> Schematic diagram of erosion rig</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x10.png"/></fig><fig id="fig5"  position="float"><label><xref ref-type="fig" rid="fig5">Figure 5</xref></label><caption><title> Erosion damage at 30˚</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x11.png"/></fig><p>normally seen as observed in other erosion studies with pure aluminum or aluminium alloys [<xref ref-type="bibr" rid="scirp.57136-ref11">11</xref>] - [<xref ref-type="bibr" rid="scirp.57136-ref15">15</xref>] . Some particle fragments were embedded on the surfaces. The alumina particles were probably fragmented during the impact action, due to work-hardening of the aluminum surface inflicted by the permanent impacts and other aspect to consider could be that some particles made contact with embedded fragments and then were fractured. In <xref ref-type="fig" rid="fig6">Figure 6</xref>(a) and <xref ref-type="fig" rid="fig6">Figure 6</xref>(b), it is possible to observe a particle embedded on the surface with material piled-up in front of it. In addition, <xref ref-type="fig" rid="fig6">Figure 6</xref>(c) and d shows EDS spectra in two different points of the damaged surface. Here, the elements that appear in the chemical analysis are carbon (C), oxygen (O) and in the embedded particle a new element can be identified, Al, corresponding to the aluminum oxide. It is possible that a considerable amount of particles could be inserted on the surfaces due to these have high hardness combined with the soft surface of the aluminum alloy.</p></sec><sec id="s3_2"><title>3.2. Erosion Damage at 90˚</title><p>In respect to the wear damage at 90˚, the wear mechanism was high plastic deformationas that observed at 30˚. Here, it was possible to identify micro-ploughing and micro-cutting actions, embedded particles and wear debris deposited on the damaged surfaces (see Figures 7(a)-(c)). The wear mechanisms are quite consistent because of the soft structure that this aluminum alloy exhibited. The EDS analysis of <xref ref-type="fig" rid="fig7">Figure 7</xref>(d) confirmed the presence of another embedded abrasive particle by the elements found. These were carbon (C), oxygen (O) and aluminum (Al).</p></sec><sec id="s3_3"><title>3.3. Volume Loss and Erosion Rates</title><p>The volume loss was obtained dividing the mass loss (g) by the density of AISI 6061 (2.70 g/cm<sup>3</sup>). Two tests were conducted for each incident angle and an average volume loss and standard deviation was obtained. The maximum volume loss (mm<sup>3</sup>) was reached at 30˚, where the micro-cutting and micro-ploughing actions caused an increase in the material removal. On the other hand, the least volume loss was seen at 90˚. All the results were really close in this particular case. <xref ref-type="fig" rid="fig8">Figure 8</xref> shows the graph of the volume loss against the elapsed time. In all the incident angles, the volume loss was increased in relation to the time.</p><p>The total erosion value was also calculated and the results are presented in <xref ref-type="fig" rid="fig9">Figure 9</xref>(a) and <xref ref-type="fig" rid="fig9">Figure 9</xref>(b). It</p><fig-group id="fig6"><label><xref ref-type="fig" rid="fig6">Figure 6</xref></label><caption><title> (a) (b) Erosion at 30˚; (c) EDS piled-up material in front of the abrasive particle; (d) EDS embedded particle.</title></caption><fig id ="fig6_1"><label>(b)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x12.png"/></fig><fig id ="fig6_2"><label>(c)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x13.png"/></fig><fig id ="fig6_3"><label>(d)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x14.png"/></fig><fig id ="fig6_4"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x15.png"/></fig></fig-group><p>was obtained dividing the volume loss (mm<sup>3</sup>) by the total mass of particles (g) that impacted the surface after 20 min as indicated in ASTM G76-95 [<xref ref-type="bibr" rid="scirp.57136-ref9">9</xref>] . As mentioned previously, the maximum erosion rate was at 30˚ reducing progresively up to 90˚. Here, it is possible to conclude that this material in these particular testing conditions exhibited a ductile type behaviour based on the erosion literature graph presented in different erosion studies [<xref ref-type="bibr" rid="scirp.57136-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.57136-ref15">15</xref>] . This is a typical behavior of an aluminium alloy because of its high ductility, tenacity and high capacity to be deformed.</p><fig-group id="fig7"><label><xref ref-type="fig" rid="fig7">Figure 7</xref></label><caption><title> (a) (b) Erosion at 90˚; (c) Different erosion zone at 90˚; (d) EDS embedded particle.</title></caption><fig id ="fig7_1"><label>(b)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x16.png"/></fig><fig id ="fig7_2"><label>(c)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x17.png"/></fig><fig id ="fig7_3"><label>(d)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x18.png"/></fig><fig id ="fig7_4"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x19.png"/></fig></fig-group></sec></sec><sec id="s4"><title>4. Conclusions</title><p>1) The aluminum alloy AISI 6061 showed its maximum erosion rate at 30˚. This material exhibited typical ductile type behavior because of its high ductility, tenacity and softness. The lowest erosion rate was exhibited at 90˚, where work-hardening could be a factor to decrease the cutting efficiency of the abrasive particles on the surface.</p><fig id="fig8"  position="float"><label><xref ref-type="fig" rid="fig8">Figure 8</xref></label><caption><title> Graph volume loss vs. time</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x20.png"/></fig><fig-group id="fig9"><label><xref ref-type="fig" rid="fig9">Figure 9</xref></label><caption><title> (a) Total erosion rate vs. time; (b) Total erosion rate vs. impact angle.</title></caption><fig id ="fig9_1"><label>(b)</label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x21.png"/></fig><fig id ="fig9_2"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/4-1180279x22.png"/></fig></fig-group><p>2) SEM images were used to identify the wear mechanisms, which were characterized by high plastic deformation with typical damage modes such as micro-cutting and micro-ploughing actions, several grooves were formed on the surfaces due to the sliding component of the abrasive particles, with material piled-up at the sides and in the front of the particle trajectory. Embedded particles of alumina were also seen on the surfaces.</p></sec><sec id="s5"><title>Acknowledgements</title><p>We recognize the experimental support of CNMN-IPN (Center of Nano science and Micro and Nanotechnology) of the National Polytechnic Institute to complete the present work.</p></sec></body><back><ref-list><title>References</title><ref id="scirp.57136-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Budinski, K.G. (1995) Erosion of 316 Stainless Steel by Dicalcium Phosphate. Wear, 186-187, 145-149.  http://dx.doi.org/10.1016/0043-1648(95)07165-2</mixed-citation></ref><ref id="scirp.57136-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Macchini, R., Bradley, M.S.A. and Deng, T. (2013) Influence of Particle Size, Density, Particle Concentration on Bend Erosive Wear in Pneumatic Conveyors. 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