White, yellow and red sand samples were collected from several locations in the UAE. White sand is most commonly found close to the seashore (composed mainly of rhombic calcite) whereas yellow and red sands are in the inland desert. The yellow and red colors of the particles are related to the presence of iron oxides coating. Mikawer, Aritain and Hannon zeolites were obtained from areas with the same names in Jordan. Porcelanite was obtained from the Azraq area in Jordan. Kaolin, a hydrated aluminum silicate, was lot #120M0110V, from Sigma Aldrich (USA). Alumina was from Riedel-de-Haen (Germany) and silica was from Sharlau (Spain). Zeolites were pulverized to a fine powder. Sand and zeolite samples were washed repeatedly with deionized distilled water, dried to a constant weight at 110˚C then passed through a 300 μm sieve.

All primary chemicals used were of analytical reagent grade. Pb(NO₃)₂, NaOH and HNO₃ were from Panreac (Spain).

Pb(II) concentrations were determined using a Varian Liberty axial sequential inductively coupled plasma- atomic emission spectrometer “ICP-AES” (Australia). pH was measured on a 550A Thermo Orion pH meter (USA) fitted with a combined glass electrode. Solutions were shaken at 25.0˚C using an Edmund Buhler KS-15/ TH-15 shaker (Germany). Sand and zeolite samples were sieved using impact test sieves from Standard Sieve (USA), mesh model BS410, 1986 ST. Three brass frames with sieve sizes 300, 150 and 75 µm were employed. Fraction selected for experiments were less than 300 µm in diameter.

XRF images and spectra were obtained using a Horiba, XGT-7200V X-ray analytical microscope with silicon drift detector (SDD). Intensity measurements of compressed powdered samples were conducted using a tube voltage of 50 kV and an automatic tube current of 1 mA max with acquisition time of 60 s. Detected elements were Al, Si, K, Ca, Ti, Sr, S, Cl, Mg, Cr, V, Mn, Br, and Fe. Adsorbent images were taken using a charge- coupled device (CCD) as the X-ray detector. The CCD had a 100-fold magnifying scale.

SEM micrographs on sands were obtained using a high resolution TESCAN Vega 3-LMU, equipped with a 4-lens electron optics system and has a magnification range 2.5 - 1,000,000. Micrographs on platinum coated samples of zeolites and porcelanite were obtained using an FEI-INSPECT-F50, equipped with high resolution Schottky field emission (FEG), with magnification up to nano size.

Batch equilibration studies on sand were performed using 0.100 dm³ Pb(II) solutions. Initial Pb(II) concentrations were 300 ppm for all adsorbents. Additional removal experiments were carried out using 30 ppm solutions on alumina and silica, and 1000 ppm solutions on zeolites. Runs were conducted in triplicates. A known mass of adsorbent was added to Pb(II) solutions, the pH adjusted to the optimal removal value of 4.0 using 1.0 mol dm⁻³ HNO₃, then equilibrated at 25.0˚C for 2 h at 200 rpm. Final Pb(II) concentrations were determined by ICP. Prolonging the contact time between adsorbent and solution beyond 2 h did not result in further removal of Pb(II).

The dependence of Pb(II) removal efficiency for 300 ppm solutions on adsorbent dosage is shown in Figure 1. It is apparent that zeolites and porcelanite are highly efficient in removing Pb(II) from aqueous solutions. Zeolite efficiencies follow the order Hannon > Mikawer > Aritain and that for porcelanite is second to Hannon. The three zeolites, porcelanite and yellow sand are capable of completely removing lead from solutions containing 300 ppm Pb(II) at adsorbent dosages in the range 0.6 - 1.0 g/0.100 dm³. Other adsorbents are less efficient and follow the order white sand > red sand > kaolinite > silica > alumina. The maximum removal capacity of each adsorbent, defined as lead removed (mg) per g adsorbent, is reported in Table 1.

White and red sands are also capable of completely removing Pb(II), but only at significantly higher adsorbent dosages (2). For kaolinite, silica and alumina, 100% removal efficiencies could only be attained with low (30 ppm) Pb(II) concentrations and at adsorbent dosages higher than 3.0 g/0.100 dm³.

High removal efficiencies with zeolites was observed even for 1000 ppm Pb(II) solutions. At this concentration, 100% removal was attained with zeolite dosages above 2.5 g/0.100 dm³. Maximum adsorbent capacities for

Pb(II) are shown in Table 1. The results suggest that intermediate Si/Al ratios, in the range 2.70 - 2.93, listed in Table 3, correspond to optimal efficiency for this class of adsorbers.

Zeolite tuff locations are given in Table 2. All samples are hypohyaline grey, red to light brown in color with rounded vesicles of different sizes. Most of the vesicles are partially filled with secondary zeolites. Calcite occurs partially as a filling material in the vesicles and between zeolites. X-ray diffraction analysis proved the presence of smectite as an alteration products of the tuffaceous material (balsatic in composition) [16] . All sam-

ples contain phillipsite which occurs as colorless radiating aggregates in the cement and grows at the expense of the glassy matrix. Phillipsite is also found as single prismatic crystals of spherulitic texture. Chabazite occurs in Mikawer and Hannon as isolated crystals or aggregates [15] . The crystals are characterized by rhombohedral cleavage with penetration twinning and zoning and vary in size from few microns up to 200 µm. Faujasite occurs only in the Hannon zeolite, growing as an aggregate on the vesicles wall with a size range 50 - 100 µm. The crystals are octahedrons, colorless, equant and isotropic. Mikawer and Aritain samples are reddish brown due to the presence of the phillipsite-chabazite tuff. For Mikawer and Aritain, total zeolites are 57% and CEC is 140 meq/100g [17] . Hannon samples are gray faujasite-phillipsite in 6 m thick horizon, have 29% faujasite (highest in Jordan), 45% total zeolites and a CEC of 154 meq/100g [17] .

Thick deposits of porcelanite (active silica) are found in northeastern Jordan (Badia region) and samples for this study were collected from the Azraq area, located within this region. Porcelanite occurs in two layers: the lower (0.6 - 1.3 m thick) is white, gray, and pink and the upper (0.4 - 0.6 m) is white-gray. The layers are separated by dark brown-black chert (5 - 15 cm) and chalk (0.6 - 1.8 m). The mineralogical composition of porcelanite is dominated by opal-CT (cristoballite-tridymite) and quartz. The SiO₂ content is >90%. The high purity of the porcelanite layers and the low iron content (average 0.06%) result in a high average whiteness index (87%) [15] . Opal-CT is poorly crystalline and its SiO₂ phase consists of partially unshared SiO₄ tetrahedra. Its broken edges and large surface area contribute to its high adsorption capacity. It has the same chemical composition as quartz (sand). Quartz is made up of SiO₄ tetrahedra shared in all directions (3-dimensional structure, with no broken edges), which explains its electrical neutrality and poor adsorption capacity [16] .

Chemical compositions of zeolites, sands and kaolinite, as determined by XRF, are given in Table 3. Metal oxide content and the corresponding bulk molar ratios of Si/Al (number of silicon framework atoms/number of aluminum framework atoms) ratios are also shown. This ratio varies from 1.40 for kaolinite to 4.68 for red sand. The Si/Al ratio has been shown to play an important role also in the conversion of fly ash compounds into zeolites [18] . For the most efficient adsorbents, the range is narrow, 2.70 - 2.93, suggesting that very low or very high ratios inhibit removal. Pure alumina (Al₂O₃) and pure silica (SiO₂), representing both extremes of this ratio, are not efficient adsorbers. Kaolinite, with a ratio of 1.40, is also not efficient, primarily because of the electrical neutrality of the Si-tetrahedral and Al-octahedral sheets of kaolinite (two-dimensional 1:1 structure). Whereas zeolites are relatively rich in iron and sands in calcium, it is not certain how, if at all, these metals contribute to their adsorption properties. Table 3 also shows that, with the exception of white sand, magnesium is present in fair amounts in both zeolites and sands. By contrast, white sand is exceptionally rich in lime (CaO) due to the presence of calcite (CaCO₃). Zeolites and kaolinite have significantly higher content of TiO₂ when compared to sands. Although porcelanite does not contain aluminum, its high adsorptive behavior is probably due to its fine size fraction and the presence of negative charge along the broken edges of the shared SiO₄ tetrahedra that form the framework structure of its SiO₂ phases [15] .

SEM micrographs for the three zeolites, porcelanite and the three types of sand are presented at various resolutions in Figures 2-4, respectively. The micrographs show that sands have significantly larger grain size (lower porosity) than zeolites or porcelanite, with portions of the sand surfaces being very smooth. The lower porosity of sand in comparison with zeolites and porcelanite is related to the absence of adsorptive surfaces. Zeolites and porcelanite have a typical microporous texture that results from their fine crystal size (high surface areas) (Figure 2 and Figure 3). Figure 2 also shows the euhedral nature of zeolites (phillipsite). Zeolites that have a channel like structure and high cation exchange capacity (CEC) can act as molecular sieves [13] . Figure 3 illustrates the microporous texture and large surface area of porcelanite. Figure 4 illustrates the morphology of the three sand-silt size varieties. All sand samples have three-dimensional crystal forms. The mineralogical composition of the three types is variable as some indicate cleavage planes (Figure 4(a) and Figure 4(b)). White and yellow sands are dominated by the electrically neutral calcite (CaCO₃). Red sand is dominated by quartz (SiO₂) which has an electrically neutral tetrahedral network (tectosilicates) structure. Thus sands are electrically neutral and have relatively very small surface areas in comparison with zeolites, which have a high CEC, and porcelanite, which is highly microporous. This, at least in part, explains why zeolites and porcelanite are better adsorbers than sand. Nevertheless, the morphology, including channels and crevices, should be viewed in conjunction with chemical compositions of adsorber and adsorbate and the ability of the adsorber not only to accommodate the

latter within its structure but also to form strong bonds with it.

It is worthy of note that zeolites and porcelanite are significantly more efficient removers of Pb(II) than sands and this is notwithstanding the comparable Si/Al ratios of zeolites to those for white and yellow sands. The efficiency difference suggests that morphology, in addition to chemical composition, has an important role. In particular, a combination of factors, including shapes and sizes of the crystals, channels in the zeolites and pores in porcelanite investigated appear to favor accommodation of Pb(II).