<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">JEP</journal-id><journal-title-group><journal-title>Journal of Environmental Protection</journal-title></journal-title-group><issn pub-type="epub">2152-2197</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/jep.2014.58075</article-id><article-id pub-id-type="publisher-id">JEP-46826</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Earth&amp;Environmental Sciences</subject></subj-group></article-categories><title-group><article-title>
 
 
  The Numerical Investigation on Oil Slick Behavior behind the Oil Boom
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>ai</surname><given-names>Gong</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pavel</surname><given-names>Tkalich</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Haihua</surname><given-names>Xu</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Tropical Marine Science Institute, National University of Singapore, Singapore City, Singapore</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>tmsgk@nus.edu.sg(AG)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>11</day><month>06</month><year>2014</year></pub-date><volume>05</volume><issue>08</issue><fpage>739</fpage><lpage>744</lpage><history><date date-type="received"><day>9</day>	<month>April</month>	<year>2014</year></date><date date-type="rev-recd"><day>2</day>	<month>May</month>	<year>2014</year>	</date><date date-type="accepted"><day>24</day>	<month>May</month>	<year>2014</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
   The dynamics of contained oil spills is investigated based on multiphase CFD (Computational Fluid Mechanics) model. The oil slick shape behind the oil boom under water current is studied. The velocity field in the oil slick is compared with the velocity field in pure water flow. The thickness of the oil slick is studied quantitatively. It is found that there is a fixed linear relationship between the oil slick relative thickness and the Froude number for different oil, different current velocity, different boom draft and different volume of oil. 
 
</p></abstract><kwd-group><kwd>Oil Spill</kwd><kwd> Oil Boom</kwd><kwd> Oil Slick</kwd><kwd> CFD</kwd><kwd> VOF (Volume of Fluid)</kwd><kwd> Multiphase Flow</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Marine oil spills can cause serious damage to natural resources and to those whose livelihoods depend on these resources. Therefore, it is important to improve techniques and equipment that facilitate spill cleanup [<xref ref-type="bibr" rid="scirp.46826-ref1">1</xref>] . The common response to an oil spill on water is to contain the oil with booms and recover it with skimming devices. However, in some situations, the booms fail to hold the oil and the oil will escape underneath the boom due to hydrodynamic forces. Poor recovery of oil using booms requires significantly higher cleanup costs. Therefore a better understanding of the dynamics of oil slicks is required [<xref ref-type="bibr" rid="scirp.46826-ref2">2</xref>] .</p><p>Besides wind and wave effects, there are three failure mechanisms for the oil boom in the current [<xref ref-type="bibr" rid="scirp.46826-ref3">3</xref>] : drainage failure, entrainment failure and critical accumulation failure. In drainage failure, the boom draft is insufficient to contain the oil slick and some oil goes underneath the barrier. Cross and Hoult described the oil slick profile theoretically [<xref ref-type="bibr" rid="scirp.46826-ref4">4</xref>] [<xref ref-type="bibr" rid="scirp.46826-ref5">5</xref>] . In entrainment failure, oil droplets are broken off from the oil and are swept underneath the boom if the buoyancy forces are insufficiently large [<xref ref-type="bibr" rid="scirp.46826-ref6">6</xref>] . Leibovich [<xref ref-type="bibr" rid="scirp.46826-ref6">6</xref>] and Milgram et al. [<xref ref-type="bibr" rid="scirp.46826-ref7">7</xref>] ascribe the entrainment to breaking of Kelvin-Helmholtz water-oil interfacial waves at sufficiently large relative velocity. Many experimental results can be found in the literatures [<xref ref-type="bibr" rid="scirp.46826-ref6">6</xref>] -[<xref ref-type="bibr" rid="scirp.46826-ref9">9</xref>] . For highly viscous oils of kinematic viscosities exceeding 3000 cSt, Delvigne [<xref ref-type="bibr" rid="scirp.46826-ref3">3</xref>] showed a third failure mechanism: critical accumulation (oil creep) for relative velocities exceeding about 0.15 m/s, independently of the boom draft. Johnston [<xref ref-type="bibr" rid="scirp.46826-ref10">10</xref>] indicated that this mode of failure is due to an insufficient circulation within the oil and suggested to use Bingham-plastic model instead of Newtonian model to improve the understanding of this mode of failure.</p><p>Although oil boom is widely used, it is far from being fully investigated. For understanding the boom failure mechanism, it is important to investigate the oil slick behavior behind the boom and the details of the flow field near the boom. For the limit of the measurement approach, it is hard to know the details of the flow field in the oil slick. CFD has its advantages to obtain the process of the oil slick propagation and the details of the flow field in the oil slick. Tkalich et al. [<xref ref-type="bibr" rid="scirp.46826-ref11">11</xref>] -[<xref ref-type="bibr" rid="scirp.46826-ref13">13</xref>] developed a multiphase oil spill model to simulate consequences of oil spill in the marine environment. Goodman et al. [<xref ref-type="bibr" rid="scirp.46826-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.46826-ref15">15</xref>] investigated the boom failure mechanisms using CFD approach. They only qualitatively studied the boom failure but did not give the quantitative details of the oil slick profiles and the velocity field. In this paper, an open source CFD software package, OpenFOAM v2.2.2, has been used to simulate the oil water flow around a boom. The details of the flow field in the oil slick are studied and the thickness of oil slick is investigated quantitatively.</p></sec><sec id="s2"><title>2. Governing Equation</title><p>For the purpose of investigating the oil slick behavior behind the boom under a water current, a CFD software, OpenFOAM, is employed to carry out the numerical simulation. In this software, the Reynolds averaged Navier- Stokes equations (RANS equations) are solved numerically and <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x5.png" xlink:type="simple"/></inline-formula> turbulence modelling is adopted. The volume of fluid (VOF) method is used to track the interface between the oil and water. The incompressible RANS momentum equation solved in the software can be written as:</p><disp-formula id="scirp.46826-formula1565"><label>(1)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x6.png"  xlink:type="simple"/></disp-formula><p>where <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x7.png" xlink:type="simple"/></inline-formula> is the fluid velocity vector, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x8.png" xlink:type="simple"/></inline-formula>is the external force vector, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x9.png" xlink:type="simple"/></inline-formula>is the fluid density, p is the pressure, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x10.png" xlink:type="simple"/></inline-formula>is the dynamic viscosity, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x11.png" xlink:type="simple"/></inline-formula>is the Reynolds stress and can be approximated by using Boussinesq’s isotropic eddy viscosity hypothesis as follows:</p><disp-formula id="scirp.46826-formula1566"><label>(2)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x12.png"  xlink:type="simple"/></disp-formula><p>where <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x13.png" xlink:type="simple"/></inline-formula> is the Kronecker delta, k is the turbulent kinetic energy, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x14.png" xlink:type="simple"/></inline-formula>is an effective viscosity, the sum of the turbulent eddy viscosity <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x15.png" xlink:type="simple"/></inline-formula> and molecular dynamic viscosity<inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x16.png" xlink:type="simple"/></inline-formula>:</p><disp-formula id="scirp.46826-formula1567"><label>(3)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x17.png"  xlink:type="simple"/></disp-formula><p>The turbulent eddy viscosity <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x18.png" xlink:type="simple"/></inline-formula> is calculated using the standard <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x19.png" xlink:type="simple"/></inline-formula> model [<xref ref-type="bibr" rid="scirp.46826-ref16">16</xref>] as follows:</p><disp-formula id="scirp.46826-formula1568"><label>(4)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x20.png"  xlink:type="simple"/></disp-formula><p>where <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x21.png" xlink:type="simple"/></inline-formula> is a dimensionless constant, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x21.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x22.png" xlink:type="simple"/></inline-formula>represents the dissipation rate of turbulent kinetic energy. The transport equations for the turbulent kinetic energy k and the dissipation rate <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x21.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x22.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x23.png" xlink:type="simple"/></inline-formula> are given by:</p><disp-formula id="scirp.46826-formula1569"><label>(5)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x24.png"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.46826-formula1570"><label>(6)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x25.png"  xlink:type="simple"/></disp-formula><p>where<inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x26.png" xlink:type="simple"/></inline-formula>, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x26.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x27.png" xlink:type="simple"/></inline-formula>, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x26.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x27.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x28.png" xlink:type="simple"/></inline-formula>, <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x26.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x27.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x28.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x29.png" xlink:type="simple"/></inline-formula>are the model constants determined experimentally.</p></sec><sec id="s3"><title>3. Numerical Simulations</title><p>The numerical simulation scenarios are chosen as the similar geometry with the real situation of the Singapore sea area. The computational domain is 30 m long and 5 m deep (see <xref ref-type="fig" rid="fig1">Figure 1</xref>). The oil boom is placed near the surface and in the middle of the computational domain in length direction. The boom draft D is chosen as 0.5 m or 1 m. The current velocity U range is chosen of 0.1 - 0.5 m/s at interval of 0.1 m/s.</p><p>There are four type of oil (listed in <xref ref-type="table" rid="table1">Table 1</xref>) used in the simulation which include from light to heavy oil and from low to high viscosity oil. The initial oil volume Q is chosen as 1.2 m<sup>3</sup> or 3.6 m<sup>3</sup> per unit boom length.</p><p>A summary of cases are listed in <xref ref-type="table" rid="table2">Table 2</xref>. For every case label, there are five different current velocities from 0.1 m/s to 0.5 m/s. Therefore, a total of 80 cases of oil slick are carried out in this study.</p><p>For the numerical simulation of all the case, the same meshes are adopted with just slight difference between different boom drafts. The total number of cells is about 53,000. The minimum cell size is 0.025 m. The finest cells are placed near the boom and the water surface. <xref ref-type="fig" rid="fig2">Figure 2</xref> shows the meshes used in the simulation.</p></sec><sec id="s4"><title>4. Analysis of the Numerical Results</title><sec id="s4_1"><title>4.1. Flow Field near the Boom</title><p>First at all, a case without oil has been carried out to compare with the case with oil. <xref ref-type="fig" rid="fig3">Figure 3</xref> shows the flow</p><table-wrap id="table1" ><label><xref ref-type="table" rid="table1">Table 1</xref></label><caption><title> Four type of oil used in simulation</title></caption><table><tbody><thead><tr><th align="center" valign="middle" ></th><th align="center" valign="middle" >Density of oil <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x30.png" xlink:type="simple"/></inline-formula> (kg/m<sup>3</sup>)</th><th align="center" valign="middle" >Viscosity of oil <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x31.png" xlink:type="simple"/></inline-formula> (10<sup>−6</sup> m<sup>2</sup>/s)</th></tr></thead><tr><td align="center" valign="middle" >Oil 1</td><td align="center" valign="middle" >888</td><td align="center" valign="middle" >70</td></tr><tr><td align="center" valign="middle" >Oil 2</td><td align="center" valign="middle" >949</td><td align="center" valign="middle" >3500</td></tr><tr><td align="center" valign="middle" >Oil 3</td><td align="center" valign="middle" >943</td><td align="center" valign="middle" >300</td></tr><tr><td align="center" valign="middle" >Oil 4</td><td align="center" valign="middle" >978</td><td align="center" valign="middle" >2300</td></tr></tbody></table></table-wrap><table-wrap id="table2" ><label><xref ref-type="table" rid="table2">Table 2</xref></label><caption><title> Summary of the simulation cases</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >D (m)</th><th align="center" valign="middle" >Oil type Q (m<sup>3</sup>/m)</th><th align="center" valign="middle" >1</th><th align="center" valign="middle" >2</th><th align="center" valign="middle" >3</th><th align="center" valign="middle" >4</th></tr></thead><tr><td align="center" valign="middle"  rowspan="2"  >1</td><td align="center" valign="middle" >1.2</td><td align="center" valign="middle" >a</td><td align="center" valign="middle" >e</td><td align="center" valign="middle" >i</td><td align="center" valign="middle" >m</td></tr><tr><td align="center" valign="middle" >3.6</td><td align="center" valign="middle" >b</td><td align="center" valign="middle" >f</td><td align="center" valign="middle" >j</td><td align="center" valign="middle" >n</td></tr><tr><td align="center" valign="middle"  rowspan="2"  >0.5</td><td align="center" valign="middle" >1.2</td><td align="center" valign="middle" >c</td><td align="center" valign="middle" >g</td><td align="center" valign="middle" >k</td><td align="center" valign="middle" >o</td></tr><tr><td align="center" valign="middle" >3.6</td><td align="center" valign="middle" >d</td><td align="center" valign="middle" >h</td><td align="center" valign="middle" >l</td><td align="center" valign="middle" >p</td></tr></tbody></table></table-wrap><fig id="fig1"  position="float"><label><xref ref-type="fig" rid="fig1">Figure 1</xref></label><caption><title> Schematic drawing of the computational domain</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x32.png"/></fig><fig-group id="fig2"><label><xref ref-type="fig" rid="fig2">Figure 2</xref></label><caption><title> Schematic drawing of the computational domain.</title></caption><fig id ="fig2_1"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x33.png"/></fig><fig id ="fig2_2"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x34.png"/></fig></fig-group><fig-group id="fig3"><label><xref ref-type="fig" rid="fig3">Figure 3</xref></label><caption><title> Comparison of the flow field near the boom with (at right) and without (at left) oil.</title></caption><fig id ="fig3_1"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x35.png"/></fig><fig id ="fig3_2"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x36.png"/></fig><fig id ="fig3_3"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x37.png"/></fig><fig id ="fig3_4"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x38.png"/></fig></fig-group><p>field near the boom of these two cases. It shows that the current velocity distribution is almost same at the section far from the boom in the case without oil (left). But for the case with oil (right), the velocity distribution is changed in the oil slick. This phenomenon means that it is not enough to estimate the boom efficiency only based on the velocity field of the case without oil. It is necessary to carry out the numerical simulation of the case with oil based on multiphase model.</p><p><xref ref-type="fig" rid="fig4">Figure 4</xref> shows the comparison of the oil slick behavior of low and high viscosity oil when the flow becomes steady. For the low viscosity oil (top figure), the oil slick is longer. For the high viscosity, a head wave is formed on the upstream edge of the slick. The streamline shows that there is only one main vortex in the oil slick for the low viscosity oil and two vortices in the oil slick for the high viscosity oil.</p></sec><sec id="s4_2"><title>4.2. Oil Slick Behaviors behind the Boom</title><p><xref ref-type="fig" rid="fig5">Figure 5</xref> shows the relationship between the densimetric Froude number and the relative thickness of the oil slick. Where the densimetric Froude number is defined as follows:</p><disp-formula id="scirp.46826-formula1571"><label>(7)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x39.png"  xlink:type="simple"/></disp-formula><p>And the relative thickness is defined as the ratio of the oil slick thickness h and the oil characteristic length</p><fig-group id="fig4"><label><xref ref-type="fig" rid="fig4">Figure 4</xref></label><caption><title> The streamline of the flow field and the behavior of the oil slick behind the boom (Top: case b; bottom: case f; current velocity U = 0.5 m/s).</title></caption><fig id ="fig4_1"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x40.png"/></fig><fig id ="fig4_2"><label></label><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x41.png"/></fig></fig-group><fig id="fig5"  position="float"><label><xref ref-type="fig" rid="fig5">Figure 5</xref></label><caption><title> The relative thickness of oil slick versus the densimetric Froude number</title></caption><graphic mimetype="image"   position="float"  xlink:type="simple"  xlink:href="http://html.scirp.org/file/9-6702308x42.png"/></fig><p><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x43.png" xlink:type="simple"/></inline-formula>. This characteristic length represent the length of the initial oil slick if set the initial oil slick in a square shape. The formula of the fitting line in <xref ref-type="fig" rid="fig5">Figure 5</xref> by using least square method is as follow:</p><disp-formula id="scirp.46826-formula1572"><label>(8)</label><graphic position="anchor" xlink:href="http://html.scirp.org/file/9-6702308x44.png"  xlink:type="simple"/></disp-formula><p>This formula shows that the oil slick thickness is an function of initial oil volume Q, the current velocity U, the density of oil <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x45.png" xlink:type="simple"/></inline-formula> and the boom draft D. The significance of the fitted line is that there is a fixed linear relation between Fr and <inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x45.png" xlink:type="simple"/></inline-formula><inline-formula><inline-graphic xlink:href="http://html.scirp.org/file/9-6702308x46.png" xlink:type="simple"/></inline-formula> in spite of boom draft, initial oil volume and the oil type. It means that the relative thickness could be estimated by densimetric Froude number without carrying out the simulation. Moreover, the oil slick thickness is significant for the boom failure.</p></sec></sec><sec id="s5"><title>5. Conclusion</title><p>A series of numerical simulation cases are carried out based on OpenFOAM multiphase solver in order to study the oil slick behavior behind the oil boom. The flow field near the boom is studied. The relationship of the relative thickness of oil slick with the Froude number is analyzed. It is found that there is a linear relationship between the relative oil slick thickness and the Froude number. This means that we can estimate the relative oil slick thickness using Froude number by the fixed linear relationship regardless of boom draft, initial oil volume and oil type.</p></sec></body><back><ref-list><title>References</title><ref id="scirp.46826-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Amini, A., Bollaert, E., Boillat, J.-L. and Schleiss, A.J. (2008) Dynamics of Low-Viscosity Oils Retained by Rigid and Flexible Barriers. Ocean Engineering, 35, 1479-1491. http://dx.doi.org/10.1016/j.oceaneng.2008.06.010</mixed-citation></ref><ref id="scirp.46826-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Chebbi, R. (2009) Profile of Oil Spill Confined with Floating Boom. 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