<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">MSA</journal-id><journal-title-group><journal-title>Materials Sciences and Applications</journal-title></journal-title-group><issn pub-type="epub">2153-117X</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/msa.2013.41009</article-id><article-id pub-id-type="publisher-id">MSA-27081</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Chemistry&amp;Materials Science</subject></subj-group></article-categories><title-group><article-title>
 
 
  Influence of Hot Band Annealing and Cold Rolling on Texture and Ridging of 430 Stainless Steel Containing Aluminum
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>udipta</surname><given-names>Patra</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lokesh</surname><given-names>Kumar Singhal</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Jindal Stainless Limited, Hisar, India.</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>psudiptapatra@gmail.com(UP)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>24</day><month>01</month><year>2013</year></pub-date><volume>04</volume><issue>01</issue><fpage>70</fpage><lpage>76</lpage><history><date date-type="received"><day>October</day>	<month>7th,</month>	<year>2012</year></date><date date-type="rev-recd"><day>November</day>	<month>4th,</month>	<year>2012</year>	</date><date date-type="accepted"><day>December</day>	<month>2nd,</month>	<year>2012</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
   An approach to optimize the processing parameters to get superior ridging resistance and mechanical properties in commercial production of 430 ferritic stainless steel has been studied. Attention was also paid to improve productivity and energy saving without hampering the surface and mechanical property aspects of the material. Hot rolled coils annealed by slow cooling under insulated cover exhibit better ridging resistance than bell annealing treatment with a minor decrease in ductility. Soaking temperature prior to hot rolling has a significant effect on ridging resistance.
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</p></abstract><kwd-group><kwd>Ridging; Hood Annealing; Bell Annealing; Microstructure; Texture; 430 Stainless Steel</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Ferritic stainless steel 430 grade is extensively used in various applications like kitchen wares, electrical appliances, automobile parts and white goods on account of its good corrosion resistance, high thermal conductivity and beautiful surface gloss as a low cost alternative to nickel containing austenitic stainless steel. Occurrence of ridging after cold forming operation can hamper the surface finish of the material necessitating considerable effort in polishing of the surface. Wright [<xref ref-type="bibr" rid="scirp.27081-ref1">1</xref>] has pointed out that ridging is associated with anisotropic plasticity of bands of contrasting textures. Shin et al. [<xref ref-type="bibr" rid="scirp.27081-ref2">2</xref>] established that differences in the deformation behavior of {001} &lt;110&gt; and {111} &lt;110&gt; grain colonies arises due to difference in their plastic strain ratio during cold forming operation thereby causing ridging. Extensive efforts have been made to minimize ridging. Kim et al. [<xref ref-type="bibr" rid="scirp.27081-ref3">3</xref>] suggested refinement of solidification structure by using EMS to avoid columnar grains with &lt;001&gt;//ND orientation is utilized for improving ridging resistance. This entails significant capital cost. Kimura et al. [<xref ref-type="bibr" rid="scirp.27081-ref4">4</xref>] advocated high interpass time during roughing in conjunction with high reduction per pass to facilitate recrystallization in the colony structures. High interpass time during rough rolling can adversely affect the productivity of the hot mill. Since 430 stainless steel has two phase α + γ structure during hot rolling, some martensite forms on cooling of the hot coils. Such coils are generally subjected to bell annealing to transform the martensite to ferrite to facilitate cold rolling. Jha et al. [<xref ref-type="bibr" rid="scirp.27081-ref5">5</xref>] concluded that continuously hot band annealed material exhibits superior roping characteristic. In this study, they also noticed that more than 25% martensite in the microstructure can cause breakage of the coil during cold rolling. Huh et al. [<xref ref-type="bibr" rid="scirp.27081-ref6">6</xref>] observed pronounced through thickness texture gradient in hot bands of this grade which had an impact on appearance of ridging in the final recrystallised sheet. Huh and Engler [<xref ref-type="bibr" rid="scirp.27081-ref7">7</xref>] suggested that introducetion of intermediate anneal during cold rolling weaken the texture gradients and minimize the extent of ridging compared to single stage cold rolled product. Avila &amp; Zapata [<xref ref-type="bibr" rid="scirp.27081-ref8">8</xref>] annealed the hot bands of 430 grade in 2 phase region and followed by controlled cooling to obtain dual phase structure. These authors noted that grain refinement due to martensite dispersion during cold rolling resulted in significant improvement in ridging. Mola et al. [<xref ref-type="bibr" rid="scirp.27081-ref9">9</xref>] found that samples without hot band annealing when subjected to cold rolling and subsequent bell annealing exhibited superior ridging resistance compared to conventional bell annealed product which was continuously annealed after cold reduction. Batch annealing is an energy intensive operation which increases cost of the finished product. The present paper highlights the beneficial use of the intrinsic heat of the hot rolled coil under an insulated hood to enable the coil to cool slowly and thereby facilitate transformation of austenite to ferrite and reduce the hardness of martensite to permit extensive cold reduction. In this manner 430 grade with superior ridging resistance has been successfully produced at a lower processing cost. The paper describes plant trials with different processing routes with variations in mode of annealing and amount of cold reduction. The study was done on coils made from continuously cast slabs through EAF-AOD-LF-CC route without using EMS. Mechanical properties, texture, ridging characteristics of product in inner and outer wrap as well as in the middle of the coils are presented.</p></sec><sec id="s2"><title>2. Experimental Detail</title><p>The chemical composition of AISI 430 ferritic stainless steel used in the current study is shown in <xref ref-type="table" rid="table1">Table 1</xref>. Four Continuously casted slabs of 200 mm thickness were hot rolled in a roughing and steckel mill to 2.5 mm thick coil. Processing schedule of these four slabs is given in Figures 1(a)-(d). Coil-A was soaked at 1170˚C and then hot rolled in roughing and finishing at steckle mill upto 2.5 mm thickness. The coil was cooled in air to room temperature and then bell annealed at 820˚C for 8 hrs. Thereafter it was cold rolled to 0.6 mm and finally continuously annealed at 820˚C. Coil B was soaked at 1210˚C and then it followed the same route of coil A, just to investigate the effect of soaking temperature. Coil C and D were kept in an insulated box just after hot rolling and allowed to cool slowly. Coil C was then directly cold rolled to 0.6 mm and finally continuous annealed at 820˚C. Coil D was subjected to 33% cold reduction and continuously annealed at 820˚C and thereafter cold rolled to 0.6 mm and finally continuously annealed at 820˚C. Samples from the centre as well as end portions were cut from the coils for microstructural characterization and mechanical property evaluation. The specimens were etched chemically by glyceregia reagent to reveal the microstructural features in optical microscope. Microstructures were examined by Carl Zeiss optical microscope and Carl Zeiss EVO-40 scanning electron microscope. Micro-texture was studied by Zeiss EVO-40 SEM attached with Oxford Inca EBSD system and analysed with HKL software. Ridging characteristics were measured after giving 20% tensile elongation by instrument manufactured by Mitutoyo. Hardness was evaluated by Vickers hardness test under 10 kg load. Tensile testing was done in a universal testing machine and Ericsson cupping test was performed for investigating the stretchability of the sheets.</p><p><xref ref-type="table" rid="table1">Table 1</xref>. Chemical composition of the steel used in this study. <img src="9-7700896\bbc31fa1-52b5-45b5-925f-df03a15dd3ba.jpg" /></p></sec><sec id="s3"><title>3. Results and Discussion</title><sec id="s3_1"><title>3.1. Ridging Resistance</title><p>Ridging height after 20% elongation under tension is shown in <xref ref-type="fig" rid="fig2">Figure 2</xref>. Ridging height is highest for Coil A and then it has decreased in coil B, C and D. In all cases coil end sample is showing higher ridging resistance than coil centre sample. As coil A and coil B had similar processing schedule and only difference is soaking temperature, better ridging resistance in coil B can be explained by the high soaking temperature. Hood annealed coils are showing better ridging resistance than bell annealed coils due to the randomization of initial texture by deformation in dual phase microstructure.</p></sec><sec id="s3_2"><title>3.2. Microstructure and Texture of Hot Bands</title><p>Microstructure of as hot rolled coil B is shown in <xref ref-type="fig" rid="fig3">Figure 3</xref>. It contains approximately 35% martensite in ferrite. Microstructure of entire cross section of coil B after bell annealing is shown in <xref ref-type="fig" rid="fig4">Figure 4</xref>. Ferrite grains are finer</p><p>near surface and relatively coarser in the center. Interspersed carbide particles are also visible. Surface region consists of equiaxed grain of size of 30 - 35 &#181;m but center layer has elongated grains with 80 - 100 &#181;m. The finer equiaxed grains constitute only 30 volume percent of the microstructure. Texture study revealed random texture in the subsurface layer and mostly α fiber component in the center region of the band. Wei et al. [<xref ref-type="bibr" rid="scirp.27081-ref10">10</xref>] studied the hot band annealing of a ferritic stainless steel and concluded that elongated ferrite grains with α fibre orientation had not recrystallized during bell annealing.</p><p>Microstructure of the coils C&amp;D after hood annealing exhibits banded structure with lamella of ferrite and tempered martensite (<xref ref-type="fig" rid="fig5">Figure 5</xref>(a)). Hardness after hood annealing decreased from nearly 200 HV to 175 HV. Hood annealed coils could be given very heavy deformation without any breakage of the coil with beneficial effect on ridging resistance. Microstructure of coil D after 33% cold reduction followed by continuous annealing is shown in <xref ref-type="fig" rid="fig5">Figure 5</xref>(b).</p></sec><sec id="s3_3"><title>3.3. Microstructure and Mechanical Properties of the Cold Rolled and Annealed Samples</title><p>In coil A&amp;B, equiaxed ferrite grains are present in both coil center and edge in the cold rolled and annealed</p><p>recondition (<xref ref-type="fig" rid="fig6">Figure 6</xref>). Recrystallized grains of ASTM 8.5 to 9 (<xref ref-type="table" rid="table2">Table 2</xref>) were observed in the center samples of the coils whereas coil end samples are slightly finer (ASTM 9 - 9.5) in size.</p><p>In the hood annealed coils, while recrystallization occurred after cold rolling and annealing, the grains are pancake shaped (<xref ref-type="fig" rid="fig7">Figure 7</xref>). The grains are also slightly finer in size as shown in <xref ref-type="table" rid="table2">Table 2</xref>. Occurrence of deformation in the presence of martensite can be the reason of finer grains in hood annealed coils.</p><p>Due to decrease in the grain size, increase in the yield strength and marginal decrease in the ductility can be observed (<xref ref-type="table" rid="table2">Table 2</xref>) in the hood annealed coils.</p></sec><sec id="s3_4"><title>3.4. Texture of the Cold Rolled and Annealed Coils</title><p><xref ref-type="fig" rid="fig8">Figure 8</xref> shows φ<sub>2 </sub>= 45˚ section of the ODF measured in the cold rolled and annealed coils. A weak &lt;111&gt;</p></sec></sec></body><back><ref-list><title>References</title><ref id="scirp.27081-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">R. N. Wright, “Anisotropic Plastic Flow in Ferritic Stainless Steels and the Roping Phenomenon,” Metallurgical and Materials Transactions, Vol. 3, No. 1, 1967, pp. 83-91.  
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