<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">ACES</journal-id><journal-title-group><journal-title>Advances in Chemical Engineering and Science</journal-title></journal-title-group><issn pub-type="epub">2160-0392</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/aces.2013.31006</article-id><article-id pub-id-type="publisher-id">ACES-26479</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Chemistry&amp;Materials Science</subject></subj-group></article-categories><title-group><article-title>
 
 
  Analysis of a Recent Biofilter Model for Toluene Biodegradation
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>uhammad</surname><given-names>Qasim</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zarook</surname><given-names>Shareefdeen</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Department of Chemical Engineering, American University of Sharjah, Sharjah, UAE</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>zshareefdeen@aus.edu(ZS)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>11</day><month>01</month><year>2013</year></pub-date><volume>03</volume><issue>01</issue><fpage>57</fpage><lpage>66</lpage><history><date date-type="received"><day>September</day>	<month>29,</month>	<year>2012</year></date><date date-type="rev-recd"><day>October</day>	<month>30,</month>	<year>2012</year>	</date><date date-type="accepted"><day>November</day>	<month>9,</month>	<year>2012</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
   This paper investigates and provides a critical analysis of the toluene biofilter model developed by Li and De Visscher. The model simulation results have been reproduced and compared with several sets of experimental data from literature. Three different model variations are considered: model with no substrate inhibition, with substrate inhibition, and with air flow rate modification. A sensitivity analysis has been performed on model to study the effect of important parameters on the removal efficiency. Model limitations and improvements have been highlighted. 
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</p></abstract><kwd-group><kwd>Air Pollution; Biofilter; Modeling; Toluene; Volatile Organic Compound</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>The upsurge of strict environmental regulations to maintain good air, soil and water quality requires the use of proper pollution control and pollution prevention equipment. Traditional pollution control technologies such as incineration, carbon adsorption and wet-scrubbing may be used to control pollution. However, these conventional techniques are becoming more expensive due to more stringent environmental regulations [<xref ref-type="bibr" rid="scirp.26479-ref1">1</xref>]. In the field of pollution control, biological treatment such as biofiltration is continuing to gain attention as an alternative to the conventional techniques.</p><p>Biofiltration is a pollution control technique that uses living microorganisms to capture and degrade pollutants from air. It is a process that combines basic mechanisms of adsorption, biodegradation and desorption of gas phase pollutants [<xref ref-type="bibr" rid="scirp.26479-ref2">2</xref>]. A biofilter is simply a packed bed that utilizes a packing material with microorganisms such as bacteria immobilized as biofilm on the surface and the pore structures of the packing material. The packing material may be particles such as peat, compost, peat/perlite mixture or organic or inorganic commercial media materials. The flow of contaminated air through the biofilter results in the degradation of the pollutants by the immobilized microorganisms. Biofilter performance is affected by a number of factors such as the composition and relative humidity of the waste stream, airflow velocity, temperature and pH of the biofilter bed, the pore size distribution, and other structural characteristics [<xref ref-type="bibr" rid="scirp.26479-ref1">1</xref>]. The surface of the porous material in the biofilter is covered with biofilms which are made of microorganisms. Treatment begins with the transfer of the contaminants from the air stream to the biofilm phase. Then, the dissolved contaminant is moved by diffusion and by advection in the air. Biotransformation finally converts the contaminant to biomass, metabolic by-products, carbon dioxide and water.</p><p>Several types of biofilters have been developed, the most typical of which include bioscrubbers, trickling bed biofilter and packed bed biofilter [<xref ref-type="bibr" rid="scirp.26479-ref3">3</xref>]. In all these technologies, pollutants in the gas stream are transferred to the biofilm and are degraded by the microorganisms. The bioscubber consists of a scrubber and a bioreactor. In the scrubber, water is sprayed counter-current to the polluted gas flow resulting in absorption of the pollutant into the water. This water is then directed to a bioreactor containing activated sludge where microorganisms degrade the pollutants. The trickling bed biofilter, on the other hand, relies on the inert packing media to support bacterial growth. The packed bed biofilter does not use a large continuous flow of water. The media used in the packed bed biofilter acts as a water reservoir as well as a support structure for the bacteria.</p><p><xref ref-type="fig" rid="fig1">Figure 1</xref> shows a simplified schematic of a biofilter [<xref ref-type="bibr" rid="scirp.26479-ref3">3</xref>].</p></sec></body><back><ref-list><title>References</title><ref id="scirp.26479-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">T. Nukunya, J. S. Debinny and T. T. Tsotsis, “Application of a Pore Network Model to a Biofilter Treating Ethanol Vapor,” Chemical Engineering Science, Vol. 60, No. 3, 2005, pp. 665-667. doi:10.1016/j.ces.2004.08.038</mixed-citation></ref><ref id="scirp.26479-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">B. V. Babu and S. Raghuvanshi, “Simulation Studies on Transient Model for Biofilter Operated in Periodic Mode,” Journal on Engineering and Technology, Vol. 1, No. 4, 2006, pp. 72-76.</mixed-citation></ref><ref id="scirp.26479-ref3"><label>3</label><mixed-citation publication-type="other" xlink:type="simple">C. R. Soccol, et al., “Biofiltration: An Emerging Technology,” Indian Journal of Biotechnology, Vol. 2, No. 2, 2003, pp. 396-410.</mixed-citation></ref><ref id="scirp.26479-ref4"><label>4</label><mixed-citation publication-type="other" xlink:type="simple">Z. Shareefdeen and A. A. Shaikh, “Analysis and Comparison of Biofilter Models,” Chemical Engineering Journal, Vol. 65, No. 1, 1998, pp. 55-61.</mixed-citation></ref><ref id="scirp.26479-ref5"><label>5</label><mixed-citation publication-type="other" xlink:type="simple">J. S. Devinny and J. Ramesh, “A Phenomenological Review of Biofilter Models,” Chemical Engineering Journal, Vol. 113, No. 2-3, 2005, pp. 187-196.  
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