<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">WJCMP</journal-id><journal-title-group><journal-title>World Journal of Condensed Matter Physics</journal-title></journal-title-group><issn pub-type="epub">2160-6919</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/wjcmp.2012.24036</article-id><article-id pub-id-type="publisher-id">WJCMP-24689</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Physics&amp;Mathematics</subject></subj-group></article-categories><title-group><article-title>
 
 
  Theoretical Estimation of Stability of Dielectric Elastomers
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>sha</surname><given-names>Dahiya</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>O.</surname><given-names>P. Thakur</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>School of Applied Sciences, Netaji Subhas Institute of Technology, University of Delhi, New Delhi, India</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>ashadh8@gmail.com(SD)</email>;<email>opthakur@yahoo.com(OPT)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>15</day><month>11</month><year>2012</year></pub-date><volume>02</volume><issue>04</issue><fpage>212</fpage><lpage>214</lpage><history><date date-type="received"><day>June</day>	<month>22nd,</month>	<year>2012</year></date><date date-type="rev-recd"><day>July</day>	<month>23rd,</month>	<year>2012</year>	</date><date date-type="accepted"><day>August</day>	<month>2nd,</month>	<year>2012</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  When dielectric elastomers sandwiched between compliant electrodes and high electric voltage is applied to the dielectric elastomers. Then due to the electrostatic force between the electrodes the elastomers expands in plane and contract out of plane so that it becomes thinner. As the thickness decreases we observe the increase in the applied electric voltage with the positive feedback effect. This positive feedback leads the electrical as well as mechanical breakdown of elastomer. By applying a mechanical pre-stretch the mechanical stability of dielectric elastomers gets also increased. In this paper, a new generalized set of strain/stretch variables q
  <sub>r</sub>
  <sup style="margin-left:-5px;">N</sup> has been introduced to get the expression for second order elastic moduli for the ideal electro elastic material deformed to orthorhombic structure. The strength of a loaded crystal determined from the new moduli has been compared with the strength of classical (Green, Stretch) moduli. It has been observed that the use of incorrect formula by ignoring shear strain leads to incorrect estimation of stability. This problem has been resolved by considering stretch variable in tensor form as generally observed in the process of electrostriction in the elastomers.
 
</p></abstract><kwd-group><kwd>Elastomers; Electromechanical Stability; Energy Convexity; Mechanical Strength; Generalised Variable</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Dielectric elastomer is a sub-category of Electroactive polymer. Dielectric elastomers are the materials with special mechanical and electrical performance, which can produced many kinds of mechanical responses with applied electric field [1-4]. Dielectric elastomers show large deformation (380%), high elastic energy density (3.4 J/g), high efficiency, high responsive speed, good reliability and durability. With these features dielectric elastomers have been intensely studied in these years due to their wide range application in different field’s for example medical, energy harvesting, soft robots, adaptive optics and electric generators [<xref ref-type="bibr" rid="scirp.24689-ref5">5</xref>]. In recent years, the stability analysis of dielectric elastomers is most popular issue, especially after Suo et al. proposed the electromechanical stability theory of dielectric elastomers [6-12]. In their research they discussed the case, when a layer of dielectric elastomer is sandwiched between two compliant electrodes and voltage applied between the electrodes then as the voltage ramps up, the layer thins down, so the same voltage produces a higher electric field which further thins down the elastomer as a positive feedback till the electrical breakdown of dielectric elastomer happen .It hinders the realization of large stable deformation. For removal of this instability, researchers used the prestretch conditions with material constants. With the positive feedback as a result of equation E = V/d where d is the thickness of dielectric elastomer, as the voltage increases then there is a possibility of mechanical breakdown of the elastomer at very high voltage after crossing the elastic limit.</p><p>In this paper, we discuss the mechanical stability of a dielectric elastomer under the influence of electric field. And we try to show that what will happen if we consider <img src="9-4800128\16c8b055-ebf6-4b9a-a09e-41105b457820.jpg" /> as stretch in case of elastomer [13-17].</p><p>In this work, we have adopted a new generalized set of strain variables <img src="9-4800128\e51239dd-af92-4712-9911-9ce1117c54c3.jpg" /> to get the expression for second order elastic constant for a form deformed to orthorhombic structure [18-19]. The strength of a loaded system determined from the new moduli has been compared with the strength of Green and Stretch moduli.</p><p><img src="9-4800128\7218ae37-5ac8-446b-8122-c5b37da761a4.jpg" />is a generalised variable containing <img src="9-4800128\43e081c8-1398-405a-a843-1666139acfac.jpg" /> which show that when field is applied on dielectric elastomer then effect of it not only produced the deformation only in one direction but it will also affect the perpendicular positions. So <img src="9-4800128\d03befd4-a7c2-46e0-95b4-fc72e3bfedbd.jpg" /> is the tensor notation of the stretch <img src="9-4800128\49b555b9-402e-4f95-a46d-52e18c248666.jpg" /> which is used by researcher for explaining the electrical stability of dielectric elastomers. This concept of generalised co-ordinate is introduced for explaining the mechanical stability of bcc iron structure but here it is used for the dielectric elastomers.</p></sec><sec id="s2"><title>2. Theoretical Approach</title><p>Consider a dielectric elastomer with three mechanical forces from three perpendicular directions and stretch λ<sub>ij</sub>.</p><p>Now we consider a new set of generalized geometric variable for a deformed structure</p><p><img src="9-4800128\76f998bc-26b1-42c7-ae44-5c1a38207b6e.jpg" /></p><p>with</p><disp-formula id="scirp.24689-formula150699"><label>(1)</label><graphic position="anchor" xlink:href="9-4800128\5728bc0b-82bf-4a47-a746-7387e3e7bea3.jpg"  xlink:type="simple"/></disp-formula><p>where <img src="9-4800128\b64dce65-2f5f-474c-b6de-53cdb32d3d1b.jpg" /> the Kroneckerdelta, K is can assume any suitable value and <img src="9-4800128\df2b49b9-706e-4943-94fa-4a8d4417d687.jpg" /> are the elements of stretch tensor.</p><p>The stretch variable defined by</p><disp-formula id="scirp.24689-formula150700"><label>(2)</label><graphic position="anchor" xlink:href="9-4800128\6f11a14e-97eb-4ce9-8c43-555389cf583f.jpg"  xlink:type="simple"/></disp-formula><p>where X<sub>j</sub> and X<sub>i</sub> are the reference and current rectangular co-ordinates of any lattice vector respectively.</p><p>The co-ordinates corresponding to new set of strain variables for an orthorhombic structure may explicitly be expressed by</p><disp-formula id="scirp.24689-formula150701"><label>(3)</label><graphic position="anchor" xlink:href="9-4800128\8c217229-341e-49ed-a701-d5ba31ae9180.jpg"  xlink:type="simple"/></disp-formula><p>where the tensor notation (ij) in Equation (1) are converted into matrix notation (r)</p><p><img src="9-4800128\4b7af925-b1b4-4083-9a4c-920ca1b2231e.jpg" /></p><p>Depending upon K, the Equation (3) leads to a desired set of strain variables. For K = 0 and K = 1 the expression results to stretch and Green variables which are <img src="9-4800128\af82cc77-e1e2-4603-ac42-78d1adde4152.jpg" /> respectively.</p><p>The generalized set of elastic moduli C<sub>rs</sub>, can be defined by</p><disp-formula id="scirp.24689-formula150702"><label>(4)</label><graphic position="anchor" xlink:href="9-4800128\ac3b3a7c-a2a5-48e1-84a0-f0d68bf55b39.jpg"  xlink:type="simple"/></disp-formula><p>where q<sub>r</sub> (r = 1, 2, 3,&#183;&#183;&#183;, 6) are generalized co-ordinates. Using Equations (3) and (4), we obtain the expression for the set of new moduli <img src="9-4800128\64f43d8c-49a0-4035-8bf2-db88ddf7d0c7.jpg" /> i.e.<img src="9-4800128\08b86e6a-bf80-4c65-bdf3-20a3b038be2b.jpg" />, <img src="9-4800128\f36507db-be3e-486f-9f34-109642021f7f.jpg" />, <img src="9-4800128\205e50df-612e-4d66-be90-b1fe4216897f.jpg" />for example</p><disp-formula id="scirp.24689-formula150703"><label>(5)</label><graphic position="anchor" xlink:href="9-4800128\35f412c3-8e64-43c0-8ee6-967ecf48b42b.jpg"  xlink:type="simple"/></disp-formula><p>Depending upon the value of K, C<sub>rs</sub> is capable of reproducing any desired set of elastic moduli.</p><p>And if Hessian (H)</p><p><img src="9-4800128\6a42282c-6fc4-4e53-a920-5048e3fbac9b.jpg" />is positive definite i.e. energy is minimum at equilibrium state. Then system must be stable.</p></sec><sec id="s3"><title>3. Stability Condition</title><p>The difference between S-strength (corresponding to K = 0) and N-strength (corresponding to new defined variable) of a deformed crystal may be shown to be given by</p><disp-formula id="scirp.24689-formula150704"><label>(6)</label><graphic position="anchor" xlink:href="9-4800128\e4a81183-11fe-45dc-b934-d6ce3f1e3a6d.jpg"  xlink:type="simple"/></disp-formula><p>(r, u, v = 1,2,&#183;&#183;&#183;,6)</p><p>In this equation using Equation (3) we show that for cubic crystal deformed to orthorhombic structure</p><disp-formula id="scirp.24689-formula150705"><label>(7)</label><graphic position="anchor" xlink:href="9-4800128\09830c18-4a4a-4e93-8d27-f8898a55ec32.jpg"  xlink:type="simple"/></disp-formula><p>Hill and Milestein calculated the values of S-G which can also be obtained from Equation (7) for K = 1</p><disp-formula id="scirp.24689-formula150706"><label>(8)</label><graphic position="anchor" xlink:href="9-4800128\373ba9ed-8919-40c9-ac12-51c9943783bf.jpg"  xlink:type="simple"/></disp-formula><p>From above equations, we obtain</p><disp-formula id="scirp.24689-formula150707"><label>(9)</label><graphic position="anchor" xlink:href="9-4800128\51aa521e-1afe-4ff9-8587-485ec5ffd9a4.jpg"  xlink:type="simple"/></disp-formula><p>Equations (7)-(9) enable the stability to be compared via the respective convexity criteria. A comparison of various strength for different loads and value of K' is given by Case 1: P<sub>1</sub>, P<sub>2</sub>, P<sub>3</sub> ≥ 0; <img src="9-4800128\3480ebea-e322-49be-883c-92fd049472cc.jpg" />≥ 0: S ≥ N ≥ G Case 2: P<sub>1</sub>, P<sub>2</sub>, P<sub>3</sub> ≥ 0; <img src="9-4800128\3fde6421-e31d-449f-9576-deb1d9bc20c7.jpg" />≤ 0: S ≥ G ≥ N Case 3: P<sub>1</sub>, P<sub>2</sub>, P<sub>3</sub> ≤ 0; <img src="9-4800128\1a006db2-aa9a-493c-aacb-82b7203c03dc.jpg" />&gt; 0: G ≥ S ≥ N Case 4: P<sub>1</sub>, P<sub>2</sub>, P<sub>3</sub> ≤ 0; <img src="9-4800128\8662fce9-44e3-43db-8b3a-36dc29796696.jpg" />&lt; 0: N ≥ G ≥ S In the above whole explanation E is the internal energy per unit reference cell and also function of generalised variable and<img src="9-4800128\0547000e-05b2-4ca1-b180-6253d3c4f5fb.jpg" />.</p></sec><sec id="s4"><title>4. Conclusion &amp; Discussion</title><p>The above whole explanation is based on the condition that the elastomer experience only the mechanical forces. But actuation in an elastomer consist effect of electric and mechanical field. So for explaining the mechanical stability it is considered that two mechanical forces are applied perpendicularly to each other and from third perpendicular direction electric field is applied to elastomer. The two mechanical forces behave as pre-stretch in elastomer. So P<sub>1</sub> and P<sub>2</sub> are equivalent to stresses produce in the elastomers due to these forces in their directions and P<sub>3</sub> is the change in elastomer due to applied electric field in its direction. On basis of the above four conditions it is clear that the system becomes stable with theoretically explained generalised variable.</p></sec><sec id="s5"><title>REFERENCES</title></sec></body><back><ref-list><title>References</title><ref id="scirp.24689-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">R. E. Pelrine, R. D. Kornbluh, Q. B. Pei, et al., “High-Speed Electrically Actuated Elastomers with Strain Greater than 100%,” Science, Vol. 287, No. 5454, 2000, pp. 836-839. doi:10.1126/science.287.5454.836</mixed-citation></ref><ref id="scirp.24689-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">E. Smela, O. Inganaas and I. Lundstrom, “Controlled Folding of Micrometer-Size Structures,” Science, Vol. 268, No. 5218, 1995, pp. 1735-1738. 
doi:10.1126/science.268.5218.1735</mixed-citation></ref><ref id="scirp.24689-ref3"><label>3</label><mixed-citation publication-type="other" xlink:type="simple">R. E. Pelrine, R. D. Kornbluh and J. P. Joseph, “Electrostriction of Polymer Dielectrics with Compliant Electrodes as a Means of Actuation,” Sensors and Actuators A: Physical, Vol. 64, No. 1, 1998, pp. 77-85. 
doi:10.1016/S0924-4247(97)01657-9</mixed-citation></ref><ref id="scirp.24689-ref4"><label>4</label><mixed-citation publication-type="other" xlink:type="simple">J. S. Plante and S. Dubowsky, “On the Properties of Dielectric Elastomer Actuators and Their Design Implications,” Smart Materials and Structures, Vol. 16, No. 20, 2007, pp. S227-S236. 
doi:10.1088/0964-1726/16/2/S05</mixed-citation></ref><ref id="scirp.24689-ref5"><label>5</label><mixed-citation publication-type="other" xlink:type="simple">E. M. Arrude and M. C. Boyce, “A Three-Dimensional Constitutive Model for the Large Stretch Behaviour of Rubber Elastic Materials,” Journal of the Mechanics and Physics of Solids, Vol. 41, No. 2, 1993, pp. 389-412. 
doi:10.1016/0022-5096(93)90013-6</mixed-citation></ref><ref id="scirp.24689-ref6"><label>6</label><mixed-citation publication-type="other" xlink:type="simple">X. H. Zhao and Z. G. Suo, “Method to Analyse Electromechanical Stability of Dielectric Elastomers,” Applied Physics Letter, Vol. 91, No. 6, 2007, Article ID: 061921. 
 doi:10.1063/1.2768641</mixed-citation></ref><ref id="scirp.24689-ref7"><label>7</label><mixed-citation publication-type="other" xlink:type="simple">X. H. Zhao, W. Hong and Z. G. Suo, “Electromechanical Coexistent States and Hysteresis in Dielectric Elastomers,” Physical Review B, Vol. 76, No. 13, 2007, Article ID: 134113. 
doi:10.1103/PhysRevB.76.134113</mixed-citation></ref><ref id="scirp.24689-ref8"><label>8</label><mixed-citation publication-type="other" xlink:type="simple">Z. G. Suo, X. H. Zhao and W. H. Greene, “A Nonlinear Field Theory of Deformable Dielectrics,” Journal of the Mechanics and Physics of Solids, Vol. 56, No. 2, 2008, pp. 476-486. doi:10.1016/j.jmps.2007.05.021</mixed-citation></ref><ref id="scirp.24689-ref9"><label>9</label><mixed-citation publication-type="other" xlink:type="simple">J. Zhou, W. Hong, X. H. Zhao, et al., “Propagation of Instability in Dielectric Elastomers,” International Journal of Solids and Structures, Vol. 45, No. 13, 2008, pp. 3739-3750. doi:10.1016/j.ijsolstr.2007.09.031</mixed-citation></ref><ref id="scirp.24689-ref10"><label>10</label><mixed-citation publication-type="other" xlink:type="simple">A. N. Norrisa, “Comment on Method to Analyse Electromechanical Stability of Dielectric Elastomers,” Applied Physics Letters, Vol. 92, No. 2, 2007, Article ID: 026101. 
doi:10.1063/1.2833688</mixed-citation></ref><ref id="scirp.24689-ref11"><label>11</label><mixed-citation publication-type="other" xlink:type="simple">R. Diaz-Calleja, E. Riande and M. J. Sanichis, “On Electromechanical Stability of Dielectric Elastomers,” Applied Physics Letters, Vol. 93, No. 10, 2008, Article ID: 101902. 
doi:10.1063/1.2972124</mixed-citation></ref><ref id="scirp.24689-ref12"><label>12</label><mixed-citation publication-type="other" xlink:type="simple">Y. J. Liu, L. W. Liu, Z. Zhang, et al., “Comment on Method to Analyse Electromechanical Stability of Dielectric Elastomers,” Applied Physics Letters, Vol. 93, No. 10, 2008, Article ID: 106101. doi:10.1063/1.2979236</mixed-citation></ref><ref id="scirp.24689-ref13"><label>13</label><mixed-citation publication-type="other" xlink:type="simple">O. P. Thakur and A. K. Singh, “Electrostriction and Electromechanical Coupling in Elastic Dielectrics at Nanometric Interfaces,” Materials Science—Poland, Vol. 27, No. 3, 2009, pp. 839-850.</mixed-citation></ref><ref id="scirp.24689-ref14"><label>14</label><mixed-citation publication-type="other" xlink:type="simple">O. P. Thakur and A. K. Singh, “Error in Estimation of Electrically Induced Deformation in Elastic Dielectric,” Material Science Research Journal, Vol. 2, No. 3-4, 2009, pp. 307-319.</mixed-citation></ref><ref id="scirp.24689-ref15"><label>15</label><mixed-citation publication-type="other" xlink:type="simple">J. A. Stratton, “Electromagnetic Theory,” McGraw-Hill, New York, 1941.</mixed-citation></ref><ref id="scirp.24689-ref16"><label>16</label><mixed-citation publication-type="other" xlink:type="simple">L. D. Landu and L. M. Lifeshitz, “Theory of Elasticity,” Pergamon Press, Oxford, 1970.</mixed-citation></ref><ref id="scirp.24689-ref17"><label>17</label><mixed-citation publication-type="other" xlink:type="simple">L. D. Landu and L. M. Lifeshitz, “Electrodynamics of Continuous Media,” 2nd Edition, Pergamon Press, Oxford, 1984.</mixed-citation></ref><ref id="scirp.24689-ref18"><label>18</label><mixed-citation publication-type="other" xlink:type="simple">K. P. Thakur, R. K. Jha and O. P. Thakur, “Convexity of Internal Energy of Cubic Crystal Deformed to Orthorhombic Structure,” Springer (Pramana)—Journal of Physics, Vol. 34, No. 3, 1990, pp. 201-215.</mixed-citation></ref><ref id="scirp.24689-ref19"><label>19</label><mixed-citation publication-type="other" xlink:type="simple">O. P. Thakur, “Theoretical Mechanical Strength of Metals,” Proceeding of 34th Congress of Indian Society of Theoretical &amp; Applied Mechanics, Coimbatore, December 1989, pp. 73-82.</mixed-citation></ref></ref-list></back></article>