<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">AM</journal-id><journal-title-group><journal-title>Applied Mathematics</journal-title></journal-title-group><issn pub-type="epub">2152-7385</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/am.2012.39154</article-id><article-id pub-id-type="publisher-id">AM-23011</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Physics&amp;Mathematics</subject></subj-group></article-categories><title-group><article-title>
 
 
  Analytical Solutions of Some Two-Point Non-Linear Elliptic Boundary Value Problems
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>embu</surname><given-names>Ananthaswamy</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lakshmanan</surname><given-names>Rajendran</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Department of Mathematics, The Madura College, Madurai, India</addr-line></aff><author-notes><corresp id="cor1">* E-mail:<email>raj_sms@rediffmail.com(EA)</email>;<email>raj_sms@rediffmail.com(LR)</email>;</corresp></author-notes><pub-date pub-type="epub"><day>27</day><month>09</month><year>2012</year></pub-date><volume>03</volume><issue>09</issue><fpage>1044</fpage><lpage>1058</lpage><history><date date-type="received"><day>July</day>	<month>16,</month>	<year>2012</year></date><date date-type="rev-recd"><day>August</day>	<month>16,</month>	<year>2012</year>	</date><date date-type="accepted"><day>August</day>	<month>23,</month>	<year>2012</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  Several problems arising in science and engineering are modeled by differential equations that involve conditions that are specified at more than one point. The non-linear two-point boundary value problem (TPBVP) (Bratu’s equation, Troesch’s problems) occurs engineering and science, including the modeling of chemical reactions diffusion processes and heat transfer. An analytical expression pertaining to the concentration of substrate is obtained using Homotopy perturbation method for all values of parameters. These approximate analytical results were found to be in good agreement with the simulation results.
 
</p></abstract><kwd-group><kwd>Two-Point Elliptic Boundary Value Problems; Bratu’s Equation; Troesch’s Problem; Non-Linear Equations; Homotopy Perturbation Method; Porous Catalyst; Numerical Simulation</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>All chemical reactions are usually accompanied with mass and energy transfer, either homogeneously or heterogeneously. Mathematical modeling for these processes is based on material and energy balance. One can generate a set of differential equations known as the reaction-diffusion problem. Owing to the strong nonlinearity of the reaction rate, mainly from the effect of temperature, reaction-diffusion equations are paid more attention in analyzing and designing chemical and catalytic reactors [<xref ref-type="bibr" rid="scirp.23011-ref1">1</xref>]. The same phenomena exist in electrochemical processes, with the add complexity of a varying potential field, and considerable research has been reviewed for electrochemical reactions occurring in the porous electrode [<xref ref-type="bibr" rid="scirp.23011-ref2">2</xref>].</p><p>&#160;Linear and nonlinear phenomena are of fundamental importance in various fields of science and engineering. Most models of real-life problems are still very difficult to solve. Therefore, approximate analytical solutions such as Homotopy perturbation method (HPM) [3-12] were introduced. This method is the most effective and convenient ones for both linear and nonlinear equations. Perturbation method is based on assuming a small parameter. The majority of nonlinear problems, especially those having strong nonlinearity, have no small parameters at all and the approximate solutions obtained by the perturbation methods, in most cases, are valid only for small values of the small parameter. Generally, the perturbation solutions are uniformly valid as long as a scientific system parameter is small. However, we cannot rely fully on the approximations, because there is no criterion on which the small parameter should exists. Thus, it is essential to check the validity of the approximations numerically and/or experimentally. To overcome these difficulties, HPM have been proposed recently. In this paper we will apply Homotopy perturbation method (HPM) to the nonlinear Bratu’s problem, Troesch’s problem, and catalytic reactions in flat particles.</p><p>Systems of non linear differential equations arise in mathematical models throughout science and engineering. When an explicit condition that a solution must satisfy is specified at one value of the independent variable, usually its lower bound, this is referred to as an initial value problem (IVP). When the conditions to be satisfied occur at more than one value of the independent variable, this is referred to as a boundary value problem (BVP). If there are two values of the independent variable at which conditions are specified, then this is a two-point boundary value problem (TPBVP). TPBVPs occur in a wide variety of problems, including the modelling of chemical reactions, heat transfer, and diffusion. They are also of interest in optimal control problems.</p><p>There are many techniques available for the numerical solution of TPBVPs for ordinary differential equations [<xref ref-type="bibr" rid="scirp.23011-ref13">13</xref>]. The standard techniques can be divided into two classes. Typical of this class are various shooting and multi-shooting approaches. The other class involves converting the TPBVP into a system of algebraic equations, and includes methods based on various versions of finite difference or collocation. Methods for solving TPBVPs usually require users to provide an initial guess for the unknown initial states and/or parameters.</p><p>The problem of reliably identifying all solutions of a TPBVP was apparently first addressed only recently, by [14,15]. Present a new approach that will rigorously guarantee the enclosure of all solutions to the TPBVP. In this paper we have obtained the analytical solutions of some nonlinear elliptic problems (Bratu’s equation, Troesch’s problem and Catalytic reactions in a flat particles) using Homotopy perturbation method.</p></sec><sec id="s2"><title>2. Mathematical Formulation of the Problem</title><p>Many problems in science and engineering require the computational of family of solutions of a non linear system of the form [<xref ref-type="bibr" rid="scirp.23011-ref16">16</xref>]:</p><disp-formula id="scirp.23011-formula32500"><label>(1)</label><graphic position="anchor" xlink:href="13-7400989\e319ec77-6def-4626-ac23-09f990bbe541.jpg"  xlink:type="simple"/></disp-formula><p>where <img src="13-7400989\0a12294e-06ae-48b7-9408-3b4765022144.jpg" /> is continuously differentiable function, y represents the solution and <img src="13-7400989\ece02abf-c871-40db-aab6-bcb8d8493f48.jpg" /> is a real parameter (i.e., Reynold’s number, load etc.). It is required to find a solution for some <img src="13-7400989\08b644a2-2d5a-4ec7-8c88-4ba8928b431e.jpg" />-interval, i.e., a path solutions,<img src="13-7400989\b3b0f839-4b02-42d2-a66a-107be54fbe69.jpg" />. Equations of the form (1) are called nonlinear elliptic eigenvalue problems if the operator G with <img src="13-7400989\e407fb91-b0dc-4a47-9301-9c3867bf08e2.jpg" /> fixed is an elliptic differential operator. Fore more details about this type of operators see [<xref ref-type="bibr" rid="scirp.23011-ref17">17</xref>]. As a typical example of nonlinear elliptic eigenvalue problems, we consider the following problem</p><p><img src="13-7400989\149e104b-58cd-4775-bbac-d5d7048d1505.jpg" />in <img src="13-7400989\1b065c36-1166-43a6-a670-a4db1f939019.jpg" /> (2)</p><p><img src="13-7400989\c18dea36-0d4f-4172-96d0-3ea889279296.jpg" />on <img src="13-7400989\9972fb74-ba8f-465f-896f-79efe0323ad5.jpg" /> (3)</p><p>where <img src="13-7400989\d0dc8254-8edd-45ba-aeda-d110dd231106.jpg" /> is Laplacian operator in one dimension.</p><p>Equation (2) arises in many physical problems. For example, in chemical reactor theory, radiative heat transfer, combustion theory, and in modelling the expansion of the universe. The function y could be a function of several variables and the domain <img src="13-7400989\34d15de5-b0f9-426f-a025-89aa86bca543.jpg" /> is usually taken to be the unit interval <img src="13-7400989\d774bbc5-d725-4ac8-bd90-13fccc1e3397.jpg" /> in<img src="13-7400989\ee9f8f81-aca9-47a1-ae18-a551d8b11916.jpg" />, or the unit square <img src="13-7400989\4ca44c40-ff17-40fc-9c1a-17cb75a68cb2.jpg" /> in<img src="13-7400989\24524d93-31a8-464c-88d5-6f879080363b.jpg" />, or the unit cube <img src="13-7400989\5d954251-b89a-4293-9bdb-952a407ec6e2.jpg" /> in<img src="13-7400989\e3585764-cb84-439a-9c55-add9408a37d8.jpg" />. Equation (1) can take several forms, for example, Bratu equation is given by</p><p><img src="13-7400989\c6663d81-959e-4edf-9fdf-391329dcab31.jpg" />in <img src="13-7400989\fb7b2b5e-dd26-4ed5-96f0-e3d132057273.jpg" />(4)</p><p><img src="13-7400989\17c576cb-d2df-468b-83a5-0af0f5eaa647.jpg" />on <img src="13-7400989\a2d8beb5-831d-4b9a-8214-1b8cfea78488.jpg" /> (5)</p><p>and a reaction-diffusion problem takes the form</p><p><img src="13-7400989\1bc5c488-5634-46a0-baee-f5db8aa849e9.jpg" />in <img src="13-7400989\31c868a5-1f64-4b33-8f7b-d225351d8c9c.jpg" />(6)</p><p><img src="13-7400989\bf42add0-9ed9-4097-a75e-a1dad087c72f.jpg" />on <img src="13-7400989\f61d4498-8f78-490f-8b5f-49f8bfb748ba.jpg" /> (7)</p><p>There are no bifurcation points in the two problems above; all singular points are fold points. The behaviour of the solution near the singular points has been studied numerically [17-19] and theoretically [20-23]. For both one and two-dimensional cases, the Bratu problem has exactly one fold point, whereas the three-dimensional case has infinitely many fold points.</p><sec id="s2_1"><title>2.1. Bratu’s Equation and Its Solution</title><p>Bratu’s equation [<xref ref-type="bibr" rid="scirp.23011-ref24">24</xref>] was first studied as a simple case of a second-order ordinary differential equation by Bratu [<xref ref-type="bibr" rid="scirp.23011-ref25">25</xref>]. The equation arises when deriving the temperature distribution for a reaction in an infinite vessel with planeparallel walls, and also in a simplification of a combustion reaction with a cylindrical vessel [<xref ref-type="bibr" rid="scirp.23011-ref26">26</xref>]. The differential equation is &#160;</p><disp-formula id="scirp.23011-formula32501"><label>(8)</label><graphic position="anchor" xlink:href="13-7400989\9a30ae75-395a-43d4-9a3f-cec3877cdf96.jpg"  xlink:type="simple"/></disp-formula><p>with boundary conditions</p><disp-formula id="scirp.23011-formula32502"><label>(9)</label><graphic position="anchor" xlink:href="13-7400989\74023ae6-23e3-4ce6-958c-12d0c7ee13df.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equations (8) and (9) using Homotopy perturbation method (See Appendix A) is</p><disp-formula id="scirp.23011-formula32503"><label>(10)</label><graphic position="anchor" xlink:href="13-7400989\b2598e10-614f-4205-92a8-8212982e51c3.jpg"  xlink:type="simple"/></disp-formula><p>where</p><disp-formula id="scirp.23011-formula32504"><label>(11)</label><graphic position="anchor" xlink:href="13-7400989\abfeebb8-166a-4c74-b0a7-376447b37292.jpg"  xlink:type="simple"/></disp-formula></sec><sec id="s2_2"><title>2.2. Reaction Diffusion Equation and Its Solution</title><p>Consider the reaction diffusion equation [<xref ref-type="bibr" rid="scirp.23011-ref16">16</xref>]</p><disp-formula id="scirp.23011-formula32505"><label>(12)</label><graphic position="anchor" xlink:href="13-7400989\66def15e-ee73-48ce-8bb4-8c49f867e9a9.jpg"  xlink:type="simple"/></disp-formula><p>with the boundary conditions</p><disp-formula id="scirp.23011-formula32506"><label>(13)</label><graphic position="anchor" xlink:href="13-7400989\b359971f-3f03-4d55-a500-f44507507c5d.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equations (12) and (13) using Homotopy perturbation method (See Appendix C) is</p><disp-formula id="scirp.23011-formula32507"><label>(14)</label><graphic position="anchor" xlink:href="13-7400989\0287d378-6679-4630-b8d1-a149d322e073.jpg"  xlink:type="simple"/></disp-formula><p>where <img src="13-7400989\9430c3da-c720-4987-9ac8-03a7304d1b15.jpg" /> is defined by Equation (11).</p></sec><sec id="s2_3"><title>2.3. Troesch’s Problem and Its Solution</title><p>Troesch’s problem comes from the investigation of the confinement of a plasma column under radiation pressure. The problem was first described and solved by Weibel [<xref ref-type="bibr" rid="scirp.23011-ref27">27</xref>]. It has become a widely used test problem, and has been solved many times, including in analytical closed form [<xref ref-type="bibr" rid="scirp.23011-ref28">28</xref>] by using a shooting method [<xref ref-type="bibr" rid="scirp.23011-ref29">29</xref>], by using a Laplace transform decomposition technique [<xref ref-type="bibr" rid="scirp.23011-ref30">30</xref>] and most recently by using a modified Homotopy perturbation technique [<xref ref-type="bibr" rid="scirp.23011-ref31">31</xref>]. The differential equation is</p><disp-formula id="scirp.23011-formula32508"><label>(15)</label><graphic position="anchor" xlink:href="13-7400989\a467fd8f-8b26-448f-9d87-6052d52e0b11.jpg"  xlink:type="simple"/></disp-formula><p>with the boundary conditions</p><disp-formula id="scirp.23011-formula32509"><label>(16)</label><graphic position="anchor" xlink:href="13-7400989\dd919849-fe64-4aef-aa5c-de04f60eca76.jpg"  xlink:type="simple"/></disp-formula><p>The known analytical, closed form solution [<xref ref-type="bibr" rid="scirp.23011-ref28">28</xref>] of Equations (15) and (16) is given by</p><disp-formula id="scirp.23011-formula32510"><label>(17)</label><graphic position="anchor" xlink:href="13-7400989\9ff05af8-6943-472f-a9f0-25b3ae2265bb.jpg"  xlink:type="simple"/></disp-formula><p>where <img src="13-7400989\4de2038c-eff6-464d-a48f-1388be86176d.jpg" /> is the derivative at <img src="13-7400989\2a90ed1e-beb5-4208-afff-4245f4edecdb.jpg" /> and the constant m is the solution to the equation</p><disp-formula id="scirp.23011-formula32511"><label>(18)</label><graphic position="anchor" xlink:href="13-7400989\7f43ea94-6229-4800-adc5-fc7b6d4cd475.jpg"  xlink:type="simple"/></disp-formula><p>We have obtained the analytical solution of Equations (15) and (16) using Homotopy perturbation method (See Appendix F) is</p><disp-formula id="scirp.23011-formula32512"><label>(19)</label><graphic position="anchor" xlink:href="13-7400989\3d07e339-5961-4dbf-8390-9e3f2b2144ec.jpg"  xlink:type="simple"/></disp-formula></sec><sec id="s2_4"><title>2.4. Catalytic Reactions in a Flat Particle and Its Solution</title><p>This example arises in a study of heat and mass transfer for a catalytic reaction within a porous catalyst flat particle [<xref ref-type="bibr" rid="scirp.23011-ref32">32</xref>]. The differential equation is the direct result of a material and energy balance. Assuming a flat geometry for the particle and that conductive heat transfer is negligible compared to convective heat transfer yields the differential equation.</p><disp-formula id="scirp.23011-formula32513"><label>(20)</label><graphic position="anchor" xlink:href="13-7400989\f4b6d0bb-680a-4cb6-a6fe-17b1945cd1fb.jpg"  xlink:type="simple"/></disp-formula><p>with boundary conditions</p><disp-formula id="scirp.23011-formula32514"><label>(21)</label><graphic position="anchor" xlink:href="13-7400989\ceafc858-b534-4125-9dbd-d1da5d36de22.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of the Equations (20) and (21) using Homotopy perturbation method [33-41] (See Appendix H) is</p><disp-formula id="scirp.23011-formula32515"><label>(22)</label><graphic position="anchor" xlink:href="13-7400989\781265e9-21b2-4607-a017-1f278781eb90.jpg"  xlink:type="simple"/></disp-formula><p>where</p><disp-formula id="scirp.23011-formula32516"><label>(23)</label><graphic position="anchor" xlink:href="13-7400989\1bc375f5-26d8-415a-8bc7-4170cdc51634.jpg"  xlink:type="simple"/></disp-formula></sec></sec><sec id="s3"><title>3. Numerical Simulation</title><p>The non-linear equations [Equations (3), (7), (10) and (15)] for the given boundary conditions are solved by numerically. The function pdex4, in Matlab software is used to solve two-point boundary value problems (BVPs) for ordinary differential equations given in Appendix B, Appendix D, Appendix E, Appendix G, Appendix I, Appendix J and Appendix K. The numerical results are also compared with the obtained analytical expressions [Equations (5), (6), (9), (14), (17) and (18)] for all values of parameters<img src="13-7400989\a7973060-0389-48cc-99f1-8150a2541842.jpg" />, <img src="13-7400989\f1337b5e-dca6-422a-92fb-c09c9bec8725.jpg" />, <img src="13-7400989\1ebd1f91-8bfb-47e1-8efd-7812e241044e.jpg" />and<img src="13-7400989\2d0d572b-2c58-4acf-9fdc-342a329bb9ed.jpg" />.</p></sec><sec id="s4"><title>4. Results and Discussion</title><p><xref ref-type="fig" rid="fig1">Figure 1</xref> represents the dimensionless concentration <img src="13-7400989\b0366a2f-ce89-4e71-a3e3-9ccab1dd0739.jpg" /> versus the dimensionless distance t for different values of the dimensionless parameter<img src="13-7400989\4c78f79d-7a2f-492a-a1f6-a88e2e1aa2fa.jpg" />. From this figure, it is evident that the values of the dimensionless concentration <img src="13-7400989\76c16a75-d719-48b8-b2cd-935052dc3cd7.jpg" /> increases when dimensionless parameter <img src="13-7400989\2f451c20-329a-432d-bff9-b6f0b283c32e.jpg" /> increases. Figures 2(a)-(d) show the concentration <img src="13-7400989\c841aa37-e005-42ed-8cba-ed0b0b97ffe5.jpg" /> versus dimensionless distance t for various values of dimensionless parameters <img src="13-7400989\3880bc81-0b10-4a94-b0dd-7c242d08274c.jpg" /> and<img src="13-7400989\dd630982-a061-40d5-b3cf-a6506724493f.jpg" />. From these figures, it is obvious that the values of the dimensionless concentration<img src="13-7400989\dbe1b3ad-7adf-4d8e-a47d-9dbec069aa68.jpg" /> increases when dimensionless parameters <img src="13-7400989\9aa8daa5-3b3a-4f60-9cfd-77047cc2fbf2.jpg" /> increases for the fixed values of<img src="13-7400989\f76cb61a-b059-4a4f-9ad7-a35c9f707b40.jpg" />. From the Figures 3(a) and (b), it is clear that the concentration <img src="13-7400989\64d6ffa6-4033-4e6e-ada0-ea091862bff3.jpg" /> decreases for the different values of the dimensionless parameter<img src="13-7400989\aa6f50d2-540d-453e-bae7-3baab6d833dc.jpg" />, for the various values of<img src="13-7400989\4df462c1-9fb4-4d81-b3eb-21b4e71cd2da.jpg" />. The dimensionless concentration<img src="13-7400989\3a5392fe-fcd4-4edd-8c4b-e07dbcdd1de8.jpg" />versus the dimensionless distance t for different values of dimensionless parameter <img src="13-7400989\739e3277-9e9e-4eb3-8e3a-368e582eba94.jpg" /> is plotted in <xref ref-type="fig" rid="fig4">Figure 4</xref>.</p><p>From this figure, it shows that the concentration <img src="13-7400989\02ef86d0-6bb8-4373-84c1-f85f80407c7a.jpg" /> decreases for the various values of<img src="13-7400989\7fc149a0-fdf7-47f8-acd8-e53fc4026bb2.jpg" />. Figures 5(a)-(d) shows the dimensionless concentration <img src="13-7400989\65059c8f-abae-4245-9621-3734d8a165c8.jpg" /> in the reactor versus the dimensionless distance down the reactor t. From these figures it is clear that the concentration <img src="13-7400989\b142fa10-6492-4b6d-8b55-11ad3735d620.jpg" /> decreases for the fixed values of <img src="13-7400989\cd70c8b4-65ed-4299-ae1b-c23adfca5eb4.jpg" /> and <img src="13-7400989\6033b152-e98b-4407-a68b-78db8a17a19b.jpg" /> for the different values of<img src="13-7400989\2d5f5761-7cba-43c6-b704-081d907f00dd.jpg" />.</p><p>Figures 6 and 7 shows the dimensionless concentration <img src="13-7400989\9e81e9a1-a4ae-4100-85ad-6928c4e69ca6.jpg" /> versus the dimensionless distance t. From these figures it is clear that the concentration <img src="13-7400989\6823c980-3d32-4e6d-9bbc-093c2839453f.jpg" /> decreases for the fixed values of <img src="13-7400989\d4896ca3-3f78-4313-8b5b-ccf7e29a9e94.jpg" /> and <img src="13-7400989\ba72588b-4254-40ee-8e36-d92cc18002aa.jpg" /> for the different values of<img src="13-7400989\1739c6f7-dd59-4a1b-8f1d-069b9de80172.jpg" />.</p></sec><sec id="s5"><title>5. Conclusion</title><p>The steady state non-linear reaction-diffusion equation has been solved analytically and numerically. The dimensionless concentrations <img src="13-7400989\ef2726a6-c274-417f-99c4-32410b4dee9e.jpg" /> in the reactor at the position t are derived by using the HPM. The primary result of this work is simple approximate calculations of concentration for all values of dimensionless parameters<img src="13-7400989\fa7f5b8e-2fc9-412e-99c9-8e41c652b334.jpg" />, <img src="13-7400989\6ab7d197-2556-4161-b149-4105c049961f.jpg" />, <img src="13-7400989\00aad5ad-435a-434a-a665-fb80a2b1a9d4.jpg" />and<img src="13-7400989\d5020eb4-f7b3-45c7-af81-cdbd3ddcc2a9.jpg" />. The HPM is an extremely simple method and it is also a promising method to solve other non-linear equations. This method can be easily extended to find the solution of all other non-linear equations.</p></sec><sec id="s6"><title>6. Acknowledgements</title><p>This work was supported by the University Grants Commission (F. No. 39-58/2010(SR)), New Delhi, India. The authors are thankful to Mr. M. S. Meenakshisundaram, The Secretary, Dr. R. Murali, The Principal and Dr.</p><p>L. Rajendran, Assistant Professor, Department of Mathematics, The Madura College, Madurai for their encouragement.</p></sec><sec id="s7"><title>REFERENCES</title></sec><sec id="s8"><title>Appendix A: Solution of Bratu’s Equation Using HPM</title><p>In this Appendix, we indicate how the Equation (10) is derived. When y is small, Equation (8) is reduces to</p><disp-formula id="scirp.23011-formula32517"><label>(A1)</label><graphic position="anchor" xlink:href="13-7400989\a0e64d46-9d05-4bf0-a5fa-30f095e326ab.jpg"  xlink:type="simple"/></disp-formula><p>We construct the Homotopy for the Equation (A1) is as follows:</p><disp-formula id="scirp.23011-formula32518"><label>(A2)</label><graphic position="anchor" xlink:href="13-7400989\68e03001-e6c3-4a92-8a52-9e7231635972.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equation (8) with Equation (9) is</p><disp-formula id="scirp.23011-formula32519"><label>(A3)</label><graphic position="anchor" xlink:href="13-7400989\a563fc60-5eef-41aa-afaa-cfaa910045d9.jpg"  xlink:type="simple"/></disp-formula><p>Substituting the Equation (A3) into an Equation (A2) we get</p><disp-formula id="scirp.23011-formula32520"><label>(A4)</label><graphic position="anchor" xlink:href="13-7400989\43c40348-40f1-4a73-9830-87aed5c74434.jpg"  xlink:type="simple"/></disp-formula><p>Comparing the coefficients of like powers of p in Equation (A4) we get</p><disp-formula id="scirp.23011-formula32521"><label>(A5)</label><graphic position="anchor" xlink:href="13-7400989\c737a93c-4820-42cd-82b4-852e772a7086.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32522"><label>(A6)</label><graphic position="anchor" xlink:href="13-7400989\f991e8d9-071a-4cc4-8f4e-61730186f69f.jpg"  xlink:type="simple"/></disp-formula><p>The initial approximations are as follows&#160;</p><disp-formula id="scirp.23011-formula32523"><label>(A7)</label><graphic position="anchor" xlink:href="13-7400989\d8b60be0-3947-4a9b-9eaa-753b81dfcf48.jpg"  xlink:type="simple"/></disp-formula><p><img src="13-7400989\661d91e1-c3ed-49d8-90d6-e39c9c7e4b7a.jpg" /><img src="13-7400989\f13df498-f005-4bbc-bdca-f1f8be174fd2.jpg" /> (A8)</p><p>Solving the Equation (A5) and the Equation (A6) and using the boundary conditions Equation (A7) and the Equation (A8) we obtain the following results:</p><disp-formula id="scirp.23011-formula32524"><label>(A9)</label><graphic position="anchor" xlink:href="13-7400989\172a3dc0-2853-4583-8c39-767fa042cad0.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32525"><label>(A10)</label><graphic position="anchor" xlink:href="13-7400989\ca949378-5914-4ad5-a28f-86886c3047f3.jpg"  xlink:type="simple"/></disp-formula><p>where b is defined in Equation (9). According to the HPM, we can conclude that</p><disp-formula id="scirp.23011-formula32526"><label>(A11)</label><graphic position="anchor" xlink:href="13-7400989\65ef9dbf-925c-4b20-b978-af068a5566ef.jpg"  xlink:type="simple"/></disp-formula><p>After putting the Equation (A9) and Equation (A10) into an Equation (A11) we obtain the solution in the text.</p></sec><sec id="s9"><title>Appendix B: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (8) and (9)</title><p>function pdex4 m = 0;</p><p>x = linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,:))</p><p>title('u1(x,t)')</p><p>xlabel('Distance x')</p><p>ylabel('u1(x,2)')</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=2;</p><p>F =lamda*exp(u)</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = ul;</p><p>ql = 0;</p><p>pr = ur-0;</p><p>qr = 0;</p></sec><sec id="s10"><title>Appendix C: Solution of Reaction Diffusion Equation Using HPM</title><p>In this Appendix, we indicate how Equation (14) is derived. When <img src="13-7400989\5f6de1d4-aeb8-4918-a1cb-fa0356f37b46.jpg" /> is small, Equation (12) is reduces to</p><disp-formula id="scirp.23011-formula32527"><label>(C1)</label><graphic position="anchor" xlink:href="13-7400989\5f516925-547c-4cce-ad3c-06fad0106ba5.jpg"  xlink:type="simple"/></disp-formula><p>We construct the Homotopy for Equation (C1) is as follows:</p><disp-formula id="scirp.23011-formula32528"><label>(C2)</label><graphic position="anchor" xlink:href="13-7400989\8f11d3ed-8877-440e-953b-72bf714318ab.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equation (12) with Equation (13) is</p><disp-formula id="scirp.23011-formula32529"><label>(C3)</label><graphic position="anchor" xlink:href="13-7400989\0a55717a-6529-4bc2-9a23-c52a107cb1dd.jpg"  xlink:type="simple"/></disp-formula><p>Substituting Equation (C3) into an Equation (C2) we get</p><disp-formula id="scirp.23011-formula32530"><label>(C4)</label><graphic position="anchor" xlink:href="13-7400989\d63f00a7-81d3-42be-a476-0070a9e7c72a.jpg"  xlink:type="simple"/></disp-formula><p>Comparing the coefficients of like powers of p in Equation (C4) we get</p><disp-formula id="scirp.23011-formula32531"><label>(C5)</label><graphic position="anchor" xlink:href="13-7400989\53310afd-5527-4fc5-bdae-0ad0f27fba4f.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32532"><label>(C6)</label><graphic position="anchor" xlink:href="13-7400989\17a1f19b-7b0f-4dc5-a265-4c2716f3171d.jpg"  xlink:type="simple"/></disp-formula><p>The initial approximations are as follows:&#160;</p><disp-formula id="scirp.23011-formula32533"><label>(C7)</label><graphic position="anchor" xlink:href="13-7400989\7ade7677-fc82-4a90-94cd-c078eadcdf7c.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32534"><label>(C8)</label><graphic position="anchor" xlink:href="13-7400989\c54aa98a-fb10-483d-93b4-efe6ac93c3a6.jpg"  xlink:type="simple"/></disp-formula><p>Solving the Equations (C5) and (C6) and using the boundary conditions Equation (C7) and the Equation (C8) we obtain the following results:</p><disp-formula id="scirp.23011-formula32535"><label>(C9)</label><graphic position="anchor" xlink:href="13-7400989\cae25b4e-bad7-4707-8eb1-9ce9f9a86093.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32536"><label>(C10)</label><graphic position="anchor" xlink:href="13-7400989\b398e3da-f404-4df3-bf3c-897b694c8571.jpg"  xlink:type="simple"/></disp-formula><p>where b is defined in the text Equation (6). According to the HPM, we can conclude that</p><disp-formula id="scirp.23011-formula32537"><label>(C11)</label><graphic position="anchor" xlink:href="13-7400989\db9f73ac-b5a3-41e7-8f4f-3f532fe0012d.jpg"  xlink:type="simple"/></disp-formula><p>After putting Equation (C9) and Equation (C10) into an Equation (C11) we obtain the solution in the text.</p></sec><sec id="s11"><title>Appendix D: Matlab Program Is to Find the Numerical Solution of the Non-Linear Differential Equations (12) and (13)</title><p>function pdex4 m = 0;</p><p>x = linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,:))</p><p>title('u1(x,t)')</p><p>xlabel('Distance x')</p><p>ylabel('u1(x,2)')</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=1.5;</p><p>alpha=0.5;</p><p>F =lamda*exp(u/(1+(alpha*u)));</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = ul;</p><p>ql = 0;</p><p>pr = ur-0;</p><p>qr = 0;</p></sec><sec id="s12"><title>Appendix E: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (12) and (13)</title><p>function pdex4 m = 0;</p><p>x = linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,J)</p><p>title(‘u1(x,t)’)</p><p>xlabel(‘Distance x’)</p><p>ylabel(‘u1(x,2)’)</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=0.3;</p><p>alpha=30;</p><p>F =lamda*exp(u/(1+(alpha*u)));</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = ul;</p><p>ql = 0;</p><p>pr = ur-0;</p><p>qr = 0;</p></sec><sec id="s13"><title>Appendix F: Solution of Troesch’s Problem Using HPM</title><p>In this Appendix, we indicate how the Equation (19) is derived.</p><p>When <img src="13-7400989\662f6d9f-2695-4353-896e-b078b7ae1697.jpg" /> is small, Equation (15) is reduces to</p><disp-formula id="scirp.23011-formula32538"><label>(E1)</label><graphic position="anchor" xlink:href="13-7400989\67d5c7cd-9314-4e84-b408-6cd2894cf7cf.jpg"  xlink:type="simple"/></disp-formula><p>We construct the Homotopy for the Equation (E1) is as follows:</p><disp-formula id="scirp.23011-formula32539"><label>(E2)</label><graphic position="anchor" xlink:href="13-7400989\9a58049b-549f-48bf-8a69-c6fd3d5afed8.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equation (15) with Equation (16) is</p><disp-formula id="scirp.23011-formula32540"><label>(E3)</label><graphic position="anchor" xlink:href="13-7400989\c660780e-49f9-4c1d-a5f5-93e9dddca717.jpg"  xlink:type="simple"/></disp-formula><p>Substituting the Equation (E3) into an Equation (E2) we get</p><disp-formula id="scirp.23011-formula32541"><label>(E4)</label><graphic position="anchor" xlink:href="13-7400989\06abb6a4-8e30-4f10-9b86-b1c222ec878a.jpg"  xlink:type="simple"/></disp-formula><p>Comparing the coefficients of like powers of p in Equation (E4) we get</p><disp-formula id="scirp.23011-formula32542"><label>(E5)</label><graphic position="anchor" xlink:href="13-7400989\5d17212b-a35f-4fe2-a854-53a62d073673.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32543"><label>(E6)</label><graphic position="anchor" xlink:href="13-7400989\9a12fdb8-261e-4a81-9225-c9f2e47bde85.jpg"  xlink:type="simple"/></disp-formula><p>The initial approximations are as follows&#160;</p><disp-formula id="scirp.23011-formula32544"><label>(E7)</label><graphic position="anchor" xlink:href="13-7400989\4595fb38-8b6b-42e9-ad2a-82a68c29ecf6.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32545"><label>(E8)</label><graphic position="anchor" xlink:href="13-7400989\120efb1f-bfc4-48ba-a59d-2ad5539132b0.jpg"  xlink:type="simple"/></disp-formula><p>Solving the Equation (E5) and the Equation (E6) and using the boundary conditions Equation (E7) and the Equation (E8) we obtain the following results:</p><disp-formula id="scirp.23011-formula32546"><label>(E9)</label><graphic position="anchor" xlink:href="13-7400989\e3403366-93eb-4558-bf5e-dd64366f6b4e.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32547"><label>(E10)</label><graphic position="anchor" xlink:href="13-7400989\5c168e47-b456-41c3-b783-2dd27ff0771d.jpg"  xlink:type="simple"/></disp-formula><p>According to the HPM, we can conclude that</p><disp-formula id="scirp.23011-formula32548"><label>(E11)</label><graphic position="anchor" xlink:href="13-7400989\04df617f-d637-4f02-b9a8-ebcb6d3203eb.jpg"  xlink:type="simple"/></disp-formula><p>After putting the Equation (E9) and the Equation (E10) into an Equation (E11) we obtain the solution in the text.</p></sec><sec id="s14"><title>Appendix G: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (15) and (16)</title><p>function pdex4 m = 0;</p><p>x = linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,:))</p><p>title('u1(x,t)')</p><p>xlabel('Distance x')</p><p>ylabel('u1(x,2)')</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=2.8;</p><p>F =-lamda*(sinh(lamda*u))</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = ul;</p><p>ql = 0;</p><p>pr = ur-1;</p><p>qr = 0;</p></sec><sec id="s15"><title>Appendix H: Solution of Catalytic Reactions in a Flat Particle Using HPM</title><p>In this Appendix, we indicate how the Equation (22) is derived. When <img src="13-7400989\1dbccbee-1dda-4054-91ef-e5941cfbdc71.jpg" /> is small, Equation (20) is reduces to</p><disp-formula id="scirp.23011-formula32549"><label>(H1)</label><graphic position="anchor" xlink:href="13-7400989\0f1e5091-f6f7-49a9-a3be-2d2c5c309e0c.jpg"  xlink:type="simple"/></disp-formula><p>We construct the Homotopy for the Equation (H1) is as follows:</p><disp-formula id="scirp.23011-formula32550"><label>(H2)</label><graphic position="anchor" xlink:href="13-7400989\4fa0fd4d-2cf4-4530-b726-90fc3723655b.jpg"  xlink:type="simple"/></disp-formula><p>The analytical solution of Equation (20) with Equation (21) is</p><disp-formula id="scirp.23011-formula32551"><label>(H3)</label><graphic position="anchor" xlink:href="13-7400989\9de6b513-2ee9-4c20-a813-e960b3cb2587.jpg"  xlink:type="simple"/></disp-formula><p>Substituting the Equation (E3) into an Equation (E2) we get</p><disp-formula id="scirp.23011-formula32552"><label>(H4)</label><graphic position="anchor" xlink:href="13-7400989\7fd4dcee-e59c-48f7-b87c-aadc901dbfdb.jpg"  xlink:type="simple"/></disp-formula><p>Comparing the coefficients of like powers of p in Equation (H4) we get</p><disp-formula id="scirp.23011-formula32553"><label>(H5)</label><graphic position="anchor" xlink:href="13-7400989\3d69aa85-3d60-450c-b286-02294a228ef2.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32554"><label>(H6)</label><graphic position="anchor" xlink:href="13-7400989\c8ded004-f4b8-4523-94b0-ff867f32cd34.jpg"  xlink:type="simple"/></disp-formula><p>The initial approximations are as follows&#160;</p><disp-formula id="scirp.23011-formula32555"><label>(H7)</label><graphic position="anchor" xlink:href="13-7400989\66b7dbec-0564-4669-84ae-085632531e0d.jpg"  xlink:type="simple"/></disp-formula><p><img src="13-7400989\c5844199-8044-414e-92d1-453d782c0548.jpg" /><img src="13-7400989\61b1fa5c-c1a0-438e-851e-7412e764a112.jpg" /> (H8)</p><p>Solving the Equation (H5) and the Equation (H6) and using the boundary conditions Equation (H7) and the Equation (H8) we obtain the following result:</p><disp-formula id="scirp.23011-formula32556"><label>(H9)</label><graphic position="anchor" xlink:href="13-7400989\f77f8cfd-e4d5-451b-b847-a6f984a93c5c.jpg"  xlink:type="simple"/></disp-formula><disp-formula id="scirp.23011-formula32557"><label>(H10)</label><graphic position="anchor" xlink:href="13-7400989\aff09694-7d36-4fb3-80c0-6f469bd66496.jpg"  xlink:type="simple"/></disp-formula><p>where k is defined in the text Equation (23).</p><p>According to the HPM, we can conclude that</p><disp-formula id="scirp.23011-formula32558"><label>(H11)</label><graphic position="anchor" xlink:href="13-7400989\01073966-4a75-4075-966f-8434e63d09f3.jpg"  xlink:type="simple"/></disp-formula><p>After putting the Equation (H9) and the Equation (H10) into an Equation (H11) we obtain the solution in the text.</p></sec><sec id="s16"><title>Appendix I: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (20) and (21)</title><p>function pdex4 m = 0;</p><p>x =linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,J)</p><p>title(‘u1(x,t)’)</p><p>xlabel(‘Distance x’)</p><p>ylabel(‘u1(x,2)’)</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=4;</p><p>beta=0.1;</p><p>gamma=5;</p><p>F=-lamda*u*exp(beta*gamma*(1-u)/(1+beta*(1-u)));</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>% -------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = 0;</p><p>ql = 1;</p><p>pr = ur(1)-1;</p><p>qr = 0;</p></sec><sec id="s17"><title>Appendix J: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (20) and (21)</title><p>function pdex4 m = 0;</p><p>x =linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,:))</p><p>title('u1(x,t)')</p><p>xlabel('Distance x')</p><p>ylabel('u1(x,2)')</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=1;</p><p>beta=0.15;</p><p>gamma=10;</p><p>F=-lamda*u*exp(beta*gamma*(1-u)/(1+beta*(1-u)));</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = 0;</p><p>ql = 1;</p><p>pr = ur(1)-1;</p><p>qr = 0;</p></sec><sec id="s18"><title>Appendix K: Matlab Program Is to Find the Numerical Solution of the Non Linear Differential Equations (20) and (21)</title><p>function pdex4 m = 0;</p><p>x =linspace(0,1);</p><p>t=linspace(0,10000);</p><p>sol= pdepe(m,@pdex4pde,@pdex4ic,@pdex4bc,x,t);</p><p>u1 = sol(:,:,1);</p><p>figure plot(x,u1(end,:))</p><p>title('u1(x,t)')</p><p>xlabel('Distance x')</p><p>ylabel('u1(x,2)')</p><p>%-----------------------------------------------------------------</p><p>function [c,f,s] = pdex4pde(x,t,u,DuDx)</p><p>c = 1;</p><p>f = DuDx;</p><p>lamda=1;</p><p>beta=0.1;</p><p>gamma=15;</p><p>F=-lamda*u*exp(beta*gamma*(1-u)/(1+beta*(1-u)));</p><p>s = F;</p><p>%-----------------------------------------------------------------</p><p>function u0 = pdex4ic(x); %create a initial conditions u0 = 1;</p><p>%-----------------------------------------------------------------</p><p>function[pl,ql,pr,qr]=pdex4bc(xl,ul,xr,ur,t) %create a boundary conditions pl = 0;</p><p>ql = 1;</p><p>pr = ur(1)-1;</p><p>qr = 0;</p></sec><sec id="s19"><title>Appendix: L Nomenclature</title><p>Symbol&#160;&#160;&#160;&#160; Meaning</p><p><img src="13-7400989\c3a881bd-cba3-42a6-b36f-2ef6f63d2db3.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless distance down the reactor</p><p><img src="13-7400989\20118cfb-e6cd-43b1-98a8-20ff0b92fcc9.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless concentration in the reactor</p><p><img src="13-7400989\c1df2032-4bc9-427d-810f-3bf2f7ae9a6d.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless parameter</p><p><img src="13-7400989\e2ae1bc8-69a8-415f-8437-6d3fec031d0b.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless parameter</p><p><img src="13-7400989\fec62edc-f5c7-496a-85f0-6678526d6ef5.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless parameter</p><p><img src="13-7400989\31568bf7-829b-4ac1-bee5-f0e26f2857af.jpg" />&#160;&#160;&#160;&#160;&#160;&#160;&#160;&#160; Dimensionless parameter</p></sec><sec id="s20"><title>NOTES</title></sec></body><back><ref-list><title>References</title><ref id="scirp.23011-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Y. 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