The sedimentological section was conducted at outcrops in the Akoumoutt area (Figure 3). The section is located at latitude N14˚57'41.3" and longitude E05˚41'34.4" (Figure 1(B)). The Ader Doutchi Formation (Ar) is characterized by deposits with an estimated thickness of approximately 30 meters, as shown in Figure 3. The stratigraphic organization is as follows:

Ader Doutchi member 1 (Ar¹) is characterized by a thickness of 4 m, comprising a succession of sedimentary rocks, including ferruginous mudstones, which are occasionally accompanied by floating ferruginous oolites, compact ferruginous clays, and compact clayey sandstones. The latter are overlied by a hardened clay surface (Figure 3, samples Ak2 to Ak6).Ader Doutchi member 2 (Ar²) has a base measuring 0.3 m consisting of two levels of ferruginous clay with termitic tubing (Figure 3, samples Ak7 and Ak8). The depositional environment of these sediments is characterized by a high degree of fracturing, resulting in the Formation of blocks measuring from decimeters to multiple decimeters in size. These blocks are particularly evident in flat areas spanning several tens of meters. The presence of blocks of ferruginous or microconglomeratic sandstone has been documented. These levels are overlain by an outcrop gap measuring approximately 13 meters in thickness, as illustrated in Figure 3. In thin sections, these deposits exhibit oolites, angular and sub-rounded quartz grains, and microfractures. These characteristics suggest that the deposits were formed nearly to the sources of sedimentation.Ader Doutchi member 3 (Ar³), which possesses a thickness of 10 meters, is composed of ferruginous sandstones, ferruginous oolites, and ferruginous mudstones (Figure 3, samples Ak9 to Ak12), which correspond to the upper part of the Ct¹ Formation (Figure 3).

Figure 3. Ader Doutchi formation is overlain by the bedrock of the Garadaoua formation: A-lithostratigraphic section, approximately 2 kilometers southwest of the village of Akoumoutt (localization Figure 1), and various Ct¹ outcrops in the Akoumoutt area: B-Photographs illustrating the boundary between the Barmou member (MB and the Ader Doutchi 1 member (Ar¹), C-Ferruginous mudstones exhibiting traces of burrows at the Ypresian-Oligocene Ar² boundary, D-Microconglomeratic blocks from the Ar³ top, and E-Ar³ top deposits.

4.2.1. Major Elements

According to the works of [15] and [70], the major element composition of fine siliciclastic rocks is generally controlled by clay minerals and non-clay silicate phases. As illustrated in Table 2, the values of the primary oxides (Al₂O₃, SiO₂, Fe₂O₃, TiO₂, MnO, P₂O₅, K₂O, CaO, MgO, Na₂O) detected in the argillites and ferruginous sandstones within the study area are presented. Al₂O₃ was identified as the most prevalent oxide in the sample examined. The contents of the various oxides is as follow: Al₂O₃ ranges from 6.22% to 70.03% (mean of 44.35%), while SiO₂ ranges from 0% to 76.43% (mean of 27%). The ranges of Fe₂O₃, MgO, TiO₂, MnO, K₂O, and CaO are respectively, from 4.57% to 27.2% (mean of 20.6%), from 1.46% to 3.87% (mean of 2.6%), from 0.06% to 5.68% (mean of 1.32%), from 0% to 4.5% (mean of 0.6%), from 0.01% to 0.57% (mean of 0.2%), and from 0.02 to 0.44 (mean of 0.23%). The Na₂O range is from 0.46% to 3.08%. The P₂O₅ contents in four samples ranged from 0.04% to 2.44%, with an average of 1.75%. These results suggest that the samples are depleted in K₂O, CaO, Na₂O and P₂O₅.

[15] reported that the K₂O/Al₂O₃ ratio values for clays are less than 0.3, and those for feldspars range from 0.3 to 0.9. This assertion is supported by the findings of ([15]), values ranging from 0.002 to 0.05) indicating a preponderance of clay minerals over potassium-containing minerals, such as potassium feldspars and micas. The K₂O/Al₂O₃ ratio values of the analyzed range from 0 to 0.06 (Table 1), indicating that the clay phase is predominant. The Ct¹ samples are distinguished by a deficiency in P₂O₅, alkalis (Na₂O and K₂O), and alkaline earths (MgO and CaO). This simultaneous depletion could be attributed to weathering conditions in the source zone ([28]). The positive correlations between the main oxides (Fe₂O₃ and P₂O₅, Table 1) and Al₂O₃ suggest an association with clay minerals ([22]). The data demonstrate depletion in oxides such as SiO₂, K₂O, TiO₂, CaO and Na₂O, and an enrichment in Al₂O₃, Fe₂O₃, MgO and MnO, when compared to the average UCC and PAAS values. Most of the samples examined exhibited a substantial decrease in P₂O₅ and MnO levels relative to the mean values of UCC and PAAS (Table 1). The depletion of K₂O, CaO, and Na₂O in the sedimentary deposits is not only indicative of quartz dissolution, but also suggests that the sediments have undergone chemical alteration in the source area ([51]; [2]). Compared with UCC, the levels of major elements are considerably lower. The observed depletion of Na₂O and K₂O in the samples is indicative of a low content of Na-rich plagioclase and potassium feldspar, a result that is consistent with petrographic analysis.

On average, the shale samples have lower SiO₂ contents than the UCC, suggesting that the observed variations are likely attributed to the effect of quartz dissolution ([6]; [27]). A comparison of the samples revealed that only one specimen (Ak5) demonstrates a higher SiO₂ content relative to the UCC and PASS (Table 1).

Table 1. Major elements composition of 11 samples obtained from Akoumoutt Ct, PAAS and UCC is presented.

UCC: Upper Continental Crust, PAAS “Middle Post-Australian Shale”, as defined by ([84]; [67]). CIA: the chemical index of alteration is an alteration used to quantify the intensity of chemical erosion processes in a specific environment. The following indices are employed: plagioclase index of alteration (PIA), chemical index of weathering (CWI), and index of compositional variability (CVI).

4.2.2. Trace Elements

The ratios of trace elements, such as V/Ni ([13]; [31]; [59]; [75]; [60]; [80]; [89]), or Cu/Zn ([38], have been used to elucidate paleoclimatic redox conditions during the deposition of sedimentary rocks. According to ([60]), the predominant factor influencing the relative proportions of Vanadium (V) and Nickel (Ni) in sedimentary rocks is the depositional environment. [76] and [91], posited that vanadium (V) demonstrates enhanced binding efficacy in sediments containing organic matter within anoxic environments when compared with nickel (Ni) and chromium (Cr). As proposed by [91], and [76], variations in the V/(V + Ni) and V/(V + Cr) ratios can be used to indicate the oxygenation of the depositional environment. The ratios V/(V + Ni) and V/(V + Cr) have been identified as potential indicators of the degree of oxygenation within the depositional environment. High V/(V + Ni) ratios, ranging from 0.76 and 0.90, are indicative of sedimentary rocks formed within a deep anoxic water column ([41]; [62]). In Ct¹ formation, the ratio of vanadium to nickel (V/(V + Ni)) ranges from 0.6 à 0.93 (Table 2). A single sample was found to have a zero V/(V + Ni) (Table 2). The data indicates that the ferruginous sandstones and clays of the Akoumoutt section were formed in a marine, margino-littoral, and continental environment, predominantly in anoxic shallow water (Table 2 and Figure 14). The presence and nature of the ferruginous oolites (Oγ, Oα) indicate a shallow water environment. The present study investigates the depth of the Ader Doutchi Formation during its emplacement in the study area.

Table 2. A comprehensive examination of the trace elements present in samples from the Ct¹ Formation in the Akoumoutt section. Elemental concentrations are expressed in parts per million (ppm). The depositional environments were estimated from the Sr/Ba ratio.

V/Ni ratios exceeding 3 are indicative of a reducing environment, while ratios ranging between 1.9 and 3 signify a suboxic environment ([31]). The Ct¹samples obtained from the Akoumoutt area exhibit a V/Ni ratio ranging from 0 to 14, with an average value of 6.41, as shown in Table 2. This finding suggests that the sediments were deposited in environments characterized by predominantly reducing conditions (Ar¹ member), suboxic to reducing anoxic conditions (Ar² member), and reducing conditions (Ar³ member). These results are consistent with the presence of pyrite dispersed in the rock matrix, as pyrite is indicative of a reducing environment and shallow water ([34]; [81]). The observations are consistent with the findings from thin section analysis, which indicated the presence of pyrite and oolites in the samples studied (Figure 4). The “Ader Doutchi siderolite series” was given this designation due to the significant alteration of pyrite to siderolite, as described by ([3]; [25]; [35]; [68]). The Ader Doutchi siderolite series is underlain by laminated black clays and marls ([20]). As indicated in the research by [20], there have been documented cases of plant debris being transformed into charcoal and pyrite crystals. However, traces of burrows and significant bioturbation have been detected in some Ct¹ deposits, particularly in the Ar² member of the study area (Figure 3(C)). According to ([7]), this phenomenon suggests periodic aeration of the sediments, thereby facilitating the activities and survival of burrowing organisms and bioturbators. In summary, an alternating pattern between oxic and anoxic conditions was observed during the establishment of Ct¹ in the Akoumoutt sector. This finding is consistent with the alternation of wet and dry periods in the Ader Doutchi, which transitions from the Ypresian to Miocene epoch.

Figure 4. Microphotograph of thin sections from the Oligo-Miocene deposits of Continental terminal 1. Meaning of abbreviations used: ‘’Ox’’ denotes iron oxide, “Po” indicates port, “Qzf” represents fractured quartz, “Sid” signifies siderite, “Py” is pyrite, “Of” is fractured oolite, “Oc” is composite oolite, “Moi” is micro-oolite, “Oγ” is gamma oolite, and “Oα” is alpha oolite.

According to [16], [18], and [17], the Cr/Th ratio is indicative of a mafic source when it ranges between 25 and 500. According to [67], and [84], the Cr/Th ratio value in the UCC is 7.76. The mean ratio of Ct¹ samples from the Akoumoutt area ranges from 0 to 190, with a mean of 38.5, which is indicative of a mafic source (Table 2). Two samples exhibited a Cr/Th ratio of 0, while one sample demonstrated a ratio of 5 (Table 2). This finding further corroborates the hypothesis that felsic or intermediate sources are also present.

Cr/V values for Ct¹ ferruginous clays range from 0 to 1.94, with an average of 0.88, and are relatively close to those for UCC (0.8) and PAAS (0.7) (Table 2). Elevated values relative to those of UCC and PASS are indicative of Cr enrichment relative to V, while comparatively lower values are indicative of Cr depletion relative to V. Ultramafic rocks are characterized by their tendency to exhibit high Cr/V ratios ([66]). Consequently, the low Cr/V ratios recorded in the samples confirm the significant absence of sediments originating from ultramafic rocks in the deposits studied. The lower Cr/V values indicate a low input of sediments from mafic rocks.

Table 3. Correlation between the major and trace elements present in samples extracted from the Ct¹ formation within the Akoumoutt area.

According to [32], a Cr/Ni ratio greater than 3 indicates Cr enrichment of fine-grained sediments, which is linked to the process of sediment fractionation. Consequently, Cr/Ni values less than 3 are indicative of Cr depletion in rocks. In samples from the Akoumoutt area, Cr/Ni values range from 0 to 13.33, with an average of 4.86. This observation suggests the presence of Cr enrichment in the rock Formation. This finding indicates a Cr enrichment of Ct¹ sediments (Table 2). The analysis yielded a statistically negative correlation between Cr and Ni (Table 3). According to [32], Cr/Ni values greater than 3 suggest substantial sediment fractionation of Ct¹ deposits within the Akoumoutt area (Table 2).

As demonstrated in Table 3, a correlation matrix illustrates the relationship between major oxides (Al₂O₃, SiO₂, Fe₂O₃, TiO₂, MnO, P₂O₅, K₂O, CaO, MgO, Na₂O) and specific elements (Ni, Cu, Zn, Zr, Nb, V, Cr, Sr, Rb, and Ba). In addition, a robust negative correlation was observed between SiO₂ concentration and Al₂O₃ as well as Fe₂O₃, as evidenced in Table 3. This result suggests that the majority of SiO₂ is present in detrital form.

As part of the present study, an evaluation of sediment composition, maturity, and weathering was conducted. In addition to the calculation of geochemical indices, such as CIA, PIA, ICV, and CIW, several parameters must be taken into consideration. The analyses were based on the formulas and diagrams proposed by [15]; [16]; [45]; [72]; [79].

The intensity and duration of weathering in clastic sediments can be assessed by examining the relationships between alkaline elements and alkaline earths elements ([73]). The impact of chemical weathering on the composition of siliciclastic sedimentary rocks can be evaluated by measuring the degree of chemical weathering. Many weathering indices have been documented in the extant literature; however, the most frequently employed are the chemical index of alteration (CIA), as proposed by earths ([72]), and the chemical index of weathering (CIW), as developed by ([40]). It is imperative to acknowledge that the latter is calculated differently from the CIA. The central chemical index of alteration (CIA) has been assigned the mission of monitoring the progressive conservation of feldspars into clay minerals. The application of this index is presented on the fact that feldspars are the most abundant minerals in the upper continental crust and that the major process involved in the chemical weathering is the alteration of feldspars to form clay minerals ([67]; [72]). The CIA has been used for monitoring the progressive alteration of feldspars into clay minerals. The application of this index is predicated on the fact that feldspars are the most abundant minerals in the upper continental crust and that the major process involved in chemical weathering is the alteration of feldspars to form clay minerals [67]; [72]. [72] developed the chemical index of alteration (CIA) formula, which is employed to assess the degree of chemical alteration. The chemical index of alteration (CIA) formula to assess the degree of chemical alteration is: CIA = [Al₂O₃/(Al₂O₃ + CaO* + K₂O + Na₂O)] × 100.

Despite the absence of petrographic analysis, the low concentration of calcium oxide (CaO) indicates that the calcium oxide present in the samples is associated with silicate phases. This assertion is supported by [29]. As indicated by [72], a CIA of 100 is indicative of complete transformation of feldspar to clay minerals, such as kaolinite.

According to [50] and [62], an increased intensity of chemical weathering may indicate a decrease in tectonic activity and/or a climate shift towards warmer, wetter climatic conditions, which are more conducive to chemical weathering in the source region. In environments characterized by arid or cold conditions, sediment is primarily attributable to abrasion and attrition processes. These processes entail the physical disintegration of the parent materials, accompanied by negligible chemical alteration. Additionally, the degree of chemical weathering was assessed using an additional chemical index of weathering (CIW).

Another effective measure for calculating the degree of chemical weathering is the plagioclase index of alteration (PIA, [29]), calculated by the following formula: the proportion of insoluble inorganic compounds (PIA) is calculated using the following formula: the proportion of insoluble inorganic compounds (PIA) is calculated using the following formula: PIA = [(Al₂O₃ − K₂O)/ (Al₂O₃ + CaO + Na₂O − K₂O)] × 100.

However, it should be noted that the CIA and PIA may not provide satisfactory results, particularly in samples with significant variations in calcium content ([16]). To achieve more reliable results, particularly in cases where high concentrations of CaO are present, [16] developed a formula to calculate the degree of chemical weathering in sandstones with high CaO content. This formula, referred to as the chemical index of weathering (CIW), is expressed as CIW = [Al₂O₃/(Al₂O₃ + Na₂O)] × 100. The values of the CIW (ranging from 75 to 99) obtained from the samples indicate intense to moderate weathering of first-cycle sediments. Alternatively, these values may also reflect recycling under semi-arid to semi-humid climatic conditions. CIW values also signify a dominant felsic source and sediment recycling processes ([28]). As [40] observed, the variability of K+ during weathering can introduce error into the CIA, as [72] presumed that K₂O was a mobile component. According to [40], the presence of K⁺ can facilitate the formation of K minerals or be adsorbed onto other clay minerals through ion exchange, even after entering solution.

The CIW values for the analyzed samples were (Table 1) range from 75 to 99, with an average of 85. CIW values are similar to those of CIA and PIA. The elevated CIW values (nearly reaching 100), detected in the examined specimens are suggestive of substantial chemical weathering. We can see that the CIW index increase in proportion to the degree of Na and Ca depletion in the sediments. This result is consistent with the documented negative correlation between Al₂O₃, Na₂O, and CaO (Table 3). According to [40], the discrepancy between CIW values for parent rock and sediments serves as an indicator of the extent of chemical alteration experienced by the weathered material.

The CIA, PIA, and CIW values in Ct¹ of the study area demonstrate respective variations ranging from 72 to 99, 74 to 99, and 75 to 99, as illustrated in Figure 5 and in Table 1. [72] reported CIW values of 0 for diopside, 30 to 40 for fresh basalt, 45 to 55 for granites and granodiorites, 50 for albite, anorthite, and unweathered potassium feldspars, and 75 for muscovite. Additionally, the values reported for illite, montmorillonite, and beidellite range from 75 to 85, while kaolinite and chlorite exhibit values approaching 100. The CIA values found in most samples from Ct¹ in the Akoumoutt sector are above 85, consistent with the presence of kaolinite, bauxite, and laterite, identified as the main minerals. The CIA, PIA, and CIW values indicate substantial alterations in the deposits under study (Figure 5). A single specimen displays indications of moderate weathering, as illustrated in Figure 5. The CIA values of the Ct¹ ferruginous clay samples from the Akoumoutt section (ranging from 72 to 99) (Table 1) clearly indicate intense chemical alteration.

Figure 5. Geochemical profiles of Ypresian to Miocene Ct¹ deposits, as proposed by [26], delineated by the CIA, PIA and CIW.

The compositional variations observed in the samples were mapped onto the Log(Fe₂O₃^t/K₂O) versus Log(SiO₂/Al₂O₃) binary diagram proposed by [44]. The observed variations suggest that the Ct¹ series in the Akoumoutt area is predominantly composed of ferruginous clays (Figure 6).

The [79] diagram was used to determine the provenance of Ypresian to Miocene sediments in the Ader Doutchi sub-basin (Figure 7). The F1 and F2 discrimination factors proposed by [79] were employed to estimate sediment provenance. The projection of samples from the Ypresian to Miocene in age formation in the Akoumoutt area, reveals the prevalence of a mafic igneous source (Figure 7). The presence of detrital quartz grains has been used as a key indicator of the emplacement of the Continental terminal 1 deposits (Figure 7). The detrital quartz source is attributed to the sediments recycling, in conjunction with a gradual input of feldspar ([1]).

Figure 6. Chemical classification of Ct¹ sediments from the Akoumoutt area in the Log (Fe₂O₃^t/K₂O) versus Log(SiO₂/Al₂O₃) binary proposed by [44].

Figure 7. Provenance of Ypresian to Miocene sediments in the Ader Doutchi sub-basin, as determined by the F1 versus F2 discrimination diagram proposed by [79].

The ratios of TiO₂ versus Zr (Figure 8) and TiO₂ versus Al₂O₃ (Figure 9, Figure 10) demonstrate that most sediments originate from felsic igneous rocks, with the presence of sediments from intermediate sources. The determination of sediment sources from TiO₂ and Zr ratios is based on the premise that these are the most stable heavy minerals and can retain the geochemical signatures of source rocks ([71]). As illustrated in Figures 8-10, a discernible correlation is apparent between mafic and intermediate igneous sources. The majority of Ct¹ samples are classified as originating from granodioritic and alkaligranitic sources (Figure 10). These results are consistent with those of studies conducted by [48], [48] and [49], in the undifferentiated Continental terminal deposits of the Kandi basin (Benin).

Figure 8. Scatter plot of TiO₂ versus Zr for Ct¹ samples from the Akoumoutt area, following the modifications of [7] to the original study [42].

Figure 9. The provenances of sediments from the Ypresian to Miocene in age of the Ader Doutchi sub-basin delineated based on the TiO₂ versus Al₂O₃ binary diagram proposed by [42].

Figure 10. Al₂O₃ versus TiO₂ binary diagram of samples from the Ader Doutchi Formation which is Ypresian to Miocene in age, based on the diagram proposed by [59].

[59] employed Al₂O₃/TiO₂ curves to determine the provenance of siliciclastic sediments. The Ct¹ ferruginous clay samples from the Akoumoutt area fall within the granodiorite and alkaligranite range of the Al₂O₃/TiO₂ diagram (Figure 10), indicating that the sediments originate from acid igneous rocks. According to [43] and [21], the Al₂O₃/TiO₂ ratio and SiO₂ content exhibit variation in igneous rocks. According to [42], the Al₂O₃/TiO₂ ratio varies between 3 and 8 for mafic igneous rocks, between 8 and 21 for intermediate rocks, and between 21 and 70 for felsic rocks ([7]). Two samples have Al₂O₃/TiO₂ ratios of 1071 (Ak7) and 798 (Ak11). The Al₂O₃/TiO₂ ratio of the majority of Ct¹ samples from the Akoumoutt area ranges from 1 to 269, with an average of 100, which suggests that the source rocks are likely intermediate or reworked igneous rock sediments. The range of SiO₂ values in the samples is from 0% to 76%, with an average of 27%.

The mean SiO₂ (µ 44%) of the base levels (Ar¹) approximates that of mafic sources, while the Ar², which represents a sedimentation gap, exhibits virtually no silica (SiO₂ < 0%). Similarly manner, Ar³ exhibits an average SiO₂ content of 19%. The low SiO₂ values observed in the analyzed samples can be attributed to its dissolution in favor of Al₂O₃, as demonstrated in Table 1. This dissolution could also be explained by the low SiO₂ content in relation to UCC (Table 1) ([6]; [27]).

The results of projecting geochemical data in the diagrams of [42], modified by [7] and [59], indicate a dominance of felsic sources. Conversely, the projection of samples from the Ct¹ Formation in the [79] diagram reveals a preponderance of mafic sources. A comprehensive analysis of the Ct¹ samples in the V-Ni-Th*10 ternary diagram, as delineated by [12], reveals that the sediments under scrutiny are derived from both mafic and felsic sources (Figure 11).

Figure 11. The V-Ni-Th*10 ternary diagram ([12]), provides a visual representation of the complex interplay among the elements. The shaded regions in the Figure delineate the composition of ultramafic, mafic, and felsic rocks. The ferruginous sandstones and mudstones of the Akoumoutt Ct¹ are near the mafic and intermediate source rocks. However, a single sample has been identified as originating from a felsic source.

Figure 12. Transition from Ypresian to Miocene sediments within the Ader Doutchi sub-basin determination based on the ICV versus CIA diagrams presented by [58].

The results of sample projection, as illustrated in the ICV versus CIA binary diagram proposed by [58], demonstrate that the sediments of the Ct¹ Formation are predominantly mature and have undergone significant alteration (Figure 12). The sedimentary deposits from the Ader Doutchi Formation demonstrate notable signs of weathering, with occasional instances of moderate weathering (Figure 12). A comprehensive analysis of the chemical and petrological properties of the Ct¹ deposits reveals significant alterations (Figure 4 and Figure 5). These alterations are accompanied by a notable absence of Na₂O and K₂O, along with relatively high SiO₂ (mean of 44%) at the base (Ar¹) (Table 1). These observations are essential in determining the maturity of the Ader Doutchi Formation deposits, suggesting the presence of an advanced sedimentary process. As demonstrated in Table 1, the ICV values for the marine series range from 1.13 to 4.2 (>>1), indicating consistency with compositional maturity.

The climate is one of the primary factors that influence the mineralogy, weathering, and chemical composition of sedimentary rocks ([9]). The SiO₂ versus Al₂O₃ + K₂O + Na₂O binary diagram in Figure 13, proposed by [83], has been employed to ascertain climatic conditions. Intense chemical weathering has been demonstrated to be strongly associated with a warm, humid climate ([73]). [59] proposed the Sr/Cu ratio as a significant indicator of paleoclimatic conditions. Sr/Cu ratios that exceed 5 are indicative of a warm, arid climate, while Sr/Cu ratios ranging from 1.3 to 5 suggest a warm, humid climate ([59]). The Sr/Cu ratios of the samples under study range from 0.67 to 16.40 (Table 2). The values observed in this study align with the data represented in the SiO₂ vs. Al₂O₃ + Na₂O + K₂O graph in Figure 13. This finding suggests the presence of a climate characterized by variations in temperature and precipitation, ranging from hot and humid to hot and arid conditions, during the development of the Ct¹ Formation in the Akoumoutt area (Figure 13). The results of the analysis reveal a correlation between high CIA values and the observed alteration in the paleoenvironments (Table 1).

The Sr/Ba ratio has been identified as a reliable indicator of environmental salinity in sedimentary rocks ([90]). [23] hypothesized that low Sr/Ba ratios are indicative of low salinity associated with a freshwater environment, while high Sr/Ba ratios are indicative of high salinity associated with a marine environment. According to studies by [82], Sr and Ba exhibit sensitivity to paleosalinity variations and are more concentrated in seawater than in freshwater. The authors demonstrated that variations in sedimentary environments have the potential to disrupt the correlation between these factors. Barium (Ba) is readily precipitated as BaSO₄, while strontium (Sr) exhibits greater mobility due to its higher solubility compared to that of Ba ([88]; [87]). Consequently, the Sr/Ba ratio has been employed as a proxy for paleoenvironmental changes in sedimentary rocks [88]. A Sr/Ba ratio greater than 1 indicates the presence of a marine deposit, whereas a ratio less than 1 is indicative of a continental deposit [88]. The Sr/Ba ratio values for the Ct¹ ferruginous mudstones and oolitic ferruginous sandstones in the study area range from 0.36 à 3.98 (Table 2). Four of the 11 samples (Ak2, Ak3, Ak9, and Ak10), exhibited a Sr/Ba ratio greater than 1, suggesting a sedimentation in a marine environment (Table 2). The seven remaining samples (Ak4, Ak5, Ak6, Ak7, Ak8, Ak11, and Ak12) that exhibit Sr/Ba ratios below 1, are indicative of a sedimentation in a continental environment (Table 2). The Sr/Ba ratio values of the Akoumoutt sector sediments indicate fluctuations in sea level, with the installation of a marine to intermediate domain during the deposition of the Ar¹ and Ar² members and the return to open marine conditions during the sedimentation of the Ar³ member (Figure 14). This phenomenon is indicative of the confluence of both fresh and marine water sources, exhibiting intermediate salinity characteristics. According to [7], this phenomenon is characteristic of deltaic environments, such as the Western Baram Delta, where freshwater flows into the ocean. The deltaic and marine depositional paleoenvironments determined in this study are consistent with the findings of research in the Continental terminal of the Iullemmeden Basin by [68] and [54]. The authors demonstrated that the Ader Doutchi rubefied series represents a transitional unit deposited in marine to margino-littoral and continental environments.

Figure 13. Paleoclimatic discrimination of the Continental terminal deposits in the Akoumoutt area, is derived from the SiO₂ versus (Al₂O₃ + K₂O + Na₂O) binary diagram of [83].

The geochemical signatures of sediments have been used to determine their provenance ([5]; [72]; [78]). The SiO₂/Al₂O₃ ratio, as previously theorized by these authors, demonstrates sensitivity to both the recycling process and weathering. The SiO₂/Al₂O₃ ratio has historically served as a proxy for evaluating the maturity of sediments. In unweathered igneous rocks, the typical SiO₂/Al₂O₃ ratio ranges from 3 in basic environments to 5 in acidic environments, while it is 5-6 in sedimentary rocks ([5]). [72] proposed the discriminant diagram using K2O/Na2O versus SiO₂ to establish various tectonic settings of clastic rocks (Figure 15). [65] proposed the SiO₂/Al₂O₃ versus K₂O/Na₂O diagram to further clarify tectonic discrimination (Figure 16). Projection of the samples from Ct¹ in the Akoumoutt area in the diagrams of [72] and [65] indicates that the sediments originate essentially from an oceanic island arc, in particular an evolved arc with felsic plutonic detritus (Figure 15 and Figure 16). Two samples suggest emplacement in a context of an active continental margin (Figure 15 and Figure 16). These sediment sources could be the proximal mountainous reliefs that constitute the Touareg shield, such as the Aïr, Adrar des Iforas, and Hoggar mountains. During the Cenozoic, the Tuareg Shield (Aïr, Adrar des Iforas and Hoggar), which corresponds to an ancient Pan-African active margin associated with island arcs, underwent bulging ([61]) and represents a province with high topography. Consequently, the crystalline and crystallophyllous rocs on the various terranes of the Tuareg Shield could represent the main sources of detrital sediments filling the Ypresian to Miocene Ader Doutchi sub-basin.

Figure 14. The projection of the Ader Doutchi Formation samples is represented in the Sr versus Ba diagram, as proposed by [92].

Figure 15. Presentation of the discriminant Log (K₂O/Na₂O) versus SiO₂ diagram of samples from the Ader Doutchi Formation in the Akoumoutt area. This Figure demonstrates the provenance of sediments from an oceanic island arc and an active continental margin, as indicated by the diagram proposed by [72].

Figure 16. Tectonic discrimination diagram SiO₂/Al₂O₃ vs K₂O/Na₂O for sedimentary rocks after [65]. ACM = active continental margin; PM = passive margin; A1 = arc setting, basaltic and andesitic detritus; A2 = evolved arc setting, felsic plutonic detritus.