<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article">
 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">
    ojg
   </journal-id>
   <journal-title-group>
    <journal-title>
     Open Journal of Geology
    </journal-title>
   </journal-title-group>
   <issn pub-type="epub">
    2161-7570
   </issn>
   <issn publication-format="print">
    2161-7589
   </issn>
   <publisher>
    <publisher-name>
     Scientific Research Publishing
    </publisher-name>
   </publisher>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="doi">
    10.4236/ojg.2025.1511044
   </article-id>
   <article-id pub-id-type="publisher-id">
    ojg-147686
   </article-id>
   <article-categories>
    <subj-group subj-group-type="heading">
     <subject>
      Articles
     </subject>
    </subj-group>
    <subj-group subj-group-type="Discipline-v2">
     <subject>
      Earth 
     </subject>
     <subject>
       Environmental Sciences
     </subject>
    </subj-group>
   </article-categories>
   <title-group>
    The Paleoproterozoic Two-Mica Granites of the West African Craton: A Petrological and Geochemical Study of the Ferké Batholith and Associated Plutons, Ivory Coast
   </title-group>
   <contrib-group>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Koffi Alexis
      </surname>
      <given-names>
       N’Dri
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff1"> 
      <sup>1</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Ziandjêdé Hervé
      </surname>
      <given-names>
       Siagné
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff1"> 
      <sup>1</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Wilfried
      </surname>
      <given-names>
       Digbeu
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff2"> 
      <sup>2</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Yacouba
      </surname>
      <given-names>
       Coulibaly
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff3"> 
      <sup>3</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Alain Nicaise
      </surname>
      <given-names>
       Kouamelan
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff3"> 
      <sup>3</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       N’dri Eudes Sati
      </surname>
      <given-names>
       Tegan
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff3"> 
      <sup>3</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Gbélé
      </surname>
      <given-names>
       Ouattara
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff1"> 
      <sup>1</sup>
     </xref>
    </contrib>
   </contrib-group> 
   <aff id="aff1">
    <addr-line>
     aInstitut National Polytechnique Félix Houphouët-Boigny, Laboratoire des Sciences Géographiques, du Génie Civil et des Géosciences, Ecole Supérieure des Mines et Géologie, Yamoussoukro, Côte d’Ivoire
    </addr-line> 
   </aff> 
   <aff id="aff2">
    <addr-line>
     aUniversité de Man, UFR Sciences Géologiques et Minières, Département de Géologie et Matériaux, Man, Côte d’Ivoire
    </addr-line> 
   </aff> 
   <aff id="aff3">
    <addr-line>
     aLaboratoire de géologie, ressources minérales et énergétiques/Unité de formation des Sciences de la Terre et des Ressources Minières, Université Félix Houphouët-Boigny, Abidjan, Côte d’Ivoire
    </addr-line> 
   </aff> 
   <pub-date pub-type="epub">
    <day>
     06
    </day> 
    <month>
     11
    </month>
    <year>
     2025
    </year>
   </pub-date> 
   <volume>
    15
   </volume> 
   <issue>
    11
   </issue>
   <fpage>
    849
   </fpage>
   <lpage>
    865
   </lpage>
   <history>
    <date date-type="received">
     <day>
      8,
     </day>
     <month>
      October
     </month>
     <year>
      2025
     </year>
    </date>
    <date date-type="published">
     <day>
      25,
     </day>
     <month>
      October
     </month>
     <year>
      2025
     </year> 
    </date> 
    <date date-type="accepted">
     <day>
      25,
     </day>
     <month>
      November
     </month>
     <year>
      2025
     </year> 
    </date>
   </history>
   <permissions>
    <copyright-statement>
     © Copyright 2014 by authors and Scientific Research Publishing Inc. 
    </copyright-statement>
    <copyright-year>
     2014
    </copyright-year>
    <license>
     <license-p>
      This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/
     </license-p>
    </license>
   </permissions>
   <abstract>
    The Paleoproterozoic basement of Ivory Coast, a key component of the West African Craton (WAC), is intruded by numerous granitoid suites. Among these, the two-mica granites (leucogranites) form a significant component, predominantly represented by the North-South trending Ferké Batholith. This study synthesizes petrographic and geochemical data from the Ferké Batholith and other leucogranite plutons across Ivory Coast to constrain their petrogenesis and geodynamic setting. Petrographically, these leucogranites are characterized by a quartz + K-feldspar + plagioclase + biotite + muscovite ± garnet assemblage. Geochemically, they are high-silica (68.5 - 74.8 wt% SiO
    <sub>2</sub>), potassic to shoshonitic, and range from metaluminous to strongly peraluminous. Multi-element spider diagrams show enrichment in Large-Ion Lithophile Elements (LILE: Rb, Ba, Th, U) and negative anomalies in Nb, Ta, Ti, and Eu. Chondrite-normalized REE patterns display LREE enrichment [(La/Yb)N = 11.6 − 51.5] and variable negative Eu anomalies (Eu/Eu* = 0.54 − 1.05). The geochemical signatures indicate a dual origin: a crustal source (peraluminous granites of Ferké, Abidjan, Grand-Lahou) likely involving partial melting of Archean TTG-like protoliths, and a mantle-derived component with crustal assimilation (metaluminous granites of Katiola, Nassian, and some from Bouaké and Dabakala). Tectonic discrimination diagrams suggest emplacement in syn-collisional to volcanic arc settings during the Eburnean orogeny. The enrichment in LILE is attributed to a combination of magmatic differentiation and crustal contamination. This study underscores the genetic link between these leucogranites and the Paleoproterozoic crustal evolution of the West African Craton.
   </abstract>
   <kwd-group> 
    <kwd>
     Two-Mica Granite
    </kwd> 
    <kwd>
      Leucogranite
    </kwd> 
    <kwd>
      Geochemistry
    </kwd> 
    <kwd>
      Petrogenesis
    </kwd> 
    <kwd>
      Eburnéen Orogeny
    </kwd> 
    <kwd>
      West African Craton
    </kwd> 
    <kwd>
      Ivory Coast
    </kwd>
   </kwd-group>
  </article-meta>
 </front>
 <body>
  <sec id="s1">
   <title>1. Introduction</title>
   <p>The West African Craton (WAC), stabilized during the Paleoproterozoic Eburnean orogeny (~2.1 Ga), represents a fundamental unit of the Earth’s continental crust. In Ivory Coast, the crystalline basement is a testament to a complex crustal evolution involving three major Precambrian orogenies (Leonian, Liberian, and Eburnéen) and constitutes over 97% of the national territory, with the remainder covered by a Mesozoic-Tertiary coastal basin <xref ref-type="bibr" rid="scirp.147686-1">
     [1]
    </xref>. This ancient basement, aged over 1.6 billion years, is predominantly composed of a diverse suite of granitoid rocks, which form its architectural backbone <xref ref-type="bibr" rid="scirp.147686-2">
     [2]
    </xref>. This suite includes granodiorites, alkaline granites, calc-alkaline granites, tonalites, trondhjemites, and two-mica granites (leucogranites). Their formation is intrinsically linked to the tectonic processes that shaped the craton, making them critical for understanding the geodynamic evolution of West Africa. Consequently, they have been the focus of numerous lithostratigraphic and geochemical studies aimed at deciphering their genesis <xref ref-type="bibr" rid="scirp.147686-3">
     [3]
    </xref>-<xref ref-type="bibr" rid="scirp.147686-7">
     [7]
    </xref>.</p>
   <p>Among these, the two-mica leucogranites hold particular significance. They are predominantly represented by the vast, N-S trending Ferké Batholith—a ~400 km long intrusive body—but are also recorded in numerous other plutons across the Paleoproterozoic domain of the country <xref ref-type="bibr" rid="scirp.147686-8">
     [8]
    </xref> <xref ref-type="bibr" rid="scirp.147686-9">
     [9]
    </xref>. Despite their widespread occurrence and importance, a comprehensive synthesis of their distribution, petrographic character, and geochemical signature has been lacking. Previous studies have often been localized, leaving a gap in the holistic understanding of this major granite group.</p>
   <p>This study aims to address this gap by building upon foundational work to provide a unified analysis. The specific objectives are to: 1) systematically map and describe the petrographic units of the major two-mica granite plutons across Ivory Coast; 2) characterize their geochemical signatures using major, trace, and rare earth element data; 3) integrate petrographic and geochemical data to understand petrogenetic processes and source characteristics; and 4) propose a coherent geodynamic model for their emplacement within the Eburnean orogeny. By achieving these objectives, this work contributes to a more nuanced model for the formation of the Paleoproterozoic crust in the West African Craton.</p>
  </sec><sec id="s2">
   <title>2. Geological Setting</title>
   <p>The West African Craton (WAC) records a long and complex Precambrian evolution marked by the Leonian, Liberian, and Eburnean orogenies. Its basement is composed of Archean and Paleoproterozoic granitoids that reflect different tectono-magmatic environments (<xref ref-type="fig" rid="fig1">
     Figure 1
    </xref>). The Archean granitoids, dated between 3.0 and 2.5 Ga, are mainly represented by tonalite-trondhjemite-granodiorite (TTG) associations, granodiorites, granites, and charnockites, locally reworked under granulite facies metamorphism <xref ref-type="bibr" rid="scirp.147686-10">
     [10]
    </xref> <xref ref-type="bibr" rid="scirp.147686-11">
     [11]
    </xref>. These TTG-type assemblages are typical of early cratonic crust and greenstone belt terranes.</p>
   <p>During the Paleoproterozoic, the Eburnean orogeny (2.2 - 1.8 Ga) generated a wide range of granitoids with variable structural positions and geochemical signatures. Early classifications <xref ref-type="bibr" rid="scirp.147686-6">
     [6]
    </xref> <xref ref-type="bibr" rid="scirp.147686-8">
     [8]
    </xref> distinguished syntectonic heterogeneous batholiths (Baoulé-type, equivalent to Cape Coast granites in Ghana) from post-tectonic homogeneous plutons (Bondoukou-type, equivalent to Dixcove granites). Later refinements emphasized their emplacement in distinct tectonic domains: granitoids of folded eugeosynclinal zones (Abronian granitoids, Eburnean I) and granitoids of folded miogeosynclinal zones and activated intermediate massifs (Baoulé granitoids, Eburnean II) <xref ref-type="bibr" rid="scirp.147686-3">
     [3]
    </xref>. Geochemical studies further revealed that Ivorian Eburnean granitoids are generally leucocratic, sodic, and feldspathic, but poorer in ferromagnesian and calcic components compared to global analogues <xref ref-type="bibr" rid="scirp.147686-12">
     [12]
    </xref>.</p>
   <p>Two major Paleoproterozoic granitoid generations are recognized. The first (2200 - 2150 Ma) is closely associated with greenstone belts and dominated by TTG-type suites (granodiorites, tonalites, trondhjemites). The second (2150 - 1800 Ma) is related to volcanic-sedimentary ridges and includes monzogranites, granodiorites, tonalites, and leucogranites <xref ref-type="bibr" rid="scirp.147686-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147686-13">
     [13]
    </xref>-<xref ref-type="bibr" rid="scirp.147686-16">
     [16]
    </xref>. Together, these granitoids reflect the transition from Archean TTG-dominated crustal growth to Paleoproterozoic syn- to post-orogenic magmatism during the Eburnean cycle, which played a major role in the stabilization and evolution of the southern WAC.</p>
   <p>The geology of Côte d’Ivoire is part of the West African Craton (WAC), which includes Archean and Paleoproterozoic terranes stabilized between 3450 and 1600 Ma <xref ref-type="bibr" rid="scirp.147686-17">
     [17]
    </xref>-<xref ref-type="bibr" rid="scirp.147686-19">
     [19]
    </xref> (<xref ref-type="fig" rid="fig1">
     Figure 1
    </xref>). The country lies within the Man Shield, one of the major exposures of the craton, and is composed of ~97.5% Precambrian basement rocks and ~2.5% of a narrow Cretaceous-Tertiary coastal sedimentary basin. The Precambrian basement is divided into two main structural domains separated by the Sassandra fault: 1) the Kenema-Man Archean domain to the west, shaped by the Leonian (3300 - 2900 Ma) and Liberian (2900 - 2700 Ma) orogenies, and 2) the Baoulé-Mossi Paleoproterozoic domain to the east, structured during the Eburnean orogeny (2500 - 1600 Ma), sometimes subdivided into a Burkinian event (2400 - 2150 Ma) and the Eburnean sensu stricto (2120 - 1800 Ma) cycle <xref ref-type="bibr" rid="scirp.147686-20">
     [20]
    </xref>. The Archean domain is dominated by gneissic granitoids, greenstone relics, and high-grade metamorphic rocks, whereas the Paleoproterozoic domain is characterized by predominantly felsic lithologies metamorphosed under greenschist to amphibolite facies conditions. The latter includes two structural zones <xref ref-type="bibr" rid="scirp.147686-9">
     [9]
    </xref> <xref ref-type="bibr" rid="scirp.147686-21">
     [21]
    </xref>: the SASCA zone in the southwest, where Archean and Birimian units coexist, and a broader geosynclinal-type zone dominated by Birimian volcano-sedimentary sequences and granitoid intrusions oriented NE-SW. Structurally, the Eburnean evolution is marked by three major defor</p>
   <fig id="fig1" position="float">
    <label>Figure 1</label>
    <caption>
     <title>
      <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 1. Geological map of the West African Craton showing the location of the study area (modified after <xref ref-type="bibr" rid="scirp.147686-22">
       [22]
      </xref>).</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId13.jpeg?20251128040255" />
   </fig>
   <p>Mation phases: an early brittle deformation (D1) responsible for the formation of Eburnean troughs and the Sassandra fault system; a ductile phase (D2) associated with regional folding and metamorphism; and a late Eburnean phase (D3, 1800 - 1550 Ma) that localized shear zones and was partly coeval with Tarkwaian sedimentation. A distinctive feature of the Ivorian basement is the widespread development of two-mica granites, particularly the Ferkessédougou Batholith (syntectonic muscovite-rich leucogranite). This body extends over ~400 km in length and up to 50 km in width, cutting across the country from NE to SW and separating the Archean and Paleoproterozoic domains <xref ref-type="bibr" rid="scirp.147686-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147686-12">
     [12]
    </xref> (<xref ref-type="fig" rid="fig2">
     Figure 2
    </xref>). These granites are aligned parallel to the tectonic fabric of the surrounding metasedimentary units and are mostly restricted to the Paleoproterozoic domain, being virtually absent in the Archean terranes. Overall, the geological framework of Côte d’Ivoire reflects the juxtaposition of Archean and Paleoproterozoic crustal blocks, later intruded by granitoids and affected by successive deformation and metamorphism during the Eburnean cycle, followed by post-orogenic brittle faulting and dolerite-kimberlite intrusions.</p>
   <fig id="fig2" position="float">
    <label>Figure 2</label>
    <caption>
     <title>
      <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 2. Simplified map of two-mica granites in Côte d’Ivoire (modified after <xref ref-type="bibr" rid="scirp.147686-23">
       [23]
      </xref>). 1-Ferke batholith; 2-Dabakala batholith; 3-Kowara batholith; 4-Nassian batholith; 5-Minignan batholith; 6-Bouake batholith; 7-Batholiths of the N’Douci, Skensi, and Anyama regions.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId14.jpeg?20251128040255" />
   </fig>
  </sec><sec id="s3">
   <title>3. Methodology</title>
   <p>The data used in this study are derived from the doctoral theses of Casanova, Yobou, and Doumbia <xref ref-type="bibr" rid="scirp.147686-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147686-7">
     [7]
    </xref> <xref ref-type="bibr" rid="scirp.147686-12">
     [12]
    </xref>, which were based on extensive field campaigns and laboratory analyses. Petrographic analyses were carried out on thin sections to determine the lithology and mineral parageneses, allowing for detailed characterization of the constituent minerals and their textures.</p>
   <p>Geochemical analyses employed multiple techniques. Major and minor elements were quantified using ICP-ES, while trace elements were measured by ICP-MS at the CRPG in Nancy <xref ref-type="bibr" rid="scirp.147686-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147686-7">
     [7]
    </xref>. Casanova’s earlier work also utilized emission spectrography, atomic absorption spectrophotometry, and colorimetry, depending on the element analyzed. To ensure consistency and comparability across the entire geochemical dataset, all data were normalized to common reference standards and reprocessed using contemporary calibration methods. This integrated approach provides precise information on rock chemical composition and offers a reliable basis for tectono-geochemical interpretation of the Precambrian basement of Côte d’Ivoire. The data were processed using standard petrological software and plotted on discriminant diagrams (TAS, R1-R2, Pearce diagrams, multi-element spidergrams, REE patterns) to classify the rocks and infer their petrogenesis and tectonic setting.</p>
  </sec><sec id="s4">
   <title>4. Results</title>
   <sec id="s4_1">
    <title>4.1. Petrography</title>
    <p>The granites and leucogranites of Côte d’Ivoire display significant textural and mineralogical variability, reflecting diverse magmatic and tectonic conditions. The Ferké-Niakaramandougou leucogranites are syntectonic, muscovite-dominated, with well-developed foliation and lineation. Two facies are recognized: a medium- to coarse-grained facies, granitic to porphyrogranular, and a fine-grained border facies, microgranular to micro-porphyritic. Quartz ranges from subhedral to euhedral, alkali feldspar is xenomorphic or perthitic, and plagioclase commonly exhibits twinning and sillimanite inclusions. Biotite is automorphic and elongate, often interlayered with muscovite, which occurs in multiple generations.</p>
    <p>The Katiola-Marabadiassa massifs (Kowara and N’Zi) contain mesocratic porphyrogranites, enriched in biotite and plagioclase. Intense mylonitization is observed in the N’Zi massif, associated with mineral lineation and injection of pegmatites with muscovite ± tourmaline ± garnet. Two-mica granites from Bouaké, Zuénoula, Dabakala-Nassian, and Abidjan are granitic to porphyrogranular, composed mainly of quartz, microcline, plagioclase, chloritized biotite, and muscovite. Accessory minerals include garnet, apatite, zircon, epidote, and magnetite.</p>
    <p>Korhogo and Kong granites exhibit granoblastic to porphyrogranular textures, with biotite, muscovite, quartz, and feldspars, and accessories such as tourmaline and spodumene. In the SASCA domain, six petrographic types were identified, ranging from foliated granites with large muscovite lamellae to weakly oriented, leucocratic granites. Tectonic structures, including foliation, lineation, and mortar-like textures, are frequent, especially in deformed massifs.</p>
    <p>Overall, the Precambrian granites exhibit substantial variability in texture, mica proportions, and accessory minerals, reflecting a strong syn- and post-emplacement tectonomagmatic influence. This mineralogical and textural diversity allows clear differentiation between leucocratic, mesocratic, and highly deformed to migmatitic facies.</p>
   </sec>
   <sec id="s4_2">
    <title>
     <xref ref-type="bibr" rid="scirp.147686-"></xref>4.2. Geochemistry</title>
    <p>The two-mica granites from the studied massifs display a remarkable chemical homogeneity. They are consistently silica-rich (SiO<sub>2</sub> = 68.5 - 74.8 wt.%) and aluminum-rich (Al<sub>2</sub>O<sub>3</sub> = 13.3 - 17.2 wt.%, average 14.9 wt.%), with alumina saturation indices generally above 1.13 (<xref ref-type="table" rid="tableS1">
      Table S1
     </xref> in Supplementary material). Total alkalis (Na<sub>2</sub>O + K<sub>2</sub>O) range from 6.8 wt.% to 10.2 wt.%, although four Kowara samples yield slightly lower values (5.5 - 6.8 wt.%). K<sub>2</sub>O dominates over Na<sub>2</sub>O, with an average K<sub>2</sub>O/Na<sub>2</sub>O ratio of 1.18, indicating the predominance of alkali feldspar over sodic plagioclase, which is mainly albite-oligoclase with CaO &lt; 3.5 wt.%. The Na<sub>2</sub>O + K<sub>2</sub>O/CaO ratio reaches up to 16.3. Mafic constituents are scarce, as shown by the sum of TiO<sub>2</sub> + FeOt + MnO + MgO rarely exceeding 7% (mean 2.1%).</p>
    <p>In the TAS diagram <xref ref-type="bibr" rid="scirp.147686-24">
      [24]
     </xref>, the samples (SiO<sub>2</sub> = 58.2 - 74.8 wt.%; Na<sub>2</sub>O + K<sub>2</sub>O = 5.8 - 10.2 wt.%) plot within the granite field, extending toward alkaline granites (<xref ref-type="fig" rid="fig3(a)">
      Figure 3(a)
     </xref>). Most samples fall in the acidic domain, ranging from subalkaline to alkaline compositions, whereas Kowara rocks are the least siliceous and lie at the granite-quartz diorite boundary. The R1-R2 diagram of De la Roche <xref ref-type="bibr" rid="scirp.147686-25">
      [25]
     </xref> indicates limited compositional variation, from quartz syenite to granodiorite (<xref ref-type="fig" rid="fig3(b)">
      Figure 3(b)
     </xref>). Granites from Ferkéssédougou, Abidjan, and Bouaké cluster within the granite field, while Grand-Lahou samples lie at the granite-alkaline granite boundary. Dabakala samples fall between granite and granodiorite, and Kowara leucogranites show granodioritic affinities. These classifications confirm the granitic affinity of the Abidjan, Bouaké, Katiola, Ferkéssédougou, Grand-Lahou, and Nassian intrusions, and the granodioritic to tonalitic character of Kowara and part of Dabakala.</p>
    <p>The two-mica granites follow the calc-alkaline trend close to the A pole, consistent with their evolved nature. In the K<sub>2</sub>O vs. SiO<sub>2</sub> diagram of Peccerillo and Taylor <xref ref-type="bibr" rid="scirp.147686-26">
      [26]
     </xref> (<xref ref-type="fig" rid="fig3(c)">
      Figure 3(c)
     </xref>), samples from Abidjan, Bouaké, Grand-Lahou, Katiola, and Ferké plot between the high-K calc-alkaline and shoshonitic series, with one Ferké sample in the calc-alkaline field. Dabakala rocks are more scattered, ranging from tholeiitic to shoshonitic affinities, likely due to alkali mobility. Kowara and Nassian samples fall within the calc-alkaline series. In the alumina saturation diagram of Barton and Young <xref ref-type="bibr" rid="scirp.147686-27">
      [27]
     </xref>, the granites are mostly peraluminous (<xref ref-type="fig" rid="fig3(d)">
      Figure 3(d)
     </xref>). Abidjan and Ferké range from weakly to strongly peraluminous, Kowara rocks are strongly peraluminous (ASI &gt; 1.1), and Grand-Lahou is weakly peraluminous. Bouaké and Dabakala vary from metaluminous to strongly peraluminous, while Katiola and Nassian are generally metaluminous (ASI &lt; 1). <xref ref-type="fig" rid="fig3(d)">
      Figure 3(d)
     </xref> reveals the granite types for the two-mica granites studied. The Nassian, Katiola, and Grand-Lahou granites are I-type, while those from Kowara are S-type. Those from Abidjan, Bouaké, Dabakala, and Ferké straddle I- and S-types.</p>
    <p>Overall, the two-mica granites from Côte d’Ivoire are predominantly peraluminous, silica-rich, and K-rich, with compositions ranging from syenogranite to granodiorite. Their calc-alkaline to shoshonitic affinities and evolved geochemical features highlight their magmatic differentiation and the influence of source composition.</p>
    <fig id="fig3" position="float">
     <label>Figure 3</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 3. Chemical variation diagrams for the two-mica granites illustrate the geochemical features that distinguish the studied rocks. (a) Plot of Na<sub>2</sub>O + K<sub>2</sub>O vs. SiO<sub>2</sub> (after <xref ref-type="bibr" rid="scirp.147686-24">
        [24]
       </xref>; adapted from <xref ref-type="bibr" rid="scirp.147686-28">
        [28]
       </xref>); (b) Plot of R₁ vs. R<sub>2</sub> (<xref ref-type="bibr" rid="scirp.147686-25">
        [25]
       </xref>); (c) Plot of K<sub>2</sub>O vs. Na<sub>2</sub>O (<xref ref-type="bibr" rid="scirp.147686-26">
        [26]
       </xref>), as modified by <xref ref-type="bibr" rid="scirp.147686-29">
        [29]
       </xref>); (d) Plot of alumina saturation (<xref ref-type="bibr" rid="scirp.147686-27">
        [27]
       </xref>).</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId15.jpeg?20251128040259" />
    </fig>
    <p>The trace element compositions of the two-mica granite massifs are illustrated in primitive mantle-normalized diagrams (<xref ref-type="fig" rid="fig4">
      Figure 4
     </xref>). The multi-element spectra display broadly similar patterns, characterized by enrichment in incompatible LILE (Cs, Rb, Ba, Sr) and HFSE (Th, U, Ta, Nb, Zr). The rocks also show a pronounced positive Pb anomaly and negative K and Ti anomalies. The Ba enrichment indicates a lack of significant fractionation of K-feldspar, while the positive Sr anomaly is attributed to plagioclase melting, as Sr readily substitutes for Ca in its crystal structure. Negative Ti anomalies reflect the fractionation of accessory phases such as Fe-Ti oxides and sphene, typical of intermediate to acidic magmas <xref ref-type="bibr" rid="scirp.147686-30">
      [30]
     </xref> (<xref ref-type="fig" rid="fig4">
      Figure 4
     </xref>). The enrichment in HFSE may be related to the separation of accessory minerals such as zircon, which is known to host Zr, Y, Hf, and Yb <xref ref-type="bibr" rid="scirp.147686-31">
      [31]
     </xref>.</p>
    <p>A total of eleven whole-rock analyses from the Ferkéssédougou (7 samples) and Kowara (4 samples) massifs were used to characterize REE distribution (<xref ref-type="table" rid="tableS1">
      Table S1
     </xref> in Supplementary material). The Ferké granites show variable total REE contents ranging from 28 to 489 ppm, with the lowest and highest concentrations recorded in samples T9N2 and T-14, respectively. The Ferké leucogranites display parallel REE spectra with low to moderate slopes (<xref ref-type="fig" rid="fig5(a)">
      Figure 5(a)
     </xref>, indicating a moderate enrichment in light REE (LREE) (LaN = 17.58 - 350 × chondrite) and moderate to strong fractionation [(La/Yb)N = 11.58 - 51.50]. Sample T-14 is distinguished by its strong REE enrichment, interpreted as reflecting a low degree of partial melting of garnet-bearing crustal sources. Europium anomalies are generally weak to absent (Eu/Eu* = 0.54 - 0.97). The lack of Eu anomaly in T-14 may be explained by oxidizing conditions, under which Eu³⁺ cannot be incorporated into feldspars <xref ref-type="bibr" rid="scirp.147686-7">
      [7]
     </xref>.</p>
    <p>The Kowara granites show more homogeneous REE contents, ranging from 65.6 to 100 ppm, with spectra broadly parallel and comparable to those of Ferké (<xref ref-type="fig" rid="fig5(b)">
      Figure 5(b)
     </xref>. These rocks are enriched in LREE with weak to moderate fractionation [(La/Yb)N = 11.48 - 21.79], except for sample SEP-1, which displays stronger fractionation [(La/Yb) N = 51.50]. No significant europium anomaly is observed in this massif (Eu/Eu* = 0.93 - 1.05).</p>
    <fig id="fig4" position="float">
     <label>Figure 4</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 4. Primitive mantle-normalized multi-element spider diagrams for the studied Cote d’Ivoire two-mica granite suites. (a) Abidjan; (b) Bouaké; (c) Dabakala; (d) Katiola; (e) Nassian; (f) Grand-Bassam; (g) Tai; (h) Kowara; and (i) Ferké (chondrite values from <xref ref-type="bibr" rid="scirp.147686-32">
        [32]
       </xref>).</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId16.jpeg?20251128040259" />
    </fig>
    <fig id="fig5" position="float">
     <label>Figure 5</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 5. Chondrite-normalized rare earth element (REE) patterns for the studied Cote d’Ivoire two-mica granite suites. (a) Kowara and (b) Ferké (chondrite values from <xref ref-type="bibr" rid="scirp.147686-32">
        [32]
       </xref>).</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId17.jpeg?20251128040259" />
    </fig>
   </sec>
  </sec><sec id="s5">
   <title>5. Discussion</title>
   <sec id="s5_1">
    <title>
     <xref ref-type="bibr" rid="scirp.147686-"></xref>5.1. Nomenclature</title>
    <p>The classification of two-mica granites, long based solely on field observations and petrography, appears more complex when examined through geochemical data. The use of various discrimination diagrams highlights greater lithological diversity within the studied plutons. Most samples belong to the two-mica granite group, identified in the Abidjan, Bouaké, Dabakala, Ferké, Grand-Lahou, Nassian, and Katiola plutons, consistent with the Casanova and Yobou findings <xref ref-type="bibr" rid="scirp.147686-7">
      [7]
     </xref> <xref ref-type="bibr" rid="scirp.147686-12">
      [12]
     </xref>. However, some samples show distinct compositions. These rocks had previously been described as leucogranites by <xref ref-type="bibr" rid="scirp.147686-4">
      [4]
     </xref> and as (meso)granites with two micas by <xref ref-type="bibr" rid="scirp.147686-12">
      [12]
     </xref>. Similarly, two Dabakala samples (N˚ 72 and 86) correspond to leucogranitic tonalites, although <xref ref-type="bibr" rid="scirp.147686-12">
      [12]
     </xref> classified them as granites with two micas. Finally, sample N˚ 185 from Bouaké, interpreted by Casanova as a leucogranite with two micas, is more accurately a syenite. These comparisons indicate that, depending on the diagram used, some samples may shift between classification fields, while remaining within closely related petrographic categories. Overall, despite these variations, all the studied rocks clearly fall within the broader granitoid suite.</p>
   </sec>
   <sec id="s5_2">
    <title>5.2. Geodynamic Context</title>
    <p>Geochemical data reveal close relationships between the chemical composition of the granites and their geodynamic settings, in the Nb vs. Y diagram (<xref ref-type="fig" rid="fig6(a)">
      Figure 6(a)
     </xref>, the Ferké granites plot within the syn-collisional granite field, whereas the Kowara granites fall in the volcanic-arc granite field. The Rb vs. (Y + Nb) diagram confirms these trends (<xref ref-type="fig" rid="fig6(b)">
      Figure 6(b)
     </xref>: the two-mica granites from Ferké are mainly syn-collisional, while those from Kowara plot in the volcanic-arc field, reflecting subduction-related influences <xref ref-type="bibr" rid="scirp.147686-7">
      [7]
     </xref>. In the R1-R2 diagram <xref ref-type="bibr" rid="scirp.147686-25">
      [25]
     </xref> (<xref ref-type="fig" rid="fig6(c)">
      Figure 6(c)
     </xref>, most Ferké granites lie in the syn-collisional field. The two-mica granites from Abidjan and Bouaké fall into both the late-orogenic and syn-collisional fields, whereas the Grand-Lahou granites are restricted to the late-orogenic field. Finally, the Kowara granites plot along the boundary between the pre-collisional and syn-collisional fields, suggesting emplacement in a transitional setting between active convergence and collisional stages.</p>
    <fig id="fig6" position="float">
     <label>Figure 6</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 6. Tectonic discrimination diagrams for the Côte d’Ivoire two-mica granite suites. (a) Nb vs. Y plot; (b) Rb vs. (Yb + Nb) plot (Pearce et al., 1984); (c) R1 vs. R2 plot (De La Roche et al., 1980), modified by Batchelor and Bowden (1985).</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId18.jpeg?20251128040301" />
    </fig>
   </sec>
   <sec id="s5_3">
    <title>
     <xref ref-type="bibr" rid="scirp.147686-"></xref>5.3. Petrogenesis and Geotectonic Implications</title>
    <p>Geochemical data indicate that the two-mica granites of Côte d’Ivoire are predominantly meta- to strongly peraluminous and show a calc-alkaline to high-K calc-alkaline trend. Based only on geochemical characteristics, clear compositional differences are observed between massifs. The Ferké, Abidjan, and Grand-Lahou massifs display strongly peraluminous signatures, consistent with a crustal affinity <xref ref-type="bibr" rid="scirp.147686-33">
      [33]
     </xref>. The Kowara granites share similar features with Ferké, also suggesting a crustal source. In contrast, the Katiola and Nassian granites are meta-aluminous, pointing to a mantle contribution <xref ref-type="bibr" rid="scirp.147686-33">
      [33]
     </xref>. The Bouaké and Dabakala massifs range from meta- to peraluminous, implying a dual origin that combines both crustal and mantle sources. These results corroborate earlier studies <xref ref-type="bibr" rid="scirp.147686-4">
      [4]
     </xref> <xref ref-type="bibr" rid="scirp.147686-34">
      [34]
     </xref> <xref ref-type="bibr" rid="scirp.147686-35">
      [35]
     </xref>, which emphasized the mixed origin of Ivorian granitoids. However, Doumbia et al. (1998) reported that all the granitoids (Ferké, Kowara, Katiola) exhibit juvenile characteristics, evidenced by mantle-like low initial Sr isotopic compositions (0.700 - 0.702) and positive ε<sub>Nd</sub> values (+1.5 to +2.7). The potassic enrichment of these granites is consistent with advanced magmatic differentiation <xref ref-type="bibr" rid="scirp.147686-3">
      [3]
     </xref>. Gamsonré <xref ref-type="bibr" rid="scirp.147686-36">
      [36]
     </xref>, studying granitoids in Burkina Faso, attributed K enrichment to the progressive destruction of biotite during granitization, releasing potassium that accumulates in more evolved rocks. Rare earth element (REE) patterns and multi-element diagrams reveal negative Eu anomalies in the Ferké granites, reflecting feldspar fractionation. The fractionation of heavy REE further suggests residual garnet and, to a lesser extent, zircon in the source <xref ref-type="bibr" rid="scirp.147686-7">
      [7]
     </xref>. Elevated concentrations of Rb, Ba, Th, and U in the Ferké, Abidjan, Bouaké, Dabakala, Grand-Lahou, and Kowara granitoids cannot be explained solely by magmatic differentiation and likely result from crustal contamination, as highlighted by Sr isotopic composition and positive epsilon Nd values <xref ref-type="bibr" rid="scirp.147686-7">
      [7]
     </xref>. On the Martin tectonic discrimination diagrams <xref ref-type="bibr" rid="scirp.147686-37">
      [37]
     </xref>, Ferké and Kowara leucogranites fall mainly within the Archean granitoid field, with some Kowara samples straddling the Archean-post-Archean boundary (<xref ref-type="fig" rid="fig7(a)">
      Figure 7(a)
     </xref>. Their position indicates that the protoliths of these leucogranites are TTG-type sources. Geotectonically, the two-mica granites of Ferké, Abidjan, Bouaké, Dabakala, and Grand-Lahou are linked to a collisional setting, whereas the granodioritic two-mica granites of Kowara are more consistent with a subduction-related context. The evidence indicates that the granites of Ferké, Abidjan, Bouaké, Dabakala, and Grand-Lahou were formed from magma generated by a collisional event, whereas those from Kowara originated from the fusion of sediments and/or crustal anatexis. This interpretation aligns with broader geodynamic models proposed for Archean cratons <xref ref-type="bibr" rid="scirp.147686-11">
      [11]
     </xref> <xref ref-type="bibr" rid="scirp.147686-37">
      [37]
     </xref>-<xref ref-type="bibr" rid="scirp.147686-39">
      [39]
     </xref>. These models suggest that TTG suites formed through partial melting of undepleted oceanic crust in Archean subduction zones. The REE-depleted signatures of TTG are explained by garnet ± amphibole retention in the melting residue. Interestingly, mechanisms first proposed for Archean crustal evolution may extend into the Paleoproterozoic, as illustrated by the Birimian granitoids of Côte d’Ivoire. Beyond horizontal subduction-related processes, vertical tectonic styles such as sagduction <xref ref-type="bibr" rid="scirp.147686-40">
      [40]
     </xref> may also have influenced the geodynamic evolution of these terranes, adding complexity to their petrogenetic history. The multi-element diagrams of the two-mica granites from Côte d’Ivoire, normalized to the primitive mantle <xref ref-type="bibr" rid="scirp.147686-41">
      [41]
     </xref>, show a close similarity to those of the two-mica granites from Central Bretagne, France <xref ref-type="bibr" rid="scirp.147686-42">
      [42]
     </xref> (<xref ref-type="fig" rid="fig7(b)">
      Figure 7(b)
     </xref>. These features suggest that they may have formed under similar tectonic or magmatic conditions, such as crustal anatexis (partial melting of continental crust) in a collisional or post-collisional setting. This is confirmed by studies conducted by <xref ref-type="bibr" rid="scirp.147686-43">
      [43]
     </xref>, who reveal that the Central Bretagne granite results from the Hercynian orogen formed by the collision of the Sud Gondwana plate, the Laurentia plate, and the Laurasia plate.</p>
    <fig id="fig7" position="float">
     <label>Figure 7</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147686-"></xref>Figure 7. (a) Position of the Ferké and Kowara leucogranites on the (La/Yb) N vs. (Yb) N diagram <xref ref-type="bibr" rid="scirp.147686-37">
        [37]
       </xref>. (b) Comparison spider diagrams of the two-mica granites from Côte d’Ivoire with those from France.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/1211901-rId19.jpeg?20251128040302" />
    </fig>
   </sec>
  </sec><sec id="s6">
   <title>6. Conclusions</title>
   <p>The two-mica granites of the Ivory Coast, prominently represented by the extensive Ferké Batholith, constitute a petrogenetically significant component of the Paleoproterozoic crust within the West African Craton. This integrated petrographic and geochemical study demonstrates that these leucogranites, while sharing a common mineralogical signature, exhibit remarkable geochemical diversity that reveals a complex petrogenetic history. Their high-silica, potassic to shoshonitic, and predominantly peraluminous character, coupled with distinct enrichments in LILE and LREE with negative Nb-Ta-Ti-Eu anomalies, points to a dual origin. This involves both the anatexis of ancient, TTG-like Archean crustal protoliths, producing the strongly peraluminous varieties of Ferké, Abidjan, and Grand-Lahou, and the involvement of mantle-derived magmas with significant crustal assimilation, giving rise to the metaluminous granites of Katiola and Nassian and the hybrid compositions of Bouaké and Dabakala.</p>
   <p>Tectonic discrimination analyses firmly place the emplacement of these granitoids within the dynamic framework of the Eburnean orogeny, transitioning from volcanic-arc settings to syn-collisional environments. This evolution reflects the progressive crustal thickening and convergence that culminated in the stabilization of the craton. The geochemical signatures are not merely a product of fractional crystallization but are profoundly shaped by source composition, partial melting conditions, and interaction with the continental crust.</p>
   <p>In summary, this synthesis underscores that the two-mica granites of Ivory Coast are more than just a widespread lithological unit; they are critical archives of the Paleoproterozoic crustal evolution of the West African Craton. They record the intricate interplay between reworked ancient crust and juvenile mantle additions during a major orogenic cycle. To further refine this petrogenetic model, future research should prioritize high-precision geochronology (e.g., U-Pb on zircon) coupled with detailed isotopic studies (Nd-Sr-Hf) to precisely constrain the timing of magmatism and quantitatively assess the contributions of their diverse source components.</p>
  </sec><sec id="s7">
   <title>Acknowledgements</title>
   <p>This work is partially supported by the Ministry of Higher Education and Scientific Research of Côte d’Ivoire (MESRS).</p>
  </sec><sec id="s8">
   <title>Appendix</title>
   <table-wrap id="table1">
    <label>
     <xref ref-type="table" rid="table1">
      Table 1
     </xref></label>
    <caption>
     <title>
      <xref ref-type="bibr" rid="scirp.147686-"></xref>Table S1. Geochemistry data in Supplementary material.<xref ref-type="bibr" rid="scirp.147686-https://docs.google.com/spreadsheets/d/1HL0il8JIXORstdxj97Kbfr2eSucIgiWg/edit?usp=sharing&amp;ouid=116111865943465123694&amp;rtpof=true&amp;sd=true">
       https://docs.google.com/spreadsheets/d/1HL0il8JIXORstdxj97Kbfr2eSucIgiWg/edit?usp=sharing&amp;ouid=116111865943465123694&amp;rtpof=true&amp;sd=true
      </xref></title>
    </caption>
   </table-wrap>
  </sec>
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