<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article">
 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">
    jmmce
   </journal-id>
   <journal-title-group>
    <journal-title>
     Journal of Minerals and Materials Characterization and Engineering
    </journal-title>
   </journal-title-group>
   <issn pub-type="epub">
    2327-4077
   </issn>
   <issn publication-format="print">
    2327-4085
   </issn>
   <publisher>
    <publisher-name>
     Scientific Research Publishing
    </publisher-name>
   </publisher>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="doi">
    10.4236/jmmce.2025.136021
   </article-id>
   <article-id pub-id-type="publisher-id">
    jmmce-147339
   </article-id>
   <article-categories>
    <subj-group subj-group-type="heading">
     <subject>
      Articles
     </subject>
    </subj-group>
    <subj-group subj-group-type="Discipline-v2">
     <subject>
      Chemistry 
     </subject>
     <subject>
       Materials Science, Engineering
     </subject>
    </subj-group>
   </article-categories>
   <title-group>
    Petrographic and Geochemical Characteristics of the Séguéla Granitoids, Northwestern Côte d’Ivoire
   </title-group>
   <contrib-group>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Brice Roland
      </surname>
      <given-names>
       Kouassi
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff1"> 
      <sup>1</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Brou Koffi
      </surname>
      <given-names>
       Joseph
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff2"> 
      <sup>2</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Kouadio David
      </surname>
      <given-names>
       Koffi
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff2"> 
      <sup>2</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Aissata
      </surname>
      <given-names>
       Ouedraogo
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff2"> 
      <sup>2</sup>
     </xref>
    </contrib>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Alain Nicaise
      </surname>
      <given-names>
       Kouamelan
      </given-names>
     </name> 
     <xref ref-type="aff" rid="aff2"> 
      <sup>2</sup>
     </xref>
    </contrib>
   </contrib-group> 
   <aff id="aff1">
    <addr-line>
     aDépartement de Géosciences, UFR Sciences Biologiques, Université Peleforo Gon Coulibaly, Korhogo, Côte d’Ivoire
    </addr-line> 
   </aff> 
   <aff id="aff2">
    <addr-line>
     aLaboratoire de Géologie, Ressources Minérales et Energétiques, UFR Sciences de la Terre et des Ressources Minières, Université Félix Houphouët-Boigny (UFHB, Abidjan-Cocody), Abidjan, Côte d’Ivoire
    </addr-line> 
   </aff> 
   <pub-date pub-type="epub">
    <day>
     30
    </day> 
    <month>
     10
    </month>
    <year>
     2025
    </year>
   </pub-date> 
   <volume>
    13
   </volume> 
   <issue>
    06
   </issue>
   <fpage>
    381
   </fpage>
   <lpage>
    395
   </lpage>
   <history>
    <date date-type="received">
     <day>
      11,
     </day>
     <month>
      October
     </month>
     <year>
      2025
     </year>
    </date>
    <date date-type="published">
     <day>
      17,
     </day>
     <month>
      October
     </month>
     <year>
      2025
     </year> 
    </date> 
    <date date-type="accepted">
     <day>
      17,
     </day>
     <month>
      November
     </month>
     <year>
      2025
     </year> 
    </date>
   </history>
   <permissions>
    <copyright-statement>
     © Copyright 2014 by authors and Scientific Research Publishing Inc. 
    </copyright-statement>
    <copyright-year>
     2014
    </copyright-year>
    <license>
     <license-p>
      This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/
     </license-p>
    </license>
   </permissions>
   <abstract>
    This paper focuses on the study of granitoids within the large transition zone of the seguela region in northwestern cote d’ivoire. This area is characterized, in its northern part, by the presence of a large porphyroid granitoid massif. Petrographic and geochemical analyses allow us to group the lithological units of the study area into three main facies: 1) granites, 2) granodiorite, and 3) migmatites. The granites have a calc-alkaline affinity and a slightly peraluminous chemistry, whereas the granodiorite and migmatites are generally metaluminous. The migmatites are moderately to strongly calc-alkaline. Similarities in the multi-element and rare-earth element spectra of the different lithologies suggest a common source of emplacement. However, the positive eu anomalies in the granites and the negative anomalies in the granodiorite and migmatites may indicate that the granites derived from the partial melting of a more or less differentiated crustal protolith with plagioclase remaining in the residue. We can therefore consider that the studied granitoids and migmatites were generated in subduction zones. This subduction is consequently responsible for the release of potassium-rich fluids, leading to the formation of pink granites rich in potassium feldspar.
   </abstract>
   <kwd-group> 
    <kwd>
     Granitoids
    </kwd> 
    <kwd>
      Migmatites
    </kwd> 
    <kwd>
      Calc-Alkaline
    </kwd> 
    <kwd>
      Séguéla
    </kwd> 
    <kwd>
      Partial Melting
    </kwd>
   </kwd-group>
  </article-meta>
 </front>
 <body>
  <sec id="s1">
   <title>1. Introduction</title>
   <p>The Séguéla region, which constitutes the study area, is located in the northwestern part of Côte d’Ivoire, West Africa. Côte d’Ivoire, which lies within the West African Craton, is geologically dominated by two major domains: the Archean and the Paleoproterozoic. The study area belongs to the Archean-Proterozoic transition zone, situated to the east of the Archean Domain and the Sassandra Fault, and along the western margin of the Paleoproterozoic Domain (<xref ref-type="fig" rid="fig1">
     Figure 1
    </xref>). The various lithologies observed in the area include tonalitic gneisses, migmatites, volcano-plutonic belts, granitoid plutons of diverse composition, and metasedimentary rocks intruded by plutons <xref ref-type="bibr" rid="scirp.147339-1">
     [1]
    </xref>. Previous works <xref ref-type="bibr" rid="scirp.147339-2">
     [2]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-5">
     [5]
    </xref> have shown that this western part of the Archean domain in Côte d’Ivoire is composed of gray tonalitic and trondhjemitic gneisses, charnockites, greenstone rocks metamorphosed under granulite facies, magnetite-bearing banded quartzites, and biotite migmatites. These formations are intruded by pink granites and basic-ultrabasic complexes. This entire assemblage has been attributed to the Leonian (3.5 - 2.9 Ga) and Liberian (2.9 - 2.6 Ga) orogenic cycles by earlier authors <xref ref-type="bibr" rid="scirp.147339-6">
     [6]
    </xref>.</p>
   <p>In Côte d’Ivoire, the crustal evolution experienced three major Precambrian orogenies: the Liberian, Leonian, and Eburnean. The resulting basement, older than 1.6 Ga, occupies almost the entire territory except for the extreme south, which is covered by the coastal basin <xref ref-type="bibr" rid="scirp.147339-7">
     [7]
    </xref>. The granitoids make up the majority of the outcrops of this Precambrian basement and are highly diverse, thus representing significant geological components of the country <xref ref-type="bibr" rid="scirp.147339-8">
     [8]
    </xref>. The granitoids of Côte d’Ivoire have been the subject of numerous lithostratigraphic and geochemical studies aimed at understanding their genesis <xref ref-type="bibr" rid="scirp.147339-9">
     [9]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-14">
     [14]
    </xref>. Following in the footsteps of these earlier works, we have focused particular attention on the granitoids of the Séguéla region, which is known as a diamond-bearing zone. It is therefore necessary to undertake petrographic and geochemical studies to contribute to a better understanding of these rocks in this region.</p>
  </sec><sec id="s2">
   <title>
    <xref ref-type="bibr" rid="scirp.147339-"></xref>2. Geological Setting</title>
   <p>
    <xref ref-type="bibr" rid="scirp.147339-"></xref>Geologically, Côte d’Ivoire forms part of the West African Craton, more specifically within the Man-Leo Shield <xref ref-type="bibr" rid="scirp.147339-6">
     [6]
    </xref>. The country is predominantly underlain by a Precambrian basement (97.5%) and a younger sedimentary cover (2.5%). This basement, which includes the study area, is subdivided into two major domains: the Kenema-Man Domain to the west and the Baoulé-Mossi Domain to the east, separated by the major transcurrent Sassandra Fault. Previous studies <xref ref-type="bibr" rid="scirp.147339-2">
     [2]
    </xref> <xref ref-type="bibr" rid="scirp.147339-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147339-15">
     [15]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-17">
     [17]
    </xref> have shown that the Kenema-Man Domain is largely composed of Archean terrains made up of a granito-gneissic basement complex and supracrustal greenstone belts. These rocks were successively affected by the Leonian orogeny (3.4 - 3.0 Ga) <xref ref-type="bibr" rid="scirp.147339-18">
     [18]
    </xref> <xref ref-type="bibr" rid="scirp.147339-19">
     [19]
    </xref> and the Liberian orogeny (2.9 - 2.7 Ga) <xref ref-type="bibr" rid="scirp.147339-2">
     [2]
    </xref> <xref ref-type="bibr" rid="scirp.147339-18">
     [18]
    </xref>, and were later overprinted by the Eburnean orogeny <xref ref-type="bibr" rid="scirp.147339-20">
     [20]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-22">
     [22]
    </xref>. In contrast, the Baoulé-Mossi Domain to the east is mainly composed of Paleoproterozoic formations deformed and metamorphosed during the Eburnean event <xref ref-type="bibr" rid="scirp.147339-20">
     [20]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-23">
     [23]
    </xref>. The lithologies of the Kenema-Man Domain are predominantly TTG-type (tonalite-trondhjemite-granodiorite) suites, associated with kinzigitic metasediments, magnetite-bearing quartzites, and granulitic metabasalts <xref ref-type="bibr" rid="scirp.147339-2">
     [2]
    </xref> <xref ref-type="bibr" rid="scirp.147339-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147339-15">
     [15]
    </xref> <xref ref-type="bibr" rid="scirp.147339-21">
     [21]
    </xref> <xref ref-type="bibr" rid="scirp.147339-24">
     [24]
    </xref>. Between the Archean and Paleoproterozoic domains sensu stricto lies a transition zone, bounded by the Sassandra Fault to the west and approximately longitude 6˚W to the east. This zone exhibits clear Archean inheritance, marked by crustal relics dated at about 3.2 Ga in the southern part of the SASCA Domain <xref ref-type="bibr" rid="scirp.147339-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147339-25">
     [25]
    </xref> <xref ref-type="bibr" rid="scirp.147339-26">
     [26]
    </xref>.</p>
   <p>Located in the west-central part of Côte d’Ivoire, the Séguéla region belongs to this Archean-Proterozoic transition zone, lying east of the Archean Domain and the Sassandra Fault, and along the western margin of the Paleoproterozoic Domain (<xref ref-type="fig" rid="fig1(A)">
     Figure 1(A)
    </xref>). The region is well known for its diamondiferous field, fed by kimberlite and lamproite dykes (<xref ref-type="fig" rid="fig1(A)">
     Figure 1(A)
    </xref>). These dykes intrude granite plutons separated by amphibolite panels belonging to the Birimian formations. The granites are monzonitic, containing biotite and hornblende, and display well-differentiated pegmatitic and aplitic cupolas, as well as porphyroid margins <xref ref-type="bibr" rid="scirp.147339-1">
     [1]
    </xref> (<xref ref-type="fig" rid="fig1(B)">
     Figure 1(B)
    </xref>). Their N170˚ orientation is structurally controlled by the contact between the Archean and Paleoproterozoic lithospheres of the West African Craton.</p>
   <fig id="fig1" position="float">
    <label>Figure 1</label>
    <caption>
     <title>
      <xref ref-type="bibr" rid="scirp.147339-"></xref>Figure 1. Geological map of Côte d’Ivoire and the study area. A-Simplified geological map of Côte d’Ivoire (modified after <xref ref-type="bibr" rid="scirp.147339-27">
       [27]
      </xref>). B-Geological map of the Séguéla region (published by the Directorate of Mines and Geology) showing the sampling locations.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/2711145-rId13.jpeg?20251120102127" />
   </fig>
  </sec><sec id="s3">
   <title>3. Analytical Method</title>
   <sec id="s3_1">
    <title>3.1. Sample Collection and Optical Petrography</title>
    <p>The studied samples belong to the granitoids of the Séguéla region (<xref ref-type="fig" rid="fig1(B)">
      Figure 1(B)
     </xref>). In the field, the various lithologies were first described macroscopically before sampling for more detailed analyses, including microscopic observations and whole-rock geochemical analyses. Accordingly, nine (09) thin sections were prepared from fresh samples for petrographic examination under a polarizing microscope at the Laboratory of Geology and Mineral Resources, Department of Earth and Mineral Resources Sciences, Félix Houphouët-Boigny University, Cocody.</p>
   </sec>
   <sec id="s3_2">
    <title>3.2. Bulk Whole-Rock Analysis</title>
    <p>
     <xref ref-type="bibr" rid="scirp.147339-"></xref>The aim of the geochemical study is to investigate the geochemical characteristics of the rocks in order to understand the distribution of chemical elements within these different lithologies, as well as the factors and processes controlling this distribution. To this end, the study focused on major and trace elements in six rock samples (<xref ref-type="table" rid="table1">
      Table 1
     </xref>). This approach allows for the identification of potential genetic relationships between the rocks, determination of the magmatic source(s), and reconstruction of the geodynamic environment of emplacement using diagrams derived from major and trace element data. Specifically, the study relies on the elemental abundances, and using specialized diagrams, it evaluates the distribution of these elements among the different rock types. The chemical analyses of the rock samples collected from the study area were performed by determining major elements using X-ray fluorescence (XRF) on whole-rock powders, and trace elements using inductively coupled plasma mass spectrometry (ICP-MS). The six (6) samples selected, were reduced by cone-and-quartering to obtain a ~ 50 g subsam ple, which was then pulverized in an agate-lined puck-and ring vibratory mill to &lt; 50 μm. Final powders were sent for whole rock analysis to Bureau Veritas in Vancouver (Can ada), where forty-eight elements were analyzed (LF600 (LF100-EXT + XF700 + TC000) package) including. A detailed description of this analytical technique is provided in <xref ref-type="bibr" rid="scirp.147339-28">
      [28]
     </xref>.</p>
   </sec>
  </sec><sec id="s4">
   <title>4. Results</title>
   <sec id="s4_1">
    <title>4.1. Petrographic Data</title>
    <p>In this study, the collected rocks can be grouped into two main lithological sets: granitoids sensu stricto and migmatites (migmatized granitoids or anatexites).</p>
    <p>Pink Granite (SEG03)</p>
    <p>The pink granites observed in the study area were located along the Dyakala-Békoro axis (<xref ref-type="fig" rid="fig2(A)">
      Figure 2(A)
     </xref>). They are massive and generally coarse-grained. At outcrop scale, they consist of quartz, feldspars, and biotite. Under the microscope (<xref ref-type="fig" rid="fig2(B)">
      Figure 2(B)
     </xref>), the rock displays a porphyroblastic coarse-grained texture and is composed of the following major minerals: quartz, the most abundant mineral, with medium-sized grains often showing undulatory extinction; orthoclase occurring as medium-sized crystals; microcline, less abundant than orthoclase, generally large-grained; plagioclase, less abundant, strongly altered to sericite; and biotite, a minor mineral, brownish to greenish in color, medium-sized, and undergoing chloritization.</p>
    <p>Biotite Granite (SEG05)</p>
    <p>This rock was observed along the Békoro-Séguéla and Séguéla-Samadougou axes. It exhibits a coarse-grained texture. At outcrop, it is composed of quartz, plagioclase, and biotite. Microscopically (<xref ref-type="fig" rid="fig2(C)">
      Figure 2(C)
     </xref>), the rock consists of: abundant quartz of variable grain size with pronounced undulatory extinction; highly sericitized plagioclase; less abundant microcline, occasionally containing altered plagioclase crystals; and biotite of variable size, automorphic, with myrmekitic textures characterized by fine quartz vermicules within alkali feldspar crystals.</p>
    <p>Granodiorite (SEG07)</p>
    <p>
     <xref ref-type="bibr" rid="scirp.147339-"></xref>Observed along the Somadougou-Mamouroula axis (<xref ref-type="fig" rid="fig2(D)">
      Figure 2(D)
     </xref>), the granodiorite is massive, mesocratic, and coarse-grained. At outcrop, it consists of quartz, plagioclase, amphibole, and biotite. Microscopically (<xref ref-type="fig" rid="fig2(E)">
      Figure 2(E)
     </xref> and <xref ref-type="fig" rid="fig2(F)">
      Figure 2(F)
     </xref>), the rock comprises: abundant microcline with large- to medium-sized crystals; medium-grained quartz; automorphic brown biotite; and minor pyroxene, automorphic, showing myrmekitic textures.</p>
    <p>Biotite Migmatite (SEG08)</p>
    <p>Observed along the Suala-Kavéna axis (<xref ref-type="fig" rid="fig2(G)">
      Figure 2(G)
     </xref>), this rock has a coarse-grained texture and consists of quartz, feldspars, and biotite at the outcrop scale. Microscopically, it shows a porphyroblastic coarse-grained texture and is composed of: quartz, the most abundant, anhedral, with undulatory extinction; microcline, also abundant, generally large, sometimes strongly altered to sericite, with grid-like twinning; biotite, automorphic, brownish to greenish, variable in size; and minor myrmekite, consisting of fine vermicules of quartz and plagioclase, which is less abundant and anhedral to subhedral.</p>
    <p>Biotite-Amphibole Migmatite (SEG02)</p>
    <p>Observed along the Békoro-Séguéla axis, this rock shows an outcrop foliation of N50˚ - 60˚ NW and a left-lateral shear along N110˚. It exhibits a coarse-grained texture and is composed mainly of quartz, feldspars, and biotite. Microscopically (<xref ref-type="fig" rid="fig2(I)">
      Figure 2(I)
     </xref>), it contains: abundant anhedral quartz with undulatory extinction; microcline, less abundant than quartz, generally large, with grid-like twinning; minor subhedral amphibole with two basal cleavages intersecting at ~120˚; biotite, often included in amphiboles, greenish in color; minor pyroxene, anhedral to subhedral; and garnet, automorphic, less abundant, included in pyroxene.</p>
    <p>Biotite-Amphibole-Pyroxene Migmatite (SEG09)</p>
    <p>Located along the Kavéna-Séguéla and Séguéla-Nyanangoro axes, this rock shows a left-lateral shear at N30˚ at outcrop. It has a porphyroblastic coarse-grained texture and consists of quartz, feldspars, and biotite. Microscopically (<xref ref-type="fig" rid="fig2(H)">
      Figure 2(H)
     </xref>), it comprises: abundant anhedral quartz with pronounced undulatory extinction; less abundant large-grained microcline with grid-like twinning; biotite as automorphic to subautomorphic phenocrysts, brown to greenish; minor myrmekite, occurring as fins quartz vermicules; minor pyroxene, anhedral to subhedral; and titanite, pale yellow in color.</p>
    <fig id="fig2" position="float">
     <label>Figure 2</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147339-"></xref>Figure 2. Macroscopic and microscopic features of granitoids and migmatites from the study area. A and B—Macrophotograph and microphotograph of pink granite (SEG03), respectively. C—Microphotograph of biotite granite. D—Photograph of granodiorite (SEG07). E-F—Microphotographs of granodiorite (SEG07). G—Photograph of biotite migmatite. H—Microphotograph of biotite-amphibole-pyroxene migmatite. I—Microphotograph of biotite-amphibole migmatite. Mineral abbreviations: Bt: biotite; Or: orthoclase; Mi: microcline; Amp: amphibole; Pyr: pyroxene; Qz: quartz; Pl: Plagioclase; Chl: Chlorite.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/2711145-rId14.jpeg?20251120102129" />
    </fig>
   </sec>
   <sec id="s4_2">
    <title>4.2. Geochemistry of the Séguéla Granitoids</title>
    <p>To characterize the granitoids, the chemical compositions of the collected samples were plotted on various rock classification diagrams. In the normative Q’/ANOR diagram of <xref ref-type="bibr" rid="scirp.147339-29">
      [29]
     </xref> (<xref ref-type="fig" rid="fig3(A)">
      Figure 3(A)
     </xref>), the Séguéla granitoids show trends from monzogranitic (SEG2, SEG3, SEG5, and SEG8) to granodioritic compositions (SEG7 and SEG9).</p>
    <p>Granites</p>
    <p>
     <xref ref-type="bibr" rid="scirp.147339-"></xref>These rocks are characterized by high contents of SiO<sub>2</sub> (70.6% - 73.1%), Al<sub>2</sub>O<sub>3</sub> (13.9% - 14.8%), and K<sub>2</sub>O (3.93% - 4.44%), and low contents of Fe<sub>2</sub>O<sub>3</sub> (1.85% - 2.37%), MgO (0.43% - 0.52%), TiO<sub>2</sub> (0.23% - 0.24%), and CaO (1.63% - 2.21%) (<xref ref-type="table" rid="table1">
      Table 1
     </xref>). In the diagram of <xref ref-type="bibr" rid="scirp.147339-30">
      [30]
     </xref> (<xref ref-type="fig" rid="fig3(B)">
      Figure 3(B)
     </xref>), these granites display a slightly peraluminous and strongly calc-alkaline character, as confirmed by the K<sub>2</sub>O vs. SiO<sub>2</sub> binary diagram of <xref ref-type="bibr" rid="scirp.147339-31">
      [31]
     </xref> (<xref ref-type="fig" rid="fig3(C)">
      Figure 3(C)
     </xref>).</p>
    <p>Granodiorites</p>
    <p>
     <xref ref-type="bibr" rid="scirp.147339-"></xref>This rock type is characterized by SiO<sub>2</sub> = 65.6%, Al<sub>2</sub>O<sub>3</sub> = 15.2%, MgO = 2.08%, Fe<sub>2</sub>O<sub>3</sub> = 4.92%, CaO = 3.54%, and TiO<sub>2</sub> = 0.6%. The diagram of <xref ref-type="bibr" rid="scirp.147339-30">
      [30]
     </xref> indicates that it is metaluminous (<xref ref-type="fig" rid="fig3(B)">
      Figure 3(B)
     </xref>) and calc-alkaline, as shown in the K<sub>2</sub>O vs. SiO<sub>2</sub> diagram of <xref ref-type="bibr" rid="scirp.147339-31">
      [31]
     </xref> (<xref ref-type="fig" rid="fig3(C)">
      Figure 3(C)
     </xref>).</p>
    <p>Migmatites</p>
    <p>
     <xref ref-type="bibr" rid="scirp.147339-"></xref>These rocks display SiO<sub>2</sub> contents ranging from 64.8% to 71.2%, MgO from 0.65% to 2.4%, Fe<sub>2</sub>O<sub>3</sub> from 2.32% to 6.66%, Al<sub>2</sub>O<sub>3</sub> from 14.4% to 14.6%, and CaO from 1.74% to 3.64%. Na<sub>2</sub>O and K<sub>2</sub>O vary from 3.76% to 4.22% and 1.9% to 5.16%, respectively, while TiO<sub>2</sub> ranges from 0.27% to 0.65%. Migmatites are generally metaluminous to slightly peraluminous (<xref ref-type="fig" rid="fig3(B)">
      Figure 3(B)
     </xref>). In the K<sub>2</sub>O vs. SiO<sub>2</sub> diagram of <xref ref-type="bibr" rid="scirp.147339-31">
      [31]
     </xref>, the migmatites plot within the shoshonitic and calc-alkaline fields (<xref ref-type="fig" rid="fig3(C)">
      Figure 3(C)
     </xref>).</p>
    <p>The projection of the different granitoids (granites, granodiorites, and migmatites) from the study area onto Harker-type diagrams <xref ref-type="bibr" rid="scirp.147339-32">
      [32]
     </xref> (<xref ref-type="fig" rid="fig4">
      Figure 4
     </xref>) shows a linear distribution, with a negative correlation between SiO<sub>2</sub> and most other oxides (Al<sub>2</sub>O<sub>3</sub>, Fe<sub>2</sub>O<sub>3</sub>, CaO, MgO, MnO, Na<sub>2</sub>O, and TiO<sub>2</sub>), except for K<sub>2</sub>O, which exhibits a positive correlation.</p>
    <table-wrap id="table1">
     <label>
      <xref ref-type="table" rid="table1">
       Table 1
      </xref></label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147339-"></xref>Table 1. Major and trace element composition of granitoids and migmatites from the Séguéla region.</title>
     </caption>
     <table class="MsoTableGrid custom-table" border="0" cellspacing="0" cellpadding="0"> 
      <tr> 
       <td class="custom-bottom-td acenter" width="32.82%"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td acenter" width="19.96%" colspan="2"><p style="text-align:center">Granites</p></td> 
       <td class="custom-bottom-td acenter" width="17.29%"><p style="text-align:center">Granodiorite</p></td> 
       <td class="custom-bottom-td acenter" width="29.94%" colspan="3"><p style="text-align:center">Migmatites</p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td custom-top-td acenter" width="32.82%"><p style="text-align:center">Samples</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="9.98%"><p style="text-align:center">SEG03</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="9.98%"><p style="text-align:center">SEG05</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="17.29%"><p style="text-align:center">SEG07</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="9.98%"><p style="text-align:center">SEG08</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="9.98%"><p style="text-align:center">SEG09</p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="9.98%"><p style="text-align:center">SEG02</p></td> 
      </tr> 
      <tr> 
       <td class="custom-top-td acenter" width="32.82%"><p style="text-align:center">wt%</p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="17.29%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">SiO<sub>2</sub></p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">73.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">70.6</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">65.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">71.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">64.8</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">70.4</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Al<sub>2</sub>O<sub>3</sub></p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">13.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">14.8</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">15.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">14.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">14.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">14.6</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Fe<sub>2</sub>O<sub>3</sub></p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.85</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.37</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">4.92</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.53</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6.66</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.32</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">CaO</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.63</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.21</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">3.54</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.77</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.64</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.74</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">MgO</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.43</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.52</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">2.08</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.65</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.69</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Na<sub>2</sub>O</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.59</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.9</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">4.39</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.84</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.22</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.76</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">K<sub>2</sub>O</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.44</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.93</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">2.53</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.18</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.16</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">MnO</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.02</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.02</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.08</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.04</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.09</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.05</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">TiO<sub>2</sub></p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.24</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.23</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.34</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.65</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.27</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">P<sub>2</sub>O<sub>5</sub></p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.07</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.12</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.23</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.13</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.14</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.09</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">LOI</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.18</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">−0.06</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.16</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.25</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">−0.04</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">SUM</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">99.45</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">98.64</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">99.33</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">99.28</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">99.25</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">99.04</p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td acenter" width="32.82%"><p style="text-align:center">A/CNK</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">1.02</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">1.01</p></td> 
       <td class="custom-bottom-td acenter" width="17.29%"><p style="text-align:center">0.93</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">1.02</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">0.93</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">0.98</p></td> 
      </tr> 
      <tr> 
       <td class="custom-top-td acenter" width="32.82%"><p style="text-align:center">Trace elements</p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="17.29%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Ba</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1433</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1512</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">940</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1168</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">426</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1260</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Co</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.3</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">18.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.4</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Cs</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.7</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">1.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.3</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Hf</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6.7</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">4.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.8</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.1</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Nb</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.3</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">14.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">15.4</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Rb</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">130.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">98.8</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">82.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">158.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">132.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">187.3</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Sn</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">&lt;1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">&lt;1</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Sr</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">462.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">569.1</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">546.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">428.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">416.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">406.5</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Ta</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.4</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.8</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Th</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">14</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">8.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">15.8</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">9.7</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">U</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.9</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.9</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Zr</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">141.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">255.9</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">172.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">212.8</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">189.1</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">118.3</p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td acenter" width="32.82%"><p style="text-align:center">Y</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">3.6</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">5.5</p></td> 
       <td class="custom-bottom-td acenter" width="17.29%"><p style="text-align:center">31.4</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">9.7</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">16</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">21.6</p></td> 
      </tr> 
      <tr> 
       <td class="custom-top-td acenter" width="32.82%"><p style="text-align:center">Rare earth elements (REE)</p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="17.29%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">La</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">29.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">43.1</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">57.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">60.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">34.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">33.9</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Ce</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">54</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">82.3</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">97.2</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">119.5</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">66.6</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">68.6</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Pr</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.28</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.9</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">12.04</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">11.96</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.51</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">7.82</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Nd</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">16.7</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">25.4</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">46</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">41.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">28.4</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">29.8</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Sm</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.86</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.24</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">8.65</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.72</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.84</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Eu</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.03</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.92</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">1.65</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.23</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.21</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.02</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Gd</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.13</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">7.31</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.49</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.05</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">5.18</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Tb</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.15</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.28</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">1.12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.38</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.56</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.81</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Dy</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.71</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.24</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">5.83</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.88</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.45</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Ho</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.11</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.21</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">1.13</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.61</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.79</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Er</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.35</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.51</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">3.12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.9</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.68</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.15</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Tm</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.05</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.08</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.41</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.27</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.29</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Yb</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.37</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.48</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">2.33</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.82</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.69</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.75</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Lu</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.06</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.06</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.3</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.12</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.27</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.2</p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td acenter" width="32.82%"><p style="text-align:center">R</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">111.47</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">167.85</p></td> 
       <td class="custom-bottom-td acenter" width="17.29%"><p style="text-align:center">244.79</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">248.22</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">155.21</p></td> 
       <td class="custom-bottom-td acenter" width="9.98%"><p style="text-align:center">162.76</p></td> 
      </tr> 
      <tr> 
       <td class="custom-top-td acenter" width="32.82%"><p style="text-align:center">Calculate elements ratios</p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="17.29%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="9.98%"><p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">LaN/YbN</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">52.65</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">59.29</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">16.35</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">48.72</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">13.44</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">12.79</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">LaN/SmN</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">9.67</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">8.11</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">4.07</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">6.45</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">4.33</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.44</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">GdN/YbN</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.82</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.56</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">2.52</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">3.42</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.92</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.38</p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.82%"><p style="text-align:center">Eu/Eu*</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">2.046</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">1.082</p></td> 
       <td class="acenter" width="17.29%"><p style="text-align:center">0.641</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.85</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.844</p></td> 
       <td class="acenter" width="9.98%"><p style="text-align:center">0.565</p></td> 
      </tr> 
     </table>
    </table-wrap>
    <fig id="fig3" position="float">
     <label>Figure 3</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147339-"></xref>Figure 3. Positions of granitoids and migmatites in various rock classification, nomenclature, and differentiation diagrams. A—Normative Q’/ANOR diagram <xref ref-type="bibr" rid="scirp.147339-29">
        [29]
       </xref>. B—A/NK vs. A/CNK diagram <xref ref-type="bibr" rid="scirp.147339-30">
        [30]
       </xref>. C—Binary K<sub>2</sub>O vs. SiO<sub>2</sub> diagram <xref ref-type="bibr" rid="scirp.147339-31">
        [31]
       </xref>. D—Primitive mantle-normalized multi-element diagram <xref ref-type="bibr" rid="scirp.147339-33">
        [33]
       </xref>. E—Chondrite-normalized REE spectra <xref ref-type="bibr" rid="scirp.147339-34">
        [34]
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/2711145-rId15.jpeg?20251120102130" />
    </fig>
    <fig id="fig4" position="float">
     <label>Figure 4</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.147339-"></xref>Figure 4. Granitoids and migmatites from the study area plotted on oxide vs. SiO<sub>2</sub> Harker-type diagrams <xref ref-type="bibr" rid="scirp.147339-32">
        [32]
       </xref>. Legend as in <xref ref-type="fig" rid="fig3(A)">
        Figure 3(A)
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/2711145-rId16.jpeg?20251120102130" />
    </fig>
    <p>The granites, granodiorites, and migmatites exhibit variable trace element contents. Notably, elements such as Ba, Rb, Sr, and Zr show relatively high concentrations. Among these, the granites display the highest Ba contents (1433 - 1512 ppm) compared to the granodiorites and migmatites (<xref ref-type="table" rid="table1">
      Table 1
     </xref>).</p>
    <p>In the primitive mantle-normalized multi-element diagram of <xref ref-type="bibr" rid="scirp.147339-33">
      [33]
     </xref> (<xref ref-type="fig" rid="fig3(D)">
      Figure 3(D)
     </xref>), the spectra overall show enrichment in Rb and K, and to a lesser extent in Ba, for both granites and granodiorites. A depletion in Nb, Ta, Sr, Cs, P, and Ti is observed in all rock types. Additionally, a moderate to slight enrichment in Hf and Zr is noted. All rocks display a negative U anomaly, except for the migmatite SEG9, which exhibits a pronounced enrichment.</p>
    <p>The total REE (ΣREE) contents of the granites are generally high, ranging from 111.47 to 167.85 ppm. The granites show negative slopes, reflecting a fractionation ratio (La/Yb)<sub>N</sub> of 52.65 - 59.29. When normalized to chondrites <xref ref-type="bibr" rid="scirp.147339-34">
      [34]
     </xref>, the spectra indicate LREE enrichment with (La/Sm)<sub>N</sub> ratios of 8.11 - 9.66, and HREE depletion with (Gd/Yb)<sub>N</sub> ratios of 2.52 - 3.56. These rocks also exhibit positive Eu anomalies, except for sample SEG03 (<xref ref-type="fig" rid="fig3(E)">
      Figure 3(E)
     </xref>), with Eu/Eu ratios* of 1.08 - 2.04.</p>
    <p>The granodiorite has a high ΣREE (244.79 ppm) and shows a negative slope with a (La/Yb)<sub>N</sub> of 16.35, indicating significant LREE enrichment ((La/Sm)<sub>N</sub> = 4.07) and HREE depletion. It exhibits a pronounced negative Eu anomaly (Eu/Eu* = 0.64) (<xref ref-type="fig" rid="fig3(E)">
      Figure 3(E)
     </xref>).</p>
    <p>The migmatites have ΣREE values ranging from 155.21 to 248.22 ppm, with negative slopes and (La/Yb)<sub>N</sub> ratios between 12.79 and 48.71, reflecting LREE enrichment ((La/Sm)<sub>N</sub> = 3.44 − 6.44) and HREE depletion ((Gd/Yb)<sub>N</sub> = 1.92 − 3.41). They also display strong negative Eu anomalies (Eu/Eu* = 0.56 − 0.85) and a slight tendency toward negative Ce anomalies (Ce/Ce* = 0.97 − 1.04) (<xref ref-type="fig" rid="fig3(E)">
      Figure 3(E)
     </xref>).</p>
   </sec>
  </sec><sec id="s5">
   <title>5. Discussion</title>
   <p>The study area is located in the central part of the Archean-Proterozoic transition zone defined by <xref ref-type="bibr" rid="scirp.147339-4">
     [4]
    </xref> <xref ref-type="bibr" rid="scirp.147339-26">
     [26]
    </xref>, where Archean relics have been identified within the juvenile Birimian formations. The kimberlitic dykes of the Séguéla region crosscut two granite plutons separated by small amphibolite panels belonging to the Paleoproterozoic Birimian formations of the West African Craton. These are biotite- and hornblende-bearing monzonitic granites, exhibiting differentiated pegmatitic and aplitic cupolas as well as porphyroid margins <xref ref-type="bibr" rid="scirp.147339-1">
     [1]
    </xref>. They have been Pb/Pb dated at 3132 ± 9 Ma to 3141 ± 2 Ma <xref ref-type="bibr" rid="scirp.147339-4">
     [4]
    </xref>. The kimberlitic structures do not crop out naturally, as they are covered by several meters of colluvium. The granitoids belong to the granito-gneissic complexes of the Séguéla region. Our study confirms the presence of granites, granodiorites, and migmatites. Petrographically, these rocks are dominated by quartz and feldspars, with microcline more abundant than plagioclase, which is often sericitized and occurs as myrmekite. This mineral is considered metasomatic, associated with tectonic activity <xref ref-type="bibr" rid="scirp.147339-35">
     [35]
    </xref>.</p>
   <p>Metasomatism has been suggested <xref ref-type="bibr" rid="scirp.147339-11">
     [11]
    </xref> as responsible for microclination of feldspars in Eburnean granitoids, resulting in increased potassium content. This phenomenon is also observed in Archean formations and can be attributed to varying degrees of crustal recycling within the West African Craton during the Eburnean <xref ref-type="bibr" rid="scirp.147339-17">
     [17]
    </xref> <xref ref-type="bibr" rid="scirp.147339-25">
     [25]
    </xref> <xref ref-type="bibr" rid="scirp.147339-36">
     [36]
    </xref>-<xref ref-type="bibr" rid="scirp.147339-38">
     [38]
    </xref>. The migmatitic nature of the studied granitoids suggests a crustal anatectic origin, supported by field observations of magmatic banding, reflecting segregation between granite neosome and granodiorite paleosome <xref ref-type="bibr" rid="scirp.147339-39">
     [39]
    </xref>.</p>
   <p>Geochemically, the Séguéla granitoids exhibit a metaluminous to slightly peraluminous character and a calc-alkaline to shoshonitic trend, marked by K<sub>2</sub>O enrichment. This potassium enrichment is accompanied by an increase in SiO<sub>2</sub>, as shown in the Harker diagrams <xref ref-type="bibr" rid="scirp.147339-32">
     [32]
    </xref> (<xref ref-type="fig" rid="fig4">
     Figure 4
    </xref>). According to <xref ref-type="bibr" rid="scirp.147339-40">
     [40]
    </xref>, peraluminous characteristics indicate a crustal affinity, whereas metaluminous signatures suggest a mantle contribution, implying a dual origin for the Séguéla granitoids. This aligns with previous studies <xref ref-type="bibr" rid="scirp.147339-13">
     [13]
    </xref> <xref ref-type="bibr" rid="scirp.147339-41">
     [41]
    </xref> reporting dual origins for Ivorian granitoids. According to <xref ref-type="bibr" rid="scirp.147339-42">
     [42]
    </xref> <xref ref-type="bibr" rid="scirp.147339-43">
     [43]
    </xref>, A/CNK ratios between 1 and 1.1 correspond to granitoid generations of I- and S-type, indicating a possible mixture of metaluminous magmas with more differentiated crustal assimilation. The opposite trends observed in the Harker binary diagrams of Al<sub>2</sub>O<sub>3</sub>/SiO<sub>2</sub> and K<sub>2</sub>O/SiO<sub>2</sub>, as well as the negative Sr and Eu anomalies and positive Eu anomalies in the granites, reflect the mixing of two chemically distinct sources or magmatic assimilation. The similar patterns of multi-element and rare earth element (REE) spectra for the granitoids and migmatites may suggest a common origin for the formation of these rocks.</p>
   <p>The potassic nature of these granitoids can also be explained by rock evolution: more differentiated rocks tend to be richer in potassium <xref ref-type="bibr" rid="scirp.147339-10">
     [10]
    </xref>. However, potassium and biotite enrichment may also reflect crustal metasomatism. For instance, <xref ref-type="bibr" rid="scirp.147339-44">
     [44]
    </xref> studying Ouahigouya granitoids (Burkina Faso) attributes high potassium to the progressive breakdown of ferromagnesian minerals, particularly biotite, which releases potassium into the evolving rock.</p>
   <p>
    <xref ref-type="bibr" rid="scirp.147339-"></xref>The similarities in REE and multi-element patterns among granites, granodiorites, and migmatites suggest a common magmatic source. Positive Eu anomalies in granites versus negative anomalies in granodiorites and migmatites indicate that granites likely formed by partial melting of a moderately differentiated crustal protolith, and enriched in residual plagioclase. Overall, the granitoids and migmatites were likely generated in subduction-related zones, akin to Archean TTGs <xref ref-type="bibr" rid="scirp.147339-45">
     [45]
    </xref>. Subduction-induced fluid release facilitated the formation of K-rich pink granites.</p>
  </sec><sec id="s6">
   <title>6. Conclusions</title>
   <p>This study provides a petrographic and geochemical characterization of the Séguéla granitoids.</p>
   <p>Petrographically, the rocks are predominantly quartz-feldspar, with main ferromagnesians being green-brown biotite and green hornblende. The dominance of microcline likely reflects metasomatism linked to Eburnean tectonics, affecting much of the West African Craton.</p>
   <p>
    <xref ref-type="bibr" rid="scirp.147339-"></xref>Geochemically, the analyzed rocks define a calc-alkaline to slightly shoshonitic chemistry for migmatites. Both granitoids and migmatites are metaluminous to peraluminous, with strong LILE enrichment (Cs, Ba, Rb, K) and pronounced Nb-Ta depletion, indicating a subduction-related environment (or remelting of a subduction-derived source). The REE patterns are consistent with this geodynamic setting, resembling Archean TTGs, suggesting formation through subduction-related melting of mafic and ultramafic rocks transformed into eclogite, followed by crustal recycling. Indeed, these rocks exhibit high (La/Yb)<sub>N</sub> fractionation rates ranging from 12.79 to 59.29 and heavy rare earth element (HREE) depletion with (Gd/Yb)<sub>N</sub> ratios ranging from 1.92 to 3.56.</p>
   <p>Future work should include geochronological studies (trace elements and isotopes) to determine the ages of these granitoids and migmatites, identify their protoliths, and perform structural analyses to evaluate the tectonic relationships within the study area and better define their Archean character.</p>
  </sec><sec id="s7">
   <title>Acknowledgements</title>
   <p>I would like to express my sincere gratitude to PASRES (Strategic Support Program for Scientific Research) and to the T2GEM project (Geophysical and Geochemical Technologies for Mining Exploration) for funding this research.</p>
  </sec>
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