The Hula Valley and Lake Kinneret are located in the northern part of Israel’s Syrian-African Great Rift Valley. Lake Kinneret is the only natural freshwater lake in Israel and its water quality including the cardinal impact of nutrient migrations from the Hula Valley is therefore a national concern. The total annual national water supply is 2.11 bcm (10⁹ m³), of which 0.55 bcm is sourced from the Kinneret-Jordan water system. The area of the Kinneret drainage basin is 2730 km² and is located mostly to the north of the lake, of which the total Hula Valley is about 200 km². Three major headwater rivers, The Hatzbani, Banyas, and Dan originate from the Hermon Mountain region and flow into the northern part of the Kinneret drainage basin. These rivers converge to form the Jordan River. Prior to the late 1950s, the Jordan River flowed through the Hula Valley through three tributaries that inflowed into the old Lake Hula. From the old Lake Hula, situated at an altitude of 61 - 68 masl (above sea level), the Jordan River flows downstream into Lake Kinneret (Mean WL 211 mbsl) for a distance of approximately 15 km. Before the drainage of the Hula wetlands and old Lake Hula, the Valley was characterized by old Lake Hula and 3500 ha of swampland. The swampy area was totally covered by water in the winter and partly covered in the summer. To the north of the swamps was an area (3200 ha) where water table levels were high in winter, thus making agricultural cultivation impossible. During the summer, when underground water levels declined, this 3200-ha land surface was efficiently cultivated. After drainage, land use was converted into agricultural management. Several processes of organic matter oxidation and the usage of inappropriate irrigation methods which enhanced soil properties deterioration initiated concerns about Kinneret water quality: Frequent outbreaks of subsurface unsecured fire; Soil surface subsidence deteriorating the hydrological system; Nitrogen mineralization has led to the accumulation of nitrates, increasing the risk of partial migration into Lake Kinneret causing deterioration of its water quality. A reclamation project was implemented, the Hula Project (HP), resuming its current 30 years of existence. The Intrusion of Gypsum into the Peat organic matter has contributed to increased levels of sulfate and calcium, enhancing soil salinization. The present study examines the impact of climate conditions and consequently soil moisture on Alkalinity (ALK), Total Dissolved Solids (TDS) and Sulfate (SO₄) concentrations and Electrical Conductivity (EC), and pH properties on drained waters from the Peat Soil in the Hula Valley. The objective of the present study is to evaluate the impact of the HP on the fluctuations of Sulfate, Carbonate, Electrical Conductivity and pH in the Hula Peat soil-drained waters. The Hula Project challenges were agricultural crops improvement, prevention of soil properties devastation and Kinneret water quality protection. Nevertheless, information about Peat soil response to ecological changes aimed at management predictability was incomplete. Consequently, evaluation of temporal and seasonal distribution of nutrients (SO₄, Alkalinity, TDS) and physicochemical parameters (EC, pH) are critically required.

Results given in Table 1 & Table 2 indicate the tight correlation between Alkalinity, Total Dissolved Solids, Electrical Conductivity, and Sulfate suggested to be dependents of soil moisture which is strongly affected by climate (rain capacity) conditions. The high correlation between EC, TDS and Alkalinity emphasizes the impact of soil moisture. The exceptionally low level of fluctuations presented by pH and TSS values is an indication of the ineffective impact of soil moisture on pH and TSS. ( Figures 1-16 )

The similarity of seasonal distribution of concentrations of TDS, SO₄, Alkalinity, and EC, and rain capacity within the Peat soil (Station 57) drained waters is clearly shown in Figures 2-6 .

The insignificance of nonlinear seasonal distribution (monthly) relations of pH and the concentration of Total Suspended Solids (TSS) within the Peat spill drained waters (Station 57) is shown in Figure 7 and Figure 8 .

The obvious linear significant relation between TDS and EC is confirmed in Figure 9 . The higher the soil moisture, accompanied by salt flushing, the greater the enhancement of EC.

Obvious Inverse relations of TDS and EC with TSS are consequently confirmed in Figure 9 & Figure 10 .

Results of temporal distribution given in Figures 12-15 indicate a decline in nutrient (Alkalinity, SO₄) concentrations and EC and TDS during 1994-2009 and increase onwards. Information about distributional pattern of rain capacity and consequently intensity, presented as annual rainy days is given in Figure 16 . The pattern similarity of temporal rain capacity and nutrient distribution is emphasized.

Cases of wetlands drainage aimed at extending food production land use are well known in Europe and the USA [8] - [10] . The drainage of the Hula Valley concluded the search for food production combined with the prevention of Lake Kinneret water quality. Soil Survey [11] confirmed 21% (750 ha), 34% (1200 ha), 19% (660 ha) and 26% (910 ha) of the Hula Valley soils are lacustrine marl, Peat soil, Transition Peat soil and alluvial soil respectively [12] . The Peat soil in the Hula Valley contains huge loads of Gypsum (CaSO₄) and migration of ${\text{SO}}_4^{2-}$—from the Peat-Soil into Lake Kinneret might have an impact on water quality. A long period of heavy bloom-forming P. gatunenze domination was replaced by Cyanobacteria including N₂-fixers in Lake Kinneret. The competitive properties of ${\text{SO}}_4^{2-}$ with Molybdenum were documented [13] - [15] . In the Lake Kinneret-Hula ecosystem, enhancement or reduction of supplemental ${\text{SO}}_4^{2-}$ induces strengthening or weakening competition with ${\text{MoO}}_4^{2-}$ affecting suppression of N₂-Fixer Cyanobacterium. Consequently, sulfate migration from the Hula Valley into Lake Kinneret might have an impact on the development of the Bloom Forming Harmful Cyanobacteria (BFHC).

Previous studies have documented the high content of Gypsum (CaSO₄) in the Hula Peat soil [3] - [7] . The Gypsum is significantly dissolved in water releasing free Ca²⁺ and ${\text{SO}}_4^{2-}$. The decline of rainfall, and consequently lowered river discharge and suppression of ${\text{SO}}_4^{2-}$ concentrations and loads in the Hula Valley runoffs, River Jordan and Lake Kinneret waters were documented [16] . Carbonate sources and consequently Alkalinity properties in the Peat soil are mostly from lacustrine marl sediments. The documented [17] linkage between high alkalinity and high base cations content, such as Ca²⁺, and Mg²⁺, providing suitable conditions for the precipitation of Fe is relevant to the Hula Peat soil ecosystem. The sulfate sources include the breakdown of proteins into amino acids, which releases oxidized Sulfur. Sulfate existence is dependent on aerobic conditions maintenance. Sulfide production through Anaerobic conditions development was not documented in the Hula Peat soil whilst rarely traced (7 - 8 µM) in the sediments of Lake Agmon-Hula [18] . Enhanced activity of anaerobic sulfate-reducing bacteria was observed in surface soils from P-enriched areas, which yielded 10³ to 10⁴ times higher numbers of these bacteria compared to soils from P-unimpacted sites [19] . Agricultural crops within the Hula Peat Soil land are intensively P-fertilized [12] whilst anaerobic conditions are very scarce in the surface soil layer. Therefore, reducing Sulfate to sulfide is not predicted. Frequencies of anoxic condition within the shallow layers of Hula Peat soil are presently scarce but it might be possible in deeper layers contacting crops root system. Therefore, the prediction of sulfate reductive bacteria existence and toxic sulfide production within the agricultural crops root system is negligible.

The migration of Gypsum (CaSO₄) derivate, the ${\text{SO}}_4^{2-}$ is moisture dependent, the higher the soil moisture, the higher is ${\text{SO}}_4^{2-}$ drained concentration and vice versa [18] [20] . Dryness conditions therefore initiate the decline of ${\text{SO}}_4^{2-}$ migration from the Hula Valley towards Lake Kinneret.

Averaged (SD) nutrient concentrations in water samples collected in Station 57 close to the beginning of Hula Project implementation (1994-1996) indicate wetting after a long period of dryness characterized by fluctuated values and percentage SD levels [18] :

Ca²⁺—403 (SD 236) ppm.

${\text{SO}}_4^{2-}$—997 (SD 752) ppm.

Alkalinity (Carbonate)—192 (SD 61) ppm.

pH—6.6 - 7.6.

Results given in Table 1 & Table 2 indicate two major geochemical components which control the EC measure of the Peat soil drained waters (Station 57): Carbonate as Alkalinity (ppm CaCO₃) and Sulfate capacities. Unpredictable, negligible pH level of fluctuation was indicated. The distributional pattern similarity of seasonal (monthly) changes in nutrient concentrations ( Figure 3-6 ) highlighted the potential of its dependence on climate conditions: rainy winter-spring and dry summer-fall months ( Figure 2 ). During winter-spring time, soil moisture is high as the result of rain wettability whilst during post rainy season, summer-fall months, soil moisture declines. Water content and wettability are probably the major factors that enhance nutrient migration and consequently induce the similarity of the major nutrient distribution patterns. Moreover, the evaluation of the correlation between nutrient migrations and annual rain capacity did not indicate a temporal trend. Whereas consideration of the temporal distribution of rain capacity in terms of the number of rainy days has indicated migrated nutrient concentration enhancement through an increased number of rainy days. In other words, the rain capacity is an insufficient factor and its distribution as a number of rainy days distribution and also by intensity, is critical ( Figures 12-16 ). The dominant impact of soil moisture on nutrient migrations is a combinative effect of capacity and seasonal prolongation. The dominant impact of soil moisture on nutrient migrations in the Peat soil is also supported by the distinct relation between TDS and EC ( Figure 8 ). Moreover, the complex interactions between TDS, TSS and EC are shown in Figures 9-11 : inverse relations between EC and TSS as well as between TSS and TDS confirm distinct positive relations between soil moisture (expressed as TDS) and EC ( Figure 9 ). It is essential to note that nutrient migration in this study is evaluated using spatial and temporal measurements, whereas geochemical processes are not accounted for. An indirect confirmation of the sole impact of soil wettability is coming from the stable with negligible fluctuation of the pH values. The temporal trends of nutrient migration and their dependence on soil moisture and consequently climate changes emphasize the management implication outcome: enhancement of summer irrigation water allocation aimed at salts leaching.

Quantified temporal and seasonality of climate condition of rain capacity measures as mm/annum or periodical distribution respective to the number of rainy days, and nutrient migrations from the Hula Peat soil are dependently correlated. The higher the rain capacity or temporal distributional dispersed, the higher the nutrient concentration. The ecological significance of correlative similarity between migration dynamics of Alkalinity, Sulfate, Total Dissolved Solids and Electrical Conductivity confirm mutual properties of weakness adhesion onto the peat soil particles. A common abrupt response is the increase of soil salinity. Additional irrigation water allocation to enhance salts leaching is therefore recommended.

The author would like to express his sincere appreciation to Prof. D. Levanon and D. Klein for their fruitful and friendly collaboration; V. Orlov-Levin and M. Peres for providing unpublished data supply; T. Natanson and E. Yasur for their assistance in field sampling.

The author carried out data analysis, evaluation and the preparation of the original draft and final version.

The data presented in this study are available on request from the corresponding author.

This study was supported by the MIGAL-Galilee Scientific Research Institute.