Interest in clay as a raw material for construction goes back to ancient times
[1]
. The Egyptian pyramids and other great historical monuments were built using clay
[1]
. Fired or compressed bricks are the technological element used in all earthen constructions
[2]
[3]
. Today, a number of studies focus on the applications of ceramic clays in several areas around the world
[4]
-
[11]
, as well as in Africa
[12]
-
[23]
.
In Cameroon, the use of clays as construction materials is gaining momentum
[24]
-
[31]
. The work focuses either on the characterization of lateritic or alluvial clays for their use as building materials
[27]
-
[29]
, or on the evolution of physicochemical and mechanical properties during the firing process
[25]
[26]
[30]
[31]
.
However, local people continue to face difficulties linked to the fragility of earthen materials in their constructions. This is due to a lack of knowledge regarding the processes involved, as clays do not have the same origins, let alone the same mineralogical or chemical compositions. However, numerous researchers have already recommended methods for selecting and improving the mechanical quality of bricks
[32]
[33]
. Selection involves separating healthy clay from impurities, notably organic matter or coarse factions
[32]
[33]
. Improving the mechanical quality of bricks involves compressing the materials, firing or other various amendments. The addition of 10%wt CaCO3 or the mixture of clay with lateritic gave to improve the mechanical quality of fired bricks, are cited as examples
[15]
[34]
.
2. Materials and Methods2.1. Geological Settings
The study area extends from parallels 5˚36'50.09'' to 5˚53'02'' north latitude and from meridians 10˚15'36.19'' to 10˚22'20.43'' east longitude (
Figure 1
). The substratum is marked by the presence of the Cameroon Volcanic Line (CVL). The CVL is a N30˚E alignment of anorogenic plutonic complexes and oceanic and continental volcanic massifs from the Gulf of Guinea to Lake Chad
[35]
. The CVL comprises some sixty anorogenic complexes composed of various plutonic rocks (granite, syenite, diorite, gabbro) of mantle origin and alkaline to hyper alkaline affinity, sometimes associated volcanism
[36]
. They were emplaced in the Upper Cretaceous (73 Ma) to the Middle Eocene (40 Ma). The oceanic and continental volcanic massifs are also alkaline. The volcanism began around 44Ma and continues episodically until now
[37]
. The development of magmatism appears to be linked to the reactivation of ancient Pan-African structures
[38]
. The rejection of an NE-SW mega-crack triggered volcanic activity from the Tertiary to now and a succession of horsts and grabens defining the Cameroon Line
[38]
. The peneplain and the southern part of the western plateau have been rejuvenated by very recent volcanic eruptions. Most of them erupted, while three of them had vulcanic regimes accompanied by variable ash projections
[39]
.
Figure 1. Study area location.
2.2. Field Work
Alluvial clays derived from the weathering of basalts and migmatites in the locality of Mbouda constitute the key material of the present study. Clay samples were collected from three wells (P1, P2 and P3) dug in the three representative clay facies, namely white clay (AB), black clay (AN) and red clay (AR). For each well, two samples were collected and mixed from the clay stratum as follows: P1 (AB1 and AB2); P2 (AN1 and AN2) and P3 (AR1 and AR2). Samples AB, AN and AR are the result of mixtures AB1 + AB2, AN1 + AN2 and AR1 + AR2, respectively.
2.3. Laboratory Analysis
These properties were evaluated at the MIPROMALO (Mission for the Promotion of Local Materials) laboratory in Yaoundé (Cameroon). Physical analyses (grain size distribution) and ceramic tests (color, cohesion, resonance, linear shrinkage, porosity, density, water absorption and compressive strength) were also carried out there.
Samples were analyzed at the Mineralogical and Geochemical Analysis ACME LAB in Vancouver, Canada. Mineralogical analysis was carried out using the diffractometric (DRX) principle
[40]
. X-ray diffraction patterns were obtained with a Bruler D8 Advance Eco type diffractometer of 1kw power, gas flow with copper (CuKɑ) anode of wavelength 1.5418 Å. Electron acceleration conditions in the tube were 40.125 KV and 25 mA with an Xe-type energy-dispersive. Analyses were carried out on non-oriented powder with ground particles smaller than 50 μm.
Figure 2. Sampling wells.
3. Results3.1. Field Results
The soil profiles of the wells are characteristic of two horizons, A and B, with different textures (
Figure 2
). The colorations of the clays are different in the three wells, with black clays (AN) in well 1, white clays (AB) in well 2 and red clays (AR) in well 3. The color of the alluvial clays is closely linked to the nature of the material in which they are found. The black color results from the importance of organic matter
[33]
; the white color is linked to the presence of kaolinite, while the red color shows the influence of iron oxides
[13]
[29]
[41]
[42]
.
3.2. Laboratory Results
The distribution of the proportions of the different granular families is shown in
Table 1
. The AN material is characterized by a high proportion of sand (64%), while the AR sample is characterized by high levels of silt (33.6) and clay (33.6). The clay content of the analyzed materials ranges from 9.3% to 35.5%. The grading was very tight for samples AB and AR, and spread out for sample AN. These results show that sand content is significant in all the samples examined (64.4%, 55.2% and 30.9% for AN AB and AR respectively). These large quantities of sand in the samples are thought to be responsible for the brittleness of bricks made from these local materials. The consequence is that houses built with earth bricks cannot withstand the slightest environmental weathering.
<xref ref-type="bibr" rid="scirp.135746-"></xref>Table 1. Grain size fractions of samples.
Sample
% of gravelФ > 2 mm
% of sand 2 > Ф > 0.02 mm
% of silt 0.02 > Ф > 0.002 mm
% of clay Ф < 0.002 mm
AN
1.3
64.4
25.0
9.3
AB
2.6
55.2
8.8
33.4
AR
0.3
30.9
33.6
35.2
Ceramic properties such as linear shrinkage (
Figure 3
), density (
Figure 4
), water absorption (
Figure 5
) and compressive strength (
Figure 6
) show that water absorption decreases while the other ceramic parameters increase with firing temperature. The departure of the water is due to the densification of the bricks, which is reflected in the increase in linear shrinkage, density and strength. In fact, this behaviour is common to all brick specimens subjected to firing
[13]
[29]
[41]
[42]
. The compressive strength of the specimens is low because of the high sand content, except for AB, which is an alluvial clay rich in kaolinite. Alluvial clays appear more suitable for the manufacture of fired bricks than lateritic clays
[25]
.
Figure 3. Diagram showing the variation of linear shrinkage during the firing process.
Figure 4. Diagram showing the variation of density during the firing process.
<xref ref-type="bibr" rid="scirp.135746-"></xref>Figure 5. Diagram showing the variation of water absorption during the firing process.
Figure 6. Diagram showing the variation of compressive strength during the firing process.
Qualitative analysis by X-ray diffractometry on disoriented powder was carried out on three samples. Recognition of the mineralogical composition led to the production of diffractograms and indexing of the hkl lines characteristic of the main minerals.
Figures 7-9
depict diffractograms. The AN(P1) sample contains minerals such as kaolinite, anatase, quartz, goethite, hematite, biotite and gibbsite. The mineralogical composition of sample AB(P2) consists of chlorite, kaolinite, anatase, quartz, biotite, hematite, muscovite, goethite and magnetite. Sample AR(P3) contains the following minerals: chlorite, kaolinite, anatase, quartz, biotite, hematite, muscovite, goethite and gibbsite.
Figure 7. Diffractogram of the AN sample.
Figure 8. Diffractogram of the AB sample.
Figure 9. Diffractogram of the AR sample.
Geochemical analysis of the samples (AN, AB, AR) enabled the major elements to be expressed as a percentage (%) of oxides. The assessment (
Table 2
) reveals high SiO2 content ranging from 47.68% to 52.87%, with an average of 49.52%. The Al2O3 content ranged from 24.77% to 28.13%, with an average of 26.62%. The Fe2O3 content varies from 1.45% to 5.13%, with an average of 3.16%. MgO content ranged from 0.32% to 0.40%, with an average of 0.37%. CaO concentrations ranged from 0.04% to 1.08%, with an average of 0.39%. Na2O content varied from 0.10% to 0.13%, with an average of 0.11%. K2O content ranged from 1.08% to 2.71%, with an average of 1.81%. The other sample contents of TiO2 (1.69% - 2.29%), P2O5 (0.26% - 0.48%) and MnO (0.01% - 0.13%) have very poor content.
<xref ref-type="bibr" rid="scirp.135746-"></xref>Table 2. Major element content (in % oxides) of samples.
Oxide
DL
Sample
ANP1
ABP2
ARP3
AVERAGE
PAAS
UCC
SiO2
0.01
52.87
48.02
47.68
49.52
62.8
66
Al2O3
0.01
26.97
28.13
24.77
26.62
18.9
15.2
Fe2O3
0.04
1.45
2.90
5.13
3.16
6.5
4.5
MnO
0.01
0.01
0.01
0.02
0.013
0.11
0.1
MgO
0.01
0.32
0.38
0.40
0.37
2.2
2.2
CaO
0.01
1.08
0.04
0.04
0.39
1.3
4.2
Na2O
0.01
0.10
0.11
0.13
0.11
1.2
3.9
K2O
0.01
1.08
1.81
2.71
1.87
3.7
3.4
TiO2
0.01
1.69
2.29
2.12
2.03
1
0.5
P2O5
0.01
0.26
0.34
0.48
0.36
0.16
0.17
LOI
−5.1
14.13
14.99
16.24
15.12
0
0
Total
-
99.96
99.02
99.72
99.57
97.87
100.17
Total - LOI
-
85.83
84.0311
83.48449
84.45
-
-
DL: Detection Limit.
4. Discussion of the Results
Earthen buildings in the Bouda area are made using compressed earth blocks. This method reduces environmental pollution caused by the use of kiln fuel in the fired brick production industries
[43]
-
[46]
. The results obtained in this research are in agreement with the work showing that unfired bricks are characterised by low strength and high permeability
[3]
. The main handicap of compressed blocks being their high sand and organic matter content
[32]
[33]
. Prior treatment of the material is necessary by removing the coarse fraction and organic matter from the clay
[32]
[33]
. Even, when healthy clay is used, the mechanical quality of compressed earth blocks remains mediocre
[3]
[8]
. To improve the mechanical quality of earth blocks, several treatments are envisaged, mainly material mixtures and firing
[13]
[31]
[33]
[34]
[47]
-
[49]
. When the preliminary treatments are applied, brick solidification mechanisms based on microstructural and molecular arrangements under the effect of pressure or temperature are likely to occur, in accordance with the results of numerous studies
[6]
[17]
[27]
[35]
[50]
-
[57]
.
The results of the particle size analysis show a high sand content in all the samples with low clay fraction. These are responsible for the changes in the ceramic parameters. The high sand content explains the good evolution of density, which is accompanied by low compressive strength and low percentage of linear shrinkage, as well as water absorption, since these three parameters are closely linked to the clay fraction. The results obtained in this work are similar to those obtained by other authors who have proposed amendments to improve the mechanical quality of bricks
[32]
-
[34]
[57]
. The mineralogical series as well as chemical analysis enabled a rapid classification of clays as alumino-siliocate materials
[25]
[27]
-
[29]
[35]
. The chemical composition of the samples (AR, AB and AN) is favourable for the crystallisation of kaolinite and quartz, whereas quartz is unfavourable for the cohesion and consolidation of fired bricks
[33]
. Similarly, high levels of iron oxides also play the same unfavorable role as quartz
[27]
. In contrario, other minerals can play an important role in the mineralogical transformations that affect them during the firing process necessary to acquire the good mechanical properties of fired bricks. The main mineralogical transformations contributing to the acquisition of good mechanical properties in bricks have been listed
[58]
-
[60]
.
5. Conclusions
When closing this work devoted to the ceramic properties of three specimens clays from Mbouda deposit, the following conclusions are deduced:
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