<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article">
 <front>
  <journal-meta>
   <journal-id journal-id-type="publisher-id">
    msa
   </journal-id>
   <journal-title-group>
    <journal-title>
     Materials Sciences and Applications
    </journal-title>
   </journal-title-group>
   <issn pub-type="epub">
    2153-117X
   </issn>
   <issn publication-format="print">
    2153-1188
   </issn>
   <publisher>
    <publisher-name>
     Scientific Research Publishing
    </publisher-name>
   </publisher>
  </journal-meta>
  <article-meta>
   <article-id pub-id-type="doi">
    10.4236/msa.2024.159019
   </article-id>
   <article-id pub-id-type="publisher-id">
    msa-135632
   </article-id>
   <article-categories>
    <subj-group subj-group-type="heading">
     <subject>
      Articles
     </subject>
    </subj-group>
    <subj-group subj-group-type="Discipline-v2">
     <subject>
      Chemistry 
     </subject>
     <subject>
       Materials Science
     </subject>
    </subj-group>
   </article-categories>
   <title-group>
    Superplasticized vs. Conventional Concrete: A Comparative Review
   </title-group>
   <contrib-group>
    <contrib contrib-type="author" xlink:type="simple">
     <name name-style="western">
      <surname>
       Mark
      </surname>
      <given-names>
       Bediako
      </given-names>
     </name>
    </contrib>
   </contrib-group> 
   <aff id="affnull">
    <addr-line>
     aAdvanced Material Science Division, CSIR-Building and Road Research Institute, Kumasi, Ghana
    </addr-line> 
   </aff> 
   <pub-date pub-type="epub">
    <day>
     29
    </day> 
    <month>
     08
    </month>
    <year>
     2024
    </year>
   </pub-date> 
   <volume>
    15
   </volume> 
   <issue>
    09
   </issue>
   <fpage>
    271
   </fpage>
   <lpage>
    284
   </lpage>
   <history>
    <date date-type="received">
     <day>
      22,
     </day>
     <month>
      July
     </month>
     <year>
      2024
     </year>
    </date>
    <date date-type="published">
     <day>
      26,
     </day>
     <month>
      July
     </month>
     <year>
      2024
     </year> 
    </date> 
    <date date-type="accepted">
     <day>
      26,
     </day>
     <month>
      August
     </month>
     <year>
      2024
     </year> 
    </date>
   </history>
   <permissions>
    <copyright-statement>
     © Copyright 2014 by authors and Scientific Research Publishing Inc. 
    </copyright-statement>
    <copyright-year>
     2014
    </copyright-year>
    <license>
     <license-p>
      This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/
     </license-p>
    </license>
   </permissions>
   <abstract>
    The global awareness and utilization of superplasticizers (SPs) in concrete have significantly contributed to developing resilient and sustainable infrastructure. Despite this, many developing nations face limited adoption of SPs in construction practices due to a lack of knowledge. This study provides a concise overview of concrete’s mechanical and durability properties, comparing formulations with and without superplasticizers. The focus is on compressive and flexural strengths, modulus of elasticity, water sorptivity, and chloride penetration. The results underscore the considerable improvement in both mechanical and durability properties when SPs are incorporated. The study recommends the widespread use of SPs, particularly in developing countries, to enhance the longevity of concrete structures.
   </abstract>
   <kwd-group> 
    <kwd>
     Superplasticizers
    </kwd> 
    <kwd>
      Concrete
    </kwd> 
    <kwd>
      Mechanical Properties
    </kwd> 
    <kwd>
      Durability
    </kwd> 
    <kwd>
      Developing Countries
    </kwd>
   </kwd-group>
  </article-meta>
 </front>
 <body>
  <sec id="s1">
   <title>1. Introduction</title>
   <p>
    <xref ref-type="bibr" rid="scirp.135632-"></xref>Ensuring the attainment of designated strength and improved durability in concrete remains a paramount concern for building engineers. Nevertheless, achieving these benchmarks proves challenging due to the inherent difficulty in precisely controlling water content, particularly in field conditions. In an attempt to enhance concrete workability, additional water is often introduced, yet this practice can lead to heightened porosity once the water evaporates. Theoretically, the ideal water-to-cement ratio for full hydration is around 25% of the cement mass <xref ref-type="bibr" rid="scirp.135632-1">
     <a href="#ref1">[1]</a>
    </xref>. Unfortunately, achieving flowable concrete with such a low water content is practically unattainable.</p>
   <p>The advent of superplasticizers has emerged as a solution, offering building engineers a more accessible means to achieve desired mechanical properties and bolster concrete durability. Superplasticizers facilitate high early and late strength development, improved modulus of elasticity, and reduced porosity, thereby enhancing overall concrete durability <xref ref-type="bibr" rid="scirp.135632-2">
     [2]
    </xref>-<xref ref-type="bibr" rid="scirp.135632-4">
     [4]
    </xref>. The widespread use of superplasticizers in concrete is well-established in developed countries, impacting various concrete types such as lightweight, heavyweight, prestressed, vacuum, self-compacting, autoclaved aerated, and fiber-reinforced concrete (FRC) <xref ref-type="bibr" rid="scirp.135632-4">
     [4]
    </xref>. However, in many developing countries, this innovation is not as widely recognized.</p>
   <p>Many building engineers adhere steadfastly to traditional concrete formulation methods in numerous developing nations, including West African countries. Their reliance on prescriptive European Standards is unwavering, making it challenging to advocate for adopting superplasticizers. Despite the proven benefits demonstrated in developed countries, building engineers in these regions remain skeptical about incorporating superplasticizers into their concrete practices.</p>
   <p>In the absence of knowledge about superplasticizers, engineers typically resort to increasing water content as the sole means to enhance workability. However, this practice, aimed at improving workability, inadvertently leads to high porosity, negatively impacting the mechanical and durability aspects of concrete, particularly in developing countries. The widespread issue of poor-grade concrete due to elevated porosity is a common challenge faced in these regions. In contrast, advanced and developed countries successfully achieve superior mechanical and durability properties by incorporating superplasticizers. For example, in Japan, superplasticizers are reported to be an integral component in almost all concrete production <xref ref-type="bibr" rid="scirp.135632-1">
     [1]
    </xref>.</p>
   <p>While superplasticizers play a crucial role in optimizing cement hydration for superior performance, the acknowledgment of their contribution to concrete is often understated by many authors. In contemporary concrete formulation, attaining high-performance concrete is relatively straightforward with the use of superplasticizers. These substances disperse cement particles through either electrostatic or steric repulsive forces, promoting the repulsion of cement powder and an increase in shear potential. Consequently, this leads to improved workability without the need for additional water, which could introduce more pores and compromise the mechanical and durability characteristics of concrete.</p>
   <p>Second-generation superplasticizers, such as Sulphonated Naphthalene Formaldehyde (SNF) and Sulphonated Melamine Formaldehyde (SMF), as well as the latest generation in the form of polycarboxylate ethers, have proven successful in enhancing the technical properties of concrete. It is crucial to highlight and disseminate information on the successful applications of superplasticizers in improving concrete properties. This study aims to provide comprehensive data on the use of superplasticizers and their impact on the mechanical and durability behavior of concrete. Mechanical properties considered in this study encompass compressive, flexural, and modulus of elasticity, while durability parameters include sorptivity and the rapid chloride penetration test.</p>
  </sec><sec id="s2">
   <title>
    <xref ref-type="bibr" rid="scirp.135632-"></xref>2. Superplasticizers in Concrete</title>
   <p>
    <xref ref-type="bibr" rid="scirp.135632-"></xref>Superplasticizers, recognized as potent water reducers, are commonly employed to enhance the workability of concrete. These substances, characterized by high-density molecular polymers, are soluble in water <xref ref-type="bibr" rid="scirp.135632-5">
     [5]
    </xref>. Widely used superplasticizers include sulfonated melamine formaldehyde condensate (SMF), sulfonated naphthalene formaldehyde condensates (SNF), and polycarboxylate ether-based superplasticizers (PCE) <xref ref-type="bibr" rid="scirp.135632-6">
     [6]
    </xref> <xref ref-type="bibr" rid="scirp.135632-7">
     [7]
    </xref>. The second-generation admixtures encompass SMF and SNF-based SPs, while PCE-based SPs are classified as new-generation.</p>
   <p>Various types of superplasticizers exhibit distinct actions on cement particles, yet their fundamental impact is to disperse these particles by adsorbing superplasticizer molecules onto the surface of hydrating cement particles <xref ref-type="bibr" rid="scirp.135632-8">
     [8]
    </xref> <xref ref-type="bibr" rid="scirp.135632-9">
     [9]
    </xref>. Cement grains possess surface charges, and Vander Waal forces cause these particles to flocculate upon contact with water <xref ref-type="bibr" rid="scirp.135632-8">
     [8]
    </xref>. This results in the entrapment of water needed to enhance concrete workability, requiring less water for cement hydration <xref ref-type="bibr" rid="scirp.135632-10">
     [10]
    </xref>. Superplasticizers adsorbed onto cement grain surfaces eliminate attractive interparticle forces responsible for yield stress, thereby enhancing concrete workability <xref ref-type="bibr" rid="scirp.135632-11">
     [11]
    </xref> <xref ref-type="bibr" rid="scirp.135632-12">
     [12]
    </xref>.</p>
   <fig id="fig1" position="float">
    <label>Figure 1</label>
    <caption>
     <title>
      <xref ref-type="bibr" rid="scirp.135632-"></xref>Figure 1. Deflocculation mechanism by creating a charge on cement particles <xref ref-type="bibr" rid="scirp.135632-8">
       [8]
      </xref>.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId16.jpeg?20240829114326" />
   </fig>
   <p>
    <xref ref-type="bibr" rid="scirp.135632-"></xref></p>
   <fig id="fig2" position="float">
    <label>Figure 2</label>
    <caption>
     <title>Figure 2. Deflocculation mechanism by electrostatic/stearic repulsive forces <xref ref-type="bibr" rid="scirp.135632-10">
       [10]
      </xref>.</title>
    </caption>
    <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId17.jpeg?20240829114326" />
   </fig>
   <p>The second-generation and new-generation admixtures, while both functioning to deflocculate cement particles, employ different mechanisms for this action. SNF and SMF induce dispersions of cement agglomerates through the presence of negatively charged anionic groups, ensuring polymer adsorption on cement powder surfaces <xref ref-type="bibr" rid="scirp.135632-13">
     [13]
    </xref>. <xref ref-type="fig" rid="fig1">
     Figure 1
    </xref> illustrates the mechanism of second-generation SPs. In the case of PCEs, the mechanism involves adsorption on the cement particle surface and neutralization of heterogeneous charged distributions on the cement powder. The adsorbed PCE on cement particles then introduces electrostatic/stearic repulsion among cement particles (refer to <xref ref-type="fig" rid="fig2">
     Figure 2
    </xref>) <xref ref-type="bibr" rid="scirp.135632-10">
     [10]
    </xref>.</p>
  </sec><sec id="s3">
   <title>
    <xref ref-type="bibr" rid="scirp.135632-"></xref>3. Mechanical Properties of Concrete with and without Superplasticizers</title>
   <sec id="s3_1">
    <title>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>3.1. Compressive Strength</title>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>Compressive strength serves as a widely employed parameter for assessing the load-bearing capacity of structures. The utilization of superplasticizers (SPs) in concrete contributes to the enhancement of compressive strength properties. In their study on fiber-reinforced concrete, Aruntaş et al. <xref ref-type="bibr" rid="scirp.135632-4">
      [4]
     </xref> observed that the inclusion of SPs led to increased concrete strength compared to the control concrete, evident after curing for 28, 90, and 180 days. Matias et al. <xref ref-type="bibr" rid="scirp.135632-14">
      [14]
     </xref> incorporated SPs in concrete utilizing recycled coarse aggregates as a substitute for natural coarse aggregates. Despite the recognized strength loss associated with saturated recycled aggregates, the introduction of SPs by Matias et al. <xref ref-type="bibr" rid="scirp.135632-14">
      [14]
     </xref> mitigated this effect, resulting in concrete strength similar to the control concrete.</p>
    <p>In a study by Manami et al. <xref ref-type="bibr" rid="scirp.135632-15">
      [15]
     </xref>, four distinct superplasticizers (PCE, LC, SMF, and SNF) were employed in concrete containing fly ash (refer to <xref ref-type="fig" rid="fig3">
      Figure 3
     </xref>). The compressive strength of the control concrete was 46 MPa, while those of the concrete containing SMF, SNF, LS, and PCE superplasticizers were 58, 56, 52, and 53 MPa, respectively. These findings emphasize that the incorporation of SPs in concrete enhances the overall strength performance of the material.</p>
    <p>Cheah et al. <xref ref-type="bibr" rid="scirp.135632-16">
      [16]
     </xref> demonstrated the positive impact of polycarboxylate ether-based superplasticizers (PCEs) in their research on ternary blended binder concrete, employing 50% cement with a combined 50% ground granulated blast furnace slag (GGBS) and fly ash (FA). The compressive strength of concrete with 50% Ordinary Portland Cement (OPC) containing GGBS-PFA at 50% and 60% cement levels exhibited a significant increase ranging between 9% and 42% at both early (7 days) and late ages (28 days), surpassing the compressive strength of the control concrete.</p>
    <p>In a separate study, Arslan et al. <xref ref-type="bibr" rid="scirp.135632-17">
      [17]
     </xref> investigated the application of a novel chitosan-based superplasticizer in concrete. As depicted in <xref ref-type="fig" rid="fig4">
      Figure 4
     </xref>, their findings indicated an increase in compressive strength rates for sulfonated graft and sulfonated chitosan. Specifically, the observed enhancements were 9.1% and 5.5% for 1-day compressive strength, 13.4% and 10.2% for 3 days compressive strengths, 8.3% and 4.1% for 7 days compressive strengths, and finally, 13.3% and 10.9% for 28 days compressive strengths, respectively.</p>
    <p>Numerous studies by various researchers, such as those conducted by Cheah et al. <xref ref-type="bibr" rid="scirp.135632-18">
      [18]
     </xref>, and Arslan et al. <xref ref-type="bibr" rid="scirp.135632-19">
      [19]
     </xref>, have consistently demonstrated that the use of superplasticizers (SNFs and PCEs) contributes to higher compressive strength in concrete. Sardinha et al. <xref ref-type="bibr" rid="scirp.135632-20">
      [20]
     </xref>, in their investigation on the replacement of cement with fine marble dust, noted that the inclusion of superplasticizers resulted in increased concrete strength even with a reduced cement content.</p>
    <p>The improvement in compressive strength observed in concrete containing superplasticizers can be attributed to the enhanced compactness facilitated by the presence of superplasticizers, coupled with a low water-cement ratio. This is particularly notable in concrete containing pozzolan <xref ref-type="bibr" rid="scirp.135632-15">
      [15]
     </xref> <xref ref-type="bibr" rid="scirp.135632-17">
      [17]
     </xref> <xref ref-type="bibr" rid="scirp.135632-21">
      [21]
     </xref>. Tkaczewska’s study <xref ref-type="bibr" rid="scirp.135632-22">
      [22]
     </xref> further revealed a reduction in voids in concrete when superplasticizers are utilized, leading to increased early and late strength in the material.</p>
    <fig id="fig3" position="float">
     <label>Figure 3</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.135632-"></xref>Figure 3. Compressive strength of fly ash concrete containing different types of superplasticizers <xref ref-type="bibr" rid="scirp.135632-15">
        [15]
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId18.jpeg?20240829114327" />
    </fig>
    <fig id="fig4" position="float">
     <label>Figure 4</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.135632-"></xref>Figure 4. Compressive strength of reference and superplasticizer concrete <xref ref-type="bibr" rid="scirp.135632-17">
        [17]
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId19.jpeg?20240829114327" />
    </fig>
   </sec>
   <sec id="s3_2">
    <title>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>3.2. Flexural Strength</title>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>The flexural strength of concrete, which assesses a concrete beam’s ability to withstand bending loads before failure, is a critical property in structural design. Numerous studies have consistently indicated that the incorporation of superplasticizers (SPs) in concrete leads to an enhancement in flexural strength. In a study by Cheah et al. <xref ref-type="bibr" rid="scirp.135632-16">
      [16]
     </xref>, the impact of SP on the flexural behavior of concrete with a ternary mixture of cement, slag, and fly ash was investigated. Their findings revealed that concrete with 50% and 60% replacement of Ordinary Portland Cement (OPC) by GGBS-PFA exhibited higher flexural strength values at 7, 28, 56, and 90 days compared to the control concrete.</p>
    <p>The superior performance of the ternary blended concrete over the control concrete is attributed to the SP-induced improvement in the brittleness of the cement system and the increased density of the concrete resulting from a lower water-cement ratio <xref ref-type="bibr" rid="scirp.135632-23">
      [23]
     </xref>.</p>
    <p>In their investigation, Al-Hussaini et al. <xref ref-type="bibr" rid="scirp.135632-24">
      [24]
     </xref> examined the impact of superplasticizers (SPs) on concrete reinforced with waste plastic fibers. Their results demonstrated a notable enhancement in the flexural behavior of the concrete, particularly during the late curing period of 28 days, when SPs were added. The improvement in flexural behavior with the addition of SPs exceeded 289% compared to the control concrete. This significant enhancement can be attributed to the improved workability and reduced water content in the concrete containing SPs. The reduction in water content contributes to an improved density of the concrete, thereby enhancing its flexural properties.</p>
   </sec>
   <sec id="s3_3">
    <title>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>3.3. Static Elastic and Dynamic Modulus of Concrete</title>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>The modulus of elasticity (MoE), also known as Young’s modulus, is a crucial property in concrete, playing a defining role in the deformability of structures and the interaction between reinforcement and concrete <xref ref-type="bibr" rid="scirp.135632-25">
      [25]
     </xref>. MoE significantly influences the safety, durability, and service life of reinforced concrete structures <xref ref-type="bibr" rid="scirp.135632-3">
      [3]
     </xref>. This parameter is directly linked to the shortening of concrete components under compressive stress and is impacted by factors like creep and shrinkage <xref ref-type="bibr" rid="scirp.135632-26">
      [26]
     </xref>. The creeping effect or stress shortening induces the redistribution of internal stresses within reinforced concrete structures, affecting columns, beams, or walls.</p>
    <p>Currently, establishing a consensus on the ideal procedure for determining the modulus of elasticity (MoE) poses challenges due to the nonlinear nature of concrete under stress-strain deformation. Various empirical models for static elastic modulus exist in different standards and codes, establishing relationships between MoE and compressive strength <xref ref-type="bibr" rid="scirp.135632-27">
      [27]
     </xref>-<xref ref-type="bibr" rid="scirp.135632-29">
      [29]
     </xref>.</p>
    <p>Dynamic elastic modulus holds significant importance in applications where concrete is subjected to dynamic loads, such as scenarios involving sudden loads on concrete structures. Several models have been developed to establish correlations between static elastic modulus and dynamic modulus using pulsonic velocity in nondestructive testing (NDT) methods <xref ref-type="bibr" rid="scirp.135632-30">
      [30]
     </xref>. These models are found in standards like ACI, EN, and IS, as well as those developed by researchers <xref ref-type="bibr" rid="scirp.135632-27">
      [27]
     </xref>-<xref ref-type="bibr" rid="scirp.135632-29">
      [29]
     </xref> <xref ref-type="bibr" rid="scirp.135632-31">
      [31]
     </xref> <xref ref-type="bibr" rid="scirp.135632-32">
      [32]
     </xref>. Despite the wealth of research in the field of static elastic modulus, there is a limited body of work concerning dynamic elastic modulus in concrete with and without chemical and mineral admixtures.</p>
    <p>Pereira et al. <xref ref-type="bibr" rid="scirp.135632-25">
      [25]
     </xref> investigated the static elastic modulus using two distinct superplasticizers, namely lignosulphonate and polycarboxylate ether, in concrete incorporating recycled coarse aggregates. Their findings revealed a significant increase in the modulus of elasticity (MoE) when superplasticizers were employed, with an improvement ranging between 20.7% (lignosulphonate) and 33.0% (PCE) compared to concrete without a superplasticizer.</p>
    <p>In a related study, Bravo et al. <xref ref-type="bibr" rid="scirp.135632-18">
      [18]
     </xref> explored the impact of polycarboxylate-based superplasticizers on recycled aggregate concretes. <xref ref-type="table" rid="table1">
      Table 1
     </xref> illustrates their results, incorporating recycled aggregates at various percentages (0%, 10%, 25%, 50%, and 100%). The outcomes presented in <xref ref-type="table" rid="table1">
      Table 1
     </xref> demonstrate that the modulus of elasticity in recycled aggregate concretes containing superplasticizers exhibited superior performance compared to concretes without superplasticizers.</p>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>The enhanced performance of the static elastic modulus in concrete containing superplasticizers is ascribed to the improved bonding observed at the interfacial transition zone between cement and coarse aggregates <xref ref-type="bibr" rid="scirp.135632-18">
      [18]
     </xref>. Zhu and Bartos <xref ref-type="bibr" rid="scirp.135632-33">
      [33]
     </xref> have pointed out that the aggregate paste transition zone undergoes densification and stiffening, consequently leading to an improvement in the overall stiffness of the concrete.</p>
    <table-wrap id="table1">
     <label>
      <xref ref-type="table" rid="table1">
       Table 1
      </xref></label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.135632-"></xref>Table 1. MoE of recycled aggregate concrete with no SP and with SP <xref ref-type="bibr" rid="scirp.135632-18">
        [18]
       </xref>.</title>
     </caption>
     <table class="MsoTableGrid custom-table" border="0" cellspacing="0" cellpadding="0"> 
      <tr> 
       <td rowspan="3" class="acenter" width="21.12%" colspan="2"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td acenter" width="78.88%" colspan="10">RA incorporation (%)<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">0<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">10<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.90%">25<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">50<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">100<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.90%"><p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">Ecm28<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">St. Dev<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">Ecm28<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">St. Dev<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.90%">Ecm28<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">St Dev<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">Ecm28<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">St Dev<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.89%">Ecm28<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="7.90%">St Dev<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td rowspan="4" class="custom-top-td acenter" width="8.80%">No SP<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="12.32%">Valnor CRA<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">40.5<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0.2<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">39.1<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0.4<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.90%">34.6<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">29.2<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0.9<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">21.1<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.90%">0.5<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">Retria CRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">37.7<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">35.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">31.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.2<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">26.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">Vimajas FRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">38.6<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.9<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">34.9<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">31.9<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.2<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">23.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0.6<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">AmbileiFRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">40.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">38<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.2<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">37.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">32.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0.6<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td rowspan="4" class="custom-top-td acenter" width="8.80%">With SP<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="12.32%">Valnor CRA<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">44.6<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0.5<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">46.5<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">1<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.90%">40.7<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">1.1<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">39<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">0.1<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.89%">29.2<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="7.90%">0.4<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">Retria CRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">42<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">40.9<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">37.2<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">28.3<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0.8<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">Vimajas FRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">43.8<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">38.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.4<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">32.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">26.8<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0.3<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="12.32%">AmbileiFRA<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%"><p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">49.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">47.6<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">42.9<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">0.6<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.89%">38.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="7.90%">0.2<p style="text-align:center"></p></td> 
      </tr> 
     </table>
    </table-wrap>
   </sec>
  </sec><sec id="s4">
   <title>
    <xref ref-type="bibr" rid="scirp.135632-"></xref>4. Durability</title>
   <p>Concrete durability is characterized by its ability to withstand various forms of deterioration, including weathering, chemical attacks, abrasion, and other deteriorative processes. In essence, durable concrete retains its original form, quality, and functionality when subjected to environmental exposure <xref ref-type="bibr" rid="scirp.135632-34">
     [34]
    </xref>. The service life of concrete is deemed complete when it becomes unsafe and economically impractical.</p>
   <p>The assessment of concrete durability involves various methods that examine transport mechanisms, such as sorptivity, porosity, water absorption, and sorption. These transport properties provide insights into the nature of pore size within the concrete material. Additionally, studies on chloride migration and penetration, as well as evaluations of resistance against sulfate and acidic attacks, are common methods employed to gauge concrete performance in the face of chemical challenges. This overview will specifically focus on sorptivity and rapid chloride penetration as key parameters in assessing concrete durability.</p>
   <sec id="s4_1">
    <title>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>4.1. Sorptivity</title>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>Sorptivity, defined as the rate of water absorption in concrete pores through capillary suction, is a critical parameter <xref ref-type="bibr" rid="scirp.135632-15">
      [15]
     </xref>. Capillary sorptivity is influenced by the pore distribution and microstructural properties inherent in the concrete <xref ref-type="bibr" rid="scirp.135632-2">
      [2]
     </xref>. The sorptivity value of concrete plays a crucial role in assessing its susceptibility to the ingress of aggressive chemicals through the pores, potentially causing deterioration. Aggressive substances, such as sulfates and chlorides, known for their capacity to damage concrete, typically infiltrate through water transport. In experimental setups, water is commonly utilized as the primary transport medium, and a lower sorptivity value indicates greater resistance to water absorption, while a higher value implies the opposite.</p>
    <p>In the investigation conducted by Manami et al. <xref ref-type="bibr" rid="scirp.135632-15">
      [15]
     </xref>, the sorptivity of fly ash concrete was examined using various superplasticizers, namely PCE, LC, SMF, and SNF, and compared with control concrete. <xref ref-type="fig" rid="fig5">
      Figure 5
     </xref> illustrates the findings of Manami et al. <xref ref-type="bibr" rid="scirp.135632-15">
      [15]
     </xref>, wherein the control concrete with 35% fly ash content is compared to superplasticizer concretes, also containing 35% fly ash. The study revealed that all concretes containing superplasticizers exhibited lower sorptivity compared to the control concrete. Furthermore, the research demonstrated that PCE-based admixtures were more effective in reducing the sorptivity of concrete than LS, SMF, and SNF superplasticizers.</p>
    <p>Andrade Neto et al. <xref ref-type="bibr" rid="scirp.135632-19">
      [19]
     </xref> explored the utilization of sugarcane bagasse ash in concrete, replacing up to 20% of cement by weight with bagasse ash. The incorporation of bagasse in the concrete was accompanied by the addition of a polycarboxylate-based superplasticizer admixture. The sorptivity values obtained for reference, 5%, 10%, and 15% bagasse content were 0.21, 0.07, 0.05, and 0.04 kg/m<sup>2</sup>/min<sup>1/2</sup>, respectively. Their findings indicated that a combination of physical and pozzolanic effects played a role in reducing pore interconnectivity, consequently decreasing sorptivity.</p>
    <p>In the studies conducted by Sardinha et al. <xref ref-type="bibr" rid="scirp.135632-20">
      [20]
     </xref>, it was established that the inclusion of superplasticizers in concretes incorporating marble dust led to a reduction in water absorption. This reduction was attributed to the superplasticizers’ ability to decrease the water-to-cement (w/c) ratio, consequently lowering the porosity of the concrete. <xref ref-type="fig" rid="fig6">
      Figure 6
     </xref> illustrates the results of sorptivity studies from Sardinha et al. <xref ref-type="bibr" rid="scirp.135632-20">
      [20]
     </xref>.</p>
    <p>Najimi et al. <xref ref-type="bibr" rid="scirp.135632-35">
      [35]
     </xref> conducted a study to assess the impact of natural zeolite on the durability properties of concrete. In their investigation, cement was replaced by 15% and 30% weight of natural zeolite, and a melamine-based superplasticizer was incorporated. The water penetration or sorptivity performance of the control concrete at 28 and 90 days was measured at 15 mm. However, in concrete with 15% and 30% zeolite content, the sorptivity levels were reduced to 13 mm and 11 mm, and 9 mm and 10 mm, respectively. After 28 days of curing, the water penetration depths of concrete with 15% and 30% zeolite were reduced by about 13% and 40% compared to the control specimens. At the age of 90 days, the performance of concrete with 15% and 30% zeolite was nearly identical and approximately 33% better than non-zeolite concrete.</p>
    <p>Various studies have highlighted the reasons why incorporating superplasticizers (SPs) in concrete results in lower sorptivity. Authors suggest that SPs enhance cement hydration and improve the compactness of the concrete matrix, thereby reducing permeability <xref ref-type="bibr" rid="scirp.135632-36">
      [36]
     </xref> <xref ref-type="bibr" rid="scirp.135632-37">
      [37]
     </xref>. In the case of concretes containing both SPs and pozzolans, SPs enhance the pozzolanic action, contributing to the denseness of the concrete and consequently lowering sorptivity <xref ref-type="bibr" rid="scirp.135632-35">
      [35]
     </xref>.</p>
    <fig id="fig5" position="float">
     <label>Figure 5</label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.135632-"></xref>Figure 5. Sorptivity coefficient of concrete containing different types of superplasticizers <xref ref-type="bibr" rid="scirp.135632-15">
        [15]
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId20.jpeg?20240829114327" />
    </fig>
    <fig id="fig6" position="float">
     <label>Figure 6</label>
     <caption>
      <title>Figure 6. Water absorption after 72 h <xref ref-type="bibr" rid="scirp.135632-20">
        [20]
       </xref>.</title>
     </caption>
     <graphic mimetype="image" position="float" xlink:type="simple" xlink:href="https://html.scirp.org/file/7703006-rId21.jpeg?20240829114327" />
    </fig>
   </sec>
   <sec id="s4_2">
    <title>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>4.2. Rapid Chloride Permeability Test (RCPT)</title>
    <p>
     <xref ref-type="bibr" rid="scirp.135632-"></xref>The assessment of concrete durability commonly involves studying its resistance to chloride penetration, which is closely linked to low permeability, a dominant factor in the deterioration process <xref ref-type="bibr" rid="scirp.135632-38">
      [38]
     </xref>. Chloride ion corrosion represents a major failure mode leading to a decline in the mechanical properties and durability of concrete <xref ref-type="bibr" rid="scirp.135632-39">
      [39]
     </xref>. The Rapid Chloride Penetration Test (RCPT) is a widely used method for evaluating concrete durability. This test is based on the principle that negatively charged chloride ions are attracted to a positive electrode. It involves measuring the total charge passed through a concrete sample over a six-hour duration, applying a direct current potential difference of 60 V across the sample ends <xref ref-type="bibr" rid="scirp.135632-40">
      [40]
     </xref>. The total charge passing through the concrete is considered indicative of the permeability of the concrete to chloride ions.</p>
    <p>
     <xref ref-type="table" rid="table2">
      Table 2
     </xref> presents the findings from the research conducted by Ramachandran et al. <xref ref-type="bibr" rid="scirp.135632-2">
      [2]
     </xref>, where three different types of concrete were produced: one without a superplasticizer (NC), another with SNF superplasticizer (SP), and the third with fly ash and SNF superplasticizer (FA). The results indicate that concretes labeled FA and SP exhibited lower permeability compared to the concrete without SP and/or FA. The combined effect of FA and SP significantly reduced chloride permeability.</p>
    <p>Summarizing the performance of concretes containing superplasticizers, it is evident that they offer superior resistance to the ingress of chloride ions compared to concrete without superplasticizers. This enhanced performance is attributed to the increased compactness of concrete when superplasticizers are included. Superplasticizers are recognized for reducing the water-to-cement ratio of concrete while simultaneously improving its workability. Tkaczewska <xref ref-type="bibr" rid="scirp.135632-22">
      [22]
     </xref> has suggested that as the water-to-cement ratio decreases, total porosity is also reduced, leading to an improved density of the concrete.</p>
    <table-wrap id="table2">
     <label>
      <xref ref-type="table" rid="table2">
       Table 2
      </xref></label>
     <caption>
      <title>
       <xref ref-type="bibr" rid="scirp.135632-"></xref>Table 2. Chloride permeability test <xref ref-type="bibr" rid="scirp.135632-2">
        [2]
       </xref>.</title>
     </caption>
     <table class="MsoTableGrid custom-table" border="0" cellspacing="0" cellpadding="0"> 
      <tr> 
       <td rowspan="2" class="acenter" width="32.06%">Concrete type<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td acenter" width="67.94%" colspan="3">Chloride permeability test (in Coulombs)<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="custom-bottom-td custom-top-td acenter" width="22.64%">90 days<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="22.64%">180 days<p style="text-align:center"></p></td> 
       <td class="custom-bottom-td custom-top-td acenter" width="22.66%">365 days<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="custom-top-td acenter" width="32.06%">NC<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="22.64%">7302.6<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="22.64%">2261.5<p style="text-align:center"></p></td> 
       <td class="custom-top-td acenter" width="22.66%">2730<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.06%">FA<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.64%">284.1<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.64%">526.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.66%">120<p style="text-align:center"></p></td> 
      </tr> 
      <tr> 
       <td class="acenter" width="32.06%">SP<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.64%">3030<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.64%">2332.5<p style="text-align:center"></p></td> 
       <td class="acenter" width="22.66%">2180<p style="text-align:center"></p></td> 
      </tr> 
     </table>
    </table-wrap>
   </sec>
  </sec><sec id="s5">
   <title>5. Conclusions and Recommendations</title>
   <p>While the use of superplasticizers (SPs) in concrete is well-established in the global north, there is a notable lack of awareness in the global south regarding their application in concrete works. This study provides a concise overview of the mechanical and durability properties of concrete with and without SPs. Mechanical properties such as compressive strength, flexural strength, and modulus of elasticity are covered, along with durability indicators like water sorptivity and chloride penetration using the rapid chloride permeability test.</p>
   <p>The overview underscores that the inclusion of SPs in concrete enhances both mechanical (compressive strength, flexural strength, and modulus of elasticity) and durability properties (water sorptivity and chloride penetration) compared to concrete without SPs.</p>
   <p>In the case of compressive and flexural strength, the superior performance of concrete with SPs is attributed to lower porosity resulting from reduced water content and increased denseness or compactness of the concrete. Regarding modulus of elasticity (MoE), the enhancement seen in SP-included concrete is linked to the improved interfacial transition zone (ITZ) between the paste and aggregates, leading to a stiffer and denser concrete matrix. These factors of denseness, concrete compactness, and low porosity are also key in explaining the improved performance of SP-included concrete compared to non-SP concretes.</p>
   <p>Given that the overview demonstrates the positive impact of SPs on the mechanical and durability properties of concrete, it is anticipated that this study will provide valuable information to building professionals, particularly in the global south, emphasizing the importance of incorporating SPs in concrete formulation.</p>
  </sec><sec id="s6">
   <title>Data Availability Statement</title>
   <p>The data that support the findings of this study are available from the corresponding author upon reasonable request.</p>
  </sec>
 </body><back>
  <ref-list>
   <title>References</title>
   <ref id="scirp.135632-ref1">
    <label>1</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Flatt, R.J. (1998) Analysis of Superplasticizers Used in Concrete. Analusis, 26, 28-34. &gt;https://doi.org/10.1051/analusis:199826020028 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref2">
    <label>2</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Ramachandran, D., George, R.P., Vishwakarma, V. and Kamachi Mudali, U. (2016) Strength and Durability Studies of Fly Ash Concrete in Sea Water Environments Compared with Normal and Superplasticizer Concrete. KSCE Journal of Civil Engineering, 21, 1282-1290. &gt;https://doi.org/10.1007/s12205-016-0272-4 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref3">
    <label>3</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Parra, C., Valcuende, M. and Gómez, F. (2011) Splitting Tensile Strength and Modulus of Elasticity of Self-Compacting Concrete. Construction and Building Materials, 25, 201-207. &gt;https://doi.org/10.1016/j.conbuildmat.2010.06.037 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref4">
    <label>4</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Aruntaş, H.Y., Cemalgil, S., Şimşek, O., Durmuş, G. and Erdal, M. (2008) Effects of Super Plasticizer and Curing Conditions on Properties of Concrete with and without Fiber. Materials Letters, 62, 3441-3443. &gt;https://doi.org/10.1016/j.matlet.2008.02.064 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref5">
    <label>5</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Mardani-Aghabaglou, A., Tuyan, M., Yılmaz, G., Arıöz, Ö. and Ramyar, K. (2013) Effect of Different Types of Superplasticizer on Fresh, Rheological and Strength Properties of Self-Consolidating Concrete. Construction and Building Materials, 47, 1020-1025. &gt;https://doi.org/10.1016/j.conbuildmat.2013.05.105 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref6">
    <label>6</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Devi, K., Aggarwal, P. and Saini, B. (2019) Admixtures Used in Self-Compacting Concrete: A Review. Iranian Journal of Science and Technology, Transactions of Civil Engineering, 44, 377-403. &gt;https://doi.org/10.1007/s40996-019-00244-4 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref7">
    <label>7</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Sathyan, D. and Anand, K.B. (2019) Influence of Superplasticizer Family on the Durability Characteristics of Fly Ash Incorporated Cement Concrete. Construction and Building Materials, 204, 864-874. &gt;https://doi.org/10.1016/j.conbuildmat.2019.01.171 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref8">
    <label>8</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Björnström, J. and Chandra, S. (2003) Effect of Superplasticizers on the Rheological Properties of Cements. Materials and Structures, 36, 685-692. &gt;https://doi.org/10.1007/bf02479503 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref9">
    <label>9</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Houst, Y.F., Bowen, P., Perche, F., Kauppi, A., Borget, P., Galmiche, L., et al. (2008) Design and Function of Novel Superplasticizers for More Durable High Performance Concrete (Superplast Project). Cement and Concrete Research, 38, 1197-1209.&gt;https://doi.org/10.1016/j.cemconres.2008.04.007 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref10">
    <label>10</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Kong, X., Zhang, Y. and Hou, S. (2013) Study on the Rheological Properties of Portland Cement Pastes with Polycarboxylate Superplasticizers. Rheologica Acta, 52, 707-718. &gt;https://doi.org/10.1007/s00397-013-0713-7 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref11">
    <label>11</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Stecher, J. and Plank, J. (2019) Novel Concrete Superplasticizers Based on Phosphate Esters. Cement and Concrete Research, 119, 36-43. &gt;https://doi.org/10.1016/j.cemconres.2019.01.006 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref12">
    <label>12</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Flatt, R. and Schober, I. (2012) Superplasticizers and the Rheology of Concrete. In: Roussel, N., Ed., Understanding the Rheology of Concrete, Elsevier, 144-208. &gt;https://doi.org/10.1533/9780857095282.2.144 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref13">
    <label>13</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Torres, A., Aguayo, F., Allena, S. and Ellis, M. (2019) The Effect of Various Superplasticizers on Ultra High Strength Concrete. In: Martirena-Hernandez, J.F., Alujas-Díaz, A. and Amador-Hernandez, M., Eds., Proceedings of the International Conference of Sustainable Production and Use of Cement and Concrete, Springer International Publishing, 167-173. &gt;https://doi.org/10.1007/978-3-030-22034-1_19 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref14">
    <label>14</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Matias, D., de Brito, J., Rosa, A. and Pedro, D. (2013) Mechanical Properties of Concrete Produced with Recycled Coarse Aggregates—Influence of the Use of Superplasticizers. Construction and Building Materials, 44, 101-109. &gt;https://doi.org/10.1016/j.conbuildmat.2013.03.011 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref15">
    <label>15</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Manomi, N., Sathyan, D. and Anand, K.B. (2018) Coupled Effect of Superplasticizer Dosage and Fly Ash Content on Strength and Durability of Concrete. Materials Today: Proceedings, 5, 24033-24042. &gt;https://doi.org/10.1016/j.matpr.2018.10.196 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref16">
    <label>16</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Cheah, C.B. and Ramli, M. (2013) The Engineering Properties of High Performance Concrete with HCWA-DSF Supplementary Binder. Construction and Building Materials, 40, 93-103. &gt;https://doi.org/10.1016/j.conbuildmat.2012.10.010 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref17">
    <label>17</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Arslan, H., Aytaç, U.S., Bilir, T. and Şen, Ş. (2019) The Synthesis of a New Chitosan Based Superplasticizer and Investigation of Its Effects on Concrete Properties. Construction and Building Materials, 204, 541-549. &gt;https://doi.org/10.1016/j.conbuildmat.2019.01.209 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref18">
    <label>18</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Bravo, M., de Brito, J., Evangelista, L. and Pacheco, J. (2017) Superplasticizer’s Efficiency on the Mechanical Properties of Recycled Aggregates Concrete: Influence of Recycled Aggregates Composition and Incorporation Ratio. Construction and Building Materials, 153, 129-138. &gt;https://doi.org/10.1016/j.conbuildmat.2017.07.103 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref19">
    <label>19</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Andrade Neto, J.d.S., de França, M.J.S., Amorim Júnior, N.S.d. and Ribeiro, D.V. (2021) Effects of Adding Sugarcane Bagasse Ash on the Properties and Durability of Concrete. Construction and Building Materials, 266, Article 120959. &gt;https://doi.org/10.1016/j.conbuildmat.2020.120959 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref20">
    <label>20</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Sardinha, M., de Brito, J. and Rodrigues, R. (2016) Durability Properties of Structural Concrete Containing Very Fine Aggregates of Marble Sludge. Construction and Building Materials, 119, 45-52. &gt;https://doi.org/10.1016/j.conbuildmat.2016.05.071 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref21">
    <label>21</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Pereira, P., Evangelista, L. and de Brito, J. (2012) The Effect of Superplasticisers on the Workability and Compressive Strength of Concrete Made with Fine Recycled Concrete Aggregates. Construction and Building Materials, 28, 722-729. &gt;https://doi.org/10.1016/j.conbuildmat.2011.10.050 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref22">
    <label>22</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Tkaczewska, E. (2014) Effect of the Superplasticizer Type on the Properties of the Fly Ash Blended Cement. Construction and Building Materials, 70, 388-393. &gt;https://doi.org/10.1016/j.conbuildmat.2014.07.096 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref23">
    <label>23</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Sha, F., Li, S., Liu, R., Li, Z. and Zhang, Q. (2018) Experimental Study on Performance of Cement-Based Grouts Admixed with Fly Ash, Bentonite, Superplasticizer and Water Glass. Construction and Building Materials, 161, 282-291. &gt;https://doi.org/10.1016/j.conbuildmat.2017.11.034 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref24">
    <label>24</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Al-Hussaini, O.M., AL-Baghdadi, W.H., Al-Labban, S.N. and Jabal, Q.A. (2020) Investigation the Properties of Waste Plastic Fiber Concrete Modified with HP-570 Super-Plasticizer. IOP Conference Series: Materials Science and Engineering, 978, Article 012026. &gt;https://doi.org/10.1088/1757-899x/978/1/012026 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref25">
    <label>25</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Pereira, P., Evangelista, L. and de Brito, J. (2012) The Effect of Superplasticizers on the Mechanical Performance of Concrete Made with Fine Recycled Concrete Aggregates. Cement and Concrete Composites, 34, 1044-1052. &gt;https://doi.org/10.1016/j.cemconcomp.2012.06.009 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref26">
    <label>26</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Alsalman, A., Dang, C.N., Prinz, G.S. and Hale, W.M. (2017) Evaluation of Modulus of Elasticity of Ultra-High Performance Concrete. Construction and Building Materials, 153, 918-928. &gt;https://doi.org/10.1016/j.conbuildmat.2017.07.158 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref27">
    <label>27</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     American Concrete Institute (ACI) (2014) Commentary on Building Code Requirements for Structural Concrete (ACI 318R-14). American Concrete Institute, 317 p.
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref28">
    <label>28</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     ACI Committee 363 (2010) Report on High-Strength Concrete (ACI 363R-10). ACI, 27 p.
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref29">
    <label>29</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Ma, J., Dehn, F., Tue, N.V., Orgasms, M. and Schmidt, D. (2004) Comparative Investigations on Ultra-High Performance Concrete with and without Coarse Aggregates. Proceedings of the 1st International Symposium on Ultra-High Performance Concrete, Kassel, 13-15 September 2004, 205-212.
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref30">
    <label>30</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Pal, P. (2019) Dynamic Poisson’s Ratio and Modulus of Elasticity of Pozzolana Portland Cement Concrete. International Journal of Engineering and Technology Innovation, 9, 131-144.
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref31">
    <label>31</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Popovic, J.S. (2008) A Study of Static and Dynamic Modulus of Elasticity of Concrete. 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref32">
    <label>32</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Noguchi, T., Tomosawa, F., Nemati, K.M., Chiaia, B.M. and Fantilli, A.P. (2009) A Practical Equation for Modulus of Elasticity of Concrete. ACI Structural Journal, 106, 690-696.
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref33">
    <label>33</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Zhu, W. (2005) Microstructure and Properties of Interfacial Transition Zone in SCC. SCC 2005-China—1st International Symposium on Design, Performance and Use of Self-Consolidating Concrete, Changsha, 26-28 May 2005, 319-327. 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref34">
    <label>34</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Patel, V. and Shah, N. (2016) Durability Study of M70 Grade Structural Concrete. Iranian Journal of Science and Technology, Transactions of Civil Engineering, 41, 241-248. &gt;https://doi.org/10.1007/s40996-016-0046-8 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref35">
    <label>35</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Najimi, M., Sobhani, J., Ahmadi, B. and Shekarchi, M. (2012) An Experimental Study on Durability Properties of Concrete Containing Zeolite as a Highly Reactive Natural Pozzolan. Construction and Building Materials, 35, 1023-1033. &gt;https://doi.org/10.1016/j.conbuildmat.2012.04.038 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref36">
    <label>36</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Law, D.W., Adam, A.A., Molyneaux, T.K., Patnaikuni, I. and Wardhono, A. (2014) Long Term Durability Properties of Class F Fly Ash Geopolymer Concrete. Materials and Structures, 48, 721-731. &gt;https://doi.org/10.1617/s11527-014-0268-9 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref37">
    <label>37</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Dhanya, S., Anand, K.B. and Mini, K.M. (2016) Experimental Study on Portland Pozzolana Cement-Superplasticiser Compatibility in Mortar. International Journal of Earth Science and Engineering, 9, 539-544. 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref38">
    <label>38</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Sujay, H.M., Nair, N.A., Sudarsana Rao, H. and Sairam, V. (2020) Experimental Study on Durability Characteristics of Composite Fiber Reinforced High-Performance Concrete Incorporating Nanosilica and Ultra Fine Fly Ash. Construction and Building Materials, 262, Article 120738. &gt;https://doi.org/10.1016/j.conbuildmat.2020.120738 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref39">
    <label>39</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Biskri, Y., Achoura, D., Chelghoum, N. and Mouret, M. (2017) Mechanical and Durability Characteristics of High Performance Concrete Containing Steel Slag and Crystalized Slag as Aggregates. Construction and Building Materials, 150, 167-178. &gt;https://doi.org/10.1016/j.conbuildmat.2017.05.083 
    </mixed-citation>
   </ref>
   <ref id="scirp.135632-ref40">
    <label>40</label>
    <mixed-citation publication-type="other" xlink:type="simple">
     Ramasamy, V. (2011) Compressive Strength and Durability Properties of Rice Husk Ash Concrete. KSCE Journal of Civil Engineering, 16, 93-102. &gt;https://doi.org/10.1007/s12205-012-0779-2
    </mixed-citation>
   </ref>
  </ref-list>
 </back>
</article>