This study focuses on exoscopic analyses of detrital zircon grains of Archean and Paleoproterozoic age, contained in the sediments from the Niamey Neoproterozoic sandstones (Niamey region), with a view to confirming the sediments sources already proposed (Kénéma-Man domain for Archean-age zircons and Baoulé Mossi domain for Paleoproterozoic-age zircons). Exoscopic analysis reveals that Archean zircon grains are more corroded, with rounded to sub-rounded shapes, while Paleoproterozoic zircon grains are less corroded and mostly angular in shape. The strong corrosion of Archean zircon grains, implying long-distance transport, is consistent with the remoteness of the Kenema-Man domain which are the source these sediments. The fact that the Paleoproterozoic zircon grains show little or no wear implies a proximal source of sediments, corresponding to the Baoulé Mossi domain.
In Niger, Niamey sandstones overlie unconformably the Paleoproterozoic terrains (Birimian schists and granites) of the southeastern edge of the West African Craton (WAC) [1] [2] . Classically, due to their stratigraphic position, they have been considered as equivalent to the sediments of the neighboring Taoudenni and Gourma basins to the north [3] [4] [5] , and of the Volta basin to the south [6] . However, few studies have been carried out on Niamey sandstones, so that their age and origin are still debated.
Radiometric data obtained in these sandstones indicate the presence of two classes of detrital zircons: on the one hand, Archean-age zircons (2588 ± 10 to 3392 ± 9 Ma) and, on the other, Paleoproterozoic zircons, with ages ranging from 1822 ± 9 to 2436 ± 17 Ma [7] . Correlations of these ages from the Niamey region with those terrains form other regions of the West African Craton indicate that the Archean Kénéma-Man and Paleoproterozoic Baoulé Mossi domains represent the sources, respectively, of Archean and Paleoproterozoic zircons from the Niamey sandstones [7] (Figure 1). However, Scanning Electron Microscope (SEM) shape analysis of these zircon grains has not been performed to verify these sediments sources.
The aim of this study is to confirm the sediments sources, already proposed (Kénéma-Man and Baoulé Mossi domains), that make up the Niamey sandstones, by analyzing zircon grains. Specifically, the aim is to:
- Analyze the shape and surface appearance of: Archean-age zircon grains on the one hand and Paleoproterozoic-age zircon grains, on the other;
- Match the results of these analyses with the proposed sediments sources (Kénéma-Man and Baoulé Mossi domains).
2. Location of the Niamey Neoproterozoic Sandstones
Niamey Neoproterozoic Sandstones, the subject of this study, are located in Southwestern Niger, between parallels 13˚28' and 13˚35' North latitude and meridians 02˚03' and 02˚12' East longitude (Figure 2). They are part of a set of Neoproterozoic deposits that outcrop discontinuously along the Eastern edge of the West African Craton and follow the Niger River valley [2] [7] [8] [9] [10] .
These Neoproterozoic deposits outcrop, from North to South, in the regions of: Firgoun (Firgoun sandstones), Gassa (Gassa sandstones), Niamey (Niamey sandstones) and Kirtachi-Tamou (Kirtachi sandstones) (Figure 2).
The Niamey Neoproterozoic Sandstones outcrop in two areas on either side of the Niger River [2] : Tondibia area (on the left bank of the Niger River) and Karey Gorou area (on the right bank of the Niger River) (Figure 3).
3. Geological Setting
Geologically, the Niamey region is part of the Niger Liptako province, which corresponds to the Northeastern edge of the Man Shield (Birimian domain of the Man Shield) [2] [8] [12] [13] [14] . The Liptako is bounded to the east by the Iullemmenden basin, to the north by the Gourma basin and to the southeast by the Volta basin (Figure 4). Two major geological units have been distinguished in the Niger Liptako province:
1) The Paleoproterozoic (Birimian) basement (2300 to 2000 Ma [15] ), outcropping over 2/3 of the region [8] [16] - [21] ;
3.1. Paleoproterozoic Basement Deposits of the Niger Liptako Province
The Paleoproterozoic basement of the Niger Liptako province consists of alternating greenstone belts and granitoid plutons (granitic massifs) [8] [15] [19] - [25] (Figure 4). The greenstone belts consist of metabasalts, amphibolites, ultramafic to mafic granitic rocks, often transformed into talcchists and chloritoschists,
sediments and metamorphosed volcano-sediments in the greenschist to amphibolite facies [8] [15] [20] [21] [23] [24] [25] . Granitoid plutons are composed mainly of granites, TTG (Tonalite-Trondhjemite-Granodiorite), diorites and quartz diorites, monzonite and locally syenite [8] [15] [16] [20] [21] [24] .
3.2. Neoproterozoic Deposits of the Niamey Sandstones
The lithostratigraphic column established in the Niamey sandstones comprises three lithofacies which are, from bottom to top: quartzite sandstones with hummocky cross stratification (HCS) structures, glauconitic quartzite sandstones and diamictites with faceted pebbles [1] [2] .
3.3. Oligocene Deposits of the Terminal Continental 3
The Terminal Continental deposits represent the upper terms of the Iullemmeden Basin [26] . This author defined three groups within this formation. These are, from bottom to top, the:
· Siderolithic of Ader Doutchi (Continental terminal 1 (Ct1));
· Sandy-clay with lignites (Continental terminal 2 (Ct2));
Continental terminal 3, the only Continental terminal unit to outcrop in the Niger Liptako [14] [27] [28] , is an Oligocene-age formation [29] essentially consisting of alternating clayey sandstones and ferruginous oolitic sandstones with indurated levels, more or less associated with termite tubules [14] [27] [28] . The Ct3 rests in gully unconformity on the Infracambrian deposits and/or in major unconformity on the Paleoproterozoic basement [2] [14] [27] [28] .
Quaternary deposits consist of alluvium, more or less reworked ferruginous lateritic deposits and dunes overlying Terminal Continental 3 or Paleoproterozoic basement [14] [26] [27] [28] [30] .
4. Methodology
The methodology implemented is based on Scanning Electron Microscope (Electron High Tension (EHT) = 20 kv; Work Distance (WD) = 14 mm; Signal = SE1; Magnification (Mag) = 550 X) shape and surface analyses of Archean (2588 ± 10 to 3392 ± 9 Ma [7] ) and Paleoproterozoic (1822 ± 9 to 2436 ± 17 Ma [7] ) detrital zircons from two samples (N1 and N2) of the Niamey sandstones (Figure 2). These detrital zircons were dated by the U-Pb method via the LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry) technique [7] . Radiometric dating was carried out at the “GeoPlasmaLab” laboratory of the Senckenberg Naturhistorische Sammlungen, Dresden (Germany) [7] . It should be noted that the LA-ICP-MS technique has great potential in the field of geochronology, notably due to its high sensitivities and high yields [31] [32] .
5. Results5.1. Exoscopic Analysis of Archean-Age Zircons from the Niamey Sandstones
Observed under the Scanning Electron Microscope, Archean-age zircon grains from Niamey sandstones are bluntly shiny, with rounded (Figure 5 (A), Figure 5 (C), Figure 5 (E)) to subrounded (Figure 5(B), Figure 5(D), Figure 5(F)) shapes, according to the morphoscopic classification established by [33] . According to [34] , roundness is the smoothing of crystal edges caused by abrasion. It is therefore an important parameter for estimating transport distance [33] . These morphoscopic features imply that Archean-age zircons from Niamey sandstones are of distant origin.
5.2. Exoscopic Analysis of Paleoproterozoic-Age Zircons from the Niamey Sandstones
Exoscopic analysis of Paleoproterozoic-age zircon grains from Niamey sandstones shows the predominance of angular shapes (Figures 6(A)-(F)). These features indicate a transport process involving proximity to the material source.
6. Discussion
Detrital zircon analysis is therefore a powerful tool for determining the likely sources of sediments deposited in sedimentary basins [35] [36] [37] [38] . Morphoscopic analysis of zircon grains from Niamey sandstones has enabled them to be classified into two categories:
1) corroded, rounded to subrounded, Archean-age zircon grains (between 2588 ± 10 and 3392 ± 9 Ma [7] );
2) lightly corroded, mostly angular, Paleoproterozoic-age zircon grains (between 1822 ± 9 and 2436 ± 17 Ma [7] ).
The strong corrosion of zircon grains in the first category, (predominantly rounded shapes), implies long-distance transport [33] [34] [38] . Indeed, according to [39] , the distribution of roundness gives a general idea about the distance of transport.
This result is consistent with the sediments source, the Kénéma-Man domain, proposed by [7] . According to these authors, these sediments originate from the very ancient Archean rocks of the Kénéma-Man domain, notably those of Ivory Coast and Guinea.
The fact that the zircon grains in the second category are little or not worn, due to their proximity to the material source [33] [34] [38] [39] , is also in agreement with the sediments source, the Liptako birimian terrains (Baoulé Mossi domain), proposed by [7] . Indeed, the Paleoproterozoic terrains are contiguous with the Niamey sandstones, for which they form the bedrock.
7. Conclusions
The exoscopic study of detrital zircons from Niamey sandstones enabled them to be classified into two categories:
- Archean-age zircon grains, rounded to subrounded in shape (corroded zircon grains);
Zircon grains in the first category (rounded shape) imply long-distance transport. This is consistent with the distant source of the sediments proposed (Archean domain of Kénéma-Man) in previous work.
Similarly, the shape of the Paleoproterozoic zircon grains (angular form) is in line with the proximal source of the sediments also proposed (Paleoproterozoic domain of Baoulé Mossi). In fact, the Paleoproterozoic terrains are contiguous with the Niamey sandstones, for which they form the bedrock.
Acknowledgements
The authors are deeply grateful to the anonymous reviewers for their constructive comments. The first author thanks the “PhD Geology UAM” for the collaboration.
Conflicts of Interest
The authors declare no conflicts of interest regarding the publication of this paper.
Cite this paper
Maharou, H.I., Idi Karimou, L., Amadou, D.A., Amadou, S.A.G., Sidibé, G. and Konaté, M. (2024) Exoscopy of Detrital Zircons from Niamey Neoproterozoic Sandstones (Eastern Edge of the West African Craton, Southwestern Niger): Interpretation of Detrital Sediments Provenance. Open Journal of Geology, 14, 617-628. https://doi.org/10.4236/ojg.2024.145026
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