<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">GM</journal-id><journal-title-group><journal-title>Geomaterials</journal-title></journal-title-group><issn pub-type="epub">2161-7538</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/gm.2024.141001</article-id><article-id pub-id-type="publisher-id">GM-130366</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Earth&amp;Environmental Sciences</subject></subj-group></article-categories><title-group><article-title>
 
 
  Shear Resistance of Siltous Sands Improved with &lt;i&gt;Bridelia&lt;/i&gt; Tannins
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sinko</surname><given-names>Banakinao</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Soviwadan</surname><given-names>Drovou</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Komlan</surname><given-names>Lolo</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kodjo</surname><given-names>Attipou</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Department of Civil Engineering, Polytechnic School of Lomé, University of Lomé, Lomé, Togo</addr-line></aff><aff id="aff2"><addr-line>Laboratory of Structure and Mechanic of Materials (LaS2M), University of Lomé, Lomé, Togo</addr-line></aff><pub-date pub-type="epub"><day>08</day><month>01</month><year>2024</year></pub-date><volume>14</volume><issue>01</issue><fpage>1</fpage><lpage>11</lpage><history><date date-type="received"><day>26,</day>	<month>October</month>	<year>2023</year></date><date date-type="rev-recd"><day>5,</day>	<month>January</month>	<year>2024</year>	</date><date date-type="accepted"><day>8,</day>	<month>January</month>	<year>2024</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  The ruin of several civil engineering works occurs due to shear rupture of the ground. When the stress is greater than the shear resistance, the internal friction angle and the cohesion of the soil loosen and rupture occurs. Cement and lime are often used to stabilize soils and improve soil strength. The costs and environmental problems of these technologies raise concerns and challenge researchers to innovate with clean, inexpensive materials, accessible to the most disadvantaged social classes. The question that this study seeks to answer is whether the binders derived from plant tannins, which also stabilize soils, improve the shear resistance of these soils. To do this, we determined for silty sand the shear parameters, notably the cohesion and the angle of internal friction in the non-stabilized state and when they are stabilized with the powder of the bark of the 
  <em>Bridelia</em> under different water states. The results show that the addition of 
  <em>Bridelia</em> powder to silty sand increases the cohesion of the soil by nearly 70.71% and the friction angle by 4.31%. But in unfavourable water conditions, the cohesion and internal friction angle of the silty sand material improved with 
  <em>Bridelia</em> bark powder drops drastically by nearly 81.56%. but does not dissolve completely as for the same material. When it is not stabilized. This information is an invaluable contribution in the search for solutions to increase the durability of earthen constructions by improving the water-repellent properties of soils.
 
</p></abstract><kwd-group><kwd>Silty Sand</kwd><kwd> &lt;i&gt;Bridelia&lt;/i&gt; Tannins</kwd><kwd> Shear Resistance</kwd><kwd> Cohesion</kwd><kwd> Angle of Friction</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Today more than ever, research on local materials, especially those of plant origin [<xref ref-type="bibr" rid="scirp.130366-ref1">1</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref2">2</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref3">3</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref4">4</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref5">5</xref>] gives us hope that we can decently build our habitation without ravaging the earth in search of ores to make cement or lime but better still the habitation can be built by restoring biodiversity by planting trees such as African locust bean, Bridelia, Indian tamarind, etc. [<xref ref-type="bibr" rid="scirp.130366-ref6">6</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref7">7</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref8">8</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref9">9</xref>] . From these plant species, we can extract tannins for various uses in buildings [<xref ref-type="bibr" rid="scirp.130366-ref10">10</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref11">11</xref>] .</p><p>A review of previous publications also shows that various tropical wood wastes have already been used in composites [<xref ref-type="bibr" rid="scirp.130366-ref12">12</xref>] and the thermal stability of their tannins has been studied for green adhesives [<xref ref-type="bibr" rid="scirp.130366-ref13">13</xref>] . Wood today is used as construction materials but also as packaging due to their advantages such as lightness, thermal insulation, fireproofing, sound insulation [<xref ref-type="bibr" rid="scirp.130366-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref16">16</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref17">17</xref>] . Various local materials are also used in traditional practice to protect the exterior facings of raw earth walls against bad weather and shocks [<xref ref-type="bibr" rid="scirp.130366-ref18">18</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref19">19</xref>] ; here again tannins are used. It is also worth noting that tannins have received renewed attention in recent decades for their use in several areas such as environmentally friendly biobased polymer materials [<xref ref-type="bibr" rid="scirp.130366-ref20">20</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref21">21</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref22">22</xref>] . Tannins are significantly involved in the distillation process of drinks such as brandy, whiskey, grappa, and cognac [<xref ref-type="bibr" rid="scirp.130366-ref23">23</xref>] . Their use as adhesives for wood has been known since the middle of the last century [<xref ref-type="bibr" rid="scirp.130366-ref24">24</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref25">25</xref>] , and their application for wood preservation is more recent [<xref ref-type="bibr" rid="scirp.130366-ref26">26</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref27">27</xref>] . Tannins have been suggested as alternatives to plastics and synthetic coatings [<xref ref-type="bibr" rid="scirp.130366-ref28">28</xref>] . Furan bioplastics have been successfully produced [<xref ref-type="bibr" rid="scirp.130366-ref29">29</xref>] . Over the last decade, other technical materials have been produced from tannins: insulating foams have been used in the construction of green buildings [<xref ref-type="bibr" rid="scirp.130366-ref30">30</xref>] [<xref ref-type="bibr" rid="scirp.130366-ref31">31</xref>] .</p><p>It is in the context of multiple characterizations and the use of tannins in several fields [<xref ref-type="bibr" rid="scirp.130366-ref32">32</xref>] , that the present study is located, which sets itself the objective of verifying the behavior of soil shear parameters: cohesion and angle of friction of silty sands enhanced with Bridelia tannins. To obtain samples of silty sand, they were characterized and then improved to an optimal rate of 12% Bridelia bark powder. The soil thus stabilized is tested with the rectilinear shear test to determine the cohesion and the angle of friction.</p></sec><sec id="s2"><title>2. Material and Methods</title><sec id="s2_1"><title>2.1. Test Material</title><p>The equipment used for the tests carried out are: Tares, AFNOR series sieves, an electric sieve, an electronic balance, a Casagrande cup, a groove tool, a smooth marble plate, an oven, a dryer, and the rectilinear shearing apparatus.</p></sec><sec id="s2_2"><title>2.2. Material Used</title><p>The soil used in this study is silty sand taken from Cacaveli at Lom&#233; in TOGO. The binder used is a tannic powder of the bark of Bridelia. To obtain this powder, we took the bark of Bridelia which underwent several operations which are: drying at 50˚C, sorted by hand to rid the bark of all foreign bodies, pounded with mortar to reduce the bark into smaller pieces, passed through a mill to grind. The powder obtained is sifted through a 1mm sieve. It is therefore this fine beam passing through a 1 mm sieve which served as a binder to be mixed with the soils to stabilize.</p></sec><sec id="s2_3"><title>2.3. Experimental Methodology</title><p>Four types of tests in particular: particle size analysis (NF P 94-056 standard), specific weight (NF P 94-054 standard), Atterberg limits (NF P 94-051 standard) were used to characterize the ground and the rectilinear shear test with the Casagrande box (Standard NF P 94-078), was used to determine the cohesion and the angle of internal friction. The soil was first stabilized by adding Bridelia bark powder at the optimal rate of 12%, we then obtained a sample of composite material ready for the shear test. This test first consists of reconstituting the soil by compaction following the methodology of the modified Proctor test. For each reconstituted sample, two series of test samples are taken from four shear boxes labeled 1 to 4. The first series is soaked in water for 1 hour, the second series is not soaked. We also take a third series but this time on the non-stabilized soil which will serve as a control. The four series taken are sheared under the same conditions by applying normal stresses of 0.0177 MPa, 0.0354 MPa, 0.0531 MPa and 0.0707 MPa respectively and the material is sheared according to standard NF P 94-078. The stresses and deformations during shearing are determined for each test.</p></sec></sec><sec id="s3"><title>3. Results and Discussion</title><sec id="s3_1"><title>3.1. Results</title><sec id="s3_1_1"><title>3.1.1. Soil Characterization Results</title><p>The results of the granulometry analysis tests are provided. The results contained in <xref ref-type="table" rid="table1">Table 1</xref> and the curve in <xref ref-type="fig" rid="fig1">Figure 1</xref> is the representation of the granulometry distribution of this soil. The liquid limit is 38.28% and the plasticity limit is 15.35%, the Proctor optimum dry density is 2.06 g/cm<sup>3</sup> and the Proctor optimum water content is 9.28%.</p></sec><sec id="s3_1_2"><title>3.1.2. Result of Shear Tests on Non-Stabilized and Unsoaked Silty Sand</title><p><xref ref-type="fig" rid="fig2">Figure 2</xref> gives the stresses and strains result obtained during the shear test of non-stabilized, non-soaked silty sand, for different load forces. <xref ref-type="table" rid="table2">Table 2</xref> gives the values of the shear stresses as a function of the normal stresses; these stresses made it possible to trace the intrinsic line in the Mohr plane of <xref ref-type="fig" rid="fig3">Figure 3</xref> which reflects the transition from the quasi-elastic state to the plastic state of the soil</p><table-wrap id="table1" ><label><xref ref-type="table" rid="table1">Table 1</xref></label><caption><title> Granulometry distribution</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Diameter (mm)</th><th align="center" valign="middle" >4</th><th align="center" valign="middle" >3.15</th><th align="center" valign="middle" >1</th><th align="center" valign="middle" >0.8</th><th align="center" valign="middle" >0.63</th><th align="center" valign="middle" >0.5</th><th align="center" valign="middle" >0.4</th></tr></thead><tr><td align="center" valign="middle" >Passers-by percentage</td><td align="center" valign="middle" >100</td><td align="center" valign="middle" >96.96</td><td align="center" valign="middle" >93.99</td><td align="center" valign="middle" >90.15</td><td align="center" valign="middle" >84.34</td><td align="center" valign="middle" >73.95</td><td align="center" valign="middle" >62.54</td></tr><tr><td align="center" valign="middle" >Diameter (mm)</td><td align="center" valign="middle" >0.315</td><td align="center" valign="middle" >0.25</td><td align="center" valign="middle" >0.20</td><td align="center" valign="middle" >0.16</td><td align="center" valign="middle" >0.125</td><td align="center" valign="middle" >0.10</td><td align="center" valign="middle" >0.08</td></tr><tr><td align="center" valign="middle" >Passers-by percentage</td><td align="center" valign="middle" >49.51</td><td align="center" valign="middle" >37.29</td><td align="center" valign="middle" >30.00</td><td align="center" valign="middle" >25.75</td><td align="center" valign="middle" >21.90</td><td align="center" valign="middle" >20.22</td><td align="center" valign="middle" >19.20</td></tr></tbody></table></table-wrap><table-wrap id="table2" ><label><xref ref-type="table" rid="table2">Table 2</xref></label><caption><title> Shear stresses as a function of normal stresses of non-stabilized and unsoaked silty sand</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Normal stress σ (MPa)</th><th align="center" valign="middle" >0.0177</th><th align="center" valign="middle" >0.0354</th><th align="center" valign="middle" >0.0531</th><th align="center" valign="middle" >0.0707</th></tr></thead><tr><td align="center" valign="middle" >Shear stress τ (MPa)</td><td align="center" valign="middle" >0.0426</td><td align="center" valign="middle" >0.0628</td><td align="center" valign="middle" >0.0815</td><td align="center" valign="middle" >0.01147</td></tr></tbody></table></table-wrap><p>and deduced cohesion which is 0.0165 MPa and the friction angle of 53.07˚.</p></sec><sec id="s3_1_3"><title>3.1.3. Result of Shear Tests on Non-Stabilized Silty Sand Soaked in Water</title><p>When the raw silty sand is soaked and sheared, zero cohesion and a friction angle of 54.64˚ were obtained. <xref ref-type="fig" rid="fig4">Figure 4</xref> gives the results of the stresses and strains, for different load forces, <xref ref-type="table" rid="table3">Table 3</xref> the values of the shear stresses as a function of</p><table-wrap id="table3" ><label><xref ref-type="table" rid="table3">Table 3</xref></label><caption><title> Shear stresses as a function of normal stresses of non-stabilized silty sand soaked in water</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Normal stress σ (MPa)</th><th align="center" valign="middle" >0.0177</th><th align="center" valign="middle" >0.0354</th><th align="center" valign="middle" >0.0531</th><th align="center" valign="middle" >0.0707</th></tr></thead><tr><td align="center" valign="middle" >Shear stress τ (MPa)</td><td align="center" valign="middle" >0.02619</td><td align="center" valign="middle" >0.04317</td><td align="center" valign="middle" >0.06865</td><td align="center" valign="middle" >0.10071</td></tr></tbody></table></table-wrap><p>the normal stresses, and <xref ref-type="fig" rid="fig5">Figure 5</xref> the intrinsic line of the sheared soil.</p></sec><sec id="s3_1_4"><title>3.1.4. Result of Shear Tests on Non-Stabilized Silty Sand Not Soaked in Water</title><p>The cohesion and friction angle obtained for the shear test of stabilized and unsoaked silty sand is 0.0282 MPa for cohesion and 55.63˚ for the friction angle. <xref ref-type="fig" rid="fig6">Figure 6</xref> gives the stresses and strains (for different load forces), <xref ref-type="table" rid="table4">Table 4</xref> the</p><table-wrap id="table4" ><label><xref ref-type="table" rid="table4">Table 4</xref></label><caption><title> Shear stresses as a function of normal stresses of stabilized silty sand non soaked in water</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Normal stress σ (MPa)</th><th align="center" valign="middle" >0.0177</th><th align="center" valign="middle" >0.0354</th><th align="center" valign="middle" >0.0431</th><th align="center" valign="middle" >0.0707</th></tr></thead><tr><td align="center" valign="middle" >Shear stress τ (MPa)</td><td align="center" valign="middle" >0.0426</td><td align="center" valign="middle" >0.0628</td><td align="center" valign="middle" >0.0815</td><td align="center" valign="middle" >0.01147</td></tr></tbody></table></table-wrap><p>values of the shear stresses as a function of the normal stresses, and <xref ref-type="fig" rid="fig7">Figure 7</xref> the intrinsic line of the sheared soil.</p></sec><sec id="s3_1_5"><title>3.1.5. Result of Shear Tests on Silty Sand Stabilized and Soaked in Water</title><p>The shear test of the silty sand stabilized and soaked in water gave cohesion of 0.0052 MPa and a friction angle of 53.40˚. <xref ref-type="fig" rid="fig8">Figure 8</xref> gives the stresses and strains. <xref ref-type="table" rid="table5">Table 5</xref> gives the values of the shear stresses as a function of the normal stresses. These stresses made it possible to draw the intrinsic line in <xref ref-type="fig" rid="fig9">Figure 9</xref>.</p></sec></sec><sec id="s3_2"><title>3.2. Results Analysis</title><p>To allow easy exploitation of the results of the shear tests of the material studied under different aspects, the results are summarized in <xref ref-type="table" rid="table6">Table 6</xref>. It can be seen from these results that when the soil is:</p><table-wrap id="table5" ><label><xref ref-type="table" rid="table5">Table 5</xref></label><caption><title> Shear stresses as a function of normal stresses of silty sand stabilized and soaked in water</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Normal stress σ (MPa)</th><th align="center" valign="middle" >0.0177</th><th align="center" valign="middle" >0.0354</th><th align="center" valign="middle" >0.0531</th><th align="center" valign="middle" >0.0707</th></tr></thead><tr><td align="center" valign="middle" >Shear stress τ (MPa)</td><td align="center" valign="middle" >0.03096</td><td align="center" valign="middle" >0.05017</td><td align="center" valign="middle" >0.07652</td><td align="center" valign="middle" >0.10151</td></tr></tbody></table></table-wrap><table-wrap id="table6" ><label><xref ref-type="table" rid="table6">Table 6</xref></label><caption><title> Shear test results summary</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Material condition</th><th align="center" valign="middle" >Raw silty sand</th><th align="center" valign="middle" >Soaked raw silty sand</th><th align="center" valign="middle" >Stabilized silty sand</th><th align="center" valign="middle" >Stabilized and soaked silty sand</th></tr></thead><tr><td align="center" valign="middle" >Cohesion (MPa)</td><td align="center" valign="middle" >0.0165</td><td align="center" valign="middle" >0</td><td align="center" valign="middle" >0.0282</td><td align="center" valign="middle" >0.0052</td></tr><tr><td align="center" valign="middle" >Friction angle (degree)</td><td align="center" valign="middle" >53.07</td><td align="center" valign="middle" >54.64</td><td align="center" valign="middle" >55.63</td><td align="center" valign="middle" >53.40</td></tr></tbody></table></table-wrap><p>&#183; Not stabilized, its cohesion is 0.0165 MPa and the angle of friction is 53.07˚, when it is soaked in water, the water acts and dissolves the cohesion which becomes zero, however the angle of friction increases and passes at 54.64.</p><p>&#183; Stabilized its cohesion is 0.0282 MPa. It increases by 70.71% compared to its non-stabilized state and the friction angle of 55.63˚, an increase of 4.31%. When the stabilized soil is soaked in water, the cohesion is 0.0052 MPa, a drop of nearly 81.56%. Stabilization makes the material more water-repellent.</p></sec></sec><sec id="s4"><title>4. Conclusion</title><p>This study aims to assess the influence of tannic powder of Bridelia bark on the behaviours of the shear parameters of the silty sand Bridelia bark powder composite material and to evaluate the durability of these parameters under the effect of water. Straight shear tests were carried out on the samples of non-stabilized silty sand, soaked non-stabilized silty sand, unsoaked stabilized silty sand, and stabilized and soaked silty sand. The results show that the cohesion and the friction angle of the silty sand-Bridelia bark composite material increase by nearly 70.71% for the cohesion and 4.31% for the friction angle. We also note that when this composite material is saturated with water, the cohesion drops by nearly 81.56%, but does not dissolve completely as for the same material when it is not stabilized. This information is crucial in the valorization of earth material since its durability discourages its use in the construction of buildings. In fact, in the long term, water dissolves the cohesion of the material and ends up demolishing the structure, but the present study informs us that the cohesion of the earth-powder composite material of the Bridelia bark does not disappear when the material is saturated. The composite material then becomes more water-repellent, this property is so sought after for soils in the construction of civil engineering works because for civil engineering water is the primary enemy of the soil and it is therefore necessary to find binders once in the soil increases the water-repellent properties of the soil. Further studies should focus on the use of this composite material in roadworks and dams.</p></sec><sec id="s5"><title>Conflicts of Interest</title><p>The authors declare no conflicts of interest regarding the publication of this paper.</p></sec><sec id="s6"><title>Cite this paper</title><p>Banakinao, S., Drovou, S., Lolo, K. and Attipou, K. (2024) Shear Resistance of Siltous Sands Improved with Bridelia Tannins. Geomaterials, 14, 1-11. https://doi.org/10.4236/gm.2024.141001</p></sec></body><back><ref-list><title>References</title><ref id="scirp.130366-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Abdullah, U.H., Pizzi, A., Zhou, X., Rode, K., Delmotte, L. and Mansouri, H.R. (2013) Mimosa Tannin Resins for Impregnated Paper Overlays. European Journal of Wood and Wood Products, 71, 153-162. https://doi.org/10.1007/s00107-012-0652-5</mixed-citation></ref><ref id="scirp.130366-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Basso, M.C., Giovando, S., Pizzi, A., Pasch, H., Pretorius, N., Delmotte, L. and Celzard, A. (2014) Flexible-Elastic Copolymerized Polyurethane-Tannin Foams. Journal of Applied Polymer Science, 131, Article 40499. https://doi.org/10.1002/app.40499</mixed-citation></ref><ref id="scirp.130366-ref3"><label>3</label><mixed-citation publication-type="other" xlink:type="simple">Banakinao, S., Tiem, S., Lolo, K., Koutsawa, Y. and Bedja, K.S. (2016) Dataset of the Use of Tannin of néré (Parkia-Biglobosa) as a Solution for the Sustainability of the Soil Constructions in West Africa. Data in Brief, 8, 474-483. https://doi.org/10.1016/j.dib.2016.05.072</mixed-citation></ref><ref id="scirp.130366-ref4"><label>4</label><mixed-citation publication-type="other" xlink:type="simple">Banakinao, S. (2016) Characterization and Modelling of the mechanical Behaviour of Heterogeneous Microstructures: Case of the Composite Material Soil—Pod of néré and Its Applications in Civil Constructions. Ph.D. Thesis, University of Lomé, Lomé.</mixed-citation></ref><ref id="scirp.130366-ref5"><label>5</label><mixed-citation publication-type="other" xlink:type="simple">Samah, O.D., Banakinao, S., Lolo, K. and Attipou, K. (2022) Development of Roofing Tiles Support Made from Bituminous Plywood. American Journal of Applied Sciences, 19, 99-104. https://doi.org/10.3844/ajassp.2022.99.104</mixed-citation></ref><ref id="scirp.130366-ref6"><label>6</label><mixed-citation publication-type="other" xlink:type="simple">Drovou, S., Pizzi, A., Lacoste, C., Zhang, J.Z., Abdulla, S. and El-Marzouki, F.M. (2015) Flavonoid Tannins Linked to Long Carbohydrate Chains MALDI-TOF Analysis of the Tannin Extract of the African Locust Bean Shells. Industrial Crops and Products, 67, 25-32. https://doi.org/10.1016/j.indcrop.2015.01.004</mixed-citation></ref><ref id="scirp.130366-ref7"><label>7</label><mixed-citation publication-type="other" xlink:type="simple">Kona&amp;#239;, N., Pizzi, A., Raidandi, D., Lagel, M.C., L’Hostis, C., Saidou, C., Hamido, A., Abdalla, S., Bahabri, F. and Ganash, A. (2015) Aningre (Aningeria spp.) Tannin Extract Characterization and Performance as an Adhesive Resin. Industrial Crops and Products, 77, 225-231. https://doi.org/10.1016/j.indcrop.2015.08.053</mixed-citation></ref><ref id="scirp.130366-ref8"><label>8</label><mixed-citation publication-type="other" xlink:type="simple">Drovou, S., Kassegne, K.A., Kadja, K., Koutsawa, Y. and Sanda, K. (2019) Effect of Granulometry and Binder Rate on Physical, Thermal and Mechanical Properties of Africa Antiaris (Antiaris africana) Sawdust Particleboard Made with African Locust Been Pod Husk (Parkia biglobosa) and Indian Tamarind (Pitecellobium dulce) Peel. Journal of the Indian Academy of Wood Science, 16, 94-102. https://doi.org/10.1007/s13196-019-00241-0</mixed-citation></ref><ref id="scirp.130366-ref9"><label>9</label><mixed-citation publication-type="other" xlink:type="simple">Drovou, S., Attipou, K., Kadja, K., Kassegne, K.A. and Sanda, K. (2022) Characterization of Particleboards of African Mahogany Sawdust Made with Tannic Powders of Bridelia and African Locust Bean Pods. European Journal of Wood and Wood Products, 80, 1175-1183. https://doi.org/10.1007/s00107-022-01825-3</mixed-citation></ref><ref id="scirp.130366-ref10"><label>10</label><mixed-citation publication-type="other" xlink:type="simple">Sorgo, B., Zerbo, I., Kéita, I., Dembele, C., Plea, M., Sol, V., Gomina, M. and Blancharrt, P. (2014) Strength and Creep Behaviours of Geomaterials for Building with Tannin Addition. Materials and Structures, 47, 937-946. https://doi.org/10.1617/s11527-013-0104-7</mixed-citation></ref><ref id="scirp.130366-ref11"><label>11</label><mixed-citation publication-type="book" xlink:type="simple">Banakinao, S., Tiem, S., Attipou, K. and Lolo, K. (2019) Shear Resistance of Soils Improuved with Tannins of néré pod. In: Adjallah, K., Birregah, B. and Abanda, H., Eds., Data-Driven Modeling for Sustainable Engineering, Springer, Cham, 259-265. https://doi.org/10.1007/978-3-030-13697-0_20</mixed-citation></ref><ref id="scirp.130366-ref12"><label>12</label><mixed-citation publication-type="other" xlink:type="simple">Safou-Tchiama, R., de Jéso, B., Akagah, A.G., Sèbe, G. and Pétraud, M. (2007) A Preliminary Survey of Theinterfacial Bonding of Some Tropical Hardwoods towards Succinic Anhydride and 2-Octen-1-yl Succinic Anhydridemolecules: Impact of Lignin and Carbohydrate Polymers Structure on the Chemical Reactivity. Industrial Cropsand Products, 26, 173-184. https://doi.org/10.1016/j.indcrop.2007.03.001</mixed-citation></ref><ref id="scirp.130366-ref13"><label>13</label><mixed-citation publication-type="other" xlink:type="simple">Engozogho Anris, S.P., Arsene, B.B.A., Marcia, V., Louis, D., Rodrigue, S.T. and Bertrand, C. (2019) Extractionand Characterization of Aucoumea klaineana Pierre (Okoume) Extractives. Journal of Renewable Materials, 7, 518-522. https://doi.org/10.32604/jrm.2019.04051</mixed-citation></ref><ref id="scirp.130366-ref14"><label>14</label><mixed-citation publication-type="other" xlink:type="simple">Kumar, D., Alam, M., Zou, P.X.W., Sanjayan, J.G. and Memon, R.A. (2020) Comparative Analysis of Building Insulation Material Properties and Performance. Renewable and Sustainable Energy Reviews, 131, Article ID: 110038. https://doi.org/10.1016/j.rser.2020.110038</mixed-citation></ref><ref id="scirp.130366-ref15"><label>15</label><mixed-citation publication-type="other" xlink:type="simple">Aditya, L., Mahlia, T., Rismanchi, B., Ng, H., Hasan, M., Metselaar, H., Muraza, O. and Aditiya, H. (2017) A Review on Insulation Materials for Energy Conservation in Buildings. Renewable and Sustainable Energy Reviews, 73, 1352-1365. https://doi.org/10.1016/j.rser.2017.02.034</mixed-citation></ref><ref id="scirp.130366-ref16"><label>16</label><mixed-citation publication-type="other" xlink:type="simple">Ramlee, N.A., Jawaid, M., Yamani, S.A.K., Zainudin, E.S. and Alamery, S. (2021) Effect of Surface Treatment on Mechanical, Physical and Morphological Properties of Oil Palm/Bagasse Fiber Reinforced Phenolic Hybrid Composites for Wall Thermal Insulation Application. Construction and Building Materials, 276, Article ID: 122239. https://doi.org/10.1016/j.conbuildmat.2020.122239</mixed-citation></ref><ref id="scirp.130366-ref17"><label>17</label><mixed-citation publication-type="other" xlink:type="simple">Ahmadzadeh, S., Nasirpour, A., Keramat, J., Hamdami, N., Behzad, T. and Desobry, S. (2015) Nanoporous Cellulose Nanocomposite Foams as High Insulated Food Packaging Materials. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 468, 201-210. https://doi.org/10.1016/j.colsurfa.2014.12.037</mixed-citation></ref><ref id="scirp.130366-ref18"><label>18</label><mixed-citation publication-type="other" xlink:type="simple">Bui, Q.B. (2008) Stabilité des structures en pisé: Durabilité, caractéristiques mécaniques. Ph.D. Thesis, University of Lyon, Lyon.</mixed-citation></ref><ref id="scirp.130366-ref19"><label>19</label><mixed-citation publication-type="other" xlink:type="simple">Anger, R. and Fontaine, L. (2009) Batir en terre: du grain de sable à l’architecture. Editions Belin, Cité des sciences et de l’industrie, Paris, 223 p.</mixed-citation></ref><ref id="scirp.130366-ref20"><label>20</label><mixed-citation publication-type="other" xlink:type="simple">Ogunye, F. and Boussabaine, H. (2002) Diagnosis of Assessment Methods for Weatherability of Stabilised Compressed Soil Blocks. Construction and Building Materials, 16, 163-172. https://doi.org/10.1016/S0950-0618(02)00004-1</mixed-citation></ref><ref id="scirp.130366-ref21"><label>21</label><mixed-citation publication-type="other" xlink:type="simple">Celzard, A., Tondi, G., Lacroix, D., Jeadel, G., Monod, B., Fierro, V. and Pizzi, A. (2012) Radiative Properties of Tannin-Based Glasslike, Carbon Foams. Carbon, 50, 4102-4113. https://doi.org/10.1016/j.carbon.2012.04.058</mixed-citation></ref><ref id="scirp.130366-ref22"><label>22</label><mixed-citation publication-type="other" xlink:type="simple">Kéita, I., Sorgo, B., Dembele, C., Plea, M., Zerbo, I., Guel, B., Ouedraogo, R., Gomina, M. and Blancharrt, P. (2014) Ageing of Clay and Clay-Tannin Geomaterials for Building. Construction and Building Materials, 61, 114-119. https://doi.org/10.1016/j.conbuildmat.2014.03.005</mixed-citation></ref><ref id="scirp.130366-ref23"><label>23</label><mixed-citation publication-type="other" xlink:type="simple">De Rosso, M., Marangon, M. and Flamini, R. (2020) Characterization of Ellagitannins and Oak Lactone Precursors in Oak Wood-Aged Grappa by High-Resolution Mass Spectrometry. Journal of Mass Spectrometry, 55, e4472. https://doi.org/10.1002/jms.4472</mixed-citation></ref><ref id="scirp.130366-ref24"><label>24</label><mixed-citation publication-type="other" xlink:type="simple">Pizzi, A. (1980) Tannin-Based Adhesives. Journal of Macromolecular Science, Part C, 18, 247-315. https://doi.org/10.1080/00222358008081043</mixed-citation></ref><ref id="scirp.130366-ref25"><label>25</label><mixed-citation publication-type="other" xlink:type="simple">Cesprini, E., &amp;#352;ket, P., Causin, V., Zanetti, M. and Tondi, G. (2021) Development of Quebracho (Schinopsis balansae) Tannin-Based Thermoset Resins. Polymers, 13, Article 4412. https://doi.org/10.3390/polym13244412</mixed-citation></ref><ref id="scirp.130366-ref26"><label>26</label><mixed-citation publication-type="other" xlink:type="simple">Tondi, G., Wieland, S., Wimmer, T., et al. (2012) Tannin-Boron Preservatives for Wood Buildings: Mechanical and Fire Properties. European Journal of Wood and Wood Products, 70, 689-696. https://doi.org/10.1007/s00107-012-0603-1</mixed-citation></ref><ref id="scirp.130366-ref27"><label>27</label><mixed-citation publication-type="other" xlink:type="simple">Sommerauer, L., Thevenon, M.F., Petutschnigg, A. and Tondi, G. (2019) Effect of Hardening Parameters of Wood Preservatives Based on Tannin Copolymers. Holzforschung, 73, 457-467. https://doi.org/10.1515/hf-2018-0130</mixed-citation></ref><ref id="scirp.130366-ref28"><label>28</label><mixed-citation publication-type="other" xlink:type="simple">Cesprini, E., Baccini, R., Urso, T., Zanetti, M. and Tondi, G. (2022) Quebracho-Based Wood Preservatives: Effect of Concentration and Hardener on Timber Properties. Coatings, 12, Article 568. https://doi.org/10.3390/coatings12050568</mixed-citation></ref><ref id="scirp.130366-ref29"><label>29</label><mixed-citation publication-type="other" xlink:type="simple">Li, X., Nicollin, A., Pizzi, A., et al. (2013) Natural Tannin-Furanic Thermosetting Moulding Plastics. RSC Advances, 3, 17732-17740. https://doi.org/10.1039/c3ra43095b</mixed-citation></ref><ref id="scirp.130366-ref30"><label>30</label><mixed-citation publication-type="other" xlink:type="simple">Tondi, G., Pizzi, A. and Olives, R. (2008) Natural Tannin-Based Rigid Foams as Insulation for Doors and Wall Panels. Maderas. Ciencia y tecnología, 10, 219-228. https://doi.org/10.4067/S0718-221X2008000300005</mixed-citation></ref><ref id="scirp.130366-ref31"><label>31</label><mixed-citation publication-type="other" xlink:type="simple">Tondi, G., Link, M., Kolbitsch, C., et al. (2016) Pilot Plant Up-Scaling of Tannin Foams. Industrial Crops and Products, 79, 211-218. https://doi.org/10.1016/j.indcrop.2015.11.013</mixed-citation></ref><ref id="scirp.130366-ref32"><label>32</label><mixed-citation publication-type="other" xlink:type="simple">Cesprini, E., Alberto, I., Giovando, S., et al. (2022) Chemical Characterization of Cherry (Prunus avium) Extract in Comparison with Commercial Mimosa and Chestnut Tannins. Wood Science and Technology, 56, 1455-1473. https://doi.org/10.1007/s00226-022-01401-1</mixed-citation></ref></ref-list></back></article>