The spectrophotometer, as the common instrument for analysis, is able to determine the absorption of the material to the monochromatic radiation, thus defining the content of the substance in the solution. Spectrophotometer is of high sensitivity and accuracy, which can simultaneously determine the contents of various substance components in the aqueous sample [10] . The specific experimental process is shown in Figure 1.

The sample is heated and dissolved in HCl and H₂O₂ in polytetrafluoroethylene autoclave, then transfer the mixture to oven and heat at 150˚C. Next, adding dibenzyl dithiooxamide (DbDO), KI and Vitamin C (Vc), measuring Pt and Pd contents with a double-wavelength spectrophotometer; KI, 2-mercaptobenzimidazole

(MBT) and TBP-CCl₄ are employed in order in the process of extraction separation Pt and Pd. The content of Rh in the sample solution is analyzed by extraction spectrophotometry with 2-mercaptobenzimidazole-SnBr₂ reagent.

Spectrophotometer is an advanced analysis instrument with excellent accuracy. Moreover, spectrophotometer testing is relatively inexpensive. However, the application of spectrophotometer requires consideration. For example, the testing process of the spectrometer involves the oxidation-reduction of chemical agents, which will definitely generate sewage. The disposal of the sewage is really cumbersome and expensive. Besides, the operation of spectrophotometer is difficult and the concentration of the sample to be measured is determined by the actual situation, proficient use requires extensive training and practice. Therefore, it is necessary to comprehensive consider whether spectrophotometer is indispensable based on actual needs.

AAS can also quantify precious metal content in sample. The ground state atomic vapor of the pilot sample will absorb the characteristic radiation emitted by the illuminant. The characteristic spectral line intensity weakened after being absorbed by the pilot sample, the decline degree of spectra intensity is defined as absorbance (A), the absorbance is proportional to the content of the pilot element, which law follows the Equation:

A = K C

K represents a constant, and C is the concentration of the sample solution. Various elements with different atomic structures and outer electrons arrangement will adsorb energy when migrating from the ground state to the first excited state, the resonance absorption lines of each element present different characteristics. The law provides elements qualitative basis, and the intensity of absorbed radiation is defined as quantification basis.

The methods of AAS are divided into the atomic absorption flame method and the atomic absorption graphite furnace method. The atomic absorption flame method can identify the sample concentration at ppm level. As shown in Figure 2, with the high temperature of flame, the molecules in the sample convert into atoms, the content of the sample is confirmed by measuring the absorption degree of specific wavelengths of light. The flame atomic absorption method is easy to operate and relatively inexpensive, which is suitable for large number samples rapid analysis. But the flame atomic absorption method is slightly inferior in sensitivity and accuracy, compared to the graphite furnace atomic absorption method.

The atomic absorption graphite furnace method can discern the sample concentration at the ppb level. Different from the atomic absorption flame method, during atomic absorption graphite furnace method process, the sample is first dissolved and sprayed into graphite tube, dried and pyrolyzed at high temperature. Then, the element content is measured by quantifying the absorption of the light with a specific wavelength. Compared to other methods, AAS has the superiority of high detection sensitivity and high accuracy, which is suitable for quantitative analysis [11] [12] . However, its application is hindered by difficult operations and expensive costs. Besides, AAS requires not less than 10 ml of non-toxic sample, and the mutual interference between precious metal elements cannot be ignored. Buffer agents are usually added to overcome the impact caused by metal ions. AAS has become the most widely application for Pt, Pd and Rh quantitative analysis, which show the ability to analyze trace components on precious metal content in catalyst samples.

As a precision instrument, ICP has been reported in numerous articles and standards on measuring the content of precious metals in converter or alloy. The ICP method is composed of the inductively coupled plasma atomic emission spectrometry (ICP-OES) method and inductively coupled plasma atomic emission mass spectrometry (ICP-MS) method, both of their tests rely on the generated inductively coupled plasma [13] [14] .

XRF is one of the most convenient instruments for conducting elemental analysis, which works by the interaction between X-rays and substances [15] . When the light source illuminates, the high-energy rays react with atoms. If the energy exceeds or equals the binding energy of electrons in atom orbital, electrons in the orbital are expelled and form holes, which leads the atom state to become unstable. As a result, the outer electrons of the orbit are removed from the holes, ensuring the atom is back in a stable state. During the outer electrons transition process, the energy difference between shells is emitted in the form of X-rays, generating the characteristic X-ray fluorescence. The fluorescence X-rays of various elements present specific wavelengths, and the composition of the elements is determined based on the fluorescence captured by the detector (Figure 4).

In addition to qualitative analysis, XRF performs quantitative analysis with reliable reference material. The quantitative methods of XRF include standard curve method, incremental method, internal standard method, etc. However, no matter which method is employed, we all need to use a standard sample to determine the standard curve. Furthermore, the compositions of the standard sample and the sample to be tested should at similar concentration level. XRF is non-destructive testing, which can analyze the content of multiple elements simultaneously [16] . XRF can perform the sample with a concentration above 1 mg/kg. However, XRF has certain shortcomings. XRF can only analyze the surface layer of the sample. For the samples with higher thickness, surface treatment or cutting is

required. Besides, the samples should be flat and uniform, which is favorable to X-ray irradiation and fluorescence signal reception.

With the merits of technology, the detection accuracy of instruments greatly improved. More and more methods can be used to detect the content of precious metals Pt, Pd and Rh in catalytic converters. For example, oscillographic polarography can also measure Pt, Pd and Rh after calibrating the standard curve. In practical applications, selecting the appropriate method under appropriate conditions is the key to accurate detection.