pXRF contamination is assessed by using the supplied fused silica disc to check the cleanliness of the analyser window. The analyser should only report silica (SiO₂) which is contained in the fused disc. The presence of other elements implies contamination of the analyser window with dust from the measurement environment. The contamination check is conducted on a daily basis.

A total of 11 analyses on 15^th October 2022 were conducted on the silicon blank during the Mansala Auger pXRF programme. A plot of the readings as in Figure 2 shows constant values measured during the day signifying.

· No loss in beam voltage

· No drift in measure values.

· Good filtering of X-rays emissions by the polypropylene film.

Accuracy is a measure of how close the measured value is to the true value and is influenced by the quality of reference standard used in the calibration, the calibration procedure, and the duration of the measurement [5] . pXRF accuracy is assessed by measuring elements of interest in a certified reference material (CRM) that has been assayed repeatedly by the lab supplying the material. Alternatively, a NIST check standard sample supplied with the pXRF analyser may be used. Nearness of the pXRF data to the approved value for each element provides a measure of the instrument’s accuracy. Measured values which fall within ±20% of the standard value are considered acceptable. Accuracy checks are conducted on a daily basis and will detect malfunctions of the pXRF instrument.

A total of 11 analyses were conducted on NIST 2711A for the Mansala Auger pXRF programme on 15^th October 2022. Accepted values for As and Cu in NIST 2711A are 107 ppm and 140 ppm, respectively. Values for arsenic (As) and copper (Cu) as measured by an Olympus Vanta C-Series pXRF analyser are plotted in Figure 3 and Figure 4 respectively. The figures also contain two additional traces which define the extent of acceptable values measured by this pXRF

instrument (i.e. ±20%).

Figure 3 shows:

· All values plotted above the As value in the standard, NIST 2711A;

· No value fell above the maximum acceptable As value by 20%;

· No values fell below the minimum acceptable As value by 20%.

Figure 4 shows:

· All values plotted above the Cu value in the standard, NIST 2711A;

· No value fell above the maximum acceptable Cu value by 20%;

· No values fell below the minimum acceptable Cu value by 20%.

Precision is a measure of how close repeat measurements are to one another and is influenced by statistical nature of the x-ray tube emission process, statistical nature of the sample’s x-ray absorption/emission process, statistical nature of detection process and unpredictable variations in substrate or matrix effects [5] . pXRF precision is assessed by calculating the Relative Standard Deviation (RSD) of the replicate measurements for the analytes. The RSD values should be less than 20% for most analytes, except chromium, for which the value should be less than 30% (Anon, No date). The smaller the RSD, the better the precision. pXRF precision determines the stability of the analyser in terms of measurement repeatability by doing multiple readings on a particular sample and looking at the variability of the data. Precision check is conducted on a daily basis with a different sample.

A total of 20 repeated analyses were conducted on 4 samples, 5 analyses per sample, for the entire Polymetals Mansala Auger pXRF programme on four (4) different days. A plot of the readings for Arsenic (As), Copper (Cu) and Lead (Pb) as in Figure 5 indicates a very good repeatability signifying a good stability of the pXRF analyser.

Pathfinder elements provide a means to evaluate large areas for their mineral potential by eliminating likely barren areas from the areas under consideration during exploration studies [6] . Nude et al., in their gold exploration studies in the Wa-Lawra Belt, Northwest Ghana, using a multivariate statistical approach, found that Fe and Mn are strongly associated with gold, and alongside Pb, Ag, As, and Cu, these elements could be used as pathfinders for gold in the area, with ferruginous zones as targets [7] .

With all QA/QC protocols being satisfied and generating fit for purpose data, the Mansala auger pXRF data is used to determine gold (Au) pathfinder elements(s) on the Mansala permit. Since the Mansala property lies in the Siguiri basin with expectation of a typical Orogenic gold deposit, Orogenic gold deposits

geochemical signatures including sulphur (S), copper (Cu), zinc (Zn), arsenic (As), molybdenum (Mo), antimony (Sb), tungsten (W), mercury (Hg) and Lead (Pb) were used in the analysis.

Summary statistics as in Table 1, shows As, Cu, Pb, and Zn are likely to be abundantly available on the Mansala property as these elements were detected in almost all the 130 auger samples. S and Mo are likely to be moderately present on the Mansala property whiles W, Hg and Sb are likely to be less present on the Mansala property as these elements were not detected in most of the 130 samples

used for the analysis. Correlation analysis using both log transformation and power transformation of the data as shown in Table 2 and Table 3 respectively, shows arsenic (As) to moderately correlate with gold (Au) whiles Sulphur (S) and Molybdenum (Mo) weakly correlate with Au.

Correlation analysis from the initial 130 auger samples identified arsenic as good gold (Au) pathfinder on the Mansala property. With this in mind, a soil sampling programme consisting of 500 soil samples on 12 crosslines on a 100 × 25 m grid system was initiated to delineate arsenic (As) trends at the most prospective area of the Mansala property for further exploration works. The samples collected were subjected to the pXRF QA/QC protocols instituted to generate fit for purpose data. The samples were dried, pulverised and transferred to pXRF sample cups covered with polypropylene films.

pXRF measurements were undertaken on the 500 samples taking into consideration optimum sample preparation, energy calibration checks and optimum testing time. Contamination, precision, and accuracy checks were done to ensure the generation of fit for purpose results to delineate the arsenic (As) trends for further exploration works.

Arsenic (As), the main pathfinder element of interest, has 7 ppm and 2004 ppm as minimum and maximum values respectively as shown in Table 4. Threshold determination using the boxplot, cumulative distribution, [median ± 2 MAD] and [mean ± 2sdev) gave 100, 78, 80 and 487 respectively. Since statistical analysis using the boxplot is best for identifying geochemical data outliers, the threshold value from the boxplot was used for the class boundaries (0 - 100, 100 - 200, 200 - 300, 300 - 400, >400) for plotting and delineation of the arsenic trends.

Figure 6 shows delineated Arsenic (As) trend from the soil sampling programme superimposed on auger and pit samples and geophysical structures delineated from the aeromagnetic survey. Interpretation of the pXRF soils sampling results, delineated Arsenic (As) trend coincident with the delineated NNE trend from the pits and auger samples. Discrete Arsenic (As) anomalies also occur at the west of the main NNE trend. The delineated Arsenic (As) trends are open to the North and South. The Arsenic (As) trends also confirm the high prospectivity of the area sampled that is already delineated by the pit sampling, auger drilling and aeromagnetic survey.