With the increase of energy price, the retrofitting of existing buildings with innovative insulation materials remains a key issue. Although a variety of insulation materials there is always a need for the development of new materials with improved thermophysical properties and low cost. Inorganic polymer materials are promising from this point of view. They are incombustible combining excellent physical and thermal properties with low production cost and significant environmental benefits. In this work, insulation materials with low density are produced with a low cost process and utilizing two different raw materials an industrial mineral and an industrial waste. In this paper, insulation materials with low density were produced with a low cost process utilizing two different raw materials: an industrial mineral and an industrial waste. The results indicated the potential of the application as insulation materials in the construction sector.
Although, the European citizens are becoming increasingly familiar with the concept of energy in use, that is the energy required by the occupants of an existing building, primarily for space heating, water heating and lighting, and of the need to reduce it, they have not realized yet that energy is needed not only to run a building but it also takes considerable amount of energy to create the building products and the building itself. The embodied energy of a building, defined as the total energy required to produce the building components, transport them in place and construct the building, is a significant component of its lifecycle impact and can be the equivalent of many years of operational energy. An average household contains about 1000 GJ of energy embodied in the materials used in its construction, which is equivalent to about 15 years of operational energy consumption. Moreover, it is important to point out that when increasing the level of energy performance of buildings in operation, which is the current trend in the construction of new buildings dictated by many EC (EPBD 2010/31/EU) and member state directives, the embodied energy of the building materials represents a much higher percentage of the energy spent in the whole life cycle of the building. In modern times, one of the main goals in the construction industry is to increase energy efficiency by reducing energy losses, due to the high cost of cooling and heating a building. According to a study carried out in the 27 member states of the European Union, the high percentage of energy consumption in the last twenty years (250 - 300 Mtoe) is attributed to the requirements of the buildings for heating, cooling and ventilation due to their insufficient thermal insulation.
Conventional thermal insulation materials are divided into three subcategories: lightweight concrete (Aerated Concrete) based on cement, cellular concrete produced in autoclave (Autoclaved Aerated Concrete-AAC) also based on cement and organic thermal insulation materials (extruded polystyrene-XPS (DOW), expanded polystyrene-EPS and polyurethane foam). These materials are generally of high cost, including the cost of transportation to the construction site, as a result of which they are not preferred by manufacturers and consumers, and secondly, most of them are organic based, as a result of which they not only burn and decay in case of fire, but also propagate fire to the rest area of the building. A fire in a structure is an event which can have tragic consequences including loss of life, injuries, economic damage and environmental pollution. According to the statistics of the Greek Fire Service, the incidents of fires in building facilities for the year 2017 amounted to more than 3000. At this point, the case of the fire in Eastern Attica, which resulted in more than 100 victims, should be mentioned with 2500 destroyed houses. The severity of the effects of the fire is of the utmost importance also in terms of the structural body, mainly due to the risk of loss of stability and collapse of the bearing body but also due to the financial burden caused by the interventions, reinforcements after the fire.
The search for solutions to reduce and potentially restore the problems caused by a fire, leads to the development of new porous, fire-resistant, thermal insulation materials that reduce energy consumption in buildings and protect them from fire.
The geopolymerization technology [
This work aims at demonstrating the insulation properties of inorganic polymeric materials for their application as insulation materials on buildings which achieve low density and thermal conductivity (0.06 - 0.07 W/mK) with satisfactory mechanical properties.
The slag used in the present study was provided by the metallurgical plant of the Greek company LARCO G.M.M.S.A. that treats laterites to produce ferronickel. The slag is generated during the reductive smelting of laterites in electric arc furnaces and is granulated using a flash water cooling process. For the synthesis of inorganic polymers, an adequate quantity of granulated slag was grinded to −100 μm and the resulted powder had a mean particle size (d50) of 15.05 μm measured on a MALVERN Laser Particle Size Analyzer. The chemical analysis of the slag (
| Species | % w/w |
|---|---|
| SiO2 | 41.14 |
| Al2O3 | 13.79 |
| FeO | 34.74 |
| Cr2O3 | 5.41 |
| MgO | 3.59 |
| CaO | 0.71 |
| Ni | 0.14 |
method on a SIEMENS D 5000 diffractometer is shown in
The metakaolin that was used in this study was provided from AGS Mineraux, a member of Imerys Minerals. Metakaolin had a mean particle size (d50) of 13.68 μm measured on a MALVERN Laser Particle Size Analyzer. As is shown in
Also, pure silicon dioxide (particle size < 64 μm) provided by Sigma Aldrich
| Species | % w/w |
|---|---|
| SiO2 | 52.66 |
| Al2O3 | 40.97 |
| FeO | 1.83 |
| K2O | 1.18 |
| TiO2 | 1.43 |
| Na2O | 0.71 |
was used for the synthesis of metakaolin geopolymer. (
2H2O2 → 2H2O + O2 (1)
Inorganic polymers were prepared according to the following procedure (
A homogeneous viscous paste was initially prepared by mixing mechanically the solid materials with sodium hydroxide solution at a solid to liquid ratio equal to 4 g/mL. Then the foaming agent was added in the paste, under high speed mixing and then was casted in appropriate open plastic (ERTACETAL®) moulds
and cured at ambient temperature for 48 hours. After curing, the specimens were de-moulded and the mechanical and thermophysical properties of materials were measured through a set of tests.
The geopolymer properties studied in this work include density measurement, uniaxial compressive strength and thermal conductivity. Compressive strength was measured using cubic specimens with dimensions 50 × 50 × 50 mm. The thermal properties of the geopolymer were assessed through its thermal conductivity, which was measured according to EN 12667:2001 on a 15 × 15 × 2 cm specimen.
Initially the foaming process was evaluated utilizing metakaolin as the main raw material. On this purpose the alkalinity of the solution was investigated in order to evaluate the effect on the foaming process. Three different alkalinities of sodium hydroxide were investigated (2 M, 4 M and 8 M) with a range of hydrogen peroxide 0.05% - 1% w/w to the solid mass. The solid to liquid ratio used was 4.0 g/ml which was the optimum for the foaming of the materials.
The results shown in
The same procedure was followed also for the case of the slag as raw material. The results (
Based on this data there was no sense to investigate further materials utilizing exclusively slag since the density would be high and too far from our target for insulation materials (around 350 - 450 Kg/m3).
For both cases of raw materials, increase in the percentage of hydrogen peroxide did not provide materials with lower density, since the higher amount created more and larger bubbles and voids which were not stable and collapsed, thus the developed materials had finally higher density from the ones presented above.
In order to achieve lower density and thus lower thermal conductivity, a surfactant was added, assisting in maintain the voids and bubbles in the polymeric gel, preventing them from collapsing and thus creating more porous and homogenous materials. For this purpose, Hostapur OSB surfactant was used, which is a high foaming primary surfactant (anionic wetting and air entraining agent based on Alpha-olefin sulfonate, sodium salt). As it can be shown from
specimen was 650 kg/m3 while in the right picture (specimen with the surfactant), the density of the cured material reached 450 kg/m3. The latter specimen reached a thermal conductivity value of 0.078 W/mK.
The summary of the analysis of the effect of the surfactant addition, is presented in
The last step of the analysis was to investigate the addition of slag in the synthesis which for sure would reduce the final cost of the material due to the fact that the slag is an industrial waste facing deposit problems. On this purpose the substitution of metakaolin with slag was investigated for two different percentages, 25% (
As it can be shown from
results to a decrease of the compressive strength. The optimum synthesis with the lower density reaches a compressive strength of 1.5 MPa which on the first side seems low but it should be taken into consideration that the specific material will not load bearing capacity and will only be applied as superficial material or facade/insulating material.
During the specific research inorganic polymers for applications as insulation materials were developed utilizing both an industrial mineral (metakaolin) and an industrial waste (metallurgical slag from the treatment of laterite ores). The research showed the following results:
・ Both raw materials can be foamed utilizing hydrogen peroxide as a foaming agent.
・ The alkalinity of the aqueous phase has a light effect on the foaming process of the geopolymers while at the same time the lower alkalinity results to lower density materials.
・ The materials utilized slag as raw material reach higher density comparing the ones with metakaolin which is attributed to the higher bulk density of the raw materials.
・ The lower achieved density with hydrogen peroxide and metakaolin as raw material was 450 kg/m3 which was improved by adding a surfactant which maintained the bubbles stable without collapsing phenomena.
・ The substitution of 25% of metakaolin with slag on the upper synthesis improved further the density of the final material to 400 Kg/m3.
This research has received funding from the Operational Program “Competitiveness, Entrepreneurship & Innovation” (EPAnEK) and the Regional Operational Program of the Partnership and Cooperation Agreement (NSRF) for the period 2014-2020.
The authors declare no conflicts of interest.
Sakkas, K.M., Georgopoulos, C., Krimatoglou, L., Krimatoglou, N. (2023) Innovative Inorganic Insulation Materials (Mineral Slag Based Geopolymers). Open Access Library Journal, 10: e9259. https://doi.org/10.4236/oalib.1109259