<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">IJG</journal-id><journal-title-group><journal-title>International Journal of Geosciences</journal-title></journal-title-group><issn pub-type="epub">2156-8359</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/ijg.2022.138032</article-id><article-id pub-id-type="publisher-id">IJG-119001</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Earth&amp;Environmental Sciences</subject></subj-group></article-categories><title-group><article-title>
 
 
  Geochronological Constraints for Boundary Shear Zones between Eastern Ghats Province and Bastar Craton: Implication for the Formation of Granulites and Their Exhumation History
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rajib</surname><given-names>Kar</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Miguel</surname><given-names>Angelo Stipp Basei</given-names></name><xref ref-type="aff" rid="aff2"><sup>2</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Samarendra</surname><given-names>Bhattacharya</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Anwesha</surname><given-names>Ghosh</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sanchari</surname><given-names>Chatterjee</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff2"><addr-line>Geoscience Institute, Sao Paulo University, Sao Paulo, Brazil</addr-line></aff><aff id="aff1"><addr-line>Department of Geology, University of Calcutta, Kolkata, India</addr-line></aff><pub-date pub-type="epub"><day>03</day><month>08</month><year>2022</year></pub-date><volume>13</volume><issue>08</issue><fpage>593</fpage><lpage>608</lpage><history><date date-type="received"><day>22,</day>	<month>June</month>	<year>2022</year></date><date date-type="rev-recd"><day>31,</day>	<month>July</month>	<year>2022</year>	</date><date date-type="accepted"><day>3,</day>	<month>August</month>	<year>2022</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  Shear zones in the boundary between Eastern Ghats Province (EGP) and the cratons of Singhbhum in the north and Bastar in the west provide an excel
  lent opportunity to study the tectonics of shear zone development and its
   timing in relation to the evolutionary history of the granulite suites. Detailed structural, microfabric and quartz C-axis patterns revealed a high tempera
  ture shear zone, at the western boundary between EGP and Bastar Craton 
  (BC) around Paikmal. Petrological studies in this shear zone indicated decompression coeval with stretching in the sheared granulites. Geochronological constraints provided here indicate rapid exhumation of deep seated granulites in this boundary shear zone; the timing also is late in relation to the long-lived thermal (granulite formation) event in the EGP. Additionally, our geochronological data demonstrated the ~1600 Ma event in the Eastern Ghats Belt 
  (EGB) involving sedimentation, magmatism, metamorphism and crustal
   anatexis, as a significant world event.
 
</p></abstract><kwd-group><kwd>Shear Zone</kwd><kwd> Extrusion Tectonics</kwd><kwd> Exhumation</kwd><kwd> Eastern Ghats Province</kwd><kwd> Geochronology</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>Worldwide shield areas are characterized by occurrence of Precambrian crust with contrasting tectonic units: Archaean cratonic blocks usually made up of granite-greenstone terrains surrounded by Proterozoic mobile belts have a history of preservation of rocks with high-strain and high-grade metamorphism [<xref ref-type="bibr" rid="scirp.119001-ref1">1</xref>] . Kaapvaal Craton-Limpopo Belt of African Shield, Pilbara Craton-Capricorn Belt of Australian Shield and Superior Craton-Kapuskasing Belt of Canadian Shield are the global examples. Dharwar Craton-Pandyan Belt, Mewar Craton-Aravalli Belt, Singhbhum Craton-Eastern Ghats Belt are Indian examples [<xref ref-type="bibr" rid="scirp.119001-ref2">2</xref>] . To understand the evolution of such contrasting crustal pairs, it is important to focus on the boundary areas [<xref ref-type="bibr" rid="scirp.119001-ref3">3</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref4">4</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref5">5</xref>] .</p><p>From the boundary between Bastar Craton (BC) and Eastern Ghats Province (EGP), around Paikmal, [<xref ref-type="bibr" rid="scirp.119001-ref6">6</xref>] described decompressive reaction textures in the granulitic rocks of boundary shear zone that could relate to exhumation of deep crustal granulites during shearing. Although reaction textures indicative of decompression have been described from several internal segments of the Eastern Ghats Belt (EGB) [<xref ref-type="bibr" rid="scirp.119001-ref7">7</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref8">8</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref9">9</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref10">10</xref>] , the kinematics of exhumation in these segments are not well understood. From one internal segment, around Paderu, [<xref ref-type="bibr" rid="scirp.119001-ref11">11</xref>] provided isotopic evidence of partial exhumation (10 to 8 kbar) in about 100 million years. [<xref ref-type="bibr" rid="scirp.119001-ref12">12</xref>] proposed that weak marginal zones, marked by extensional faults or shear zones, should provide evidence of rapid exhumation, compared to the much more slowly uplifted rocks of the core of the thickened mountain belt. In view of the high-temperature shear zone and reaction textures indicative of decompression during shearing, described from the northwestern margin around Paikmal, isotopic data from this domain may attest to the rapid exhumation. In this communication we present isotopic data, using multiple systematics, on rocks both from the EGP and adjoining BC. These may shed new light on the evolution of contrasting crustal pairs.</p></sec><sec id="s2"><title>2. Geological Setting</title><sec id="s2_1"><title>2.1. Eastern Ghats Belt</title><p>Presently it is believed that the EGB is a collage of several provinces/domains having distinctive geological histories [<xref ref-type="bibr" rid="scirp.119001-ref13">13</xref>] . The provinces/domains are said to be separated by structural discontinuities (<xref ref-type="fig" rid="fig1">Figure 1</xref>(a)) as represented by crustal scale shear zones [<xref ref-type="bibr" rid="scirp.119001-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref15">15</xref>] . These shear zones were described as inter-domainal shear zones. However, a recent work [<xref ref-type="bibr" rid="scirp.119001-ref16">16</xref>] convincingly demonstrated the Mahanadi Shear Zone (part of North Boundary Shear Zone) as an outcome of intra-terranne transpression in response to far field stress generated by collision of EGB with the Singhbhum Craton (SC) and thereby challenged the efficacy of the domainal classification [<xref ref-type="bibr" rid="scirp.119001-ref15">15</xref>] .</p><p>The EGB comprises three broad lithological groups, namely metapelitic granulites, charnockite-enderbite gneisses and associated mafic granulites and migmatitic gneisses. NE-SW regional tectonic trend represented by S<sub>1</sub> gneissosity [<xref ref-type="bibr" rid="scirp.119001-ref17">17</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref18">18</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref19">19</xref>] , a steep axial planar foliation, and common structural repetitions, are akin to a convergent orogen that evolved under a regional NW-SE</p><p>compression [<xref ref-type="bibr" rid="scirp.119001-ref18">18</xref>] . Oblique collisional juxtaposition of the EGB against the Singhbhum and Bastar Cratons have also been described [<xref ref-type="bibr" rid="scirp.119001-ref20">20</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref21">21</xref>] and was interpreted as a syntaxial bend during oblique collision of an indenter [<xref ref-type="bibr" rid="scirp.119001-ref22">22</xref>] . Complex tectonothermal records include ultra-high-temperature metamorphism, mostly represented by metapelitic migmatites [<xref ref-type="bibr" rid="scirp.119001-ref8">8</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref9">9</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref10">10</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref23">23</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref24">24</xref>] ; dehydration melting in different crustal protoliths [<xref ref-type="bibr" rid="scirp.119001-ref10">10</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref25">25</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref26">26</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref27">27</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref28">28</xref>] , and complex, possibly distinct P-T paths in different sectors [<xref ref-type="bibr" rid="scirp.119001-ref9">9</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref11">11</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref29">29</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref30">30</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref31">31</xref>] . Recent isotopic data, particularly, Ndmapping has confirmed that different crustal domains or provinces with unrelated pre-metamorphic history are present in the EGB [<xref ref-type="bibr" rid="scirp.119001-ref14">14</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref15">15</xref>] [<xref ref-type="bibr" rid="scirp.119001-ref18">18</xref>] .</p></sec><sec id="s2_2"><title>2.2. Study Area</title><p>The present study area around Paikmal, at the northwestern margin of the EGB, belongs to the Western Khondalite Zone (WKZ) of [<xref ref-type="bibr" rid="scirp.119001-ref32">32</xref>] and EGP of [<xref ref-type="bibr" rid="scirp.119001-ref14">14</xref>] . The area exposes dominantly metapelitic granulites (khondalites), with minor bands of mafic granulites of the EGP and granite gneisses of the BC with some mafic enclaves [<xref ref-type="bibr" rid="scirp.119001-ref21">21</xref>] . The pervasive gneissosity in the metapelitic granulites and axial traces of F<sub>2</sub> folds describe a bend from E-W in the northeast to NNE-SSW in the southwest (<xref ref-type="fig" rid="fig1">Figure 1</xref>(b)). Besides the quartzite mylonites, mylonitic fabrics are also observed in metapelitic granulites in the boundary shear zone. The granitoids of the BC have a crude gneissosity, which is at a high angle to the boundary. [<xref ref-type="bibr" rid="scirp.119001-ref6">6</xref>] described microstructures and quartz C-axis fabrics, attesting to a high-temperature shear zone separating the craton from EGB. Also, the rocks of BC are affected by the shear deformation.</p></sec></sec><sec id="s3"><title>3. Petrological Background</title><p>The dominant rocks in this boundary region of the EGP are khondalites and have the assemblage: quartz-garnet-sillimanite-K-feldspar-ilmenite&#177;rutile, with zircon as the main accessory mineral. Garnet-sillimanite and quartz-feldspar segregations define a foliation (<xref ref-type="fig" rid="fig2">Figure 2</xref>(a)), corresponding to the gneissic foliation in the field. This rock is represented by the sample 4KH, for geochronological analysis in the present study. The khondalite sample, PK4/2/05, occurs in the shear zone, has the same assemblage, but record reaction texture, ubiquitous presence of ilmenite rim on sigmoidal garnet and characteristic fibrous sillimanite growth along shear fabric (<xref ref-type="fig" rid="fig2">Figure 2</xref>(b)). This texture indicates the garnet breakdown reaction, garnet + rutile = sillimanite + ilmenite + quartz. Along the shear zone, this reaction texture (<xref ref-type="fig" rid="fig2">Figure 2</xref>(b)) strongly suggests decompression and tectonic exhumation. Petrologically the reaction was studied to quantify the degree of exhumation related to shear zone development. Other granulite lithological type, mafic granulite only occurs as minor bands in the khondalites and rare occurrence in the shear zone. The assemblage in this rock includes clinopyroxene, orthopyroxene, plagioclase, garnet, ilmenite&#177;quartz and in the shear zone sample hornblende is present but is mostly secondary and define a crude alignment, probably representing the shear deformation (<xref ref-type="fig" rid="fig2">Figure 2</xref>(c)). This sample displays reaction textures, namely, clinopyroxene + plagioclase = garnet + quartz and clinopyroxene-plagioclase-garnet triple point junction (<xref ref-type="fig" rid="fig2">Figure 2</xref>(d)). The sample, PK3/2B/05, occurs in the shear zone and displays reaction texture, namely, orthopyroxene-plagioclase symplectitic growth at garnet margin (<xref ref-type="fig" rid="fig2">Figure 2</xref>(e)) and on resorbed garnet (<xref ref-type="fig" rid="fig2">Figure 2</xref>(f)) in presence of</p><p>quartz suggests the breakdown reaction: garnet + quartz = orthopyroxene + plagioclase, indicating decompression and tectonic exhumation, presumably at the time of shear zone development.</p><p>Two samples from the adjoining BC were used in this study. The granite sample, 4BG, is of granitic composition with the assemblage: K-feldspar-plagioclase-quartz-amphibole-opaque &#177; biotite and a granoblastic fabric and displays effect of the shear deformation, namely, amphibole fish and recrystallized matrix (<xref ref-type="fig" rid="fig2">Figure 2</xref>(g)). The mafic enclave sample, 4BB, is a retrogressed amphibolite with the assemblage: plagioclase-clinopyroxene (mostly altered to chlorite)-opaque and displays a relict subophitic texture (<xref ref-type="fig" rid="fig2">Figure 2</xref>(h)).</p></sec><sec id="s4"><title>4. Mineral Chemistry</title><sec id="s4_1"><title>4.1. Analytical Procedure</title><p>The electron microprobe analyses (EPMA) were undertaken at the Geological Survey of India, Kolkata using CAMECA SX 100 machine. Operating conditions for the electron microprobe were 15 KV accelerating voltage, 0.2 nA sample current and 2 &#181;m beam diameter.</p></sec><sec id="s4_2"><title>4.2. Analytical Results</title><p>EPMA analytical data is given in <xref ref-type="table" rid="table1">Table 1</xref>. Pressure-temperature estimates for these equilibrations were derived using multi-equilibrium calculations [<xref ref-type="bibr" rid="scirp.119001-ref33">33</xref>] . P-T estimate for the mafic granulite outside the shear zone was reported as 9 Kbar,</p><table-wrap id="table1" ><label><xref ref-type="table" rid="table1">Table 1</xref></label><caption><title> Mineral compositions in granulite suite, Paikmal, Eastern Ghats Province, India</title></caption><table><tbody><thead><tr><th align="center" valign="middle" >Rock</th><th align="center" valign="middle"  colspan="3"  >Mafic granulite in the shear zone</th><th align="center" valign="middle"  colspan="2"  >Khondalite in the shear zone</th></tr></thead><tr><td align="center" valign="middle"  rowspan="2"  >Sample No</td><td align="center" valign="middle"  colspan="3"  >PK3/2B/05 (<xref ref-type="fig" rid="fig2">Figure 2</xref>(f))</td><td align="center" valign="middle"  colspan="2"  >PK4/2/05 (<xref ref-type="fig" rid="fig2">Figure 2</xref>(b))</td></tr><tr><td align="center" valign="middle" >Plagioclase</td><td align="center" valign="middle" >Garnet</td><td align="center" valign="middle" >Orthopyroxene</td><td align="center" valign="middle" >Garnet</td><td align="center" valign="middle" >Ilmenite</td></tr><tr><td align="center" valign="middle" >SiO<sub>2</sub></td><td align="center" valign="middle" >60.21</td><td align="center" valign="middle" >37.5</td><td align="center" valign="middle" >51.28</td><td align="center" valign="middle" >38.54</td><td align="center" valign="middle" >0.05</td></tr><tr><td align="center" valign="middle" >TiO<sub>2</sub></td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >45.84</td></tr><tr><td align="center" valign="middle" >Al<sub>2</sub>O<sub>3</sub></td><td align="center" valign="middle" >22.55</td><td align="center" valign="middle" >19.56</td><td align="center" valign="middle" >0.58</td><td align="center" valign="middle" >21.86</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >FeO</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >33.56</td><td align="center" valign="middle" >34.51</td><td align="center" valign="middle" >28.15</td><td align="center" valign="middle" >52.08</td></tr><tr><td align="center" valign="middle" >MnO</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >1.1</td><td align="center" valign="middle" >0.33</td><td align="center" valign="middle" >2.09</td><td align="center" valign="middle" >0.66</td></tr><tr><td align="center" valign="middle" >MgO</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >3.74</td><td align="center" valign="middle" >13.91</td><td align="center" valign="middle" >7.82</td><td align="center" valign="middle" >1.11</td></tr><tr><td align="center" valign="middle" >CaO</td><td align="center" valign="middle" >6.12</td><td align="center" valign="middle" >3.6</td><td align="center" valign="middle" >0.32</td><td align="center" valign="middle" >1.45</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Na<sub>2</sub>O</td><td align="center" valign="middle" >8.84</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >K<sub>2</sub>O</td><td align="center" valign="middle" >0.15</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Total</td><td align="center" valign="middle" >97.88</td><td align="center" valign="middle" >99.03</td><td align="center" valign="middle" >100.95</td><td align="center" valign="middle" >100.06</td><td align="center" valign="middle" >99.74</td></tr><tr><td align="center" valign="middle" >Si</td><td align="center" valign="middle" >2.74</td><td align="center" valign="middle" >3.05</td><td align="center" valign="middle" >2</td><td align="center" valign="middle" >2.99</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Ti</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >0.99</td></tr><tr><td align="center" valign="middle" >Al</td><td align="center" valign="middle" >1.21</td><td align="center" valign="middle" >1.87</td><td align="center" valign="middle" >0.03</td><td align="center" valign="middle" >2</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Fe<sup>2 +</sup></td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >2.28</td><td align="center" valign="middle" >1.13</td><td align="center" valign="middle" >1.83</td><td align="center" valign="middle" >0.96</td></tr><tr><td align="center" valign="middle" >Fe<sup>3 +</sup></td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >0.01</td></tr><tr><td align="center" valign="middle" >Mn</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >0.08</td><td align="center" valign="middle" >0.01</td><td align="center" valign="middle" >0.14</td><td align="center" valign="middle" >0.02</td></tr><tr><td align="center" valign="middle" >Mg</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >0.45</td><td align="center" valign="middle" >0.81</td><td align="center" valign="middle" >0.91</td><td align="center" valign="middle" >0.03</td></tr><tr><td align="center" valign="middle" >Ca</td><td align="center" valign="middle" >0.3</td><td align="center" valign="middle" >0.31</td><td align="center" valign="middle" >0.01</td><td align="center" valign="middle" >0.12</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Na</td><td align="center" valign="middle" >0.78</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >K</td><td align="center" valign="middle" >0.01</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td><td align="center" valign="middle" >-</td></tr><tr><td align="center" valign="middle" >Cat. total</td><td align="center" valign="middle" >5.05</td><td align="center" valign="middle" >8.03</td><td align="center" valign="middle" >3.99</td><td align="center" valign="middle" >7.99</td><td align="center" valign="middle" >2.01</td></tr><tr><td align="center" valign="middle" >P-T estimate</td><td align="center" valign="middle"  colspan="3"  >5.1 Kbar, at 600˚C</td><td align="center" valign="middle"  colspan="2"  >4.7 Kbar at 600˚C</td></tr></tbody></table></table-wrap><p>850˚C [<xref ref-type="bibr" rid="scirp.119001-ref6">6</xref>] . In the shear zone khondalite, using garnet-sillimanite-ilmenite-rutile barometer, pressure was estimated at ~4.7 kbar, at 600˚C; and in the mafic granulite using the garnet-orthopyroxene-plagioclase-quartz barometer, the estimated pressure is ~5.1 kbar at 600˚C. Hence, a minimum of 4 kbar exhumation (from 9 to 5 kbar) could be assigned to the shearing event. This comes out to around 15 km of exhumation.</p></sec></sec><sec id="s5"><title>5. Isotopic Study</title><sec id="s5_1"><title>5.1. Analytical Procedure</title><sec id="s5_1_1"><title>5.1.1. U-Pb Isotopes in Zircon and Monazite</title><p>The isotopic analyses were undertaken at the Geoscience Centre of Sao Paulo University, using a VG-354 multi-collector mass spectrometer (TIMS). For the U-Pb analytical work, the measured ratios of the NBS982 standard were <sup>204</sup>Pb/<sup>206</sup>Pb = 0.02732 &#177; 0.00003; <sup>207</sup>Pb/<sup>206</sup>Pb = 0.46656 &#177; 0.00003 and <sup>208</sup>Pb/<sup>206</sup>Pb = 0.99783 &#177; 0.00005. The laboratory blanks for the chemical procedure during the period of the analysis yielded maximum values of 15 pg for Pb and 2 pg for U. Details of the analytical procedure were the same as given in [<xref ref-type="bibr" rid="scirp.119001-ref11">11</xref>] .</p><p>Lately, we have also undertaken in situ zircon geochronology by LAICPMS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry), at the Centre of Geoscience, University of Sao Paulo, Brazil. GJ-1 zircon reference standard was used for LAICPMS analysis. GJ-1 reference age, 608 &#177; 0.4 Ma [<xref ref-type="bibr" rid="scirp.119001-ref34">34</xref>] and GJ-1 concordia age during analysis was 605.6 &#177; 1.2 Ma. The detailed procedure is given in [<xref ref-type="bibr" rid="scirp.119001-ref35">35</xref>] .</p></sec><sec id="s5_1_2"><title>5.1.2. Whole Rock Rb-Sr</title><p>The measured ratio of <sup>87</sup>Sr/<sup>86</sup>Sr obtained for NBS 987 standard was 0.710254 &#177; 22 (2σ) and the laboratory blank for the chemical procedure during the period of analysis yielded maximum value of 4 ng for Sr.</p></sec><sec id="s5_1_3"><title>5.1.3. Whole Rock Sm-Nd</title><p>The measured ratio of <sup>143</sup>Nd/<sup>144</sup>Nd obtained for La Jolla standard was 0.511857 &#177; 0.000046 (2σ) and the laboratory blanks for the chemical procedure during the period of analysis yielded maximum values of 0.4 ng for Nd and 0.7 ng for Sm.</p></sec><sec id="s5_1_4"><title>5.1.4. K-Ar Isotopes</title><p>Analytical procedure as reported in [<xref ref-type="bibr" rid="scirp.119001-ref36">36</xref>] .</p></sec></sec><sec id="s5_2"><title>5.2. Isotopic Results</title><p>U-Pb isotopic data for zircon and monazite in Khondalite (<xref ref-type="table" rid="table2">Table 2</xref>) by TIMS (Thermal Ionisation Mass Spectrometer) provide the following constraints on the time relation between granulite metamorphism and shear zone development, in this boundary shear zone. The three zircon fractions dated 948, 1036 &amp; 1056 Ma could be interpreted as a long-lived thermal (granulite-formation) event, as reported by [<xref ref-type="bibr" rid="scirp.119001-ref24">24</xref>] from the different areas in the EGP. The two older populations, 1244 and 1355 Ma could represent partially modified detrital zircons [<xref ref-type="bibr" rid="scirp.119001-ref37">37</xref>] . Two monazite fractions dated 918 &amp; 1096 Ma would further corroborate the long-lived thermal event. Monazite fraction dated 865 Ma on the other hand, could signify the beginning of the Rodinia break-up [<xref ref-type="bibr" rid="scirp.119001-ref38">38</xref>] . Monazite fraction dated 541 Ma, could represent the late Neoproterozoic thermal event in East Gondwana, which is believed to have been completely assembled by around 600 Ma [<xref ref-type="bibr" rid="scirp.119001-ref39">39</xref>] . It is important to note that though no extensive areas or rock suites of this age are recorded in the EGP, this Pan-African imprint only sporadically appears in several areas in the EGP [<xref ref-type="bibr" rid="scirp.119001-ref40">40</xref>] , as also in this presentation and has no significance in the context of an orogenic event.</p><p>Zircon U-Pb isotopic analysis by LAICPMS is presented in <xref ref-type="table" rid="table3">Table 3</xref> and <xref ref-type="fig" rid="fig3">Figure 3</xref>. Here also, two zircon populations could easily be identified. Concordant zircon population of the Grenvillian orogeny ranges between 1040 &amp; 920 Ma and</p><table-wrap id="table2" ><label><xref ref-type="table" rid="table2">Table 2</xref></label><caption><title> U-Pb isotopic data for zircon and monazite by TIMS in Khondalite (4KH), Paikmal, Eastern Ghats Province, India</title></caption><table><tbody><thead><tr><th align="center" valign="middle"  rowspan="2"  >Mineral</th><th align="center" valign="middle"  colspan="8"  >TIMS analytical data</th></tr></thead><tr><td align="center" valign="middle" >Fraction</td><td align="center" valign="middle" >Pb (ppm)</td><td align="center" valign="middle" >U (ppm)</td><td align="center" valign="middle" ><sup>206</sup>Pb/<sup>204</sup>Pb</td><td align="center" valign="middle" ><sup>206</sup>Pb/<sup>238</sup>U</td><td align="center" valign="middle" ><sup>207</sup>Pb/<sup>235</sup>U</td><td align="center" valign="middle" ><sup>207</sup>Pb/<sup>206</sup>Pb</td><td align="center" valign="middle" ><sup>207</sup>Pb/<sup>206</sup>Pb (Ma)</td></tr><tr><td align="center" valign="middle" >Zircon</td><td align="center" valign="middle" >A</td><td align="center" valign="middle" >28.7</td><td align="center" valign="middle" >225.8</td><td align="center" valign="middle" >2730</td><td align="center" valign="middle" >0.133141 &#177; 71</td><td align="center" valign="middle" >1.29737 &#177; 79</td><td align="center" valign="middle" >0.070672 &#177; 19</td><td align="center" valign="middle" >948</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >B</td><td align="center" valign="middle" >25.1</td><td align="center" valign="middle" >201.3</td><td align="center" valign="middle" >1081</td><td align="center" valign="middle" >0.124028 &#177; 66</td><td align="center" valign="middle" >1.26231 &#177; 72</td><td align="center" valign="middle" >0.073815 &#177; 15</td><td align="center" valign="middle" >1036</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >C</td><td align="center" valign="middle" >39.3</td><td align="center" valign="middle" >245</td><td align="center" valign="middle" >265</td><td align="center" valign="middle" >0.131265 &#177; 67</td><td align="center" valign="middle" >1.48238 &#177; 102</td><td align="center" valign="middle" >0.081941 &#177; 38</td><td align="center" valign="middle" >1244</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >D</td><td align="center" valign="middle" >35.3</td><td align="center" valign="middle" >256.9</td><td align="center" valign="middle" >1880</td><td align="center" valign="middle" >0.136477 &#177; 75</td><td align="center" valign="middle" >1.63236 &#177; 96</td><td align="center" valign="middle" >0.086745 &#177; 18</td><td align="center" valign="middle" >1355</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >E</td><td align="center" valign="middle" >16.1</td><td align="center" valign="middle" >132.5</td><td align="center" valign="middle" >849</td><td align="center" valign="middle" >0.122159 &#177; 85</td><td align="center" valign="middle" >1.25556 &#177; 92</td><td align="center" valign="middle" >0.074544 &#177; 14</td><td align="center" valign="middle" >1056</td></tr><tr><td align="center" valign="middle" >Monazite</td><td align="center" valign="middle" >B</td><td align="center" valign="middle" >2637</td><td align="center" valign="middle" >2715</td><td align="center" valign="middle" >1885</td><td align="center" valign="middle" >0.145719 &#177; 67</td><td align="center" valign="middle" >1.3993 &#177; 65</td><td align="center" valign="middle" >0.069646 &#177; 48</td><td align="center" valign="middle" >918</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >C</td><td align="center" valign="middle" >1633</td><td align="center" valign="middle" >1488</td><td align="center" valign="middle" >3530</td><td align="center" valign="middle" >0.133188 &#177; 65</td><td align="center" valign="middle" >1.24677 &#177; 63</td><td align="center" valign="middle" >0.067892 &#177; 101</td><td align="center" valign="middle" >865</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >D</td><td align="center" valign="middle" >2103</td><td align="center" valign="middle" >2910</td><td align="center" valign="middle" >23900</td><td align="center" valign="middle" >0.157861 &#177; 73</td><td align="center" valign="middle" >1.65473 &#177; 76</td><td align="center" valign="middle" >0.076024 &#177; 38</td><td align="center" valign="middle" >1096</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >F</td><td align="center" valign="middle" >1842</td><td align="center" valign="middle" >1914</td><td align="center" valign="middle" >1319</td><td align="center" valign="middle" >0.086651 &#177; 40</td><td align="center" valign="middle" >0.696368 &#177; 33</td><td align="center" valign="middle" >0.05831 &#177; 69</td><td align="center" valign="middle" >541</td></tr></tbody></table></table-wrap><p>consistent with the long-lived UHT event in the EGP [<xref ref-type="bibr" rid="scirp.119001-ref24">24</xref>] . The Neoproterozoic population, however, could be further sub-divided into two age groups, namely, between 815 &amp; 700 Ma and between 600 &amp; 530 Ma respectively and this is consistent with 541 Ma monazite fraction, as recorded by TIMS analysis.</p><p>The whole rock Rb-Sr and Sm-Nd isotopic data for granulites and granites of this boundary region is presented in <xref ref-type="table" rid="table4">Table 4</xref>. It is interesting to note that some mafic granulites (4MG) are observed interbanded with the khondalites (4KH), away from the shear zone, similar to that recorded from Sunki area (cf. <xref ref-type="fig" rid="fig4">Figure 4</xref>(a) in [<xref ref-type="bibr" rid="scirp.119001-ref41">41</xref>] ). Rb-Sr data in the Khondalite (4KH) indicated ~1.6 Ga Sr-model date. The Sr model date for khondalites in the EGP (including 4 KH) provide some constraints on the age of sedimentation [<xref ref-type="bibr" rid="scirp.119001-ref42">42</xref>] . Sm-Nd isotopic data for the interbanded mafic granulite (4MG), indicated mafic crust formation around 1.6 Ga.</p><p>As for the Paleoproterozoic provenance of the precursor khondalite sediments, the Nd-model date of the khondalite, 2.5 Ga and the dominantly granitic, but including some mafic rocks of the BC, as reported by [<xref ref-type="bibr" rid="scirp.119001-ref42">42</xref>] , are also recorded from granite in this boundary region.</p><p>Secondary amphibole, aligned in the direction of extension (<xref ref-type="fig" rid="fig2">Figure 2</xref>(c)) provides 580 Ma cooling age (<xref ref-type="table" rid="table4">Table 4</xref>).</p></sec></sec><sec id="s6"><title>6. Discussion</title><p>The granitoids and mafic enclaves in the adjoining BC provide information on the Archaean cratonic evolutionary array between 3.0 Ga mafic magmatism and 2.5 Ga granitic batholiths, indicated here with Nd-model (crustal derivation) ages.</p><p>In this marginal segment of the EGP, magmatism and sedimentation at ~1.6 Ga indicated by Nd-model date and Sr-model date respectively, are indicative of</p>
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