<?xml version="1.0" encoding="UTF-8"?><!DOCTYPE article  PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd"><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" dtd-version="3.0" xml:lang="en" article-type="research article"><front><journal-meta><journal-id journal-id-type="publisher-id">ANP</journal-id><journal-title-group><journal-title>Advances in Nanoparticles</journal-title></journal-title-group><issn pub-type="epub">2169-0510</issn><publisher><publisher-name>Scientific Research Publishing</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.4236/anp.2022.112005</article-id><article-id pub-id-type="publisher-id">ANP-117543</article-id><article-categories><subj-group subj-group-type="heading"><subject>Articles</subject></subj-group><subj-group subj-group-type="Discipline-v2"><subject>Biomedical&amp;Life Sciences</subject><subject> Chemistry&amp;Materials Science</subject><subject> Engineering</subject></subj-group></article-categories><title-group><article-title>
 
 
  The Effects of an Inclined Magnetic Field, Brownian Motion, and Thermophoresis on the Flow of Electrically Conducting and Chemically Reacting Casson Nanofluids Using Soret-Dufour Mechanisms
 
</article-title></title-group><contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Toyin</surname><given-names>Wasiu Akaje</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref><xref ref-type="corresp" rid="cor1"><sup>*</sup></xref></contrib><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bakai</surname><given-names>Ishola Olajuwon</given-names></name><xref ref-type="aff" rid="aff1"><sup>1</sup></xref></contrib></contrib-group><aff id="aff1"><addr-line>Department of Mathematics, Federal University of Agriculture, Abeokuta, Nigeria</addr-line></aff><pub-date pub-type="epub"><day>31</day><month>05</month><year>2022</year></pub-date><volume>11</volume><issue>02</issue><fpage>55</fpage><lpage>71</lpage><history><date date-type="received"><day>21,</day>	<month>February</month>	<year>2022</year></date><date date-type="rev-recd"><day>28,</day>	<month>May</month>	<year>2022</year>	</date><date date-type="accepted"><day>31,</day>	<month>May</month>	<year>2022</year></date></history><permissions><copyright-statement>&#169; Copyright  2014 by authors and Scientific Research Publishing Inc. </copyright-statement><copyright-year>2014</copyright-year><license><license-p>This work is licensed under the Creative Commons Attribution International License (CC BY). http://creativecommons.org/licenses/by/4.0/</license-p></license></permissions><abstract><p>
 
 
  This research explored the effects of an angled magnetic field, Brownian motion, and thermophoresis on the flow of an electrically conducting and chem
  ically reacting Casson nanofluid under the influence of the Soret-Dufour mechanism. A set of partial differential equations is generated by the flow mode. The governing partial differential equations are solved numerically using the spectral collocation method after being transformed to self-similar forms. The effect of various fluid parameters on the velocity profile, temperature profile, 
  and nanoparticle concentration is addressed. A quantitative agreement is 
  observed when previous findings are compared to the current results. The skin 
  friction, local Nusselt number, and local Sherwood number are also examined, and the results are presented in the table. This study discovered that the inclined magnetic field has a significant impact on the flow of the electrically conducting fluid by delaying its mobility within the boundary layer. The plastic dynamic viscosity, which acts as a barrier to fluid flow, is shown to degenerate the fluid velocity when the Casson parameter is increased. As a conse
  quence, the findings may be used to improve thermal science instruments and increase industrial output.
 
</p></abstract><kwd-group><kwd>Soret-Dufour Mechanism</kwd><kwd> Casson Nanofluid</kwd><kwd> Inclined Magnetic Field</kwd><kwd> Boundary Layer</kwd><kwd> Spectral Collocation Method</kwd></kwd-group></article-meta></front><body><sec id="s1"><title>1. Introduction</title><p>The magnet of hydrodynamics (MHD) phenomenon describes the motion of electrically conducting fluids with a magnetic field. In recent years, several researchers have indicated an interest in researching comparable incidents. MHD research reveals application hall accelerators as well as MHD power producers. As a result of these applications, Alao et al. [<xref ref-type="bibr" rid="scirp.117543-ref1">1</xref>] (2016) investigated the impact of a magnetic field on the unsteady heat and mass transport of a reacting fluid as a result of these applications. Shahnaz et al. [<xref ref-type="bibr" rid="scirp.117543-ref2">2</xref>] (2021) have investigated the effect of an angled magnetic field and a decreasing sheet on Casson fluid motion. Saravana et al. [<xref ref-type="bibr" rid="scirp.117543-ref3">3</xref>] investigated the aligned magnetism effect on the fluid flow of Casson fluid across a non-uniform constant stretched surface (2019). Hashim et al. [<xref ref-type="bibr" rid="scirp.117543-ref4">4</xref>] (2020) discovered aligned magnetism in Williamson liquid during Newtonian heating of an elongating sheet. Furthermore, Yusuf and Mabood [<xref ref-type="bibr" rid="scirp.117543-ref5">5</xref>] (2020) examined the chemical reaction and aligned magnetic field effect in slippery Williamson liquid through a porous wall. Using the homotopy analysis technique, Jawad et al. [<xref ref-type="bibr" rid="scirp.117543-ref6">6</xref>] (2021) investigated 3-D Casson nanofluid under the effect of Arrhenius activation energy and heat radiation. Kalaivanan et al. [<xref ref-type="bibr" rid="scirp.117543-ref7">7</xref>] (2015) used the confluent hypergeometric function to investigate the aligned magnetic field ascendancy on slip flow of Casson fluid past elongating sheet, and it was discovered that velocity distributions decreased as slip and Casson parameters increased, while temperature film increased as slip and Casson parameters increased. Jain and Parmar [<xref ref-type="bibr" rid="scirp.117543-ref8">8</xref>] (2017) investigate the entropy production of unsteady radiative Casson fluid flow through a porous material over a permeable stretched surface with an angled magnetic field. Devi et al. [<xref ref-type="bibr" rid="scirp.117543-ref9">9</xref>] (2021) used the Runge-Kutta technique to study the influence of an aligned magnetic field and an angled outer velocity on Casson fluid flow over a stretched sheet with a heat source. The results showed that when the outer velocity parameter is less than one, velocity decreases as the Casson fluid parameter, magnetic parameter, and aligned angle of magnetic field increase, whereas velocity increases when the outer velocity parameter is greater than one due to the formation of an inverted boundary layer for velocity profile in the second case. Seddeek [<xref ref-type="bibr" rid="scirp.117543-ref10">10</xref>] (2007) investigated heat and mass transfer in a viscoelastic fluid flow through a porous medium with a heat source or sink on a stretched sheet in the presence of a magnetic field.</p><p>Many engineering processes, including nuclear waste disposal, petroleum reservoirs, chemical catalytic processes and reactors, and many more, make use of double-diffusive fluid flow In a moving fluid, the phenomena of heat and mass transport processes occur concurrently; the energy fluxes created by the action of the composition gradient and temperature alongside the driving force are complex. The Soret or thermal-diffusion effect is the development of mass fluxes caused by a temperature gradient, whereas the Dufour or diffusion-thermo contribution is the development of energy fluxes induced by a composition gradient. Most literary scholars dismiss these effects since they are of a smaller magnitude than the influence anticipated by Fick’s law. Bilal et al. [<xref ref-type="bibr" rid="scirp.117543-ref11">11</xref>] (2016) investigated dissipative slip motion past a spinning cone using chemical reaction and Dufour-Soret processes. Jain and Choudhary [<xref ref-type="bibr" rid="scirp.117543-ref12">12</xref>] (2017) investigate the impact of Soret and Dufour on MHD fluid flow caused by moving permeable cylinders with radiation. In addition, Tai and Char [<xref ref-type="bibr" rid="scirp.117543-ref13">13</xref>] (2010) explore the Soret and Dufour effects on non-Newtonian fluid free convection flow down a vertical plate immersed in a porous medium with heat radiation. Non-Newtonian fluid flow, which includes both heat and mass transport phenomena, has recently sparked a lot of attention owing to its engineering applications. The bulk of non-Newtonian fluid rheological equations are quite complex and must be numerically solved. The Casson fluid motion is the most common type of non-Newtonian fluid motion. Jellies, jams, soups (food), blood, salvia (biological fluids), toothpaste, and other similar fluids are all examples. This fluid is used in polymer industries, heat exchangers, food processing, electronic cooling systems, and a number of other applications. Because of the numerous uses of non-Newtonian fluids, Fagbade et al. [<xref ref-type="bibr" rid="scirp.117543-ref14">14</xref>] (2018) successfully asserted the flowing nature of viscoelastic fluid past an accelerating penetrable surface by researching MHD natural convection. Mondal et al. [<xref ref-type="bibr" rid="scirp.117543-ref15">15</xref>] (2018) employed Soret-Dufour and thermophoresis to investigate MHD mixed convection mass transfer in an inclined plate. In addition to this effect, Ahmed et al. [<xref ref-type="bibr" rid="scirp.117543-ref16">16</xref>] (2020) elucidates the influence of Soret-Dufour mechanism, which accounts for buoyant force and viscous dissipation. Raza et al. [<xref ref-type="bibr" rid="scirp.117543-ref17">17</xref>] (2019) studied the quantitative flow of nanofluid MHD across a stretchy nonlinear porous surface. Using numerical analysis, Shafiq et al. [<xref ref-type="bibr" rid="scirp.117543-ref18">18</xref>] (2020) studied the sensitivity of the hyperbolic tangent of nanofluid bioconvective flow in a stretchy media. Hamid et al. [<xref ref-type="bibr" rid="scirp.117543-ref19">19</xref>] (2019) looked into the stability analysis and dual solutions of Casson fluid heat diffusion across an elastic surface. The free convective transient flow of a non-Newtonian fluid through a porous media is established in the work of Mabood et al. [<xref ref-type="bibr" rid="scirp.117543-ref20">20</xref>] (2020).</p><p>Previous studies did not look into the effects of an angled magnetic field on the flow of Casson nanofluids in the presence of Soret-Dufour and thermal radiation. The present research is focused on the Dynamics of Inclined Magnetic Fields, Brownian motion, and thermophoresis on the flow of electrically conducting and chemically reacting Casson nanofluids. This type of quandary, as far as we know, has never been addressed in the literature. SCM is used to solve the flow equations in this article. Graphs and tabular data are used to display numerical findings. The present study is useful in the manufacture of food and chemical engineering operations.</p></sec><sec id="s2"><title>2. Mathematical Modeling</title><p>In this work, the dynamics of a two-dimensional model of an electrically conducting, incompressible, and viscous Casson nanofluid were investigated. The plate’s surface temperature and concentration are considered to be where, and are temperatures and concentrations far from the boundary, and are wall temperatures and concentrations (see <xref ref-type="fig" rid="fig1">Figure 1</xref>). The fluid’s motion is assumed to be aided by an inclined magnetic field. The viscosity and thermal conductivity are assumed to be constant. We assumed that the magnetic Reynolds number is modest, thus we ignored induced magnetic. Thermal radiation and viscous dissipation are considered significant, allowing the fluid’s thermal state to be rigorously investigated. Furthermore, a chemical process is thought to be occurring within the boundary layer. The flow constitutive equations for Casson are explained below using Fredrickson [<xref ref-type="bibr" rid="scirp.117543-ref21">21</xref>] (1964) and the definition of viscosity given by Idowu and Falodun [<xref ref-type="bibr" rid="scirp.117543-ref22">22</xref>] (2020) as the flow constitutive equations:</p><p>τ i j = ( μ b ( T ) + P y 2 π ) 2 e i j     when   π &gt; π c τ i j = ( μ b ( T ) + P y 2 π c ) 2 e i j     when   π &lt; π c (1)</p><p>where the fluid yield stress is P y and mathematically written as:</p><p>P y = μ b ( T ) 2 π β (2)</p><p>μ b defines plastic dynamic viscosity, π = e i j e i j defines component product of deformation rate with itself and e i j defines deformation rate and π c defines critical value according to the model of Casson fluid. The Casson liquid motion where π &gt; π c , can be defined as:</p><p>μ 0 = μ b ( T ) + P y 2 π (3)</p><p>when (2) is converted into (3), the kinematic viscosity becomes susceptible to</p><p>plastic dynamic viscosity μ b , the density is ρ and the Casson term β resulted to:</p><p>μ 0 = μ b ( T ) ρ ( 1 + 1 β ) (4)</p><p>The Boussinesq approximation is considered to be valid such that the boundary layer approximation is explored. Hence, the following governing equations are derived based on the assumptions above:</p><p>∂ u ∂ x + ∂ v ∂ y = 0 (5)</p><p>u ∂ u ∂ x + v ∂ u ∂ y = ν ( 1 + 1 β ) ∂ 2 u ∂ y 2 − σ B 0 2 ρ sin 2 ( γ ) u + g β t ( T − T ∞ ) cos ( α )     + g β c ( C − C ∞ ) cos ( α ) − ν u K * (6)</p><p>u ∂ T ∂ x + v ∂ T ∂ y = α ∂ 2 T ∂ y 2 − 1 ρ c p ∂ q r ∂ y + ν c p ( 1 + 1 β ) ( ∂ u ∂ y ) 2 + σ B 0 2 c p ρ sin 2 ( γ ) u 2     + D k T c s c p ∂ 2 C ∂ y 2 + τ [ D B ( ∂ C ∂ y ) ( ∂ T ∂ y ) + D T T ∞ ( ∂ T ∂ y ) 2 ] + Q 0 ρ C p ( T − T ∞ ) (7)</p><p>u ∂ C ∂ x + v ∂ C ∂ y = D B ∂ 2 C ∂ y 2 + D T T ∞ ∂ 2 T ∂ y 2 − k l ( C − C ∞ ) + D k T T m ∂ 2 T ∂ y 2 (8)</p><p>Subject to the boundary constraints:</p><p>u = B x ,     v = − ν ( x ) ,     T = T w ,     C = C w ,     at   y = 0 (14)</p><p>u → 0 ,     T → T ∞ ,     C → C ∞ ,     as   y → ∞ (15)</p><p>u and v represents the relations u = ∂ ψ ∂ y and v = − ∂ ψ ∂ x . In the definition of u</p><p>and v, ψ ( x , y ) is the free stream that always fulfills the continuity equation. The following are the definitions of similarity variables:</p><p>η = ( B ν ) 1 2 y ,     ψ = ( ν B ) 1 2 x f ( η ) ,     θ ( η ) = T − T ∞ T w − T ∞ ,     ϕ ( η ) = C − C ∞ C w − C ∞ (16)</p><p>Using Equation (16) on Equations (10)-(13) subject to (14) and (15) to obtain:</p><p>( 1 + 1 β ) f ‴ + f f ″ + ( 1 + 1 β ) f ′   f ‴ − ( f ′ ) 2 − M sin 2 ( γ ) f ′   + G r θ cos ( α ) + G m ϕ cos ( α ) − 1 P 0 f ′ = 0 (17)</p><p>( 1 + N r P r ) θ ″ + E c ( 1 + 1 β ) ( f ″ ) 2 + f θ ′ + M E c sin 2 ( γ ) ( f ′ ) 2   + D u ϕ ″ + N b ϕ ′ θ ′ + N t ( θ ′ ) 2 + Q θ = 0 (18)</p><p>ϕ ″ + S c S o θ ″ − S c C r ϕ + S c f ϕ ′ + S c N t L n N b θ ″ = 0 (19)</p><p>Subject to:</p><p>f ′ = 1 ,     f = f w ,     θ = 1 ,     ϕ = 1 ,     at   η = 0 (20)</p><p>f ′ → 0 ,     θ → 0 ,     ϕ → 0     as   η → ∞ (21)</p><p>The control parameters are defined as follows:</p><p>M = σ B 0 2 a ρ ,     P r = ν α ,     N r = 16 σ s T 3 3 k k e ,     E c = ( a x ) 2 c p ( T w − T ∞ ) , D u = D K T ( C w − C ∞ ) c s c p ν ( T w − T ∞ ) ,     S c = ν D B ,     S o = D T ( T w − T ∞ ) T ∞ ν ( C w − C ∞ ) ,     C r = k l a , N b = τ D B ( C w − C ∞ ) ν ,     N t = τ D T ( T w − T ∞ ) T ∞ ν ,     Q = Q 0 ρ c p b ,     L n = ν D B</p><p>Are the chemical reaction parameter, Thermophoresis parameter, Magnetic M, parameter, Prandtl number Pr, thermal radiation parameter Nr, Eckert number Ec, Dufour number Du, Schmidt number Sc, Brownian motion parameter Nb, heat generation parameter Q, Lewis number Ln, and Soret numberSo.</p></sec><sec id="s3"><title>3. Method of Approach</title><p>The spectra Chebyshev collocation scheme is engaged for the numerical computation of the boundary value nonlinear derivative system of Equations (17)-(19). The</p><p>following functions f ( η ) = ∑ i = 0 N     a i T i ( η ) , θ ( ξ ) = ∑ i = 0 N     b i T i ( η ) , ϕ ( η ) = ∑ i = 0 N     c i T i ( η )</p><p>and are defined and approximated by the sum of the basic functions T n ( η ) . The basis functions are chosen as the Chebyshev polynomials</p><p>T n ( η ) = cos ( N cos − 1 η ) , − 1 ≤ η ≤ 1 , were a n , b n and c n are unidentified coefficients to be gotten. The flow range is [ 0 , ∞ ] , but changed to [ − 1 , 1 ] satisfying</p><p>the defined basis polynomials, with η = 2 ξ ξ ∞ − 1 where the far stream is taken as</p><p>ξ ∞ . Now, to have residual reduced to zero, substitute the values f ( η ) , θ ( η ) and ϕ ( η ) into Equations (17)-(19), where the coefficient a i , b i , c i and are picked to minimize the residues in the domain range. The collocation scheme is adopted in the form described by Khater et al. [<xref ref-type="bibr" rid="scirp.117543-ref23">23</xref>] (2000):</p><p>η i = cos ( i π Z ) ,       i = 0 , 1 , 2 , 3 , ⋯ , Z (22)</p><p>This produces 3 i + 3 an algebraic system of equations with 3 i + 3 been the anonymous coefficients in terms of a i , b i and c i . An iterative Newton’s technique is used i = 30 . Also, the BVP algorithm is established in Mathematical software to generate computational results.</p></sec><sec id="s4"><title>4. Results and Discussion</title><p>This paper examines a numerical simulation of dimensionless velocity, concentration, and temperature for the flow model. The Chebyshev collocation method is utilized in this paper to solve the transformed Equations (17)-(19) subject to (20) and (21). (21). The thermal Grashof number, magnetic parameter, Casson parameter, Eckert number, Brownian motion parameter, and so on all vary. We used = 3.0, Gr = Gm = 0.5, M = 1.0, Ec = 0.01, Du = 2.0, Nb = Nt = 0.7, Cr = 0.2, and So = 1.0 as the default settings for presenting all figures and creating tables. To establish the validity of the current work, we first solved a specific example of our model and then compared it to the prior results of Gopal and Kishan [<xref ref-type="bibr" rid="scirp.117543-ref24">24</xref>] (2019). Our findings in <xref ref-type="table" rid="table1">Table 1</xref> were entirely consistent with theirs.</p><p>The effect of the Casson parameter on the velocity figure is seen in <xref ref-type="fig" rid="fig2">Figure 2</xref>. Raising the Casson parameter reduces fluid velocity when the viscosity and thermal conductivity are both constant. This is due to flow resistance caused by the fluid’s plastic dynamic viscosity. As seen in <xref ref-type="fig" rid="fig2">Figure 2</xref>, raising the Casson parameter</p><table-wrap id="table1" ><label><xref ref-type="table" rid="table1">Table 1</xref></label><caption><title> Comparison of the present results with that of Gopal and Kishan [<xref ref-type="bibr" rid="scirp.117543-ref24">24</xref>] (2019) when S o = D u = 0 </title></caption><table><tbody><thead><tr><th align="center" valign="middle" >β</th><th align="center" valign="middle" >Gr</th><th align="center" valign="middle" >Gm</th><th align="center" valign="middle" >Ha</th><th align="center" valign="middle" >Ec</th><th align="center" valign="middle" >Du</th><th align="center" valign="middle" >Cr</th><th align="center" valign="middle" >So</th><th align="center" valign="middle" >Cf</th><th align="center" valign="middle" >Nu</th><th align="center" valign="middle" >Sh</th></tr></thead><tr><td align="center" valign="middle" >0.2</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.2085</td><td align="center" valign="middle" >0.6110</td><td align="center" valign="middle" >0.8123</td></tr><tr><td align="center" valign="middle" >0.4</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.4219</td><td align="center" valign="middle" >0.6110</td><td align="center" valign="middle" >0.8123</td></tr><tr><td align="center" valign="middle" >0.6</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.9312</td><td align="center" valign="middle" >0.6110</td><td align="center" valign="middle" >0.8123</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.5</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.7499</td><td align="center" valign="middle" >0.3581</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.4328</td><td align="center" valign="middle" >0.3581</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.1156</td><td align="center" valign="middle" >0.3581</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.5</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.2285</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.8633</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.5296</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.8633</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.8306</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.8633</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.7682</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >0.3513</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.5</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.4328</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >0.3513</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.6530</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >0.3513</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.1</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.6306</td><td align="center" valign="middle" >0.4365</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.2</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.8285</td><td align="center" valign="middle" >0.7793</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.3</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0264</td><td align="center" valign="middle" >0.8778</td><td align="center" valign="middle" >0.3899</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.4328</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.3106</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.5532</td><td align="center" valign="middle" >0.5559</td><td align="center" valign="middle" >0.3106</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >3.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.6736</td><td align="center" valign="middle" >0.4183</td><td align="center" valign="middle" >0.3106</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.5069</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.7655</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.4328</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >0.8633</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >3.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.2533</td><td align="center" valign="middle" >0.6935</td><td align="center" valign="middle" >1.0904</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2.0</td><td align="center" valign="middle" >1.6885</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >0.5353</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >4.0</td><td align="center" valign="middle" >1.9443</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >0.2074</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >6.0</td><td align="center" valign="middle" >2.2000</td><td align="center" valign="middle" >0.8119</td><td align="center" valign="middle" >−0.1205</td></tr></tbody></table></table-wrap><p>increases the fluid velocity figure as well as the total hydrodynamic boundary layer. Physically, the presence of an angled magnetic field, as well as plastic dynamic viscosity, causes the electrically conducting Casson fluid investigated in this work to move slowly. <xref ref-type="fig" rid="fig3">Figure 3</xref> elucidates the impact of the thermal Grashof number (Gr) on velocity. Because it has sped up fluid particle mobility, Gr serves as a buoyant force on the fluid flow. Gr is a dimensionless quantity ratio of buoyancy to viscous force defined by the fluid inside the layer. When the thermo-physical parameters stay constant, increasing the values of Gr causes an enhancement in the velocity figure and total hydrodynamic boundary layer thickness. In practice, increased thermal buoyancy indicates a laminar flow. <xref ref-type="fig" rid="fig4">Figure 4</xref> depicts the impact of the mass Grashof number (Gm) on velocity. The fluid motion increases as the value of Gm rises. The fluid velocity reaches its maximum as the species’ buoyancy force grows. The velocity has reached its peak within the plate zone and is decreasing as it approaches the free stream. <xref ref-type="fig" rid="fig5">Figure 5</xref> depicts the effect of the Eckert number (Ec) on velocity and temperature graphs. The dimensionless number in heat and mass transfer represents the viscous dissipation factor that is applied to the energy equation. Ec is a velocity-dependent function that defines the relationships between flow kinetic energy and enthalpy. Work done by Ec physically transfers kinetic energy to internal energy. <xref ref-type="fig" rid="fig5">Figure 5</xref> depicts the fluid temperature distribution when the viscous dissipative heat is higher. <xref ref-type="fig" rid="fig6">Figure 6</xref> illustrates the influence of a chemical reactive parameter (Cr) on the profiles of velocity and concentration respectively. The velocity and concentration graphs degrade as Cr concentrations rise. A chemical reaction takes place on the fluid particles and the magnetic field angled toward the plate. A decline in fluid velocity and concentration distributions implies a hazardous chemical reaction taking place within the hydrodynamic and specie boundary layers. <xref ref-type="fig" rid="fig7">Figure 7</xref> elucidate the effect of the Hartmann number (Ha) on a fluid velocity</p><p>curve. When the Hartmann number (Ha) is raised, the fluid velocity distribution shrinks. The Hartmann number is a gadget that has a significant influence on an electrically conducting fluid. In our model, an increase in the Hartmann number results in a significant drop in the velocity distribution and overall thickness of the hydrodynamic boundary layer for the case of an inclined magnetic field. This is because when the Hartmann number grows, so does the Lorentz force, which takes charge of lowering the velocity of electrically conducting fluids like the Casson fluid under consideration in this study. In <xref ref-type="fig" rid="fig8">Figure 8</xref>, the influence of the Soret parameter (So) on velocity and species distributions is illustrated. The value of So rises, raising both the velocity and concentration distributions. In the heat and mass transfer scenario, the Soret parameter (So) varies with temperature, but it is always included in the species equation. A larger Soret parameter</p><p>leads to exceptionally rapid migration of Casson nanofluid particles from the hot to the cold zone in the case of constant thermo-physical parameters investigated in this work. This kind of contribution is essential in isotope separation’s chemical engineering application. <xref ref-type="fig" rid="fig9">Figure 9</xref> and <xref ref-type="fig" rid="fig1">Figure 1</xref>0 show how the Dufour parameter influences the velocity and temperature distributions. Although it is usually included in the energy equation in the scenario of heat and mass transfer, it is a function of concentration in the physical phenomena of Dufour term. A greater Dufour parameter value drove the fluid particles into an environment where heat energy became critical. Heat energy improves the thermal condition of the fluid by increasing temperature distributions in the situation of constant thermo-physical parameters and an inclined magnetic field. <xref ref-type="fig" rid="fig1">Figure 1</xref>0 depicts the effect of the Brownian motion parameter on velocity and temperature curves. The velocity and temperature profiles improve as the Brownian motion parameter values are increased. Brownian motion increases the speed of fluids within the boundary layer. A random collision of fluid particles speeds up heat transfer within the boundary layer. As a result, the temperature distribution skews more. <xref ref-type="fig" rid="fig1">Figure 1</xref>1 depicts the influence of thermal radiation on velocity and temperature distributions. Thermal radiation contributes to the thermal state of the fluid layer physically. Raising the thermal radiation levels is now equal to increasing the fluid’s thermal state. As a result, it enhances the amounts of thermal radiation upshots the fluid’s speed and temperature distributions throughout the domain. <xref ref-type="fig" rid="fig1">Figure 1</xref>2 shows the influence of the Prandtl number on velocity and temperature distributions. A higher Prandtl number indicates more viscosity, which decreases velocities and, as a result, skin friction. Physically, a rise in the Prandtl number correlates with a reduction in fluid temperature and thermal boundary layer thickness. As a consequence, the fluid becomes quite welcoming. <xref ref-type="fig" rid="fig1">Figure 1</xref>3 depicts the influence of the Schmidt number on fluid flow and concentration</p><p>patterns. <xref ref-type="fig" rid="fig1">Figure 1</xref>3 shows how raising the concentration profile degenerates. It is the inverse percentage of the Brownian diffusion coefficient. As the moment rises, Brownian diffusion slows; causing the concentration to fall and alike result was established through Uddin et al. [<xref ref-type="bibr" rid="scirp.117543-ref25">25</xref>] (2019). Raising resulted in the same rate of spontaneous species spread, according to our numerical simulation. It’s important to note that when there’s a lot of species dispersion, the momentum diffusivity increases. The absence of species concentration is referred to as a “setting”. Rising presently reduces fluid concentration and reduces its visibility.</p><p><xref ref-type="table" rid="table2">Table 2</xref> depicts the effect of physical characteristics such as engineering factors of significance such as local skin friction, Nusselt and Sherwood number. Increased Casson parameter value increases local skin friction but has little change on Nusselt and Sherwood values. It has been discovered that increasing the thermal Grashof number and mass Grashof number raises the hydrodynamic</p><table-wrap id="table2" ><label><xref ref-type="table" rid="table2">Table 2</xref></label><caption><title> Contributions of β, Gr, Gm, Ha, Du, Cr, and So on the local skin friction (Cf), Nusselt number and Sherwood number</title></caption><table><tbody><thead><tr><th align="center" valign="middle"  rowspan="2"  >M</th><th align="center" valign="middle"  rowspan="2"  >Pr</th><th align="center" valign="middle"  rowspan="2"  >β</th><th align="center" valign="middle"  colspan="3"  >Present study</th><th align="center" valign="middle"  colspan="3"  >Gopal and Kishan [<xref ref-type="bibr" rid="scirp.117543-ref24">24</xref>] (2019)</th></tr></thead><tr><td align="center" valign="middle" >( 1 + 1 β ) C f ( 0 )</td><td align="center" valign="middle" >Nu</td><td align="center" valign="middle" >Sh</td><td align="center" valign="middle" >( 1 + 1 β ) C f ( 0 )</td><td align="center" valign="middle" >Nu</td><td align="center" valign="middle" >Sh</td></tr><tr><td align="center" valign="middle" >1</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.217582</td><td align="center" valign="middle" >0.432130</td><td align="center" valign="middle" >0.451896</td><td align="center" valign="middle" >0.217574</td><td align="center" valign="middle" >0.432128</td><td align="center" valign="middle" >0.451893</td></tr><tr><td align="center" valign="middle" >2</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.128460</td><td align="center" valign="middle" >0.43677</td><td align="center" valign="middle" >0.440688</td><td align="center" valign="middle" >0.128458</td><td align="center" valign="middle" >0.436076</td><td align="center" valign="middle" >0.0440687</td></tr><tr><td align="center" valign="middle" >3</td><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.049672</td><td align="center" valign="middle" >0.438545</td><td align="center" valign="middle" >0.432230</td><td align="center" valign="middle" >0.049668</td><td align="center" valign="middle" >0.438544</td><td align="center" valign="middle" >0.432229</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.5</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.296826</td><td align="center" valign="middle" >0.506368</td><td align="center" valign="middle" >0.364582</td><td align="center" valign="middle" >0.296824</td><td align="center" valign="middle" >0.506367</td><td align="center" valign="middle" >0.364580</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.0</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.381842</td><td align="center" valign="middle" >0.735880</td><td align="center" valign="middle" >0.045983</td><td align="center" valign="middle" >0.381841</td><td align="center" valign="middle" >0.735878</td><td align="center" valign="middle" >0.045981</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" >1.5</td><td align="center" valign="middle" ></td><td align="center" valign="middle" >0.432253</td><td align="center" valign="middle" >0.897216</td><td align="center" valign="middle" >0.020607</td><td align="center" valign="middle" >0.432251</td><td align="center" valign="middle" >0.897214</td><td align="center" valign="middle" >0.020605</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >1</td><td align="center" valign="middle" >0.200100</td><td align="center" valign="middle" >0.3603347</td><td align="center" valign="middle" >0.576828</td><td align="center" valign="middle" >0.200109</td><td align="center" valign="middle" >0.360345</td><td align="center" valign="middle" >0.576826</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >2</td><td align="center" valign="middle" >0.210308</td><td align="center" valign="middle" >0.362645</td><td align="center" valign="middle" >0.578047</td><td align="center" valign="middle" >0.201306</td><td align="center" valign="middle" >0.362643</td><td align="center" valign="middle" >0.578045</td></tr><tr><td align="center" valign="middle" ></td><td align="center" valign="middle" ></td><td align="center" valign="middle" >3</td><td align="center" valign="middle" >0.202275</td><td align="center" valign="middle" >0.363484</td><td align="center" valign="middle" >0578049</td><td align="center" valign="middle" >0.202273</td><td align="center" valign="middle" >0.363482</td><td align="center" valign="middle" >0.578045</td></tr></tbody></table></table-wrap><p>boundary layer, therefore increasing local skin friction. A species’ buoyant force is calculated using the thermal Grashof number. As the Hartmann number grows, so does the local skin friction along with the hydrodynamic boundary layer. A greater Eckert number improves local skin friction as well as the Nusselt number. As a result of excessive heat dissipation, the Eckert number generates kinetic energy, which is transformed to heat energy. A greater value of the chemical reaction parameter was shown to decrease the rate of mass transfer, whereas a higher value of the Soret and Dufour parameters was discovered to enhance the rate of mass transport. Increase the rate of heat and mass transfer.</p></sec><sec id="s5"><title>5. Conclusions</title><p>The spectral collocation approach was used to address the scenario of the dynamics of an angled magnetic field on the flow of Casson nanofluids under the effect of the Soret-Dufour mechanism. The results of the numerical calculations were graphed, while the calculations of engineering quantities of importance were discussed through tables. This study’s major results are as follows:</p><p>1) The inclined magnetic parameter is shown to have a considerable effect on fluid flow within the boundary layer by slowing down the fluid velocity distribution.</p><p>2) The Casson fluid’s plastic dynamic viscosity is detected to decelerate the fluid hydrodynamic boundary layer for a higher Casson parameter.</p><p>3) A greater value of the chemical reaction parameter is seen to reduce the fluid motion and concentration distributions.</p><p>4) The thermal Grashof number is seen to operate as a buoyancy force by significantly increasing the fluid motion.</p><p>5) The combined impacts of the Soret and Dufour processes are evident in the temperature and concentration distributions. An additional value of the Soret parameter influences fluid concentration by raising the distribution, whereas the Dufour parameter increases fluid temperature by elevating the profile.</p><p>6) The temperature boundary film tends to decline with an augmentation in the Prandtl number due to strong ambient heat diffusion.</p><p>As a result of better heat conduction and chemical species propagation, the findings in this work are critical to thermal engineering science and valuable in the growth of nanotechnology.</p><p>It will also aid in the enhancement of hydromagnetic lubricant due to the strong thermal conduction of Casson nanofluid. As a result, the research may be expanded to include flow in a concentric cylinder.</p></sec><sec id="s6"><title>Conflicts of Interest</title><p>The authors declare no conflicts of interest regarding the publication of this paper.</p></sec><sec id="s7"><title>Cite this paper</title><p>Akaje, T.W. and Olajuwon, B.I. (2022) The Effects of an Inclined Magnetic Field, Brownian Motion, and Thermophoresis on the Flow of Electrically Conducting and Chemically Reacting Casson Nanofluids Using Soret-Dufour Mechanisms. Advances in Nanoparticles, 11, 55-71. https://doi.org/10.4236/anp.2022.112005</p></sec></body><back><ref-list><title>References</title><ref id="scirp.117543-ref1"><label>1</label><mixed-citation publication-type="other" xlink:type="simple">Alao, F.I., Fagbade, A.I. and Falodun, B.O. (2016) Effects of Thermal Radiation, Soret and Dufour on an Unsteady Heat and Mass Transfer Flow of a Chemically Reacting Fluid Past a Semi-Infinite Vertical Plate with Viscous Dissipation. Journal of the Nigerian Mathematical Society, 35, 142-158.https://doi.org/10.1016/j.jnnms.2016.01.002</mixed-citation></ref><ref id="scirp.117543-ref2"><label>2</label><mixed-citation publication-type="other" xlink:type="simple">Parvin, S., Isa, S.S.P.M., Arifin, N. and Ali, F. 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