A theoretical study of a polysilicon solar cell with a radial junction in static regime under monochromatic illumination is presented in this paper. The junction radial solar cell geometry is illustrated and described. The carriers’ diffusion equation is established and solved under quasi-neutral base assumption with boundaries conditions and Bessel equations. New analytical expressions of electrons and holes photocurrent density and quantum efficiency are found. The wavelength and structural parameters (base radius, base thickness and wavelength) influences on photocurrent density and quantum efficiency are carried out and examined.
The importance that has taken renewable energies in the search for alternative sources of energy to fossil traditional energies because of their rarefaction and harmful impact on the environment is translated specially to photovoltaic energy by many studies on the solar cells. We can obtain energy by converting the solar energy to electrical energy with the semiconductor optoelectronic device such as the vertical junction solar cell or planar junction [
In this study based on a 2D modeling of a polycrystalline silicon radial junction solar cell, we made the following hypothesis:
- The grains have identical structures and electrical properties. Therefore, the study is restricted to a grain whose model is schematized in
- The solar cell is subjected to monochromatic front side illumination;
- The electrical field of crystal lattice and the thickness of space charge region are neglected.
The operation of radial junction solar cell is based on optical absorption in vertical direction (z). The photogenerated carriers’ charge collection is made in radial direction.
The transfer phenomenas of solar cell are model by the following equation of continuity numbered Equation (1) in cylindrical coordinates [
∂ 2 δ ( r , θ , z ) ∂ r 2 + 1 r ∂ δ ( r , θ , z ) ∂ r + 1 r ∂ 2 δ ( r , θ , z ) ∂ θ 2 + ∂ 2 δ ( r , θ , z ) ∂ z 2 − δ ( r , θ , z ) L 2 = − g ( λ , z ) D (1)
where:
g ( λ , z ) is carriers generation rate [
g ( λ , z ) = α ( λ ) ϕ 0 [ 1 − R ( λ ) ] e − α ( λ ) z (2)
- δ ( r , z ) : minority carriers’ density;
- D: carriers’ diffusion coefficient;
- L: carriers’ diffusion length.
As, we have an azimuthal symmetry, the angle θ is not processed [
● In the base region, the minority carriers’ movement is governed by:
∂ 2 δ n ( r , z ) ∂ r 2 + 1 r ∂ δ n ( r , z ) ∂ r + ∂ 2 δ n ( r , z ) ∂ z 2 − δ n ( r , z ) L n 2 = − g ( λ , z ) D n (3)
Referring to
– At the junction (r = Rb):
∂ δ n ( r , z ) ∂ r | r = R b = − S f 2 D n δ ( r = R b , z , λ ) (5)
– At the rear side (z = H):
∂ δ n ( r , z ) ∂ z | z = H = − S b D n δ ( r , z = H , λ ) (6)
A solution of equation is given by:
δ n ( r , z ) = ∑ k ≥ 0 ∞ f ( r , λ ) cos ( c k z ) (7)
The eigenvalues Ck which satisfy the boundary condition (6) are expressed by:
c k tan ( c k H ) = δ b D n (8)
The expression of photocurrent density is given by the following equation:
J p h b = − q D n ∫ 0 H ∂ δ n ( r , z ) ∂ r | r = R b d z (9)
Substituting δ n ( r , z ) in Equation (9); this equation becomes:
J p h b = q S f 2 c k ∑ k ≥ 0 ∞ ( A k ( λ ) I 0 ( R b L n k ) + M k ( λ ) ) sin ( c k H ) (10)
1) Internal quantum efficiency in the base
The expression of internal quantum efficiency (IQE) is giving by the following expression:
IQE ( λ ) = J p h B q ϕ 0 [ 1 − R ( λ ) ] (11)
By replacing J p h B expression (10) in Equation (11), we get Equation (12):
IQE ( λ ) = ∑ k ≥ 0 − S f 2 ϕ 0 C k [ 1 − R ( λ ) ] sin ( C k ⋅ H ) [ A k ( λ ) I 0 ( r b L n k ) + M k ( λ ) ] (12)
2) External quantum efficiency in the base
The expression of external quantum efficiency (EQE) is giving by the following expression:
EQE ( λ ) = J p h B q ϕ 0 (13)
By replacing J p h B expression (10) in Equation (13), we obtain
EQE ( λ ) = ∑ k ≥ 0 − S f 2 ϕ 0 C k sin ( C k ⋅ H ) [ A k ( λ ) I 0 ( r b L n k ) + M k ( λ ) ] (14)
I 0 ( x ) is the modified Bessel function of the first kind of zero order and I ′ 0 ( x ) is its first derivative with respect to its argument.
We present here the simulation results obtained from the previous modeling equations by using Mathcad software.
The effects of wavelength, base radius and base thickness photocurrent density are presented and analyzed.
We remark a low photocurrent density for low and big wavelength. The absorption peak is notified around 700 nm.
These phenomena are explained by electrons density variations. In additional, photocurrent density increase for 10 2 cm / s ≤ S f ≤ 10 6 cm / s because more electrons cross the junction.
For S f ≺ 10 2 cm / s , photocurrent density is almost zero because there is a low displacement and strong accumulation of electrons near the junction. Solar cell is then an open circuit state [
The following figures present variations of photocurrent density as a function
of base radius for different values of the depth creating more electrons because the emitter thickness increase.
On
The photocurrent increase with the increase of base radius Rb. The base radius increase creates a large incident light absorption, thus leading to a large of carriers photogenerations in solar cell. Also, this is due to the increasing of base radius minimizes the recombinations which lead to a storage of charge carriers in the base. Results are in good with those obtained by [
In
The internal quantum efficiency decrease when the base radius increase. This is a consequence of the increase of carriers’ density with base radius because much carriers are collected. Also, the electron maximum decrease in the base depth explaining these variations.
In
The observing of curves indicate the decrease of internal quantum efficiency with base thickness increase. This increase is relatively greater than the increase with base radius. This increase is explained also by the silicon polycrystalline which grains are small thickness.
In figures, the variations of internal quantum efficiency with wavelength for various values of base thickness and base radius are presented.
Whether
- 300 μ m ≤ λ ≤ 600 μ m , the internal quantum efficiency increase with wavelength for various values of base thickness or base radius because the absorption increase with wavelength up to reach the peak (silicon energy gap 1.12 eV). The generation of electrons is great for small values of wavelength. This low increase is
- The internal quantum efficiency maximum value is reached to 600 µm. The generation of electron is very important for this wavelength value.
- 600 μ m ≤ λ ≤ 900 μ m , the internal quantum efficiency decrease with wavelength for various values of base thickness or base radius. This decrease can be explained by the reduction of electrons density in the base. Also, for big values of wavelength, there is no electron generation in the base.
The different variations of internal quantum efficiency are explained by the photocurrent variations. Also, the internal quantum is as a function of photocurrent.
The influences of base radius on external quantum efficiency are illustrated in
The curves analysis indicates that the external quantum efficiency increase crease with base radius. For λ ≥ 700 μ m , the decrease is asymptotic as if there is none incident absorption so none photocurrent.
The impacts of base thickness on external quantum efficiency are illustrated in
The external quantum efficiency decrease with the increase of base thickness. So the reduction of base thickness traduce the decrease of the carriers surface generation.
In figures, the curves of external quantum efficiency with wavelength for various values of base thickness and base radius are plotted.
Whether the figure, the curves of internal quantum efficiency present two parts:
- 300 μ m ≤ λ ≤ 700 μ m , the decrease of external quantum efficiency is slow.
- λ ≥ 700 μ m , the decrease of external quantum efficiency is asymptotic.
For short wavelengths, only a small fraction of the light is converted into electron –holes pairs. Most photons are already absorbed in the layers that the light traverses prior to the absorber layer; this is called parasitic absorption.
This paper carried out 2D modelling of radial junction of solar cell. The effects of base radius, base thickness and wavelength on carriers’ photocurrent density and quantum efficiency are investigated.
Also, the influences of base radius, base thickness and charges carriers’ recombination velocity on photocurrent density and quantum efficiency of solar cell are presented and analyzed. The results of this study which are in good agreement with other research works [
The 2D modeling of solar cell p-n radial junction quantum efficiency is studied in first time in cylindrical coordinates according to our research. So this work will permit to study better the radial junction of solar cell. In the future, we will try to make an experimental study to confirm theoretical results with experimental results.
The authors declare no conflicts of interest regarding the publication of this paper.
Sam, R., Diasso, A., Zouma, B. and Zougmoré, F. (2020) 2D Modeling of Solar Cell p-n Radial Junction: Study of Photocurrent Density and Quantum Efficiency in Static Mode under Monochromatic Illumination. Smart Grid and Renewable Energy, 11, 191-200. https://doi.org/10.4236/sgre.2020.1112012