The as crystallized lead iodide perovskite, Graphene-CH₃NH₃PbI₃ on glass and powder crystal were fully characterized avoiding misconception in this manuscript where iodide leads source for the crystal formation, but performs as crystallization and enters in the lattice of the perovskite. The crystal structure and purity of the synthesized MAPbI₃ (CH₃NH₃PbI₃) and G-MAPbI₃ nanoparticles were determined by powder X-Ray diffraction (XRD, Diffractometer at WMSRC, JU, Bangladesh). The intensities and positions of observed diffraction peaks are good agreement and the resolution of the main diffraction peaks reflects the good crystallization of the MAPbI₃ nanoparticles. Figure 1(a) and Figure 1(b) show powder and thin film XRD peaks of synthesized Methyl ammonium Lead Iodide and graphene incorporated Methyl ammonium Lead Iodide. Major planes (110) and (220) are indexed at angle 14.08˚and 28.33˚ first and second-order peak maxima respectively and few peaks are assigned to the glass substrate which confirmed the monoclinic lattice system (Table 1). Crystallinity and volume of the unit cell are augmented with the graphene incorporation (G: 0.05 g/mole) 94.65 nm to 113.43 nm for powder and 117.15 nm to 141.94 nm (From XRD by Scherer Equation) for a thin film which was presented using full-width half maxima (FWHM) which accumulated uniformly due to sharp peaks achieved. Only a few pinholes and with quite bulky grains were found with compact perovskite layer in the top view of perovskite films (Figure 2(a)).

*(Using XRD data by full proof software).

Film thickness was measured 2 μm, 4 μm, 4.5 μm, 5 μm and 6 μm by Surface Profilometer (Dektak XT-BCSIR, Dhanmondi, Dhaka, Bangladesh) of the pristine solution, G: 0.05 g/mole, G: 0.10 g/mole, G: 0.20 g/mole and G: 0.30 g/mole respectively. The UV-Visible absorption spectra are plotted together pristine perovskite solution and with different concentrations of graphene at 400 to 800 nm (Figure 3(a) and Figure 3(b)) to further confirm the proper powder crystal and thin film formation of the graphene composites perovskite onto ITO substrate. The as-deposited Graphene incorporated were studied and compared to the pristine CH₃NH₃PbI₃ in terms of the reduction degree and the chemical

bonding by X-ray photoelectron spectroscopy (XPS) [36].

There are numerous peaks indicate different chemical bonds which confirm pristine perovskite whose graphene composition from these three FTIR (SHIMADZU, IR Tracer-21, WMSRC, JU, Bangladesh) curves spectrum of MAI, MAPbI₃ and G-MAPbI₃ (Figure 2(e)). Water molecule bond O-H stretching attributed at about 3510 cm⁻¹ presented in all three curves due to the atmospheric synthesis process. The alkenes group of C-N stretching is found in vibration mode 3120 cm⁻¹ of MAPbI₃ and 3118 cm⁻¹ for G-MAPbI₃ but this curve is smaller than MAI. The bond C-H (2960 cm⁻¹) stretching amines, C-H (1370 cm⁻¹) bending alkenes, alkenes bending NH₃ (1566 - 1570 cm⁻¹) and C-O (1630 - 1635 cm⁻¹) bending are attributed at both materials as-synthesized MAPbI₃ and G-MAPbI₃ (Table 2) [37].

Graphene incorporated CH₃NH₃PbI₃ is proposed as an effectual way to enhance PCE% of both PSCs by restraining the charge wounded stirring at the perovskite/TiO₂ interface, recovering the stability at the same time. Absorptions (Figure 3(a) and Figure 3(b)) are optimized (390 nm - 500 nm) at Graphene (0.05 g/mole) incorporation and reduced other Graphene concentration of perovskite investigating for both powder crystal and thin film. From thin film characterization i.e. the corresponding band gap is determined from Tauc plot (Graphene 0.05 g/mole) is reduced at 1.45 eV to 1.32 eV but it is larger about 2.90 eV (Table 3, Figure 4(c) and Figure 4(d)) at powder crystal. As we can see from Figure 3(a), Figure 3(b) and Figure 4(a), Figure 4(b) graphene concentration absorptions that were 0.1 g/ml, 0.2 g/ml were no answer to the specifications for thin film and powder crystal, the following stage has not been used to develop the perovskite solar cell.

*(using FTIR data by origin software).

At high humidity (99% RH) current-voltage (I-V) curves were obtained after revealing the CH₃NH₃PbI₃ solar cell for different graphene composition. The swift decline in the open circuit-voltage and short-circuit current density of the undefended CH₃NH₃PbI₃ cells showed a (Figure 5(d), Figure 5(e)) with time. After 30 days of revelation to moisture, no photovoltaic behavior is seen from the cells but Graphene incorporated PSCs still work up to 150 days (Figure 5(b)) Mounting the thickness by overlayer (~4 μm) stability of the cells from moistures are improved encapsulated with graphene/CH₃NH₃PbI₃. Graphene solution with pristine perovskite solar cell using spin coating three times mentioned little variation in cell performance with time but in a different composition of graphene deposited solar cells continuously exposed longtime to high humidity. Water molecules have to move before they can contact the CH₃NH₃PbI₃ crystal tortuosity in the path rises with increasing thickness of the composite. The best performing cell with a graphene composite demonstrated a photocurrent 0.1 mA·cm⁻² (Table 4 supporting information) and an open-circuit voltage 0.368 V (Figure 5(e)). We look forward to the perovskite degradation regardless of the series(R_S) and shunt(R_SH) resistances mechanism is calculated to

investigate the effect of graphene protective coating on the electrical performance of the PSCs. Graphene concentration reveals lower recombination losses than lead iodide that performs of the device can be optimized. Due to the low conductivity of ITO when compared with lead iodide devices fabricated utilizing graphite itself as the HTL illustrated lower short circuit current 68 μA and open-circuit voltage of 368 mV (supporting information, Figure 5(d), Figure 5(e)). Depend on different concentrations of graphene incorporation with CH₃NH₃PbI₃ PSCs, photocurrents are varied due to the graphene composite averting the direct contact of TiO₂(ETL) and performing as a buffer layer and the lead iodide.

Another degradation of the perovskite layer was investigated due to the transmission of moisture and oxygen into the perovskite which is machinery to be identical though shunt and series resistances of the cells were present [38]. Therefore, high-efficiency cells could be achieved with higher shunt resistances and lower series (compared to best-performing cells). Without any shielding graphene layer, the PSC device demonstrated shunt resistance (R_SH) 18.7 KΩ and series resistance (R_s) 20.6 KΩ. The device one with graphene (0.05 g/mole) composite revealed a reduced in both R_SH and R_S to a 16.6 KΩ and 19.3 KΩ respectively. Compared to other graphene composition lead-based PSCs R_SH and R_S resistances are growing concerning the second one. The perovskite a larger nano amalgamated is twisted in which the volume of unit cell augmented 776 (Å)³ to 2003 (Å)³ (Table 1 supporting information) owing to graphene incorporation. Beside the electrons of TiO₂ and holes of PbI₂ illustrated the way to the lower shunt resistance (R_SH) due to PbI₂ may arrive in contact with the TiO₂ [39].

The best performance of perovskite device showed (Figure 5(e)) power conversion efficiency (PCE%) 0.017% (1.5 AM at 25˚C and power 1 KW, BCSIR, Dhaka, Bangladesh), with Current density J_sc = 420 μA/cm², V_oc = 368 mV and FF = 47.2% (Table 4 supporting information). Devices were investigated in a range −5V to +5V for dark current renovating behavior of cell operating under the dark condition where the high dark current was established (Figure 5(d), Figure 5(e)) at survival of high outflow current may be due to the undeviating construct contact between the graphite (HTL) and TiO₂. Under atmospheric conditions the dispensation of CH₃NH₃PbI₃ cells reviewed with graphene composite which could consent to the high moisture impermeability. A main strategy to reduce the cost of production of perovskite solar cells for rolling-to-roll coated plate sandwiches. For the long time stability of PSCs similar perception can also be effective in the design of different materials for further research.

Two arms flask was filled with methylamine 20 ml adding hydrochloric acid 17 ml (32% in water, from Merck) drop wise with methylamine solution (40% mono, from Qualikems) and Methylammonium iodide (CH₃NH₂I:MAI) was obtained at (8˚C - 10˚C) for 1 h with stirring. MAI was potted in an ice bath for 2hrs and preserved on an oven suspiciously removing the solvent at 60˚C. Using diethyl ether (from Merck) the crystalline CH₃NH₃I was uncontaminated several times and dried light black powder of CH₃NH₃I was collected. For the synthesis of perovskite CH₃NH₃PbI₃ precursor, 0.794 g CH₃NH₃I was dissolved into 5 mL N, N-dimethylformamide and 2.305 g PbI₂ was dissolved into 5 mL N, N-dimethylformamide (1:1) separately [40]. Then the prepared solutions were added and a light yellow solution of CH₃NH₃PbI₃ was obtained (Figure 2(a)). Graphene was prepared according to a modified Hummer’s Method and it was added at concentrations 0.05 g·ml⁻¹, 0.10 g·ml⁻¹, 0.20 g·ml⁻¹ at 45 mass% with pristine perovskite (Figure 2(b)) solution to obtain G-MAPbI₃.

Using PEG (Polyethylene Glycol), TiO₂ and Distilled water respectively 1:3:20 ratios mixed at high humidity (99% RH) to obtain TiO₂ solution. Proper dispersion of TiO₂ solution to deposit uniform film PEG typically used [41]. Dr. Blade's method was followed to deposit TiO₂ film on pre-cleaned ITO (ITOs were cleaned by ultrasonic bath sequentially in normal distilled water, ethanol and acetone, pursued by drying in an oven at 60˚C). For better film stickiness substrates were transferred into a furnace to anneal at 400˚C for 25 mins. Pristine solutions were deposited on coated ITO by spin-coater (2000 rpm for the 30s) and heating 80˚C until crystal growth under atmospheric condition. Then, the substrates were sandwiched together by another graphite coated ITO (Figure 5(c)).

To analysis light absorption, transmittance, band gap calculation and co-efficient of absorbance of materials, UV-Vis Spectrophotometer (Model: UVS-2800 at a wavelength range of 200 nm - 1100 nm) were used. Determination of crystallite size, lattice parameters i.e. unit cell volume, edge length, lattice system, crystallinity and uniformity of crystal of perovskites X-Ray Diffraction (XRD) data were collected on GBC EMMA X-ray diffractometer (Cu Kα radiation, λ = 1.54 Å) at WMSRC, Jahangirnagar University, Bangladesh. The scanning angular range was 5˚ ≤ 2θ ≤ 50˚ to get possible fundamental picks for each sample. The measuring film thickness of perovskites, TiO₂, graphite and ITO, Surface Profilometer (Dektak XT-BCSIR, Dhanmondi, Dhaka, Bangladesh) was used. FTIR (SHIMADZU, IR Tracer-21, wave number 400 cm⁻¹ to 4000 cm⁻¹, WMSRC, JU, Bangladesh) was used to ensure the chemical of the bond which are present on samples. To certify the performance of perovskite solar cells, Solar Simulator (IEC 60904-9 Edition2 and ASTM E927-10 standards, BCSIR, Bangladesh) under an AM1.5G filter at 100 mW·cm⁻² was used.