Article citationsMore>>
T. Malinski, A. Ciszewski, J. Fish, E. Kubaszewski and L. Czuchajowski, “Concuctive Polymeric Cu(II) Tetrakis (3-methoxy-4-hydroxyphenyl) Porphyrin as a Photosensitizer in a Photoelectrochemical Cell,” Advanced Materials, Vol. 4, No. 5, 1992, pp. 354-357.
http://dx.doi.org/10.1002/adma.19920040508
has been cited by the following article:
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TITLE:
Enhanced Electrocatalytic Reduction of Oxygen at Electrodes Coated with a Multi-Metallic Co(II)/Pt(II) Porphyrin
AUTHORS:
Shawn Swavey, David Fresh
KEYWORDS:
Oxygen Electrocatalysis; Cobalt; Platinum; Porphyrin
JOURNAL NAME:
American Journal of Analytical Chemistry,
Vol.4 No.10A,
October
25,
2013
ABSTRACT: Edge plane pyrolytic graphite (EPG) electrodes coated with the Co(II)/Pt(II)2 analog of 5,15-bis-(4-pyridyl)-10,20-bis-(3-methoxy-4-hydroxyphenyl)porphyrin undergo an electrochemical-chemical-electrochemical (ECE) reaction when anodically scanned in 1.0 M sulfuric acid. The new redox couple formed from this anodic conditioning of the coated electrode is dependent on the pH of the solution. Roughened EPG electrodes coated with the Co(II)/Pt(II)2 trimetallic porphyrin show a catalytic shift of 400 mV for the reduction of O2 when compared to the reduction of O2 at a bare EPG electrode. An additional catalytic shift of ca. 150 mV is observed for O2 reduction at an EPG electrode coated with the Co(II)/Pt(II)2 porphyrin which has been oxidized in 1.0 M sulfuric acid. In addition to the added electrocatalysis, a significant percentage of O2 reduced at the oxidized Co(II)/Pt(II)2 EPG electrode is converted to H2O as determined by rotating disk electrode measurements.