Article citationsMore>>

E. Song, C. Shi and F. C. Anson, “Comparison of the Behavior of Several Cobalt Porphyrins as Electrocatalysts for the Reduction of O2 at Graphite Electrodes,” Langmuir, Vol. 14, No. 15, 1998, pp. 4315-4321.
http://dx.doi.org/10.1021/la980084d

has been cited by the following article:

• TITLE: Enhanced Electrocatalytic Reduction of Oxygen at Electrodes Coated with a Multi-Metallic Co(II)/Pt(II) Porphyrin

  AUTHORS: Shawn Swavey, David Fresh

  KEYWORDS: Oxygen Electrocatalysis; Cobalt; Platinum; Porphyrin

  JOURNAL NAME: American Journal of Analytical Chemistry, Vol.4 No.10A, October 25, 2013

  ABSTRACT: Edge plane pyrolytic graphite (EPG) electrodes coated with the Co(II)/Pt(II)2 analog of 5,15-bis-(4-pyridyl)-10,20-bis-(3-methoxy-4-hydroxyphenyl)porphyrin undergo an electrochemical-chemical-electrochemical (ECE) reaction when anodically scanned in 1.0 M sulfuric acid. The new redox couple formed from this anodic conditioning of the coated electrode is dependent on the pH of the solution. Roughened EPG electrodes coated with the Co(II)/Pt(II)2 trimetallic porphyrin show a catalytic shift of 400 mV for the reduction of O2 when compared to the reduction of O2 at a bare EPG electrode. An additional catalytic shift of ca. 150 mV is observed for O2 reduction at an EPG electrode coated with the Co(II)/Pt(II)2 porphyrin which has been oxidized in 1.0 M sulfuric acid. In addition to the added electrocatalysis, a significant percentage of O2 reduced at the oxidized Co(II)/Pt(II)2 EPG electrode is converted to H2O as determined by rotating disk electrode measurements.