TITLE:
Carbon Nanotubes/Metal Nanoparticle Based Nanocomposites: Improvements in Visible Photoluminescence Emission and Hydrophobicity
AUTHORS:
M. Barberio, P. Barone, F. Stranges, A. Romano, F. Xu, A. Bonanno
KEYWORDS:
Metal Nanoparticle; Carbon Nanotube; Nanocomposite; Laser Ablation; Photoluminescence
JOURNAL NAME:
Optics and Photonics Journal,
Vol.3 No.6A,
October
25,
2013
ABSTRACT: In this work, we present a study of growth and
characterization of nanocomposites, based on multiwalled carbon nanotubes and
metal nanoparticles (Al, Ag, Au, Co, Cu, Fe, Ni and Ti). We observe a very
different behavior between noble and transitions metals. All the nanocomposites
are characterized by a network of carbon nanotubes with randomly insertion of
spherical metal particles with dimensions of about 100 nm (clearly visible in
SEM images). In particular, in transition metal nanocomposites, each
tube on sheet surface is covered by particles of about 40 - 50 nm
and for all metals the XPS measurements indicate the absence of chemical bonds
and the simply physisorption of nanoparticle on carbon nanotube buckypaper.
Furthermore, the nanocomposites show very different properties respect to pure
carbon nanotubes: they are hydrophobic, their roughness is about 50% smaller
than carbon nanotube and they exhibit a strong visible photoluminescence, which
is absent in pure nanotube.