TITLE:
Study on the Structure of Peroxide Cross-Linked Polyethylene Pipes with Several Stabilizers
AUTHORS:
Hideo Hirabayashi, Akinori Iguchi, Kazushi Yamada, Hiroyuki Nishimura, Kazuhisa Ikawa, Hidekazu Honma
KEYWORDS:
Cross-Linked; Polyethylene; PEX-a; Peroxide; Structure of Cross-Linking
JOURNAL NAME:
Materials Sciences and Applications,
Vol.4 No.9,
September
3,
2013
ABSTRACT: Cross-linked polyethylene (PEX) pipes used in hot water supply are required for high mechanical strength and high creep resistance at high temperature. Especially PEX-a pipes which are made by peroxide cross-linking have better performance, such as creep resistance and thermal shock resistance than the pipes made by the other cross-linking method. Because the PEX-a pipes indicate the higher cross-link degree as compared with the other PEX pipes. In this study, the PEX-a pipes which were mixed with several stabilizers were tested to evaluate the effects on cross-link degree and the oxygen induction time. And also they are evaluated with the chlorine aqueous solution by the performance of the long-term hydrostatic pressure test and the long-term hydro dynamic pressure test. As a result, it was found that the combination of antioxidants for PEX-a pipes plays an important role to prolong the oxygen induction time without inhibiting the cross-linking. From the results of the 1H pulsed NMR measurement over the melting point of polyethylene, it was found that each peroxide PEX pipe with different antioxidant combinations indicated the different proportion and crosslink density of cross-linked region, in addition, that these pipes had the effective structure of cross-linking for the hydrostatic and hydrodynamic pressure test with the chlorine aqueous solution. Therefore, it was considered to be useful results for studies of the stricture of cross-linking of polyethylene.