Article citationsMore>>
J. Dai, G. Q. Bian, X. Wang, Q. F. Xu, M. Y. Zhou, M. Munakata, et al., “A New Method to Synthesize Unsymmetrical Dithiolene Metal Complexes of 1,3-Dithiole-2-Thione-4,5-Dithiolate for Third-Order Nonlinear Optical Applications,” Journal of America Chemistry Society, Vol. 122, 2000, pp. 11007-11008. doi:10.1021/ja001976e
has been cited by the following article:
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TITLE:
Study on the Third-order Nonlinear Optical Properties of bis(tetraethylammonium) bis(1,3-dithiole-2-thione-4,5-dithiolato)cadium
AUTHORS:
Hongliang Yang, Fujun Zhang, Xinqiang Wang, Guanghui Zhang
KEYWORDS:
Optical Nonlinearity; Kerr Gate Technology; Response Time
JOURNAL NAME:
Optics and Photonics Journal,
Vol.3 No.2B,
July
18,
2013
ABSTRACT: A dmit2- salt:
bis(tetraethylammonium)bis(1,3-dithiole-2-thione-4,5-dithiolato)cadium (CADMIT)
was synthesized. The Optical Kerr Effect (OKE) signal of its acetonitrile
solution was measured by femtosecond optical Kerr gate technique. Using CS2 OKE signal as reference signal measured under identical conditions, the
third-order optical nonlinear susceptibility, c(3), of the sample solution was
obtained to be about 2.98 x 10-14 esu at the concentration of 1.57 x 10-3 M. The second-order hyperpolarizability of its molecular was estimated to be as
large as 1.23 x 10-32 esu. Its response time was about 195 fs, which is believed to be the
contribution from the delocalized electrons.