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A. Hinz, B. Nilsson and A. Andersson, “Simulation of Transients in Heterogeneous Catalysis: A Comparison of the Stepand Pulse-Transient Techniques for the Study of Hydrocarbon Oxidation on Metal Oxide Catalysts,” Chemical Engineering Science, Vol. 55, No. 20, 2000, pp. 4385-4397.

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• TITLE: Thermodynamic Assessment of the Pt-Sb System

  AUTHORS: Jinming Liu, Yinghui Zhang, Cuiping Guo

  KEYWORDS: Pt-Sb Phase Diagram; Thermodynamic Assessment; Thermodynamic Properties; CALPHAD Technique

  JOURNAL NAME: International Journal of Nonferrous Metallurgy, Vol.2 No.3, July 3, 2013

  ABSTRACT: The Pt-Sb system was critically assessed by means of CALPHAD technique. Based on the experimental data in the literature, the excess Gibbs energies of the solution phases (liquid, rhombohedral, fcc) were modeled with the Redlich-Kister equation. The five intermetallic compounds, Pt7Sb, Pt3Sb, Pt3Sb2, PtSb, and PtSb2 were treated as stochiometric compounds and expressed as the formula (Pt)m(Sb)n. The intermetallic compound, Pt5Sb with a homogenerity ranges 0.155 -0.189 Sb, were treated as the formula (Pt,Sb)m(Pt,Sb)n. A set of self-consistent thermodynamic parameters of the Pt-Sb system was obtained.