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W. R. Lee, M. G. Kim, J. R. Choi, J. L. Park, S. J. Ko, S. J. Oh and J. Cheon, “Redox-Transmetalation Process as a Generalized Synthetic Strategy for Core-Shell Magnetic Nanoparticles,” Journal of American Chemistry Society, Vol. 127, No. 46, 2005, pp. 16090-16097. doi:10.1021/ja053659j

has been cited by the following article:

• TITLE: Synthesis and Surface Modification of Spindle-Type Magnetic Nanoparticles: Gold Coating and PEG Functionalization

  AUTHORS: Juan Mendez-Garza, Biran Wang, Alexandra Madeira, Christophe Di Giorgio, Georges Bossis

  KEYWORDS: Core@shell; Spindle-Type; Hematite; Magnetic Particles; Gold Coating; Fluorescent-PEG

  JOURNAL NAME: Journal of Biomaterials and Nanobiotechnology, Vol.4 No.3, June 26, 2013

  ABSTRACT: In this paper, we describe the synthesis of gold coated spindle-type iron nanoparticles and its surface modification by a thiolated fluorescently-labelled polyethylene glycol (PEG) polymer. A forced hydrolysis of ferric salts in the presence of phosphate ions was used to produce α-Fe2O3 spindle-type particles. The oxide powders were first reduced to α-iron under high temperature and controlled dihydrogen atmosphere. Then, the resulting magnetic spindle-type particles were covered by a shell of gold. The formation of the core@shell structure was driven by a redox-transmetalation reaction between iron(0) at the surface of particles and a gold(III) salt. Protected against oxidation, the Fe@Au core@shell nanoparticles were then grafted with a water soluble fluorescent-PEG-thiol. TEM, XRD, EDX and measurements of magnetic properties of particles confirm 1) the conversion of hematite into iron and 2) their subsequent surface protection with a gold shell. Furthermore, the functionalization of the gold nanoparticle surface with a PEG carrying a fluorescent dye was unambiguously attested by confocal laser scanning microscopy.