TITLE:
Synthesis and characterization of a ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide
AUTHORS:
Jing Chen, You-Juan Zhang, Kun-Tao Huang, Qiang Huang
KEYWORDS:
Nitronyl Nitroxide; Anionic Radical;Ladder-Like Structure; Cd (II) Complex
JOURNAL NAME:
Open Journal of Inorganic Chemistry,
Vol.3 No.3,
June
25,
2013
ABSTRACT: A ladder-like structure compound formed by cadmium (II) and anionic nitronyl nitroxide,
[Cd2(NITpBA)4(H2O)4]
(where NITpBA = 2-(4-carboxyphenyl)4,4,5,5-tetramethyl-4,5-dihydro-imidazol-1-oxyl-3-oxide), has been synthesized and
characterized. X-ray analysis reveals that the compound
1 crystallizes in the monoclinic P21/c (No. 14) space group, and [Cd2(NITpBA)4(H2O)4]
units are linked into infinite chains by radical bridging ligands.