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M. Hughes, G. Z. Chen, M. S. P. Shaffer, D. J. Fray and A. H. Windle, “Electrochemical Capacitance of a Nanoporous Composite of Carbon Nanotubes and Polypyrrole,” Chemistry of Materials, Vol. 14, No. 4, 2002, pp. 1610-1613. doi:10.1021/cm010744r

has been cited by the following article:

• TITLE: Graphene/Polypyrrole Nanocomposite as Electrochemical Supercapacitor Electrode: Electrochemical Impedance Studies

  AUTHORS: Punya A. Basnayaka, Manoj K. Ram, Lee Stefanakos, Ashok Kumar

  KEYWORDS: Capacitance; Graphene; Conducting Polymers; Equivalent Circuit; Time Constant

  JOURNAL NAME: Graphene, Vol.2 No.2, April 30, 2013

  ABSTRACT: Graphene-Polypyrrole (G/PPy) was synthesized by chemical oxidative polymerization method, and electrochemical impedance spectroscopy (EIS) analysis was employed to study the frequency response characteristics of supercapacitors based on G/PPy conducting polymer nanocomposite. It is found that a uniform G/PPy nanocomposite is formed with polypyrrole (PPy) being homogeneously surrounded by graphene nanosheets. The porous structure allowed electrolyte and ions diffusion in synthesized G/PPy nanocomposite. The metallic conductivity of Graphene-polypyrrole exhibited higher knee frequency at 125 Hz than the knee frequency of pristine PPy at 36 Hz. The high knee frequency of G/PPy supercapacitor is indicative of high power application and long cycle life. The G/PPy nanocomposite based supercapacitor with 1MH2SO4 as the electrolyte showed specific capacitances of 270 F/g at 0.1 Hz and112 F/g at 125 Hz.