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X. Gao and D. Dollimore, “The Thermal Decomposition of Oxalates: Part 26. A Kinetic Study of the Thermal Decomposition of Manganese(II) Oxalate Dihydrate,” Thermochimica Acta, Vol. 215, No. 2, 1993, pp. 47-63. doi:10.1016/0040-6031(93)80081-K

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• TITLE: Study of Crystallization Process in Se80In10Pb10 by Iso-Conversional Methods

  AUTHORS: Indra Sen Ram, Kedar Singh

  KEYWORDS: Iso-Conversional; Crystallization Kinetics; Activation Energy; Avrami Exponent

  JOURNAL NAME: Journal of Crystallization Process and Technology, Vol.3 No.2, April 30, 2013

  ABSTRACT: The crystallization kinetics of Se80In10Pb10 chalcogenide glass is studied using differential scanning calorimeter (DSC) at different heating rates (5, 10, 15 and 20 K/min) under non-isothermal conditions. Four iso-conversional methods (Kissinger-Akahira-Sunose, Flynn-Wall-Ozawa, Tang and Straink) were used to determine various kinetic parameters: crystallization temperature (Tα), activation energy of crystallization (Eα), Avrami exponent (nα) in non-isothermal mode. The transformation from amorphous to crystalline phase in Se80In10Pb10 is considered as a single step reaction mechanism.