TITLE:
Synthesis, structures, and properties of two new binuclear complexes based on carboxyl-substituted nitronyl nitroxide: [M2(NITpBA)4(H2O)2] (M = Zn and Cu)
AUTHORS:
Jing Chen, You-Juan Zhang, Kun-Tao Huang, Qiang Huang, Jun-Jie Wang
KEYWORDS:
Binuclear Complex; Carboxyl-Substituted; Nitronyl Nitroxide; Antiferromagnetic Exchange
JOURNAL NAME:
Open Journal of Inorganic Chemistry,
Vol.3 No.2,
April
30,
2013
ABSTRACT: Two new
binuclear complexes, [M2(μ-NITpBA)4(H2O)2] (M = Zn 1 and Cu
2) [where NIpBA =2-(4-carboxyl-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide], were stylized and characterized. Magnetic susceptibility measurements revealed antiferromagnetic exchange interactions
in two complexes.