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Caneschi, A., Gatteschi, D., Sessoli, R. and Rey, P. (1989) Toward molecular magnets: The metal-radical approach. Accounts of Chemical Research, 22, 392-398. doi:10.1021/ar00167a004

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• TITLE: Synthesis, structures, and properties of two new binuclear complexes based on carboxyl-substituted nitronyl nitroxide: [M2(NITpBA)4(H2O)2] (M = Zn and Cu)

  AUTHORS: Jing Chen, You-Juan Zhang, Kun-Tao Huang, Qiang Huang, Jun-Jie Wang

  KEYWORDS: Binuclear Complex; Carboxyl-Substituted; Nitronyl Nitroxide; Antiferromagnetic Exchange

  JOURNAL NAME: Open Journal of Inorganic Chemistry, Vol.3 No.2, April 30, 2013

  ABSTRACT: Two new binuclear complexes, [M2(μ-NITpBA)4(H2O)2] (M = Zn 1 and Cu 2) [where NIpBA =2-(4-carboxyl-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide], were stylized and characterized. Magnetic susceptibility measurements revealed antiferromagnetic exchange interactions in two complexes.