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A. Nytén, A. Abouimrane, M. Armand, T. Gustafsson and J. O. Thomas, “Electrochemical Performance of Li₂FeSiO₄ as a New Li-Battery Cathode Material,” Electrochemical Communications, Vol. 7, No. 2, 2005, pp. 156-160. doi:10.1016/j.elecom.2004.11.008

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• TITLE: Synthesis, Characterization and Charge-Discharge Properties of Layer-Structure Lithium Zinc Borate, LiZnBO3

  AUTHORS: Isao Tsuyumoto, Akihiro Kihara

  KEYWORDS: Oxide; Borate; Lithium; Zinc; X-Ray Diffraction; Battery

  JOURNAL NAME: Materials Sciences and Applications, Vol.4 No.4, April 29, 2013

  ABSTRACT: Layer-Structure lithium zinc borate, LiZnBO3, is prepared by a solid state reaction of LiOH·H2O, ZnO, and H3BO3 at 1000°C for 10 h. Highly preferred orientation and a layer-structure are observed in the powder XRD patterns and the SEM images, respectively. The Rietveld analysis indicates a monoclinic unit cell with space group C2/c, and the lattice parameters are refined as a = 8.827 ?, b = 5.078 ?, c = 6.171 ?, and β = 118.86°. LiZnBO3 shows the capacity of 17 mAh/g between 1.3 V and 4.3 V (vs. Li/Li+) larger than ZnO.