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R. J. Whewell, M. A. Hughes and C. Hanson, “The Kinetics of the Solvent Extraction of Copper(II) with LIX Reagents-III. The Effects of LIX 63N in LIX 64N,” Journal of Inorganic and Nuclear Chemistry, Vol. 38, No. 11, 1976, pp. 2071-2075. doi:10.1016/0022-1902(76)80471-X

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• TITLE: Extraction Kinetics of Ni(II) in the Ni2+- SO42--Ac-(Na+, H+)-Cyanex 272 (H2A2)-Kerosene-3% (v/v) Octan-1-ol System Using Single Drop Technique

  AUTHORS: Ranjit Kumar Biswas, Aneek Krishna Karmakar, Muhammad Saidur Rahman

  KEYWORDS: Kinetics; Cyanex 272; Sulphate; Kerosene; Ni2+; Single Drop Technique

  JOURNAL NAME: International Journal of Nonferrous Metallurgy, Vol.2 No.2, April 29, 2013

  ABSTRACT: The kinetics of extraction of Ni(II) in the Ni2+-SO4 2_AC- (Na+, H+)-Cyanex 272 (H2A2)-kerosene-3% (v/v) octan-1-ol system using the single falling drop technique have been reported. The flux of Ni2+ transfer (F) at 303 K in presence of 3% (v/v) octan-1-ol (de-emulsifier) can be represented as:.Depending on reaction parameters, the activation energy (Ea) and enthalpy change in activation (DH±) varies within 17 - 58 kJ/mol and 17 - 67 kJ/mol, respectively. Entropy change in activation (DS±) is always negative. Based on the empirical flux equation, Ea and DS± values, mechanisms of extractions in different parametric conditions are proposed. At low and [Ac-], and pH, the chemical controlled step is: Ni2+ + A- → NiA+; and this reaction occurs via an SN2 mechanism. But in most parametric conditions, the process is under intermediate control; and at high SO42- and [Ac-], and pH, the extraction process is under diffusion control.