TITLE:
Fabrication Parameter Optimization for a Multilayer Photovoltaic Cell Based on the Heterojunction: Zinc(II)-Meso-Tetrakis(4-Bromophenyl) Porphyrins/Fullerenes
AUTHORS:
Jorge H. Velez, M. Jesus Aguirre, P. P. Zamora, M. B. L. Cattin, M. Makha, J. C. Bernede
KEYWORDS:
Conducting Polymers; Phorphyrin Reactivity; Photovoltaic Yield; Anode Buffer Layer; CuI; MoO3
JOURNAL NAME:
Open Journal of Applied Sciences,
Vol.3 No.1,
March
29,
2013
ABSTRACT: The photoelectric properties of multilayer organic photovoltaic cells (OPV cells) were studied. The active organic layers consisted of a planar heterojunction between a layer of Meso-Tetrakis(4-BromoPhenyl) Zinc(II) Porphyrin (BrPhPZn) as electron donor (ED) and a layer fullerene molecules. The devices were fabricated in a high vacuum by thermal sublimation, a technique that allows multilayer devices realization easily by successive depositions, and it does not require solvents, achieving purer films with reproducible characteristics. Taking into account that the anodic contact, a key factor for cell efficiency, is favored by the inclusion of a thin anodic buffer layer (ABL), the effect on the yield after including one or two (ABL): MoO3 or MoO3-CuI layers was studied. The cell which has the best photovoltaic characteristics has a BrPhPZn (ED) thickness of only 12.5 nm. This small thickness is related with the low conductivity of this organic molecule. On the other hand, including a thin MoO3-CuI bilayer increased, such device’s efficiency in a 200%, with regard to a cell without ABL, getting for one cell ITO/MoO3-CuI/BrPhPZn/C60/Alq3/Al, with a 1.03% yield.