Article citationsMore>>

J. C. Wheeler and B. Widom, “Phase Transitions and Critical Points in a Model Three-Component System,” Journal of the American Chemical Society, Vol. 90, No. 12, 1968, pp. 3064-3071. doi:10.1021/ja01014a013

has been cited by the following article:

• TITLE: Potential Correlation between Spontaneous Emulsification and the Plait Point in the System Water/Benzene/Ethanol: A Phase Diagram Approach

  AUTHORS: Stig E. Friberg

  KEYWORDS: Emulsions; Spontaneous Emulsification; Phase Diagrams; Plait Point

  JOURNAL NAME: Soft, Vol.2 No.1, March 29, 2013

  ABSTRACT: The separation of phases after the stability composition at a plait point is exceeded has significant effect on the reactions during spontaneous emulsification, but experimental efforts to obtain accurate information are extremely difficult, because even the smallest scattering of the numbers has a large effect on the result. In the present contribution a model system was applied that closely mirrored experimental values and the mass ratio of the two phases could be calculated with high accuracy. Extrapolation of the ratio between phase masses towards the critical composition showed the two phase masses each close to 0.5, while a composition with a miniscule difference from this composition extrapolated to 1.0. The results showed spontaneous emulsification between solutions at the plait point and water to consist of two processes; an initial extremely fast reaction and a slower process between the aqueous phase formed in the primary emulsification and water.