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P.-O. Lowdin, “Quantum Theory of Many-Particle Systems I. Physical Interpretations by Means of Density Matrices, Natural Spin-Orbitals, and Convergence Problems in the Method of Configurational Interaction,” Physical Review, Vol. 97, No. 6, 1955, pp. 1474-1489. doi:10.1103/PhysRev.97.1474

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