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M. A. Ermakova, D. Y. Ermakov and G. G. Kuvshinov, “Effective Catalysts for Direct Cracking of Methane to Produce Hydrogen and Filamentous Carbon Part I. Nickel catalysts,” Applied Catalysisi A: General, Vol. 201, No. 1, 2000, pp. 61-70. doi:10.1016/S0926-860X(00)00433-6

has been cited by the following article:

• TITLE: Direct Preparation of Hydrogen and Carbon Nanotubes by Microwave Plasma Decomposition of Methane over Fe/Si Activated by Biased Hydrogen Plasma

  AUTHORS: Katsuya Konno, Kaoru Onoe, Yasuyuki Takiguchi, Tatsuaki Yamaguchi

  KEYWORDS: Hydrogen; Methane Decomposition; Carbon Nanotubes; Microwave Plasma; Methane; H2 Plasma Treatment

  JOURNAL NAME: Green and Sustainable Chemistry, Vol.3 No.1, February 26, 2013

  ABSTRACT: Methane was decomposed to hydrogen and carbon nanotubes (CNTs) by microwave plasma, using Fe/Si catalyst activated by biased (—150 V) hydrogen plasma for various treatment times. Upon exposure to biased hydrogen plasma, the catalyst surface becomes lumpy within 1 min, coheres between 5 and 10 min and forms particles after 20 min. The methane conversion increased up to 93% over the treatment time of 5 min. The hydrogen yield showed as similar tendency as the methane conversion and kept 83% at treatment time of 5 min. The treatment time up to 1 min increased the amount of deposited carbon, and after treatment time of 5 min it dropped; then again after treatment time of 20 min, it increased to reach a maximum value of 22 gc/gcat. Deposited carbon was found to be consisted of carbon nanotubes. It grew vertically on the catalyst surface and reached a maximum length of 30.7 nm after treatment time of 10 min. Multiple types of CNTs were present, and the CNT diameters decreased with increasing plasma treatment time.